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Mn-Cu复合催化过硫酸盐降解木质素类污染物的研究
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作者 安俊健 卢锦程 +1 位作者 汪珊珊 王鹏 《中国造纸》 北大核心 2025年第1期155-165,共11页
本研究以二氧化锰、硝酸铜和二甲基咪唑为原料,采用共沉淀法制备了MnO_(2)-Cu(mIM)2双金属复合催化剂,利用该催化剂活化过硫酸盐以降解木质素模型物香草酸。采用单因素法及响应面法研究催化剂制备和反应条件对催化剂催化活化效率的影响... 本研究以二氧化锰、硝酸铜和二甲基咪唑为原料,采用共沉淀法制备了MnO_(2)-Cu(mIM)2双金属复合催化剂,利用该催化剂活化过硫酸盐以降解木质素模型物香草酸。采用单因素法及响应面法研究催化剂制备和反应条件对催化剂催化活化效率的影响,进一步探讨了催化剂的催化机理。研究表明,在催化剂用量0.387 g/L、氧化剂初始浓度1.3 mmol/L、pH值为6.1的条件下,可以降解94.23%的香草酸;三维荧光检测表明,该催化剂可以有效催化氧化降解对造纸废水中污染物;电子顺磁共振表征表明,该降解体系中的主要反应活性物质是^(1)O_(2)、·OH和SO_(4)^(-)·,其中非自由基^(1)O_(2)起主要作用。 展开更多
关键词 过硫酸盐 Mn-cu双金属复合催化剂 木质素 造纸废水 降解
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菠菜叶对酸性高铜废水中Cu^(2+)生物吸附性研究
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作者 陈荣 张朝旭 《环境科学与技术》 北大核心 2025年第1期22-32,共11页
针对铜在矿物提取、金属加工、电镀及电子等行业产生大量强酸性高含铜废水这一问题,该文以菠菜叶为吸附剂,采用静态吸附法,考察了pH、温度、叶片完整性、Cu^(2+)初始质量浓度等因素对溶液中Cu^(2+)吸附性的影响,实验结果表明,在Cu^(2+)... 针对铜在矿物提取、金属加工、电镀及电子等行业产生大量强酸性高含铜废水这一问题,该文以菠菜叶为吸附剂,采用静态吸附法,考察了pH、温度、叶片完整性、Cu^(2+)初始质量浓度等因素对溶液中Cu^(2+)吸附性的影响,实验结果表明,在Cu^(2+)初始质量浓度为19 mg/mL、pH为1.7、反应温度为80℃、反应时间为7 h条件下,经裁剪的菠菜叶片对Cu^(2+)吸附量最大,为36 mg/g,Cu^(2+)的吸附过程符合准二级动力学模型与Freundlich吸附等温模型,说明吸附以非均质表面、物理吸附为主,菠菜叶对Cu^(2+)的吸附为自发、吸热和熵增加的过程,适用于强酸性高铜废水的直接治理,为农业产物在可持续发展概念中找到新的应用。 展开更多
关键词 菠菜叶 cu^(2+)吸附 吸附条件 吸附模型
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Ore-finding method of fault tectono-geochemistry in the Tongchang Cu-Au polymetallic orefield, Shaanxi, China:Ⅰ. Dynamics of tectonic ore-forming processes and prognosis of concealed ores 被引量:8
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作者 HAN Runsheng MA Deyun +1 位作者 WU Peng MA Gengsheng 《Chinese Journal Of Geochemistry》 EI CAS 2009年第4期397-404,共8页
Based on the research content and conception of dynamics of tectonic ore-forming processes, with the focus on the dynamics and processes of mineral source, ore formation, transport, accumulation, dissipation and miner... Based on the research content and conception of dynamics of tectonic ore-forming processes, with the focus on the dynamics and processes of mineral source, ore formation, transport, accumulation, dissipation and mineralization in response to magmatic invasion and metallogenic fluid under tectonic stress, this paper deals with the ore-finding method of fault tectono-geochemistry and its application on the basis of ore deposit genesis, "giant pressure shadow" structure and ore-finding method of tectonic stress field in the Tongchang orefield, expounds the rules of magmatic emplacement and ore fluid migration and concentration under the control of the structural stress field, hence providing the theoretical basis for the localization and prognosis of concealed ores. The fault tectono-geochemical features show that the Cu-Au polymetallic ore deposits (mineralization) in the orefield are closely related with volcano-(exhalation) sedimentation, magmatism and tectono-reworking. Fault tectono-geochemical anomalies can be applied to prognosis of metallogenetic target areas for ore exploration and can provide strong evidence of "giant pressure shadow" structure. In addition, quite a number of important target areas have been defined in combination with the characteristics of the tectonic stress field, and part of the target areas have been proved by practical activities. 展开更多
