The air cooler is an important equipment in the petroleum refining industry.Ammonium chloride(NH4 Cl)deposition-induced corrosion is one of its main failure forms.In this study,the ammonium salt crystallization temper...The air cooler is an important equipment in the petroleum refining industry.Ammonium chloride(NH4 Cl)deposition-induced corrosion is one of its main failure forms.In this study,the ammonium salt crystallization temperature is chosen as the key decision variable of NH4 Cl deposition-induced corrosion through in-depth mechanism research and experimental analysis.The functional link neural network(FLNN)is adopted as the basic algorithm for modeling because of its advantages in dealing with non-linear problems and its fast-computational ability.A hybrid FLNN attached to a small norm is built to improve the generalization performance of the model.Then,the trained model is used to predict the NH4 Cl salt crystallization temperature in the air cooler of a sour water stripper plant.Experimental results show the proposed improved FLNN algorithm can achieve better generalization performance than the PLS,the back propagation neural network,and the conventional FLNN models.展开更多
Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the r...Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.展开更多
ZrO2, CuO, Al2O3 and SiO2 mixed nanopowder was used to coat the head of sapphire single crystal fiber for improving the properties of high-temperature single crystal fiber sensor. The result indicates that the head co...ZrO2, CuO, Al2O3 and SiO2 mixed nanopowder was used to coat the head of sapphire single crystal fiber for improving the properties of high-temperature single crystal fiber sensor. The result indicates that the head coated with above mixed nanopowder shows better optical stability,shorter response time and higher thermal shock resistance, in comparison with the head coated with coarse-grained particles with the same chemical展开更多
Indium tin oxide(In_(2)O_(3)∶Sn)film is one of the most potential materials in the field of semiconductor industry.However,untreated In2O3∶Sn film has a low work function which can result in a high energy barrier th...Indium tin oxide(In_(2)O_(3)∶Sn)film is one of the most potential materials in the field of semiconductor industry.However,untreated In2O3∶Sn film has a low work function which can result in a high energy barrier that hinders the passage of carriers through the interface,thus leading to poor overall performance of directly prepared devices.In this study,crystalline transparent conductive In_(2)O_(3)∶Sn films were prepared by plasma exposure assisted magnetron sputtering under room temperature.Based on multiple testing methods,it can be found that the low temperature crystallization characteristics of In_(2)O_(3)∶Sn film were enhanced and the work function was effectively improved after Ar^(+)plasma exposure.The increase of the work function of In_(2)O_(3)∶Sn film was due to the increment of Sn⁃O bond on the surface brought by the transition from low oxidation state Sn^(2+)to high oxidation state Sn^(4+)under the action of high exposure.展开更多
A design of a slot bushing with a volumetric field has been developed, which allows to produce continuous fibers from melts with difficult processing characteristics in order to produce fibers with better operating ch...A design of a slot bushing with a volumetric field has been developed, which allows to produce continuous fibers from melts with difficult processing characteristics in order to produce fibers with better operating characteristics. The operability of the design was confirmed when solving two problems of special technological complexity. 1. 400 and 800 orifice bushings for production of continuous fibers from the basalt melt have been developed and recommended for manufacture. 2. The process of production of continuous fibers from standard glass using 2400 orifice bushing with perforated plates instead of orifice tips without air cooling, has been realized for the first time.展开更多
Titanium dioxide has been considered to be one of the most effective and environmental friendly photocatalytic material.It has been widely used in photocatalytic degradation of various pollutants.As we known,an anatas...Titanium dioxide has been considered to be one of the most effective and environmental friendly photocatalytic material.It has been widely used in photocatalytic degradation of various pollutants.As we known,an anatase crystal form typically obtained by high temperature heat treatment(>600℃),usually shows higher catalytic activity.In order to further improve the catalytic efficiency,we prepared TiO2 with a non-supercritical drying method to form a high specific surface area aerogel structure,along with an increased active contact site.However,with the inevitable of internal pores collapse in the process of high temperature crystallization,a large amount of porous structure and specific surface area is reduced.Here,to enhance the photocatalytic activity of titania,we propose a synergistic strategy to fabricate a porous titania structure with a high specific surface area.It was crystallized at a lower temperature(120℃) in a low-boiling solvent(ethanol,acetone,etc.).The lattice structure was identified by X-ray diffractometry;specific surface area(over 300 m2/g) of our sample was also measured through BET test;in the subsequent photocatalytic degradation test,the photocatalytic degradation efficiency of fabricated TiO2 is proved to be more excellent than P25 powder.By a freeze-drying/mild crystallization method,a high-specific surface area and high catalytic activity TiO2 aerogel was synthetized.This study provides some insights in the combining of crystallization and high specific surface area of titanium dioxide photocatalysis.展开更多
