Abstract--Vapor compression refrigeration cycle (VCC) system is a high dimensional coupling thermodynamic system for which the controller design is a great challenge. In this paper, a model predictive control based ...Abstract--Vapor compression refrigeration cycle (VCC) system is a high dimensional coupling thermodynamic system for which the controller design is a great challenge. In this paper, a model predictive control based energy efficient control strategy which aims at maximizing the system efficiency is proposed. Firstly, according to the mass and energy conservation law, an analysis on the nonlinear relationship between superheat and cooling load is carried out, which can produce the maximal effect on the system performance. Then a model predictive control (MPC) based controller is developed for tracking the calculated setting curve of superheat degree and pressure difference based on model identified from data which can be obtained from an experimental rig. The proposed control strategy maximizes the coefficient of performance (COP) which depends on operating conditions, in the meantime, it meets the changing demands of cooling capacity. The effectiveness of the control performance is validated on the experimental rig. Index Terms--Cooling load, model predictive control (MPC), superheat, vapor compression refrigeration cycle (VCC).展开更多
According to the problem that the selection of traditional PID control parameters is too complicated in evaporator of Organic Rankine Cycle system(ORC),an evaporator PID controller based on BP neural netw ork optimiza...According to the problem that the selection of traditional PID control parameters is too complicated in evaporator of Organic Rankine Cycle system(ORC),an evaporator PID controller based on BP neural netw ork optimization is designed. Based on the control theory,the model of ORC evaporator is set up. The BP algorithm is used to control the Kp,Kiand Kdparameters of the evaporator PID controller,so that the evaporator temperature can reach the optimal state quickly and steadily. The M ATLAB softw are is used to simulate the traditional PID controller and the BP neural netw ork PID controller. The experimental results show that the Kp,Kiand Kdparameters of the BP neural netw ork PID controller are 0. 5677,0. 2970,and 0. 1353,respectively.Therefore,the evaporator PID controller based on BP neural netw ork optimization not only satisfies the requirements of the system performance,but also has better control parameters than the traditional PID controller.展开更多
The use of nanorefrigerants in Organic Rankine Cycle(ORC)units is believed to affect the cycle environment performance,but backed with very few relevant studies.For this purpose,a life cycle assessment(LCA)has been pe...The use of nanorefrigerants in Organic Rankine Cycle(ORC)units is believed to affect the cycle environment performance,but backed with very few relevant studies.For this purpose,a life cycle assessment(LCA)has been performed for the ORC system using nanorefrigerant,the material and energy input,characteristic indicators and comprehensive index of environmental impact,total energy consumption and energy payback time(BPBT)of the whole life cycle of ORC system using Al_(2)O_(3)/R141b nanorefrigerant were calculated.Total environmental comprehensive indexes reveal that ECER-135 index decrease by 1.5%after adding 0.2%Al_(2)O_(3)nanoparticles to R141b.Based on the contribution analysis and sensitivity analysis,it can be found out ORC system manufacturing is of the most critical stage,where,the ECER-135 index of ORC component production is the greatest,followed by the preparation process of R141b,transportation phase,and that of Al_(2)O_(3)nanoparticles preparation is small.The retirement phase which has good environmental benefits affects the result significantly by recycling important materials.Meanwhile,the main cause and relevant suggestion for improvement were traced respectively.Finally,the environmental impacts of various power generations were compared,and results show that the power route is of obvious advantage.Among the renewable energy,ORC system using Al_(2)O_(3)/R141b nanorefrigerant with minimal environmental impact is only 0.67%of coal-fired power generation.The environmental impact of current work is about 14.34%of other nations’PV results.展开更多
A comparison on subcritical and transcritical organic Rankine cycle(ORC) system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of ...A comparison on subcritical and transcritical organic Rankine cycle(ORC) system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of the heat transfer coefficient(U) and the total heat exchange area(A)(UA values) were calculated for parametric optimization. Nine candidate working fluids were investigated and compared. Under the given conditions, transcritical systems have higher net power outputs than subcritical ones. The highest net power output of transcritical systems is 18.63 k W obtained by R218, and that of subcritical systems is 13.57 k W obtained by R600 a. Moreover, with the increase of evaporating pressure, the thermal and exergy efficiencies of transcritical systems increase at first and then decrease, but the efficiencies of subcritical ones increase. As a result, the efficiencies of transcritical systems cannot always outperform those of the subcritical ones. However, the subcritical systems have lower minimum UA values and lower expansion ratios than the transcritical ones at the maximum net power output. In addition, the transcritical cycles have higher expansion ratios than the subcritical ones at their maximum net power output.展开更多
A dedicated heat exchanger model is introduced for the optimization of heavy-duty diesel engines.The model is a prerequisite for the execution of CFD simulations,which are used to improve waste heat recovery in these ...A dedicated heat exchanger model is introduced for the optimization of heavy-duty diesel engines.The model is a prerequisite for the execution of CFD simulations,which are used to improve waste heat recovery in these systems.Several optimization methods coupled with different types of working fluids are compared in terms of exergy efficiency and heat exchanger complicity.The three considered optimization methods all lead to significant improvements in the R245fa and R1233zd systems with a comparatively low evaporation temperature.The optimal R245fa system has the highest efficiency increase(77.49%).The cyclopentane system displays the highest efficiency among the optimized ORC(Organic Rankine Cycle)systems,yet achieved by using a much heavier evaporator HEC(Heat Exchanging Core).In contrast,the 96.84%efficiency increase for the optimized R1233zd is achieved with only 68.96%evaporator weight.展开更多