关键词 构造地球化学 多金属矿田 隐伏矿预测 构造方法 断层构造 成矿过程 铜金 找矿
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“Giant pressure shadow” structure and ore-finding method of tectonic stress field in the Tongchang Cu-Au polymetallic orefield,Shaanxi,China:Ⅱ.Dynamics of tectonic ore-forming processes and prognosis of concealed ores 被引量:5
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作者 HAN Runsheng WANG Lei +2 位作者 MA Deyun GU Xiaochun FAN Zhuguo 《Chinese Journal Of Geochemistry》 EI CAS 2010年第4期455-463,共9页
The Tongchang orefield is located in the central part of the Mianxian-Lueyang-Yangpingguan area that is celebrated as a 'gold triangle' area,at the juncture of the latitudinal tectonic zone of South Qinling,th... The Tongchang orefield is located in the central part of the Mianxian-Lueyang-Yangpingguan area that is celebrated as a 'gold triangle' area,at the juncture of the latitudinal tectonic zone of South Qinling,the Longmenshan Cathysian tectonic zone and the Sichuan-Yunnan longitudinal tectonic zone,where there are distributed Cu-Au polymetallic ore deposits(occurrences) including the Tongchang,Chenjiaba,Qinjiabian,Hongtushi,Yinshangou and Xiakouyi ore deposits(mineralization).Based on the "giant pressure shadow" structure put forward and demonstrated by numerical modeling of the tectonic stress field and the static photoelasticity experiments on the basis of tectonic ore-controlling laws in the orefield,tectonic metallogenesis driven by orefield tectonic stress has been discussed in terms of its geological setting,orefield geomechanics,and tectonic stress field.It is thought that the dynamic evolution model of the tectonic stress field controls the whole process of formation of the polymetallic ore deposits(mineralization) in the orefield,as well as the deformation field.As a result,it controls the emplacement of rockbodies and the transformation of ore-source bodies,and provides both the channel-ways for ore-forming fluids and ore-hosting space.Furthermore,it controls the migration potential field of fluids and,thereafter,its flow direction,rate and volume;the tectonic stress field also controls the energy field and hence controls the position of occurrence of ore deposits and their scale.The method of tectonic stress field has been applied to ore prognosis in the orefield.The rules of magmatic emplacement and metallogenic fluid migrating and concentrating under the control of the structural stress field were expounded,hence providing the theoretical basis for the prognosis of concealed ores.In addition,a number of important target areas have been defined. 展开更多
关键词 铜金多金属矿床 构造应力场 多金属矿田 成矿过程 找矿方法 影子 压力 结构
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Cu^(2+)掺杂提高BiOBr纳米结构的吸附性和光催化活性
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作者 胡月 房国丽 +3 位作者 田景 魏杰 严祥辉 张刚 《功能材料》 北大核心 2025年第1期1156-1163,1170,共9页