A liquid modified photonic crystal fiber(PCF)integrated with an embedded directional coupler and multi-mode interferometer is fabricated by infiltrating three adjacent air holes of the innermost layer with standard 1....A liquid modified photonic crystal fiber(PCF)integrated with an embedded directional coupler and multi-mode interferometer is fabricated by infiltrating three adjacent air holes of the innermost layer with standard 1.48 refractive index liquids.The refractive index of the filled liquid is higher than that of background silica,which can not only support the transmitting rod modes but also the"liquid modified core"modes propagating between the PCF core and the liquid rods.Hence,the light propagating in the liquid modified core can be efficiently coupled into the satellite waveguides under the phase-matching conditions,resulting in a dramatic decrease of the resonant wavelength intensity.Furthermore,there is a multi-mode interference produced by modified core modes and rod modes.Such a compact(~0.91 cm)device integrated with an embedded coupler and interferometer is demonstrated for high-sensitivity simultaneous temperature(~14.72 nm∕℃)and strain(~13.01 pm∕με)measurement.展开更多
Recently,the research team led by Prof.Chen Guang(陈光)at the Engineering Research Center of Materials Behavior and Design,Ministry of Education,Nanjing University of Science and Technology,successfully manufactured a...Recently,the research team led by Prof.Chen Guang(陈光)at the Engineering Research Center of Materials Behavior and Design,Ministry of Education,Nanjing University of Science and Technology,successfully manufactured a new kind of high-temperature polysynthetic twinned(PST)TiAl single展开更多
A patent pending open-loop liquid crystal based variable optical attenuator is introduced. The temperature dependent performance is compensated through electric monitoring and adjustment utilizing liquid crystal's...A patent pending open-loop liquid crystal based variable optical attenuator is introduced. The temperature dependent performance is compensated through electric monitoring and adjustment utilizing liquid crystal's opto-electronic properties.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51876194,U1909216)the China Petrochemical Corporation Research Project(318023-2)the Zhejiang Public Welfare Technology Research Project(LGG20F030007)。
文摘The air cooler is an important equipment in the petroleum refining industry.Ammonium chloride(NH4 Cl)deposition-induced corrosion is one of its main failure forms.In this study,the ammonium salt crystallization temperature is chosen as the key decision variable of NH4 Cl deposition-induced corrosion through in-depth mechanism research and experimental analysis.The functional link neural network(FLNN)is adopted as the basic algorithm for modeling because of its advantages in dealing with non-linear problems and its fast-computational ability.A hybrid FLNN attached to a small norm is built to improve the generalization performance of the model.Then,the trained model is used to predict the NH4 Cl salt crystallization temperature in the air cooler of a sour water stripper plant.Experimental results show the proposed improved FLNN algorithm can achieve better generalization performance than the PLS,the back propagation neural network,and the conventional FLNN models.
基金the financially support of the National Natural Science Foundation of China(12164051)the Joint Foundation of Provincial Science and Technology Department-Double First-class Construction of Yunnan University(2019FY003016)+4 种基金the Young Top Talent Project of Yunnan Province(YNWR-QNBJ-2018-229)the financially support by Yunnan Major Scientific and Technological Projects(202202AG050016)Advanced Analysis and Measurement Center of Yunnan University for the sample characterization service and the Postgraduate Research and Innovation Foundation of Yunnan University(2021Y036)the financially support of the National Natural Science Foundation of China(62064013)the Application Basic Research Project of Yunnan Province[2019FB130]。
文摘Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.
文摘ZrO2, CuO, Al2O3 and SiO2 mixed nanopowder was used to coat the head of sapphire single crystal fiber for improving the properties of high-temperature single crystal fiber sensor. The result indicates that the head coated with above mixed nanopowder shows better optical stability,shorter response time and higher thermal shock resistance, in comparison with the head coated with coarse-grained particles with the same chemical
基金Sponsored by the National Science Fund for Distinguished Young Scholars of China(Grant No.51625201).
