An equation to express ion exchange selectivity coefficient was derived and used for cal- culating that of PPY film with the results obtained by cyclic voltamrnetric measurement.PPY film was synthesized by electrochem...An equation to express ion exchange selectivity coefficient was derived and used for cal- culating that of PPY film with the results obtained by cyclic voltamrnetric measurement.PPY film was synthesized by electrochemical method in aqueous solution using K_4Fc(CN)_6 as supporting electrolyte, and the anions were doped into the film.Ion exchange behaviour of doped Fe(CN)_6^(3-/4-)in the PPY film with Cl^-,NO_3^- or F^- ions in solution has been studied,and the corresponding ion exchange selec- tivity coefficients were determined.展开更多
基金This work was financially supported by the National Natural Science Foundation of China.
文摘An equation to express ion exchange selectivity coefficient was derived and used for cal- culating that of PPY film with the results obtained by cyclic voltamrnetric measurement.PPY film was synthesized by electrochemical method in aqueous solution using K_4Fc(CN)_6 as supporting electrolyte, and the anions were doped into the film.Ion exchange behaviour of doped Fe(CN)_6^(3-/4-)in the PPY film with Cl^-,NO_3^- or F^- ions in solution has been studied,and the corresponding ion exchange selec- tivity coefficients were determined.