采用一步溶剂热合成法制备了xCu-BiOBr纳米结构,研究了掺杂浓度对xCu-BiOBr纳米结构的吸附性和光催化性能的影响。结果表明,Cu掺杂有利于获得形貌、尺寸均一的xCu-BiOBr纳米结构,而且掺杂后xCu-BiOBr纳米结构的比表面积增大,吸附性增强... 采用一步溶剂热合成法制备了xCu-BiOBr纳米结构,研究了掺杂浓度对xCu-BiOBr纳米结构的吸附性和光催化性能的影响。结果表明,Cu掺杂有利于获得形貌、尺寸均一的xCu-BiOBr纳米结构,而且掺杂后xCu-BiOBr纳米结构的比表面积增大,吸附性增强,尤其0.04Cu-BiOBr对Rh B的单层饱和吸附量为9.059 mg/g,是纯BiOBr吸附量的1.6倍。同时,Cu掺杂引入杂质能级,xCu-BiOBr的带隙随Cu掺杂浓度的增加逐渐红移。但是,0.02Cu-BiOBr在可见光下展现出最高的光催化活性;随Cu掺杂量的进一步增大,xCu-BiOBr的光催化活性降低。这是因为Cu掺杂主要形成置换型固溶体,并促使其周围形成氧空位缺陷;氧空位可以俘获光生电子,从而改变光生电子、空穴的迁移和复合历程。但是,过量Cu掺杂使晶格畸变程度增大,xCu-BiOBr可能会形成载流子复合中心,这不利于光生电子、空穴的迁移,因此过量掺杂可能导致xCu-BiOBr光催化活性的降低。 展开更多
关键词 xcu-BiOBr 溶剂热法 cu掺杂 吸附性 光催化活性
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EVOLUTION OF ORE-FORMING FLUIDS AND Ag-Cu POLYMETAL MINERALIZATION IN THE LANPING BASIN, YUNNAN 被引量:1
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作者 Wang C. S., Tang J. X., Gu X. X. 《地学前缘》 EI CAS CSCD 2000年第S1期409-409,共1页
The Lanping Mesozoic—Cenozoic sedimentary basin, situated in the Middle section of the “Sanjiang" (Nujiang—Lancangjiang—Jinshajiang) area in the east margin of the Tibet plateau, is well known for its large p... The Lanping Mesozoic—Cenozoic sedimentary basin, situated in the Middle section of the “Sanjiang" (Nujiang—Lancangjiang—Jinshajiang) area in the east margin of the Tibet plateau, is well known for its large production of base\|metal sulphide deposits. The worldwide famous super\|large Jinding Pb\|Zn deposit is located in the middle of the basin. The evolution history of the Lanping basin since Mesozoic can be divided into six stages, i.e., ①active continental marginal basin (T 1—T 2); ②back\|arc rift basin (T 3—J 1); ③intracontinental depressive basin (J 2—J 3); ④foreland basin (K); ⑤strike\|slipping and mutual thrusting (E 1—E 3); and ⑥strike\|slipping and pull\|apart basin (N 1\|present). Three main types of Ag\|Cu polymetal deposits are recognized in the basin. Deposits of sedimentary exhalation\|hydrothermal reworking origin (type Ⅰ) are hosted chiefly in limestones, dolomitic limestones, and siliceous rocks of the Upper Triassic Sanhedong Formation (T 3 s ) in Sanshan area. Deposits formed through normal chemical sedimentation in closed to semi\|closed environments (type Ⅱ; e.g., Jinman and Baiyangchang) during the depressive and foreland basin stages occur in various horizons of Jurassic and Cretaceous ages. Hydrothermal reworking on deposits of this type during the Himalayan period are locally pronounced, especially in the west margin of the basin near the Lancangjiang thrust fault. The third deposit type in the basin (type Ⅲ; e.g., Baiyangping and Fulongchang) is the Ag\|bearing tetrahedrite vein deposits occurring almost in all Mesozoic—Cenozoic strata, especially in the Cretaceous. Ore minerals formed during synsedimentary periods of types Ⅰ and Ⅱ are relatively simple and dominated by chalcopyrite and bornite, though sphalerite, galena, pyrite, tetrahedrite and pyrite are also present. In the deposits of type Ⅲ as well as in the ores formed during the hydrothermal reworking period in deposits of type Ⅰ and Ⅱ, ore minerals are extremely complicated and characterized by predominant Ag\|bearing tetrahedrite and other complex sulfosalts of Cu\|Ni\|Co\|Fe\|As\|S and Cu\|Bi\|S series. The associated gangue minerals are mainly quartz, siderite, Fe\|dolomite, barite, and celestite. 展开更多