文摘Indium tin oxide(In_(2)O_(3)∶Sn)film is one of the most potential materials in the field of semiconductor industry.However,untreated In2O3∶Sn film has a low work function which can result in a high energy barrier that hinders the passage of carriers through the interface,thus leading to poor overall performance of directly prepared devices.In this study,crystalline transparent conductive In_(2)O_(3)∶Sn films were prepared by plasma exposure assisted magnetron sputtering under room temperature.Based on multiple testing methods,it can be found that the low temperature crystallization characteristics of In_(2)O_(3)∶Sn film were enhanced and the work function was effectively improved after Ar^(+)plasma exposure.The increase of the work function of In_(2)O_(3)∶Sn film was due to the increment of Sn⁃O bond on the surface brought by the transition from low oxidation state Sn^(2+)to high oxidation state Sn^(4+)under the action of high exposure.
文摘A design of a slot bushing with a volumetric field has been developed, which allows to produce continuous fibers from melts with difficult processing characteristics in order to produce fibers with better operating characteristics. The operability of the design was confirmed when solving two problems of special technological complexity. 1. 400 and 800 orifice bushings for production of continuous fibers from the basalt melt have been developed and recommended for manufacture. 2. The process of production of continuous fibers from standard glass using 2400 orifice bushing with perforated plates instead of orifice tips without air cooling, has been realized for the first time.
基金supported by the National Construction Program of First-Class University and First-Class Discipline of Chinathe Project of Novel Aerogel Materials Supported by Superel Advanced Materials Technology Co.Ltd of China。
文摘Titanium dioxide has been considered to be one of the most effective and environmental friendly photocatalytic material.It has been widely used in photocatalytic degradation of various pollutants.As we known,an anatase crystal form typically obtained by high temperature heat treatment(>600℃),usually shows higher catalytic activity.In order to further improve the catalytic efficiency,we prepared TiO2 with a non-supercritical drying method to form a high specific surface area aerogel structure,along with an increased active contact site.However,with the inevitable of internal pores collapse in the process of high temperature crystallization,a large amount of porous structure and specific surface area is reduced.Here,to enhance the photocatalytic activity of titania,we propose a synergistic strategy to fabricate a porous titania structure with a high specific surface area.It was crystallized at a lower temperature(120℃) in a low-boiling solvent(ethanol,acetone,etc.).The lattice structure was identified by X-ray diffractometry;specific surface area(over 300 m2/g) of our sample was also measured through BET test;in the subsequent photocatalytic degradation test,the photocatalytic degradation efficiency of fabricated TiO2 is proved to be more excellent than P25 powder.By a freeze-drying/mild crystallization method,a high-specific surface area and high catalytic activity TiO2 aerogel was synthetized.This study provides some insights in the combining of crystallization and high specific surface area of titanium dioxide photocatalysis.
基金National Natural Science Foundation of China(NSFC)(61635007,61425007,61377090,61575128)Guangdong Science and Technology Department(2014A030308007,2014B050504010,2015B010105007,2015A030313541)+1 种基金Science and Technology Innovation Commission of Shenzhen(GJHZ20150313093755757,JCYJ20160520163134575,JCYJ20160427104925452)Pearl River Scholar Fellowships
文摘A liquid modified photonic crystal fiber(PCF)integrated with an embedded directional coupler and multi-mode interferometer is fabricated by infiltrating three adjacent air holes of the innermost layer with standard 1.48 refractive index liquids.The refractive index of the filled liquid is higher than that of background silica,which can not only support the transmitting rod modes but also the"liquid modified core"modes propagating between the PCF core and the liquid rods.Hence,the light propagating in the liquid modified core can be efficiently coupled into the satellite waveguides under the phase-matching conditions,resulting in a dramatic decrease of the resonant wavelength intensity.Furthermore,there is a multi-mode interference produced by modified core modes and rod modes.Such a compact(~0.91 cm)device integrated with an embedded coupler and interferometer is demonstrated for high-sensitivity simultaneous temperature(~14.72 nm∕℃)and strain(~13.01 pm∕με)measurement.
文摘Recently,the research team led by Prof.Chen Guang(陈光)at the Engineering Research Center of Materials Behavior and Design,Ministry of Education,Nanjing University of Science and Technology,successfully manufactured a new kind of high-temperature polysynthetic twinned(PST)TiAl single
文摘A patent pending open-loop liquid crystal based variable optical attenuator is introduced. The temperature dependent performance is compensated through electric monitoring and adjustment utilizing liquid crystal's opto-electronic properties.