A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the mol...A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability.展开更多
Dissolved carbon(dissolved organic carbon and dissolved inorganic carbon)is the major component of the ocean carbon cycle,representing one of the largest carbon pools on Earth.Cold seeps and hydrothermal systems serve...Dissolved carbon(dissolved organic carbon and dissolved inorganic carbon)is the major component of the ocean carbon cycle,representing one of the largest carbon pools on Earth.Cold seeps and hydrothermal systems serve as the two main windows for the material and energy recycling exchange between the lithosphere and outer spheres(biosphere,hydrosphere and atmosphere).However,recent studies have found that the dynamic activities of fluids in these two extreme systems are a crucial source of‘new'carbon in the deep ocean.These carbon sources may become vital contributors to carbon and energy in marine ecosystems,which affect the global deep-sea carbon budget,and the marine ecosystems as well.In this review,we summarize the sources and formation mechanisms of dissolved carbon in the seep fluids from the cold seeps and hydrothermal vents,the contribution of methane oxidation to dissolved carbon,and the characteristics of the carbon isotope composition in the fluid.Furthermore,we analyze and discuss the influence of carbon discharged from seabed on the seawater carbon cycle by comparing and contrasting these two extreme environments.The research may assist in promoting a deeper understanding of the carbon cycle and material interaction in the ocean,particularly further carbon cycle research in the back-arc basin where cold seeps and hydrothermal vents commonly prevail.展开更多
This paper explores the existence of heteroclinic cycles and corresponding chaotic dynamics in a class of 3-dimensional two-zone piecewise affine systems. Moreover, the heteroclinic cycles connect two saddle foci and ...This paper explores the existence of heteroclinic cycles and corresponding chaotic dynamics in a class of 3-dimensional two-zone piecewise affine systems. Moreover, the heteroclinic cycles connect two saddle foci and intersect the switching manifold at two points and the switching manifold is composed of two perpendicular planes.展开更多
Nitrogen is one of the most important elements that can limit plant growth in forest ecosystems. Studies of nitrogen mineralization, nitrogen saturation and nitrogen cycle in forest ecosystems is very necessary for un...Nitrogen is one of the most important elements that can limit plant growth in forest ecosystems. Studies of nitrogen mineralization, nitrogen saturation and nitrogen cycle in forest ecosystems is very necessary for understanding the productivity of stand, nutrient cycle and turnover of nitrogen of forest ecosystems. Based on comparison and analysis of domestic and in-ternational academic references related to studies on nitrogen mineralization, nitrogen saturation and nitrogen cycle in recent 10 years, the current situation and development of the study on these aspects, and the problems existed in current researches were reviewed. At last, some advices were given for future researches.展开更多
The Rankine cycle system for waste heat recovery of heavy-duty vehicle diesel engines has been regarded as a promising tech- nique to reduce fuel consumption. Its heat dissipation in the condensation process, however,...The Rankine cycle system for waste heat recovery of heavy-duty vehicle diesel engines has been regarded as a promising tech- nique to reduce fuel consumption. Its heat dissipation in the condensation process, however, should be take:l away in time, which is an energy-consuming process. A fan-assisted auxiliary water-cooling system is employed in this paper. Results at 1300 r/min and 50% load indicate that the cooling pump and cooling fan together consume 7.66% of the recovered power. What's worse for the heavy load, cooling accessories may deplete of all the recovered power of the Rankine cycle system. Af- terwards, effects of the condensing pressure and water feeding temperature are investigated, based on which a cooling power consumption model is established. Finally, an overall efficiency optimization is conducted to balance the electric power gener- ation and cooling power consumption, taking condensing pressure, pressure ratio and exhaust bypass valve as major variables. The research suggests that the priority is to increase condensing pressure and open exhaust bypass valve appropriately at high speed and heavy load to reduce the cooling power consumption, while at low speed and light load, a lower condensing pressure is favored and the exhaust bypass valve should be closed making the waste heat recovered as much as possible. Within the sub-critical region, a larger pressure ratio yields higher overall efficiency improvement at medium-low speed and load. But the effects taper off at high speed and heavy load. For a given vehicular heavy-duty diesel engine, the overall e:'ficiency can be improved by 3.37% at 1300 r/min and 25% load using a Rankine cycle system to recover exhaust energy. The improvement becomes smaller as engine speed and load become higher.展开更多
An m-cycle system of order v and index λ, denoted by m-CS(v,λ), is a collection of cycles of length m whose edges partition the edges of λKv. An m-CS(v,λ) is α-resolvable if its cycles can be partitioned into cla...An m-cycle system of order v and index λ, denoted by m-CS(v,λ), is a collection of cycles of length m whose edges partition the edges of λKv. An m-CS(v,λ) is α-resolvable if its cycles can be partitioned into classes such that each point of the design occurs in precisely α cycles in each class. The necessary conditions for the existence of such a design are m|λv(v-1)/2,2|λ(v -1),m|αv,α|λ(v-1)/2. It is shown in this paper that these conditions are also sufficient when m = 4.展开更多
The maximal number of limit cycles for a particular type Ⅲ system x = -y + lx2 + mxy, y =x(1 + ax + by) is studied and some errors that appeared in the paper by Suo Mingxia and Yue Xiting (Annals of Differential Equa...The maximal number of limit cycles for a particular type Ⅲ system x = -y + lx2 + mxy, y =x(1 + ax + by) is studied and some errors that appeared in the paper by Suo Mingxia and Yue Xiting (Annals of Differential Equations, 2003,19(3):397-401) are corrected. By translating the system to be considered into the Lienard type and by using some related properties, we obtain several theorems with suitable conditions coefficients of the system, under which we prove that the system has at most two limit cycles. The conclusions improve the results given in Suo and Yue's paper mentioned above.展开更多