关键词 BASIN FLUIDS polymetal MINERALIZATION BASIN evolut ion Lanping BASIN
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Cu掺杂及缺陷共存对ZnO光催化影响的理论研究
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作者 张海峰 赵晋忠 +1 位作者 伊思静 卢士香 《原子与分子物理学报》 CAS 北大核心 2025年第2期24-32,共9页
采用密度泛函理论研究了Cu掺杂及缺陷共存对ZnO光催化性能的影响.计算时考虑了富O和贫O两种掺杂条件.研究结果表明富O条件有利于Cu的掺杂,贫O条件则产生抑制作用.当Cu掺杂浓度较低时,不论在何种掺杂条件下,Cu的主要掺杂方式均为Cu_(Zn)... 采用密度泛函理论研究了Cu掺杂及缺陷共存对ZnO光催化性能的影响.计算时考虑了富O和贫O两种掺杂条件.研究结果表明富O条件有利于Cu的掺杂,贫O条件则产生抑制作用.当Cu掺杂浓度较低时,不论在何种掺杂条件下,Cu的主要掺杂方式均为Cu_(Zn)型.当Cu掺杂浓度较高时,富O条件下以Cu_(Zn)-Cu_(Zn)型掺杂方式为主,贫O条件下Cu_(Zn)-Cu_(Zn)和Cu_(Zn)-Cui这两种掺杂方式都有可能出现.富O条件下Cu掺杂会促进V_(Zn)和O_(i)缺陷的产生,且引入的V_(Zn)和O_(i)缺陷趋向于距离Cu原子最近.Cu掺杂可有效降低ZnO的带隙宽度,且随着掺杂浓度的增加,相应模型的带隙宽度会继续降低.V_(Zn)、O_(i)和V_(O)缺陷共存使相应模型的带隙宽度有所增加.Cu掺杂及V_(Zn)、O_(i)、V_(O)缺陷共存使模型对可见光发生响应,扩展了模型对太阳光的吸收范围.对于Cu掺杂模型,富O条件下Cu_(Zn)-Cu_(Zn)是有利的光催化模型.对于缺陷共存模型,富O条件下Cu_(Zn)-Cu_(Zn)-V_(Zn)是有利的光催化模型,其次是Cu_(Zn)-V_(Zn)和Cu_(Zn)-O_(i),贫O条件下Cu_(Zn)-V_(O)是有利的光催化模型. 展开更多
关键词 ZNO cu掺杂 缺陷共存 密度泛函理论 光催化
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ANALYSIS OF TECTONIC EVOLUTION AND MAJOR Cu (Au) POLYMETALLIC METALLOGENIC SERIES IN NORTHEAST JIANGXI PROVINCE 被引量:1
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作者 Li Peizheng Deng Guoping and Tao Hong (College of Resource, Environment and Civil Engineering, Central South University of Technology, Changsha 410083, China ) 《Geotectonica et Metallogenia》 1999年第2期166-172,共7页
Northeast Jiangxi Province is an important area in China with closely packed Cu (Au) polymetallic metallization. The tectonic action of this area is complex and violent, and three stages of geotectonic development of ... Northeast Jiangxi Province is an important area in China with closely packed Cu (Au) polymetallic metallization. The tectonic action of this area is complex and violent, and three stages of geotectonic development of the Earth’s crust have taken place there since the Jingning Movement.Every stage formed a distinctive ore-bearing formation, and the three stages formed three suits of Cu(Au) polymetallic metallogenic series with different features. They are the Proterozoic dynamometamorphic metallogenic series, the Paleozoic exhalation-sediment metallogenic series and the Meso-Cenozoic volcano-subvolcanic metallogenic series. 展开更多
关键词 Tectonic evolution ore-bearing formation cu polymetalLIC deposit METALLOGENIC series NORTHEAST Jiangxi Province
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经济制裁背景下上市公司“被退市”的应对策略研究——以Polymetal再上市为例
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作者 曹记峰 叶枝 《财务管理研究》 2024年第11期49-56,共8页
近年来,西方频繁使用经济制裁手段来处理国家间的政治分歧。尤其是在俄乌冲突爆发后,经济制裁成为西方对俄罗斯的重要制裁方式,导致众多在欧美国家上市的俄罗斯公司陷入退市困境。在这一背景下,对于被牵连的上市公司而言,如何有效应对... 近年来,西方频繁使用经济制裁手段来处理国家间的政治分歧。尤其是在俄乌冲突爆发后,经济制裁成为西方对俄罗斯的重要制裁方式,导致众多在欧美国家上市的俄罗斯公司陷入退市困境。在这一背景下,对于被牵连的上市公司而言,如何有效应对经济制裁显得尤为重要。对此进行深入的研究,不仅具有极高的现实意义,还能为类似企业提供宝贵的应对策略和指导。通过分析Polymetal被制裁后从伦敦证券交易所主动退市并转移再上市过程中的应对策略如董事会改组、资产重组、迁册以重新注册等,对比分析各种制裁应对策略。探讨如何保护企业价值和股东利益,以及对公司造成的财务影响,为类似的境外上市公司未来面临的潜在风险提供指导与启示。 展开更多
