Energetic materials pose challenges in preparation and handling due to their contradictory properties of high-energy and low-sensitivity.The emergence of co-crystal explosives is a new opportunity to change this situa...Energetic materials pose challenges in preparation and handling due to their contradictory properties of high-energy and low-sensitivity.The emergence of co-crystal explosives is a new opportunity to change this situation.If the co-crystal explosive is coated into spherical particles with uniform particle size distribution,this contradiction can be further reduced.Therefore,binder-coated hexanitrohexaazaisowurtzitane/2,4,6-trinitrotoluene(CL-20/TNT)co-crystal microspheres were prepared by droplet microfluidic technology in this work.The coating effects of different binder formulations of nitrocellulose(NC)and NC/fluorine rubber(F2604)on the co-crystal spheres were studied.The scanning electron microscopy(SEM)results showed that the use of droplet microfluidic technology with the above binders can provide co-crystal microspheres with regular spherical morphology,uniform particle size distribution and good dispersion.X-ray diffraction(XRD),fourier-transform infrared(FT-IR),differential scanning calorimetry(DSC)and thermo-gravimetric(TG)methods were employed to compare the properties of the co-crystal microspheres,raw material and pure co-crystal.The formation of CL-20/TNT co-crystal in the microspheres was confirmed,and the co-crystal microspheres exhibited better thermal stability than the raw material and pure co-crystal.In addition,the mechanical sensitivity and combustion performance of the co-crystal microspheres were further studied.The results showed that the co-crystal microspheres were more insensitive than CL-20 and pure co-crystal,and displayed excellent self-sustained combustion performance and theoretical detonation performance.This study provides a new method for the fast,simple and one-step preparation of CL-20/TNT co-crystal microspheres,with binder coating,uniform particle size distribution,and excellent performance level.展开更多
Thermal sprayed Ni-20wt. % Al coating is fabricated on 6061-T6 aluminum alloy substrates by twin-wire arc spraying （TWAS）. Experimental results present that the average bonding strength is around 53 MPa and the aver...Thermal sprayed Ni-20wt. % Al coating is fabricated on 6061-T6 aluminum alloy substrates by twin-wire arc spraying （TWAS）. Experimental results present that the average bonding strength is around 53 MPa and the average hardness reaches 325 HV. The Vickers microhardness of NiAl and Ni3Al intermetaUic compounds is larger than that of the substrate, which is beneficial for improving the wear property. Wear mechanism exhibits features of adhesive wear. Friction and wear test results indicate that the wet friction coefficient is higher than the coefficient of dry friction after 200 cycles, and variations of the wet friction coefficient are relatively smaller.展开更多
The ground surface quality of Cr 2O 3 coatings is investigated in this paper. The influence of some typical grinding parameters on ground surface integrity is discussed in detail. It is found that the ground surface r...The ground surface quality of Cr 2O 3 coatings is investigated in this paper. The influence of some typical grinding parameters on ground surface integrity is discussed in detail. It is found that the ground surface roughness increases with the increase of depth-of-cut. The surface finish is improved as the increase of grinding speed, but too high grinding speed may result in serious vibration of the system. The increase of workpiece speed causes deterioration of surface finish and produces big grinding noise. Experiments on plateau treatment after the rough ground surface were also carried out. The surface profile of the ground surface after plateau treatment becomes much smoother than the former rough surface. Some sharp peaks on the ground surface may be effectively removed by the plateau treatment, which produces a reasonable surface profile and can stand much more load. Surface observations and analyses show that plastic deformation and micro-cracks occur on the ground surface. The material removal process is primarily a serious of localized surface fractures accompanied by multi-plastic deformations. Much more plastic deformation and micro-cracks emerge on the ground surface when the depth-of-cut increases. The increase of workpiece speed may produce more surface micro-cracks, but the relative increase of grinding speed is beneficial to ground surface quality.展开更多
基金National Natural Science Foundation of China(Grant No.22005275)to provide fund for conducting experiments。
文摘Energetic materials pose challenges in preparation and handling due to their contradictory properties of high-energy and low-sensitivity.The emergence of co-crystal explosives is a new opportunity to change this situation.If the co-crystal explosive is coated into spherical particles with uniform particle size distribution,this contradiction can be further reduced.Therefore,binder-coated hexanitrohexaazaisowurtzitane/2,4,6-trinitrotoluene(CL-20/TNT)co-crystal microspheres were prepared by droplet microfluidic technology in this work.The coating effects of different binder formulations of nitrocellulose(NC)and NC/fluorine rubber(F2604)on the co-crystal spheres were studied.The scanning electron microscopy(SEM)results showed that the use of droplet microfluidic technology with the above binders can provide co-crystal microspheres with regular spherical morphology,uniform particle size distribution and good dispersion.X-ray diffraction(XRD),fourier-transform infrared(FT-IR),differential scanning calorimetry(DSC)and thermo-gravimetric(TG)methods were employed to compare the properties of the co-crystal microspheres,raw material and pure co-crystal.The formation of CL-20/TNT co-crystal in the microspheres was confirmed,and the co-crystal microspheres exhibited better thermal stability than the raw material and pure co-crystal.In addition,the mechanical sensitivity and combustion performance of the co-crystal microspheres were further studied.The results showed that the co-crystal microspheres were more insensitive than CL-20 and pure co-crystal,and displayed excellent self-sustained combustion performance and theoretical detonation performance.This study provides a new method for the fast,simple and one-step preparation of CL-20/TNT co-crystal microspheres,with binder coating,uniform particle size distribution,and excellent performance level.
文摘Thermal sprayed Ni-20wt. % Al coating is fabricated on 6061-T6 aluminum alloy substrates by twin-wire arc spraying （TWAS）. Experimental results present that the average bonding strength is around 53 MPa and the average hardness reaches 325 HV. The Vickers microhardness of NiAl and Ni3Al intermetaUic compounds is larger than that of the substrate, which is beneficial for improving the wear property. Wear mechanism exhibits features of adhesive wear. Friction and wear test results indicate that the wet friction coefficient is higher than the coefficient of dry friction after 200 cycles, and variations of the wet friction coefficient are relatively smaller.
文摘The ground surface quality of Cr 2O 3 coatings is investigated in this paper. The influence of some typical grinding parameters on ground surface integrity is discussed in detail. It is found that the ground surface roughness increases with the increase of depth-of-cut. The surface finish is improved as the increase of grinding speed, but too high grinding speed may result in serious vibration of the system. The increase of workpiece speed causes deterioration of surface finish and produces big grinding noise. Experiments on plateau treatment after the rough ground surface were also carried out. The surface profile of the ground surface after plateau treatment becomes much smoother than the former rough surface. Some sharp peaks on the ground surface may be effectively removed by the plateau treatment, which produces a reasonable surface profile and can stand much more load. Surface observations and analyses show that plastic deformation and micro-cracks occur on the ground surface. The material removal process is primarily a serious of localized surface fractures accompanied by multi-plastic deformations. Much more plastic deformation and micro-cracks emerge on the ground surface when the depth-of-cut increases. The increase of workpiece speed may produce more surface micro-cracks, but the relative increase of grinding speed is beneficial to ground surface quality.