Aris and Amundson studied a chemical reactor and obtained the two equationsDaoud showed that at most one limit cycle may exist in the region of interest. Itis showed in this paper that other singular points exist and ...Aris and Amundson studied a chemical reactor and obtained the two equationsDaoud showed that at most one limit cycle may exist in the region of interest. Itis showed in this paper that other singular points exist and that a stable limitt cycle existsaround the singularity (1/2, 2) when K∈(9-δ, 9).展开更多
A method of combining the valve system program with the engine cycle modeling software to form a full set of working process modeling is submitted,not only considering the system as an independent part,but also as a p...A method of combining the valve system program with the engine cycle modeling software to form a full set of working process modeling is submitted,not only considering the system as an independent part,but also as a part of working process to evaluate comprehensively and indicate directly if the design is good or not.The designers can optimize the design by changing the engine structure,operation and the basic parameters of the cam on condition that the sysem should be stable so as to save large amounts of time and cost.Practical examples show that such a software package is an effective tool in optimizing the valve systems and performance of the machine.展开更多
The carbon pools of biomass,littering,and SOC wre studied with regards to carbon cycles in epikarst zone,taking an example of Yaji Karst Experiemnt Site in Guilin.This study was focused on SOC and its lability,SOC dec...The carbon pools of biomass,littering,and SOC wre studied with regards to carbon cycles in epikarst zone,taking an example of Yaji Karst Experiemnt Site in Guilin.This study was focused on SOC and its lability,SOC decomposition rate,CO 2 regime in the soils. 13 ctracing was used to persua the relation of bicarbonate in karst water to soil carbon.The results indicated sufficient carbon pool in SOC for the driveing CO 2 in the karst system.It was revealed that about 60percent of carbon in epi-karst springs resulted from SOC during spring and summer.Thus,the CO 2,driving the karstification,was not simply due to adsorption of atmospheric CO 2 but due to carbon transfer through the pathway of air-plant-soil-water.The driving force should not be overlooked for the epi-karst formation by soil as an interface of carbon environmental geochemistry.展开更多
To improve the overall thermal efficiency of the organic Rankine cycle( ORC), a simulation study was carried out for a combined heat and power( CHP) system, using the Redlich-Kuang-Soave( RKS) equation of state....To improve the overall thermal efficiency of the organic Rankine cycle( ORC), a simulation study was carried out for a combined heat and power( CHP) system, using the Redlich-Kuang-Soave( RKS) equation of state. In the system,R245 fa was selected as the working fluid. A scroll expander was modeled with empirical isentropic expansion efficiency.Plate heat exchangers were selected as the evaporator and the condenser, and detailed heat transfer models were programmed for both one-phase and two-phase regions. Simulations were carried out at seven different heat source temperatures( 80,90, 100, 110, 120, 130, 140 ℃) in combination with eight different heat sink temperatures( 20, 25, 30, 35, 40, 45, 50,55 ℃). Results showthat in the ORC without an internal heat exchanger( IHE), the optimum cycle efficiencies are in the range of 7. 0% to 7. 3% when the temperature differences between the heat source and heat sink are in the range of 70 to90 ℃. Simulations on CHP reveal that domestic hot water can be produced when the heat sink inlet temperature is higher than40 ℃, and the corresponding exergy efficiency and overall thermal efficiency are 29% to 56% and 87% to 90% higher than those in the non-CHP ORC, respectively. It is found that the IHE has little effect on the improvement of work output and efficiencies for the CHP ORC.展开更多
The sulfur cycle and its compartmental distribution within an atmosphere-plant-soil system was studied using a compartment model in the typical meadow Calamagrostis angustifolia wetland in the Sanjiang Plain Northeast...The sulfur cycle and its compartmental distribution within an atmosphere-plant-soil system was studied using a compartment model in the typical meadow Calamagrostis angustifolia wetland in the Sanjiang Plain Northeast China. The results showed that in the typical meadow C. angustifolia wetland ecosystem, soil was the main storage compartment and current hinge of sulfur in which 98.4% sulfur was accumulated, while only 1.6% sulfur was accumulated in the plant compartment. In the plant subsystem, roots and litters were the main storage compartment of sulfur and they remained 83.5% of the total plant sulfur. The calculations of sulfur turnover through the compartments of the typical meadow C. angustifolia wetland ecosystem demonstrated that the above-ground component took up 0.99 gS/m^2 from the root, of which 0.16 gS/m^2 was translocated to the roots and 0.83 gS/m^2 to the litter. The roots took in 1.05 gS/m^2 from the soil, subsequent translocation back to the soil accounted for 1.31 gS/m^2, while there was 1.84 gS/m^2 in the litter and the net transfer of sulfur to the soil was more than 0.44 gS/(m^2·a). The emission of H2S from the typical meadow C. angustifolia wetland ecosystem to the atmosphere was 1.83 mgS/(m^2·a), while carbonyl sulfide (COS) was absorbed by the typical meadow C. angustifolia wetland ecosystem from the atmosphere at the rate of 1.76 mgS/(m^2·a). The input of sulfur by the rainfall to the ecosystem was 4.85 mgS/m^2 during the growing season. The difference between input and output was 4.78 mgS/m^2, which indicated that sulfur was accumulated in the ecosystem and may cause wetland acidify in the future.展开更多