关键词 经济制裁 退市 再上市 polymetal
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PhC_(2)Cu/SrO异质结光催化降解双氯芬酸的机制研究
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作者 陈灵容 王奕舜 +4 位作者 张筱昱 刘德柱 陈平 吕文英 刘国光 《环境科学学报》 北大核心 2025年第1期123-134,共12页
药品和个人护理产品(PPCPs)因其对生态系统和人类健康的潜在威胁而广受关注.本研究提出一种新型的异质结改性思路,开发了苯乙炔铜/氧化锶(PhC_(2)Cu/SrO)异质结光催化剂并用于处理含双氯芬酸(DCF)污染废水.本研究构建的PhC_(2)Cu/SrO异... 药品和个人护理产品(PPCPs)因其对生态系统和人类健康的潜在威胁而广受关注.本研究提出一种新型的异质结改性思路,开发了苯乙炔铜/氧化锶(PhC_(2)Cu/SrO)异质结光催化剂并用于处理含双氯芬酸(DCF)污染废水.本研究构建的PhC_(2)Cu/SrO异质结中,SrO无需被光源激发,仅利用其强大的电子转移能力,便实现了PhC_(2)Cu光生电子的高效离域,进而能更高效地活化水体中的分子氧,这是高效去除废水中DCF的关键.同时,采用SEM、TEM、XRD、XPS及UV-vis DRS等方法对复合材料的形貌结构、元素分布及光学性质进行了表征.研究结果表明,构建的PhC_(2)Cu/SrO异质结具有拓宽的光响应范围和增强的载流子分离能力,掺杂比为10%的PhC_(2)Cu/SrO展现出高效的DCF光催化降解速率(0.0207 min^(-1)),达到了PhC_(2)Cu的2.62倍,表现出较好的光催化性能.此外,体系对环境中绝大多数典型的PPCPs均表现出较好的光催化活性.结合电子自旋共振测试、自由基捕获实验证实了·O_(2)^(-)和h^(+)是该体系的主要活性物种.研究显示,PhC_(2)Cu/SrO复合材料在水处理方面的应用具有一定的潜在优势. 展开更多
关键词 PhC_(2)cu DCF 电荷转移 分子氧活化
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W/Cu/S簇基超分子大环及其三阶非线性光学性质
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作者 黄志文 刘琦 郎建平 《无机化学学报》 北大核心 2025年第1期79-87,共9页
以前驱簇[Et_(4)N][Tp*WS_(3)(CuCl)_(3)]与三氟甲烷磺酸银(AgOTf)及3个有机桥联配体2,5‑二(吡啶‑4‑基)噻吩(L1)、5,5'‑双(4‑吡啶基)‑2,2'‑双噻吩(L_(2))和2,7‑双(4‑吡啶基)芘(L_(3))分别反应,得到了3个阳离子型W/Cu/S簇基超分... 以前驱簇[Et_(4)N][Tp*WS_(3)(CuCl)_(3)]与三氟甲烷磺酸银(AgOTf)及3个有机桥联配体2,5‑二(吡啶‑4‑基)噻吩(L1)、5,5'‑双(4‑吡啶基)‑2,2'‑双噻吩(L_(2))和2,7‑双(4‑吡啶基)芘(L_(3))分别反应,得到了3个阳离子型W/Cu/S簇基超分子大环化合物[(Tp*WS_(3)Cu_(3))_(2)(μ‑Cl)_(2)(μ_(4)‑Cl)(L_(1))]_(2)(OTf)_(2)(1)、[(Tp*WS_(3)Cu_(3))_(2)(μ‑Cl)_(2)(μ_(4)‑Cl)(L_(2))]_(2)(OTf)_(2)·2CHCl_(3)(2·2CHCl_(3))和[(Tp*WS_(3)Cu_(3))_(2)(μ‑Cl)_(2)(μ_(4)‑Cl)(L_(3))]_(2)(OTf)_(2)·2DMF(3·2DMF),其中Tp*=hydridotris(3,5‑dimethylpyrazol‑1‑yl)borate。对3个化合物分别进行了单晶X射线衍射、核磁、质谱、红外光谱、紫外可见光谱和元素分析等结构表征。单晶X射线衍射结果表明,3个大环的主体均是由2个L1、L_(2)和L_(3)配体和3个氯桥连接的[(Tp*WS_(3)Cu_(3))_(2)(μ‑Cl)_(2)(μ_(4)‑Cl)]^(2+)阳离子簇核组成。3个大环通过不同方式堆叠形成三维结构。核磁氢谱(^(1)H NMR)和电喷雾飞行质谱(ESI‑TOF MS)结果表明这些化合物在溶液中有较好的稳定性。Z扫描测试结果表明,3个化合物的溶液有一定的三阶非线性光学响应。 展开更多
关键词 W/cu/S簇 组装 超分子大环 结构 三阶非线性光学响应
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Geochronology and Geochemistry of the Mamupu Cu-Au Polymetallic Deposit,Eastern Tibet:Implications for Eocene Cu Metallogenesis in the Yulong Porphyry Copper Belt 被引量:4
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作者 ZHANG Xiaoxu LIN Bin +9 位作者 TANG Juxing HE Liang LIU Zhibo WANG Qin SHAO Rui DU Qiu SILANG Wangdui CIREN Ouzhu GUSANG Quzhen CIDAN Zhongga 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2022年第4期1221-1236,共16页
The Mamupu skarn-type Cu-Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt(YPCB),eastern Tibet.The Cu-Au mineralization mainly occurs as chalcopyrit... The Mamupu skarn-type Cu-Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt(YPCB),eastern Tibet.The Cu-Au mineralization mainly occurs as chalcopyrite in breccia,within the plate-like carbonate interlayer,being closely related to chloritization(e.g.,chlorite,magnetite and epidote)and skarnization(e.g.,diopside,tremolite and garnet).The ore-related quartz