回复电压测量方法(return voltage measurement,RVM)能有效检测变压器固体绝缘的含水量,然而对于含有局部峰值点的回复电压极化谱难以给出明确的诊断结论。文中在扩展Debye模型基础上,仿真分析了模型参数变化对极化谱和主时间常数CTC、...回复电压测量方法(return voltage measurement,RVM)能有效检测变压器固体绝缘的含水量,然而对于含有局部峰值点的回复电压极化谱难以给出明确的诊断结论。文中在扩展Debye模型基础上,仿真分析了模型参数变化对极化谱和主时间常数CTC、回复电压峰值最大值Urmax的影响规律,并提出将扩展Debye模型不同时间常数支路数作为新的特征量,最后验证了该特征量的可行性。仿真和试验结果表明:RVM极化谱前、中、尾3部分分别对应着油纸绝缘变压器油中偶极子转向极化、油纸界面极化和绝缘纸内偶极子转向极化、纸内界面极化;油纸绝缘老化会使扩展Debye模型各支路极化电阻减小,极化电容增大,时间常数减小;当变压器油老化严重时,极化谱有可能出现局部峰值;扩展Debye模型各时间常数支路数可作为新的RVM特征量,各时间常数支路数的变化也可使极化谱产生局部峰值,现场试验也验证了新特征量的有效性。展开更多
Statistical expression of vapour pressure equations of metals is derived from the Debye model.The statistical distribution of T_(-p) ensemble is presented in an in-elab- orate mode and the partition function is define...Statistical expression of vapour pressure equations of metals is derived from the Debye model.The statistical distribution of T_(-p) ensemble is presented in an in-elab- orate mode and the partition function is defined.The vapour pressure of eleven metals have been calculated with the Debye equation and compared with those given by the E- instein equation and empirical equation.Comparison of results of calculation from dif- ferent methods show their evident accordance within the same orders of magnitude.展开更多
This paper applies the Debye-Hückel-Onsager electrolyte solution theory to investigate the diffusivity of ions in concrete pore solutions.First,a model of the diffusion coefficient associated with the ionic speci...This paper applies the Debye-Hückel-Onsager electrolyte solution theory to investigate the diffusivity of ions in concrete pore solutions.First,a model of the diffusion coefficient associated with the ionic species,solution concentration and ambient temperature is proposed in the saturated concrete.Secondly,as an example,the effects of sodium chloride solution concentration,which are associated with influencing factors such as the ionic cloud radius,electrophoresis and relaxation,on the chloride diffusion coefficient are analyzed.It is found that the diffusion coefficient decreases with the increase in solution concentration,and the electrophoresis and ionic cloud radius are two important factors influencing the ionic diffusivity.Finally,the experiments,in which the chloride diffusion coefficients in specimens under different water-cement ratios are measured by the rapid chloride migration（RCM）method,are carried out to validate the effectiveness of the proposed model,and the results indicate that there is a generally reasonable agreement between the experimental and the proposed model results.展开更多
文摘回复电压测量方法(return voltage measurement,RVM)能有效检测变压器固体绝缘的含水量,然而对于含有局部峰值点的回复电压极化谱难以给出明确的诊断结论。文中在扩展Debye模型基础上,仿真分析了模型参数变化对极化谱和主时间常数CTC、回复电压峰值最大值Urmax的影响规律,并提出将扩展Debye模型不同时间常数支路数作为新的特征量,最后验证了该特征量的可行性。仿真和试验结果表明:RVM极化谱前、中、尾3部分分别对应着油纸绝缘变压器油中偶极子转向极化、油纸界面极化和绝缘纸内偶极子转向极化、纸内界面极化;油纸绝缘老化会使扩展Debye模型各支路极化电阻减小,极化电容增大,时间常数减小;当变压器油老化严重时,极化谱有可能出现局部峰值;扩展Debye模型各时间常数支路数可作为新的RVM特征量,各时间常数支路数的变化也可使极化谱产生局部峰值,现场试验也验证了新特征量的有效性。
文摘Statistical expression of vapour pressure equations of metals is derived from the Debye model.The statistical distribution of T_(-p) ensemble is presented in an in-elab- orate mode and the partition function is defined.The vapour pressure of eleven metals have been calculated with the Debye equation and compared with those given by the E- instein equation and empirical equation.Comparison of results of calculation from dif- ferent methods show their evident accordance within the same orders of magnitude.
基金The National Basic Research Program of China(973Program)(No.2009CB623203)the National Natural Science Foundation of China(No.51078186)+2 种基金Program for Special Talents in Six Fields of Jiangsu Province(No.2008169)the Natural Science Foundation of Jiangsu Province(No.BK2010071)China Postdoctoral Science Foundation(No.200902500)
文摘This paper applies the Debye-Hückel-Onsager electrolyte solution theory to investigate the diffusivity of ions in concrete pore solutions.First,a model of the diffusion coefficient associated with the ionic species,solution concentration and ambient temperature is proposed in the saturated concrete.Secondly,as an example,the effects of sodium chloride solution concentration,which are associated with influencing factors such as the ionic cloud radius,electrophoresis and relaxation,on the chloride diffusion coefficient are analyzed.It is found that the diffusion coefficient decreases with the increase in solution concentration,and the electrophoresis and ionic cloud radius are two important factors influencing the ionic diffusivity.Finally,the experiments,in which the chloride diffusion coefficients in specimens under different water-cement ratios are measured by the rapid chloride migration（RCM）method,are carried out to validate the effectiveness of the proposed model,and the results indicate that there is a generally reasonable agreement between the experimental and the proposed model results.