Stable isotope techniques have been proved useful as tools for studying the carbon (C) and nitrogen (N) biogeochemical cycles of ecosystem. This paper firstly introduced the basic principles and the distribution chara...Stable isotope techniques have been proved useful as tools for studying the carbon (C) and nitrogen (N) biogeochemical cycles of ecosystem. This paper firstly introduced the basic principles and the distribution characteristics of stable isotope, then reviewed the recent advances and applications of stable isotope in the C and N biogeochemical cycles of ecosystem. By applying the 13 C natural abundance technique, ecologists are able to understand the photosynthetic path and CO 2 fixation of plants, the CO 2 exchange and C balance status of ecosystem, the composition, distribution and turnover of soil organic C and the sources of organic matter in food webs, while by using the 13 C labeled technique, the effects of elevated CO 2 on the C processes of ecosystem and the sources and fate of organic matter in ecosystem can be revealed in detail. Differently, by applying the 15 N natural abundance technique, ecologists are able to analyze the biological N 2 -fixation, the N sources of ecosystem, the N transformation processes of ecosystem and the N trophic status in food webs, while by using the 15 N labeled technique, the sources, transformation and fate of N in ecosystem and the effects of N input on the ecosystem can be investigated in depth. The applications of both C and N isotope natural abundance and labeled techniques, combined with the elemental, other isotope ( 34 S) and molecular biomarker information, will be more propitious to the investigation of C and N cycle mechanisms. Finally, this paper concluded the problems existed in current researches, and put forward the perspective of stable isotope techniques in the studies on C and N biogeochemical cycles of ecosystem in the future.展开更多
In this paper, we try to use the entransy theory to analyze the heat–work conversion systems with inner irreversible thermodynamic cycles. First, the inner irreversible thermodynamic cycles are analyzed. The influenc...In this paper, we try to use the entransy theory to analyze the heat–work conversion systems with inner irreversible thermodynamic cycles. First, the inner irreversible thermodynamic cycles are analyzed. The influences of different inner irreversible factors on entransy loss are discussed. We find that the concept of entransy loss can be used to analyze the inner irreversible thermodynamic cycles. Then, we analyze the common heat–work conversion systems with inner irreversible thermodynamic cycles. As an example, the heat–work conversion system in which the working fluid of the thermodynamic cycles is heated and cooled by streams is analyzed. Our analyses show that larger entransy loss leads to larger output work when the total heat flow from the high temperature heat source and the corresponding equivalent temperature are fixed.Some numerical cases are presented, and the results verify the theoretical analyses. On the other hand, it is also found that larger entransy loss does not always lead to larger output work when the preconditions are not satisfied.展开更多
On the basis of proposing the existence of a karst carbon cycle and carbon sink at a watershed scale,this paper provides four pieces of evidence for;the integration of geology and ecology during the carbon cycle proce...On the basis of proposing the existence of a karst carbon cycle and carbon sink at a watershed scale,this paper provides four pieces of evidence for;the integration of geology and ecology during the carbon cycle processes m the karst dynamic system,and estxmated the karst carbon sink effect using the methods of comparative monitoring of paired watersheds and the carbon stable isotope tracer technique.The results of the soil carbon cycle in Maocun,Guilin,showed that the soil carbon cycle in the karst area,the weathering and dissolution of carbonate rocks under the soil,resulted in a lower soil respiration of 25% in the karstoarea than in a non-karst area (sandstone and shale),and the carbon isotope results indicated that 13.46% of the heavy carbon of the hmestone is involved in the soil carbon cycle.The comparative monitoring results m paxred watersheds,suggesting that the HCO3 concentration m a karst spring is 10 times that of a rivulet in a non-karst area,while the concentration of inorganic carbon flux is 23.8 times.With both chemical stoichiometry and carbon stable isotopes,the proportion of carbon in karst springs derived from carbonate rocks was found to be 58.52% and 37.65% respectively.The comparison on carbon exchange and isotopes at the water-gas interface between the granite and carbonate rock basins in the Li River showed that the CO2 emission of the karst water is 10.92 times that of the allogenic water from the non-karst area,while the carbon isotope of HCO3^- in karst water is lighter by 8.62%.However,this does not mean that the karst water body has a larger carbon source effect.On the contrary,it means the karst water body has a greater karst carbon sink effect.When the karst subterranean stream in Zhaidi,Guilin,is exposed at the surface,carbon-rich karst water stimulated the growth of aquatic plants.The values of carbon stable isotopes in the same species of submerged plants gradually becomes heavier and heavier,and the 512 m flow process has a maximum range of 15.46%.The calculation results showed that 12.52% of inorganic carbon is converted into organic carbon.According to the data that has been published,the global karst carbon sink flux was estimated to be 0.53-0.58 PgC/a,equivalent to 31.18%-34.41% of the global forest carbon sink flux.In the meanwhile,the karst carbon sink flux in China was calculated to be 0.051 PgC/a,accounting for 68% of its forest carbon sink flux.展开更多
基金supported by the National Natural Science Foundation of China(61233004,61221003,61374109,61473184,61703223,61703238)the National Basic Research Program of China(973 Program)(2013CB035500)+1 种基金Shandong Provincial Natural Science Foundation of China(ZR2017BF014,ZR2017MF017)the National Research Foundation of Singapore(NRF-2011,NRF-CRP001-090)
文摘Abstract--Vapor compression refrigeration cycle (VCC) system is a high dimensional coupling thermodynamic system for which the controller design is a great challenge. In this paper, a model predictive control based energy efficient control strategy which aims at maximizing the system efficiency is proposed. Firstly, according to the mass and energy conservation law, an analysis on the nonlinear relationship between superheat and cooling load is carried out, which can produce the maximal effect on the system performance. Then a model predictive control (MPC) based controller is developed for tracking the calculated setting curve of superheat degree and pressure difference based on model identified from data which can be obtained from an experimental rig. The proposed control strategy maximizes the coefficient of performance (COP) which depends on operating conditions, in the meantime, it meets the changing demands of cooling capacity. The effectiveness of the control performance is validated on the experimental rig. Index Terms--Cooling load, model predictive control (MPC), superheat, vapor compression refrigeration cycle (VCC).
