The solid complexes of Cr(AA) 2Cl 3·nH 2O of CrCl 3 with L-α-amino acids (AA=Val, Leu, Thr, Met, Arg, Phe, Try and His) have been prepared in 95% EtOH medium, and characterized structurally by elemental anal...The solid complexes of Cr(AA) 2Cl 3·nH 2O of CrCl 3 with L-α-amino acids (AA=Val, Leu, Thr, Met, Arg, Phe, Try and His) have been prepared in 95% EtOH medium, and characterized structurally by elemental analysis, chemical analysis, IR spectra and TG-DTG. The constant-volume combustion energies of the complexes have been determined by RBC-II type rotating-bomb calorimeter. The standard enthalpies of formation of the complexes have been calculated as well, which are ( -2543.16± 3.71) (Val), ( -2561.32± 4.06) (Leu), ( -2284.02± 2.95) (Thr), ( -1418.77± 4.60) (Met), ( -3218.91± 4.67) (Arg), ( -2643.90± 5.02) (Phe), ( -1707.18± 3.23) (Try) and ( -2838.05±3.45) (His) kJ/ mol, respectively.展开更多
,d,l-a-Tocopherol (vitamin E) isfound to be synthesized by condensingtrimethylhydroquinone with isophytol catalyzed by heteropoly acids (HPA) H3:PW12O40 andH3PMo12O40 at room temperature. These HPA are efficient cata...,d,l-a-Tocopherol (vitamin E) isfound to be synthesized by condensingtrimethylhydroquinone with isophytol catalyzed by heteropoly acids (HPA) H3:PW12O40 andH3PMo12O40 at room temperature. These HPA are efficient catalysts for the synthesis of d l-a-Tocopherol and can easily be separated from the reaction mixture and roused,展开更多
A novel chiral stationary phase(CysCSP) for ligand exchange chromatography was prepared by firstly synthesizing N,S-di(2-hydroxyl-3-octoxyl)propyl-L-cysteine as chiral selector via reaction of L-cysteine with glycidyl...A novel chiral stationary phase(CysCSP) for ligand exchange chromatography was prepared by firstly synthesizing N,S-di(2-hydroxyl-3-octoxyl)propyl-L-cysteine as chiral selector via reaction of L-cysteine with glycidyl octyl ether and then coating it on YWG-C-{18} bonded stationary phase. The enantiomeric resolutions of some D,L-α-amino acids were achieved on CysCSP by using cupric acetate aqueous solution as the mobile phase, under the conditions of column temperature 20 ℃ and detection at UV 254 nm. The enantioselectivities α of D,L-α-amino acids separated were found to be in the range from 1.11 to 1.38 with the resolution R-s ranging from 1.1 to 2.8 and the column efficiency being from 5 000 to 9 000 n/m. The elution order of D-isomer before L-isomer was obersaved for all D,L-amino acids used.展开更多
文摘The solid complexes of Cr(AA) 2Cl 3·nH 2O of CrCl 3 with L-α-amino acids (AA=Val, Leu, Thr, Met, Arg, Phe, Try and His) have been prepared in 95% EtOH medium, and characterized structurally by elemental analysis, chemical analysis, IR spectra and TG-DTG. The constant-volume combustion energies of the complexes have been determined by RBC-II type rotating-bomb calorimeter. The standard enthalpies of formation of the complexes have been calculated as well, which are ( -2543.16± 3.71) (Val), ( -2561.32± 4.06) (Leu), ( -2284.02± 2.95) (Thr), ( -1418.77± 4.60) (Met), ( -3218.91± 4.67) (Arg), ( -2643.90± 5.02) (Phe), ( -1707.18± 3.23) (Try) and ( -2838.05±3.45) (His) kJ/ mol, respectively.
文摘,d,l-a-Tocopherol (vitamin E) isfound to be synthesized by condensingtrimethylhydroquinone with isophytol catalyzed by heteropoly acids (HPA) H3:PW12O40 andH3PMo12O40 at room temperature. These HPA are efficient catalysts for the synthesis of d l-a-Tocopherol and can easily be separated from the reaction mixture and roused,
文摘A novel chiral stationary phase(CysCSP) for ligand exchange chromatography was prepared by firstly synthesizing N,S-di(2-hydroxyl-3-octoxyl)propyl-L-cysteine as chiral selector via reaction of L-cysteine with glycidyl octyl ether and then coating it on YWG-C-{18} bonded stationary phase. The enantiomeric resolutions of some D,L-α-amino acids were achieved on CysCSP by using cupric acetate aqueous solution as the mobile phase, under the conditions of column temperature 20 ℃ and detection at UV 254 nm. The enantioselectivities α of D,L-α-amino acids separated were found to be in the range from 1.11 to 1.38 with the resolution R-s ranging from 1.1 to 2.8 and the column efficiency being from 5 000 to 9 000 n/m. The elution order of D-isomer before L-isomer was obersaved for all D,L-amino acids used.