Cyclic voltammetry based on an electrochemical technique is one of the current methods that measure the developments of the electrochemical properties in biomaterial samples under conditions. Biomaterial structure was...Cyclic voltammetry based on an electrochemical technique is one of the current methods that measure the developments of the electrochemical properties in biomaterial samples under conditions. Biomaterial structure was changed by conductive material while these materials caused a connective network in whole of them and was able to transfer electrons inside of biomaterials. These changes in physical and chemical properties are investigated by analysis tools such as cyclic voltammetry (CV), X-radiation (XRF) and Ultraviolet-visible spectroscopy (UV-Vis). Bacterial cellulose is biodegradable, biosynthesis of A. xylinum which is a three-dimensional nano-network structure with a distinct tunnel and pore structure. In this study, the composite process produced electrically conducting bacterial cellulose pellicles containing well-dispersed and embedded multi-walled carbon nanotubes (MWCNTs) Ionic liquids (ILs), as observed in cyclic voltammetry (CV). For this purpose, we used a special tool, called OriginLab which is an industry-leading scientific graphing and data analysis software. The cyclic voltammetry graph presents the behavior of this composite which consists of a relationship between CNT dispersion, conductivity rate and changes in bacterial cellulose structure. The electrical conductivity of the cellulose/MWCNT composite was found different with respect to CNT dispersion. It was found that the incorporation process was a useful method not only for dispersing MWCNTs-ILs in an ultrafine fibrous network structure, but also for enhancing the electrical conductivity of the polymeric membranes.展开更多
The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O(1)(bipy:4,4'-bipyridine;Hpc:α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It c...The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O(1)(bipy:4,4'-bipyridine;Hpc:α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu(Ⅱ) centre adopts a pseudo octahedral geometry.Ligand 4,4'-bipyridine as a bridge coordinates to two different Cu(Ⅱ) center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated.展开更多
使用烧结法制备了Ag/AgCl固态不极化海洋电场电极,利用聚丙烯腈碳纤维T300制备了电容型海洋电场电极。研究了不极化电极和电容型电极探测海洋电场的原理,提出了两种电极的使用方法并研究了其探测性能。使用电化学工作站对两种电极进了...使用烧结法制备了Ag/AgCl固态不极化海洋电场电极,利用聚丙烯腈碳纤维T300制备了电容型海洋电场电极。研究了不极化电极和电容型电极探测海洋电场的原理,提出了两种电极的使用方法并研究了其探测性能。使用电化学工作站对两种电极进了循环伏安测量和电极对极差跟踪;使用低频低噪声放大器对两种电极的自噪声稳定速度和大小进行对比测量;在自制水槽中测试了两种电极在不同频率下的响应性能。试验结果表明两种电极均可测量1 m Hz以上的交变海洋电场;相比于Ag/AgCl电极,碳纤维电极具有极差小和自噪声稳定速度快的特点;稳定后两种电极的自噪声均为1 n V/√Hz@1 Hz。展开更多
AucoreCoshell nanoparticles with different shell thicknesses were prepared by using chemical reduction method and characterized by scanning electron microscopy（SEM） and cyclic voltammetry（CV）. The results reveal t...AucoreCoshell nanoparticles with different shell thicknesses were prepared by using chemical reduction method and characterized by scanning electron microscopy（SEM） and cyclic voltammetry（CV）. The results reveal that the prepared core-shell nanoparticles were covered by Co shell and exhibited the similar electrochemistry property with the Co nanoparticles surface. Surface enhanced Raman spectroscopy（SERS） activities of these nanoparticles were studied by using pyridine as a probe molecule. It was found that the SERS intensity depended on the Co shell thickness of the core-shell nanoparticles and was weakened with the increasing shell thickness. The SERS intensity of these AucoreCoshell nanoparticles is found to be about twenty times higher than that obtained on an electrochemically roughened cobalt electrode.展开更多
文摘Cyclic voltammetry based on an electrochemical technique is one of the current methods that measure the developments of the electrochemical properties in biomaterial samples under conditions. Biomaterial structure was changed by conductive material while these materials caused a connective network in whole of them and was able to transfer electrons inside of biomaterials. These changes in physical and chemical properties are investigated by analysis tools such as cyclic voltammetry (CV), X-radiation (XRF) and Ultraviolet-visible spectroscopy (UV-Vis). Bacterial cellulose is biodegradable, biosynthesis of A. xylinum which is a three-dimensional nano-network structure with a distinct tunnel and pore structure. In this study, the composite process produced electrically conducting bacterial cellulose pellicles containing well-dispersed and embedded multi-walled carbon nanotubes (MWCNTs) Ionic liquids (ILs), as observed in cyclic voltammetry (CV). For this purpose, we used a special tool, called OriginLab which is an industry-leading scientific graphing and data analysis software. The cyclic voltammetry graph presents the behavior of this composite which consists of a relationship between CNT dispersion, conductivity rate and changes in bacterial cellulose structure. The electrical conductivity of the cellulose/MWCNT composite was found different with respect to CNT dispersion. It was found that the incorporation process was a useful method not only for dispersing MWCNTs-ILs in an ultrafine fibrous network structure, but also for enhancing the electrical conductivity of the polymeric membranes.
文摘The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O(1)(bipy:4,4'-bipyridine;Hpc:α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu(Ⅱ) centre adopts a pseudo octahedral geometry.Ligand 4,4'-bipyridine as a bridge coordinates to two different Cu(Ⅱ) center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated.
文摘使用烧结法制备了Ag/AgCl固态不极化海洋电场电极,利用聚丙烯腈碳纤维T300制备了电容型海洋电场电极。研究了不极化电极和电容型电极探测海洋电场的原理,提出了两种电极的使用方法并研究了其探测性能。使用电化学工作站对两种电极进了循环伏安测量和电极对极差跟踪;使用低频低噪声放大器对两种电极的自噪声稳定速度和大小进行对比测量;在自制水槽中测试了两种电极在不同频率下的响应性能。试验结果表明两种电极均可测量1 m Hz以上的交变海洋电场;相比于Ag/AgCl电极,碳纤维电极具有极差小和自噪声稳定速度快的特点;稳定后两种电极的自噪声均为1 n V/√Hz@1 Hz。
文摘AucoreCoshell nanoparticles with different shell thicknesses were prepared by using chemical reduction method and characterized by scanning electron microscopy（SEM） and cyclic voltammetry（CV）. The results reveal that the prepared core-shell nanoparticles were covered by Co shell and exhibited the similar electrochemistry property with the Co nanoparticles surface. Surface enhanced Raman spectroscopy（SERS） activities of these nanoparticles were studied by using pyridine as a probe molecule. It was found that the SERS intensity depended on the Co shell thickness of the core-shell nanoparticles and was weakened with the increasing shell thickness. The SERS intensity of these AucoreCoshell nanoparticles is found to be about twenty times higher than that obtained on an electrochemically roughened cobalt electrode.