基金supported by the Key Technologies R&D program of Tianjin,China (16YFZCGX00090)
文摘According to the problem that the selection of traditional PID control parameters is too complicated in evaporator of Organic Rankine Cycle system(ORC),an evaporator PID controller based on BP neural netw ork optimization is designed. Based on the control theory,the model of ORC evaporator is set up. The BP algorithm is used to control the Kp,Kiand Kdparameters of the evaporator PID controller,so that the evaporator temperature can reach the optimal state quickly and steadily. The M ATLAB softw are is used to simulate the traditional PID controller and the BP neural netw ork PID controller. The experimental results show that the Kp,Kiand Kdparameters of the BP neural netw ork PID controller are 0. 5677,0. 2970,and 0. 1353,respectively.Therefore,the evaporator PID controller based on BP neural netw ork optimization not only satisfies the requirements of the system performance,but also has better control parameters than the traditional PID controller.
基金Fund Project in 2020,China(No.KKZ3202052058)and the support of Scientific Research Fund from Yunnan Education Department in China(No.2022J0064).
文摘The use of nanorefrigerants in Organic Rankine Cycle(ORC)units is believed to affect the cycle environment performance,but backed with very few relevant studies.For this purpose,a life cycle assessment(LCA)has been performed for the ORC system using nanorefrigerant,the material and energy input,characteristic indicators and comprehensive index of environmental impact,total energy consumption and energy payback time(BPBT)of the whole life cycle of ORC system using Al_(2)O_(3)/R141b nanorefrigerant were calculated.Total environmental comprehensive indexes reveal that ECER-135 index decrease by 1.5%after adding 0.2%Al_(2)O_(3)nanoparticles to R141b.Based on the contribution analysis and sensitivity analysis,it can be found out ORC system manufacturing is of the most critical stage,where,the ECER-135 index of ORC component production is the greatest,followed by the preparation process of R141b,transportation phase,and that of Al_(2)O_(3)nanoparticles preparation is small.The retirement phase which has good environmental benefits affects the result significantly by recycling important materials.Meanwhile,the main cause and relevant suggestion for improvement were traced respectively.Finally,the environmental impacts of various power generations were compared,and results show that the power route is of obvious advantage.Among the renewable energy,ORC system using Al_(2)O_(3)/R141b nanorefrigerant with minimal environmental impact is only 0.67%of coal-fired power generation.The environmental impact of current work is about 14.34%of other nations’PV results.
基金Project(2012AA053001) supported by the National High Technology Research and Development Program of China
文摘A comparison on subcritical and transcritical organic Rankine cycle(ORC) system with a heat source of 110 ℃ geothermal water was presented. The net power output, thermal and exergy efficiencies and the products of the heat transfer coefficient(U) and the total heat exchange area(A)(UA values) were calculated for parametric optimization. Nine candidate working fluids were investigated and compared. Under the given conditions, transcritical systems have higher net power outputs than subcritical ones. The highest net power output of transcritical systems is 18.63 k W obtained by R218, and that of subcritical systems is 13.57 k W obtained by R600 a. Moreover, with the increase of evaporating pressure, the thermal and exergy efficiencies of transcritical systems increase at first and then decrease, but the efficiencies of subcritical ones increase. As a result, the efficiencies of transcritical systems cannot always outperform those of the subcritical ones. However, the subcritical systems have lower minimum UA values and lower expansion ratios than the transcritical ones at the maximum net power output. In addition, the transcritical cycles have higher expansion ratios than the subcritical ones at their maximum net power output.
基金funded by National Engineering Laboratory for Mobile Source Emission Control Technology of China[Grant No.NELMS2019A01]the Undergraduate School of Shandong University,China[Grant No.2022Y155].