syenite porphyry(QSP)and granodiorite porphyry(GP)were emplaced at 40.1±0.2 Ma and 39.9±0.3 Ma,respectively.The QSP of Mamupu is an alkaline-rich intrusion,relatively enriched in LREE,LILE,depleted in HFSE,with no significant negative Eu and Ce anomalies,slightly high(^(87)Sr/^(86)Sr)i,lowε_(Nd)(t),uniform(^(206)Pb/^(204)Pb)i andε_(Hf)(t)values,which indicates that the porphyry magma may be caused by both the mixing of metasomatized EM II enriched mantle and thickened juvenile lower crust.The QSP in the Mamupu deposit shares a similar genesis of petrology to other ore-related porphyries within the YPCB.High oxygen fugacity and water content of the magmas are essential for the formation of porphyry and skarn Cu deposits.The QSP has similar high magmatic oxidation states and water content to the Yulong deposit,which indicates that the Mamupu has a high prospecting potential.Differences in the geological characteristics and scale of mineralization between the Mamupu and other YPCB deposits may be due to the different emplacement depths of ore-related intrusions,as well as differences in the surrounding rocks. 展开更多
关键词 skarn cu deposit GEOCHRONOLOGY GEOCHEMISTRY Mamupu Yulong porphyry copper belt Tibet
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^(40)Ar-^(39)Ar Dating of Quartz from Ore in the Baiyangping Cu-Co Polymetallic Ore-Concentrated Area, Lanping Basin, Yunnan
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作者 何明勤 刘家军 +4 位作者 李朝阳 李志明 刘玉平 杨爱平 桑海清 《Chinese Journal Of Geochemistry》 EI CAS 2004年第4期342-348,共7页
Ar- 39Ar fast neutron activation age spectrum of quartz in ore collected from the Baiyangping Cu-Co polymetallic ore-concentrated area, Lanping Basin, is saddle-shaped. The plateau age, minimum appearance age and isoc... Ar- 39Ar fast neutron activation age spectrum of quartz in ore collected from the Baiyangping Cu-Co polymetallic ore-concentrated area, Lanping Basin, is saddle-shaped. The plateau age, minimum appearance age and isochron age shown on the spectra are 56.53± 0.43 Ma, 55.52± 1.78 Ma and 55.90± 0.29 Ma respectively. The age data are consistent with each other within 1σ uncertainties. Because the given initial 40Ar/ 36Ar value of 294.7± 1.14 is very close to Nier’s value ( 295.5±5), both plateau and isochron ages may be considered as the forming time of quartz. So the age of 55.90- 56.53 Ma represents the forming age of ore deposits. It is obvious that the ore deposits were formed during the Early Himalayan period. 展开更多
关键词 年龄测定 喜玛拉雅早期运动 铜-钴多金属矿集中地区 云南西部
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Al‑Zn‑Mg‑Cu系铝合金性能优化研究现状及发展趋势
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作者 周莲 李发国 张佼 《现代交通与冶金材料》 2025年第1期94-108,122,共16页
Al⁃Zn⁃Mg⁃Cu系铝合金作为一种轻质高强结构材料,兼具优异的耐腐蚀能力和热加工性能,在航空工业中占据重要地位。热处理一直是Al⁃Zn⁃Mg⁃Cu系铝合金的研究重点,对提升合金强度、韧性和腐蚀性能的优化匹配发挥着巨大作用。新的制备技术能... Al⁃Zn⁃Mg⁃Cu系铝合金作为一种轻质高强结构材料,兼具优异的耐腐蚀能力和热加工性能,在航空工业中占据重要地位。热处理一直是Al⁃Zn⁃Mg⁃Cu系铝合金的研究重点,对提升合金强度、韧性和腐蚀性能的优化匹配发挥着巨大作用。新的制备技术能够突破传统合金化和热处理的局限,为提升Al⁃Zn⁃Mg⁃Cu系铝合金的综合性能提供新的路径,计算材料学的发展,进一步推动了合金的成分设计和工艺优化。本文介绍了热处理、增材制造技术及计算材料学对Al⁃Zn⁃Mg⁃Cu系铝合金组织和性能的影响,并对未来研究方向进行了展望。 展开更多
关键词 Al⁃Zn⁃Mg⁃cu 热处理 增材制造 计算材料学 性能优化
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硫化纳米零价铁复合材料对Cu(Ⅱ)去除性能的研究
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作者 丁亚荣 李灿华 +5 位作者 章蓝月 李家茂 何川 李明晖 朱伟长 韦书贤 《材料导报》 北大核心 2025年第2期35-42,共8页
硫化纳米零价铁(S-nZVI)及其复合材料以去除重金属的优异性能而著称,但较高的制备成本极大限制了S-nZVI的发展及应用。本工作以Na_(2)S_(2)O_(4)为单一还原剂,通过流变相反应制备S-nZVI@Ma纳米复合材料,采用SEM、TEM、EDS、XPS、XRD、F... 硫化纳米零价铁(S-nZVI)及其复合材料以去除重金属的优异性能而著称,但较高的制备成本极大限制了S-nZVI的发展及应用。本工作以Na_(2)S_(2)O_(4)为单一还原剂,通过流变相反应制备S-nZVI@Ma纳米复合材料,采用SEM、TEM、EDS、XPS、XRD、FTIR、VSM等手段对S-nZVI@Ma进行了表征,研究了S-nZVI@Ma对模拟废水中Cu(Ⅱ)的去除效果。结果表明,S-nZVI@Ma能够高效地去除模拟废液中99%以上的Cu(Ⅱ),并可利用外置磁铁将其从模拟废液中分离出来。经过五次重复利用后,S-nZVI@Ma对Cu(Ⅱ)的去除率仍保持在75%以上,表明该材料具有良好的磁回收利用性能。Cu(Ⅱ)的去除过程符合准二级动力学模型和Langmuir等温吸附模型,最大容量(qmax)为71.43 mg·g^(-1),热力学研究表明了去除过程的自发性和吸热性。利用FESEM-EDS、XRD、XPS、FTIR等手段对反应物进行表征,从电子转移的角度讨论了反应机理。以上研究可为S-nZVI的实际应用提供参考。 展开更多
关键词 硫化纳米零价铁 连二亚硫酸钠 含铜废水 吸附
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The Characteristics of Ore-Controlling Structure in Baoshan Cu-Pb-Zn Polymetallic Deposit,Hunan Province 被引量:3
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作者 QI Fan-yu1,ZHANG Zhi1,2,LI Yong-sheng1,ZHEN Shi-min1,JIA De-long1,GONG Fan-ying1,GONG Xiao-dong1,HE Peng1(1.School of Earth & Resources,China University of Geosciences Beijing,Beijing 100083,China 2.Development and Research Center,Beijing 100037 China) 《矿物学报》 CAS CSCD 北大核心 2011年第S1期823-824,共2页
The Baoshan Cu-Pb-Zn polymetallic deposit is lied in the central Nanling mineralization zone,and belongs to the junction area of the Chenzhou-Linwu fault zone and the Leiyang-Linwu fault zone.It is a significant part ... The Baoshan Cu-Pb-Zn polymetallic deposit is lied in the central Nanling mineralization zone,and belongs to the junction area of the Chenzhou-Linwu fault zone and the Leiyang-Linwu fault zone.It is a significant part of Nanling polymetallic deposit belt.The outcropping stratas consist of upper Devonian Shetianqiao,Xikuangshan Formation,Lower Carboniferous Menggong’ao,Shidengzi,Ceshui,and Zimenqiao Formation.Igneous rocks in the Baoshan ore area mainly comprise granodiorite porphyry.Furthermore,the radio isotopic age ranges from 123 Ma to 183 Ma,belonging to the early to middle Yanshanian. 展开更多
关键词 PB The Characteristics of Ore-Controlling Structure in Baoshan cu-Pb-Zn polymetallic Deposit Hunan Province ZN cu
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哈萨克斯坦努尔卡斯甘Cu-Au矿床成矿岩体矿物学和地球化学特征及其成矿意义
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作者 梁文静 黄杰 +3 位作者 吴丹 王居里 SEITMURATOVA Eleonora 安芳 《地球化学》 北大核心 2025年第1期24-38,共15页
努尔卡斯甘斑岩型Cu-Au矿床位于哈萨克斯坦东北部,已探明Cu和Au资源量分别为393万吨和229吨。与成矿有关岩体为花岗闪长玢岩和石英闪长玢岩,由石英、斜长石和角闪石组成。石英闪长玢岩中的斜长石主要为中长石,基质中的角闪石以镁质普通... 努尔卡斯甘斑岩型Cu-Au矿床位于哈萨克斯坦东北部,已探明Cu和Au资源量分别为393万吨和229吨。与成矿有关岩体为花岗闪长玢岩和石英闪长玢岩,由石英、斜长石和角闪石组成。石英闪长玢岩中的斜长石主要为中长石,基质中的角闪石以镁质普通角闪石为主。主量元素组成显示,与成矿有关岩体的成分类似于闪长岩-花岗闪长岩,与岩石学观察结果相符,岩石属高钾钙碱性系列,表现出Rb、Th、Ba、U等大离子亲石元素和轻稀土元素富集、而Nb、Ta等高场强元素亏损的特征,Sr/Y和La/Yb值与正常岛弧岩石相似。矿石中与黄铜矿伴生的辉钼矿样品的Re-Os同位素模式年龄为433±4 Ma,与前人报道的成矿岩体年龄(440~437 Ma)接近。结合前人研究成果,推断努尔卡斯甘斑岩型Cu-Au矿床是早志留世巴尔喀什-准噶尔洋壳向西北方向俯冲过程中岩浆-热液成矿作用的产物。根据与成矿有关石英闪长玢岩基质中角闪石成分确定成矿岩浆晚期温度为704~769℃,氧逸度为logfO_(2)=-13.5~-12.1、ΔFMQ=3.1~3.6,水含量为0.1%~1.9%,压力为20~250 MPa,指示基质中角闪石在岩浆侵位至0.70~7.63 km内发生结晶作用。努尔卡斯甘与成矿有关的岩浆体系具有高氧逸度和水含量,类似的岩浆环境十分有利于斑岩型矿床的形成。 展开更多