文摘A dedicated heat exchanger model is introduced for the optimization of heavy-duty diesel engines.The model is a prerequisite for the execution of CFD simulations,which are used to improve waste heat recovery in these systems.Several optimization methods coupled with different types of working fluids are compared in terms of exergy efficiency and heat exchanger complicity.The three considered optimization methods all lead to significant improvements in the R245fa and R1233zd systems with a comparatively low evaporation temperature.The optimal R245fa system has the highest efficiency increase(77.49%).The cyclopentane system displays the highest efficiency among the optimized ORC(Organic Rankine Cycle)systems,yet achieved by using a much heavier evaporator HEC(Heat Exchanging Core).In contrast,the 96.84%efficiency increase for the optimized R1233zd is achieved with only 68.96%evaporator weight.
基金This work was supported by the Chinese TMSR Strategic Pioneer Science and Technology Project(No.XDA02010300).
文摘A nonlinear dynamic simulation model based on coordinated control of speed and flow rate for the molten salt reactor and combined cycle systems is proposed here to ensure the coordination and stability between the molten salt reactor and power system.This model considers the impact of thermal properties of fluid variation on accuracy and has been validated with Simulink.This study reveals the capability of the control system to compensate for anomalous situations and maintain shaft stability in the event of perturbations occurring in high-temperature molten salt tank outlet parameters.Meanwhile,the control system’s impact on the system’s dynamic characteristics under molten salt disturbance is also analyzed.The results reveal that after the disturbance occurs,the controlled system benefits from the action of the control,and the overshoot and disturbance amplitude are positively correlated,while the system power and frequency eventually return to the initial values.This simulation model provides a basis for utilizing molten salt reactors for power generation and maintaining grid stability.
基金supported by the Shandong Provincial Natural Science Foundation(No.ZR2021MD049)the National Natural Science Foundation of China(Nos.42176057,and 92358301)the Marine Geological Survey Program(Nos.DD20230402)。
文摘Dissolved carbon(dissolved organic carbon and dissolved inorganic carbon)is the major component of the ocean carbon cycle,representing one of the largest carbon pools on Earth.Cold seeps and hydrothermal systems serve as the two main windows for the material and energy recycling exchange between the lithosphere and outer spheres(biosphere,hydrosphere and atmosphere).However,recent studies have found that the dynamic activities of fluids in these two extreme systems are a crucial source of‘new'carbon in the deep ocean.These carbon sources may become vital contributors to carbon and energy in marine ecosystems,which affect the global deep-sea carbon budget,and the marine ecosystems as well.In this review,we summarize the sources and formation mechanisms of dissolved carbon in the seep fluids from the cold seeps and hydrothermal vents,the contribution of methane oxidation to dissolved carbon,and the characteristics of the carbon isotope composition in the fluid.Furthermore,we analyze and discuss the influence of carbon discharged from seabed on the seawater carbon cycle by comparing and contrasting these two extreme environments.The research may assist in promoting a deeper understanding of the carbon cycle and material interaction in the ocean,particularly further carbon cycle research in the back-arc basin where cold seeps and hydrothermal vents commonly prevail.
文摘This paper explores the existence of heteroclinic cycles and corresponding chaotic dynamics in a class of 3-dimensional two-zone piecewise affine systems. Moreover, the heteroclinic cycles connect two saddle foci and intersect the switching manifold at two points and the switching manifold is composed of two perpendicular planes.
基金Forest Ecosystem Research of Liangshui & Maorshan Station of Heilongjiang Province (CFERN, No. 2001-02).
文摘Nitrogen is one of the most important elements that can limit plant growth in forest ecosystems. Studies of nitrogen mineralization, nitrogen saturation and nitrogen cycle in forest ecosystems is very necessary for understanding the productivity of stand, nutrient cycle and turnover of nitrogen of forest ecosystems. Based on comparison and analysis of domestic and in-ternational academic references related to studies on nitrogen mineralization, nitrogen saturation and nitrogen cycle in recent 10 years, the current situation and development of the study on these aspects, and the problems existed in current researches were reviewed. At last, some advices were given for future researches.
基金supported by the National Basic Research Program of China("973"Project)(Grant No.2011CB707206)
文摘The Rankine cycle system for waste heat recovery of heavy-duty vehicle diesel engines has been regarded as a promising tech- nique to reduce fuel consumption. Its heat dissipation in the condensation process, however, should be take:l away in time, which is an energy-consuming process. A fan-assisted auxiliary water-cooling system is employed in this paper. Results at 1300 r/min and 50% load indicate that the cooling pump and cooling fan together consume 7.66% of the recovered power. What's worse for the heavy load, cooling accessories may deplete of all the recovered power of the Rankine cycle system. Af- terwards, effects of the condensing pressure and water feeding temperature are investigated, based on which a cooling power consumption model is established. Finally, an overall efficiency optimization is conducted to balance the electric power gener- ation and cooling power consumption, taking condensing pressure, pressure ratio and exhaust bypass valve as major variables. The research suggests that the priority is to increase condensing pressure and open exhaust bypass valve appropriately at high speed and heavy load to reduce the cooling power consumption, while at low speed and light load, a lower condensing pressure is favored and the exhaust bypass valve should be closed making the waste heat recovered as much as possible. Within the sub-critical region, a larger pressure ratio yields higher overall efficiency improvement at medium-low speed and load. But the effects taper off at high speed and heavy load. For a given vehicular heavy-duty diesel engine, the overall e:'ficiency can be improved by 3.37% at 1300 r/min and 25% load using a Rankine cycle system to recover exhaust energy. The improvement becomes smaller as engine speed and load become higher.
基金the National Natural Science Foundation of China (No.10971051)
文摘An m-cycle system of order v and index λ, denoted by m-CS(v,λ), is a collection of cycles of length m whose edges partition the edges of λKv. An m-CS(v,λ) is α-resolvable if its cycles can be partitioned into classes such that each point of the design occurs in precisely α cycles in each class. The necessary conditions for the existence of such a design are m|λv(v-1)/2,2|λ(v -1),m|αv,α|λ(v-1)/2. It is shown in this paper that these conditions are also sufficient when m = 4.
文摘The maximal number of limit cycles for a particular type Ⅲ system x = -y + lx2 + mxy, y =x(1 + ax + by) is studied and some errors that appeared in the paper by Suo Mingxia and Yue Xiting (Annals of Differential Equations, 2003,19(3):397-401) are corrected. By translating the system to be considered into the Lienard type and by using some related properties, we obtain several theorems with suitable conditions coefficients of the system, under which we prove that the system has at most two limit cycles. The conclusions improve the results given in Suo and Yue's paper mentioned above.
文摘Aris and Amundson studied a chemical reactor and obtained the two equationsDaoud showed that at most one limit cycle may exist in the region of interest. Itis showed in this paper that other singular points exist and that a stable limitt cycle existsaround the singularity (1/2, 2) when K∈(9-δ, 9).
文摘A method of combining the valve system program with the engine cycle modeling software to form a full set of working process modeling is submitted,not only considering the system as an independent part,but also as a part of working process to evaluate comprehensively and indicate directly if the design is good or not.The designers can optimize the design by changing the engine structure,operation and the basic parameters of the cam on condition that the sysem should be stable so as to save large amounts of time and cost.Practical examples show that such a software package is an effective tool in optimizing the valve systems and performance of the machine.
文摘The carbon pools of biomass,littering,and SOC wre studied with regards to carbon cycles in epikarst zone,taking an example of Yaji Karst Experiemnt Site in Guilin.This study was focused on SOC and its lability,SOC decomposition rate,CO 2 regime in the soils. 13 ctracing was used to persua the relation of bicarbonate in karst water to soil carbon.The results indicated sufficient carbon pool in SOC for the driveing CO 2 in the karst system.It was revealed that about 60percent of carbon in epi-karst springs resulted from SOC during spring and summer.Thus,the CO 2,driving the karstification,was not simply due to adsorption of atmospheric CO 2 but due to carbon transfer through the pathway of air-plant-soil-water.The driving force should not be overlooked for the epi-karst formation by soil as an interface of carbon environmental geochemistry.
基金Special Fund for IndustryUniversity and Research Cooperation(No.2011DFR61130)
文摘To improve the overall thermal efficiency of the organic Rankine cycle( ORC), a simulation study was carried out for a combined heat and power( CHP) system, using the Redlich-Kuang-Soave( RKS) equation of state. In the system,R245 fa was selected as the working fluid. A scroll expander was modeled with empirical isentropic expansion efficiency.Plate heat exchangers were selected as the evaporator and the condenser, and detailed heat transfer models were programmed for both one-phase and two-phase regions. Simulations were carried out at seven different heat source temperatures( 80,90, 100, 110, 120, 130, 140 ℃) in combination with eight different heat sink temperatures( 20, 25, 30, 35, 40, 45, 50,55 ℃). Results showthat in the ORC without an internal heat exchanger( IHE), the optimum cycle efficiencies are in the range of 7. 0% to 7. 3% when the temperature differences between the heat source and heat sink are in the range of 70 to90 ℃. Simulations on CHP reveal that domestic hot water can be produced when the heat sink inlet temperature is higher than40 ℃, and the corresponding exergy efficiency and overall thermal efficiency are 29% to 56% and 87% to 90% higher than those in the non-CHP ORC, respectively. It is found that the IHE has little effect on the improvement of work output and efficiencies for the CHP ORC.
文摘The sulfur cycle and its compartmental distribution within an atmosphere-plant-soil system was studied using a compartment model in the typical meadow Calamagrostis angustifolia wetland in the Sanjiang Plain Northeast China. The results showed that in the typical meadow C. angustifolia wetland ecosystem, soil was the main storage compartment and current hinge of sulfur in which 98.4% sulfur was accumulated, while only 1.6% sulfur was accumulated in the plant compartment. In the plant subsystem, roots and litters were the main storage compartment of sulfur and they remained 83.5% of the total plant sulfur. The calculations of sulfur turnover through the compartments of the typical meadow C. angustifolia wetland ecosystem demonstrated that the above-ground component took up 0.99 gS/m^2 from the root, of which 0.16 gS/m^2 was translocated to the roots and 0.83 gS/m^2 to the litter. The roots took in 1.05 gS/m^2 from the soil, subsequent translocation back to the soil accounted for 1.31 gS/m^2, while there was 1.84 gS/m^2 in the litter and the net transfer of sulfur to the soil was more than 0.44 gS/(m^2·a). The emission of H2S from the typical meadow C. angustifolia wetland ecosystem to the atmosphere was 1.83 mgS/(m^2·a), while carbonyl sulfide (COS) was absorbed by the typical meadow C. angustifolia wetland ecosystem from the atmosphere at the rate of 1.76 mgS/(m^2·a). The input of sulfur by the rainfall to the ecosystem was 4.85 mgS/m^2 during the growing season. The difference between input and output was 4.78 mgS/m^2, which indicated that sulfur was accumulated in the ecosystem and may cause wetland acidify in the future.