关键词 矿物学 地球化学 岩浆性质 斑岩型cu-Au矿床 努尔卡斯甘
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CuBi@Cu⁃MOF复合材料电催化CO_(2)还原至HCOOH的性能
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作者 王芳芳 陈佳琪 孙为银 《无机化学学报》 北大核心 2025年第1期97-104,共8页
通过直接搅拌法制备了2种CuBi双钙钛矿材料修饰的Cu金属有机骨架(CuBi@Cu‑MOF),并系统评估了2种材料作为电催化剂在碱性体系中对CO_(2)还原反应产物的选择性和法拉第效率(FE)。结果表明,表面改性后的CuBi@Cu‑MOF催化剂表现出明显提升的H... 通过直接搅拌法制备了2种CuBi双钙钛矿材料修饰的Cu金属有机骨架(CuBi@Cu‑MOF),并系统评估了2种材料作为电催化剂在碱性体系中对CO_(2)还原反应产物的选择性和法拉第效率(FE)。结果表明,表面改性后的CuBi@Cu‑MOF催化剂表现出明显提升的HCOOH选择性,其对应的最高FE可达56%,优于Cu‑MOF催化剂本身的FE(15%)。研究结果显示,表面改性降低了电荷转移阻力,增加了活性位点数量,从而提高了电催化活性。 展开更多
关键词 cu金属有机骨架 cuBi双钙钛矿 电催化 CO_(2)还原
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改性Fe_(3)O_(4)@MIL-100(Fe)对Cu(Ⅱ)的吸附研究
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作者 石小雪 董季玲 +3 位作者 钟晨晨 杨灵医 蒋伟 钟国媛 《功能材料》 北大核心 2025年第1期1088-1098,共11页
传统液相吸附材料在吸附Cu(Ⅱ)时存在吸附性能差、难分离回收等问题,而金属有机框架(MOF)在重金属离子吸附领域极具发展潜力。基于此,研究通过经济环保低能耗的室温水相法以Fe_(3)O_(4)为核制备Fe_(3)O_(4)@MIL-100(Fe)磁性材料,通过合... 传统液相吸附材料在吸附Cu(Ⅱ)时存在吸附性能差、难分离回收等问题,而金属有机框架(MOF)在重金属离子吸附领域极具发展潜力。基于此,研究通过经济环保低能耗的室温水相法以Fe_(3)O_(4)为核制备Fe_(3)O_(4)@MIL-100(Fe)磁性材料,通过合成后修饰的方法改性得到NH2-Fe_(3)O_(4)@MIL-100(Fe),采用XRD、FT-IR、SEM、TEM、VSM和EA等对改性前后材料进行表征,探究pH、时间、浓度、温度对改性前后材料吸附Cu(Ⅱ)性能的影响。结果表明,由于NH2-Fe_(3)O_(4)@MIL-100(Fe)与Cu(Ⅱ)之间的配位和静电作用,其对Cu(Ⅱ)的吸附容量(46.77 mg/g)显著高于改性前。改性前后材料对Cu(Ⅱ)的吸附均符合伪二级动力学模型和Freundlich吸附模型;热力学研究表明,改性后材料对Cu(Ⅱ)的吸附为自发吸热过程,而改性前为自发放热过程。此外,经过5次吸附-解吸循环后,NH2-Fe_(3)O_(4)@MIL-100(Fe)对Cu(Ⅱ)的吸附容量仍略高于Fe_(3)O_(4)@MIL-100(Fe)。 展开更多
关键词 Fe_(3)O_(4)@MIL-100(Fe) 己二胺 改性 吸附 cu(Ⅱ)
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Sulfur Isotopes Geochemistry of the Nage Cu-Pb Polymetallic Deposit,Southeast Guizhou Province,China 被引量:1
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作者 LONG Xuan-lin1,ZHOU Jia-xi2,HUANG Zhi-long2,WANG Jing-song1,YANG De-zhi1,3,FAN Liang-wu2,BAO Guang-ping2,LIU Yong-kun1(1. The 102 Geological Team,Guizhou Bureau of Exploration and Development of Geology and Mineral Resources,Zunyi 563003,China 2. State key Laboratory of Ore Deposits Geochemistry,Institute of Geochemistry,Chinese Academy of Science,Guiyang 550002,China 3. China University of Geosciences(Wuhan) ,Wuhan 430074,China) evidence. 《矿物学报》 CAS CSCD 北大核心 2009年第S1期128-128,共1页
The Nage Cu-Pb polymetallic deposit is located in the transitional zone of the Yangtze craton and cathaysia,that is the southwest of Jiangnan orogenic belt. The mainly strata are Wentong formation of Mesoproterozoic S... The Nage Cu-Pb polymetallic deposit is located in the transitional zone of the Yangtze craton and cathaysia,that is the southwest of Jiangnan orogenic belt. The mainly strata are Wentong formation of Mesoproterozoic Sibo group and the Jialu formation(Qbj) ,Wuye formation(Qbw) ,Fanzhao formation(Qbf) and Gongdong formation(Qbg) of the Neoproterozoic Qingbaikou System Xiajiang group. 展开更多
关键词 PB Sulfur Isotopes Geochemistry of the Nage cu-Pb polymetallic Deposit Southeast Guizhou Province China cu
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