基金Under the auspices of Knowledge Innovation Programs of Chinese Academy of Sciences (No. KZCX2-YW-223)National Natural Science Foundation of China (No. 40803023)+1 种基金Key Program of Natural Science Foundation of Shandong Province(No. ZR2010DZ001)Talents Foundation of Chinese Academy of Sciences (No. AJ0809BX-036)
文摘Stable isotope techniques have been proved useful as tools for studying the carbon (C) and nitrogen (N) biogeochemical cycles of ecosystem. This paper firstly introduced the basic principles and the distribution characteristics of stable isotope, then reviewed the recent advances and applications of stable isotope in the C and N biogeochemical cycles of ecosystem. By applying the 13 C natural abundance technique, ecologists are able to understand the photosynthetic path and CO 2 fixation of plants, the CO 2 exchange and C balance status of ecosystem, the composition, distribution and turnover of soil organic C and the sources of organic matter in food webs, while by using the 13 C labeled technique, the effects of elevated CO 2 on the C processes of ecosystem and the sources and fate of organic matter in ecosystem can be revealed in detail. Differently, by applying the 15 N natural abundance technique, ecologists are able to analyze the biological N 2 -fixation, the N sources of ecosystem, the N transformation processes of ecosystem and the N trophic status in food webs, while by using the 15 N labeled technique, the sources, transformation and fate of N in ecosystem and the effects of N input on the ecosystem can be investigated in depth. The applications of both C and N isotope natural abundance and labeled techniques, combined with the elemental, other isotope ( 34 S) and molecular biomarker information, will be more propitious to the investigation of C and N cycle mechanisms. Finally, this paper concluded the problems existed in current researches, and put forward the perspective of stable isotope techniques in the studies on C and N biogeochemical cycles of ecosystem in the future.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51376101 and 51356001)
文摘In this paper, we try to use the entransy theory to analyze the heat–work conversion systems with inner irreversible thermodynamic cycles. First, the inner irreversible thermodynamic cycles are analyzed. The influences of different inner irreversible factors on entransy loss are discussed. We find that the concept of entransy loss can be used to analyze the inner irreversible thermodynamic cycles. Then, we analyze the common heat–work conversion systems with inner irreversible thermodynamic cycles. As an example, the heat–work conversion system in which the working fluid of the thermodynamic cycles is heated and cooled by streams is analyzed. Our analyses show that larger entransy loss leads to larger output work when the total heat flow from the high temperature heat source and the corresponding equivalent temperature are fixed.Some numerical cases are presented, and the results verify the theoretical analyses. On the other hand, it is also found that larger entransy loss does not always lead to larger output work when the preconditions are not satisfied.
基金the National Key Research and Development Program project (2016YFC0502500)a Key project of National Natural Science Foundation (41530316)the China Geological Survey Programs of the Geological Environmental Innovation.
文摘On the basis of proposing the existence of a karst carbon cycle and carbon sink at a watershed scale,this paper provides four pieces of evidence for;the integration of geology and ecology during the carbon cycle processes m the karst dynamic system,and estxmated the karst carbon sink effect using the methods of comparative monitoring of paired watersheds and the carbon stable isotope tracer technique.The results of the soil carbon cycle in Maocun,Guilin,showed that the soil carbon cycle in the karst area,the weathering and dissolution of carbonate rocks under the soil,resulted in a lower soil respiration of 25% in the karstoarea than in a non-karst area (sandstone and shale),and the carbon isotope results indicated that 13.46% of the heavy carbon of the hmestone is involved in the soil carbon cycle.The comparative monitoring results m paxred watersheds,suggesting that the HCO3 concentration m a karst spring is 10 times that of a rivulet in a non-karst area,while the concentration of inorganic carbon flux is 23.8 times.With both chemical stoichiometry and carbon stable isotopes,the proportion of carbon in karst springs derived from carbonate rocks was found to be 58.52% and 37.65% respectively.The comparison on carbon exchange and isotopes at the water-gas interface between the granite and carbonate rock basins in the Li River showed that the CO2 emission of the karst water is 10.92 times that of the allogenic water from the non-karst area,while the carbon isotope of HCO3^- in karst water is lighter by 8.62%.However,this does not mean that the karst water body has a larger carbon source effect.On the contrary,it means the karst water body has a greater karst carbon sink effect.When the karst subterranean stream in Zhaidi,Guilin,is exposed at the surface,carbon-rich karst water stimulated the growth of aquatic plants.The values of carbon stable isotopes in the same species of submerged plants gradually becomes heavier and heavier,and the 512 m flow process has a maximum range of 15.46%.The calculation results showed that 12.52% of inorganic carbon is converted into organic carbon.According to the data that has been published,the global karst carbon sink flux was estimated to be 0.53-0.58 PgC/a,equivalent to 31.18%-34.41% of the global forest carbon sink flux.In the meanwhile,the karst carbon sink flux in China was calculated to be 0.051 PgC/a,accounting for 68% of its forest carbon sink flux.