A laboratory experiment was carried out to extract iron from oolitic iron ore by a deep reduction and magnetic separation technique. The raw coal with fixed carbon of 66.54% was used as the reductant. The iron was suc...A laboratory experiment was carried out to extract iron from oolitic iron ore by a deep reduction and magnetic separation technique. The raw coal with fixed carbon of 66.54% was used as the reductant. The iron was successfully extracted from the oolitic iron ore which otherwise is nearly impossible to be separated due to its extremely fine-grain and mosaic nature. The results showed that an iron recovery rate of 90.78% and an iron content of 92.53~ of iron concentrate could be obtained by such a technique. The optimized roast temperature is 1 200℃ and time is 60 min. The subsequent magnetic separation was performed by using a magnetic field intensity of 111 kA · m^-1 and a grinding fineness less than 45 μm of 96. 19% for the sintered product.展开更多
In this study,we investigated the separation of iron and scandium from Sc-bearing red mud.The red mud object of our study contained 31.11 wt%total iron(TFe),0.0045 wt%Sc,hematite(Fe_(2)O_(3))and ferrosilite(FeO·S...In this study,we investigated the separation of iron and scandium from Sc-bearing red mud.The red mud object of our study contained 31.11 wt%total iron(TFe),0.0045 wt%Sc,hematite(Fe_(2)O_(3))and ferrosilite(FeO·SiO_(2))as the main Fe-bearing minerals.The Sc-bearing red mud was treated by a novel deep reduction roasting and magnetic separation process that includes the addition of coke and CaO to extract Fe and enriching Sc from the Sc-bearing red mud.The addition of coke and CaO enhances the transformation of hematite(Fe_(2)O_(3))to metallic iron(Fe~0)and magnetite(Fe_(3)O_(4))as well as the transformation of ferrosilite into metallic iron(Fe~0).The test results show that utilizing the new process a Fe concentrate with a TFe content of 81.22 wt%and Fe recovery of 92.96%was obtained.Furthermore,magnetic separation tailings with Sc content of 0.0062 wt%and Sc recovery of 98.65%were also obtained.The test results were achieved under the following process conditions:roasting temperature of 1373 K,roasting time of 45 min,calcium oxide dosage of 20 wt%,coke dosage of 25 wt%,grinding fineness of90%<0.04 mm,and magnetic field intensity of 0.24 T.The major minerals in the Fe concentrate are metallic iron(Fe~0)and magnetite(Fe_(3)O_(4)).The main minerals in the magnetic separation tailings with a low TFe content of 2.62%are CaO·SiO_(2),Na_(2)O·SiO_(2),FeO·SiO_(2),Ca_(3)Fe_(2)Si_(3)O_(12),CaAl_(2)SiO_6 and CaFe(SiO_(3))_(2).展开更多
High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low f...High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low ferrotitanium.However,the high levels of S,Al,and O residues in the product severely restrict its applicability in the low-cost preparation of good-quality high ferrotitanium.In this study,a novel multistage deep reduction method for preparing high-quality high ferrotitanium is proposed,and the multistage desulfurization mechanism is systematically investigated.The results indicate that multistage desulfurization is an effective method for reducing the S content of high ferrotitanium prepared via the thermite method.During the strong desulfurization stage,Ti_(2)S reacts with CaO at the slag-metal interface and produces CaS.The S content decreases,while the O content increases,with the increase of CaO in the CaO-Al_(2)O_(3)-based slag.During the deep desulfurization,Ti_(2)S is deeply reduced by the Ca and produces CaS,thus further reducing the S content.The S content decreases with the incremental addition of Ca and can be reduced to 0.035 wt%after multistage desulfurization.展开更多
基金Item Sponsored by National Natural Science Foundation of China(51074036)
文摘A laboratory experiment was carried out to extract iron from oolitic iron ore by a deep reduction and magnetic separation technique. The raw coal with fixed carbon of 66.54% was used as the reductant. The iron was successfully extracted from the oolitic iron ore which otherwise is nearly impossible to be separated due to its extremely fine-grain and mosaic nature. The results showed that an iron recovery rate of 90.78% and an iron content of 92.53~ of iron concentrate could be obtained by such a technique. The optimized roast temperature is 1 200℃ and time is 60 min. The subsequent magnetic separation was performed by using a magnetic field intensity of 111 kA · m^-1 and a grinding fineness less than 45 μm of 96. 19% for the sintered product.
基金Project supported by the Sichuan Science and Technology Program(2022YFS0462,2021YJ0057,2021YFG0268)the China Postdoctoral Science Foundation(2014M560734)。
文摘In this study,we investigated the separation of iron and scandium from Sc-bearing red mud.The red mud object of our study contained 31.11 wt%total iron(TFe),0.0045 wt%Sc,hematite(Fe_(2)O_(3))and ferrosilite(FeO·SiO_(2))as the main Fe-bearing minerals.The Sc-bearing red mud was treated by a novel deep reduction roasting and magnetic separation process that includes the addition of coke and CaO to extract Fe and enriching Sc from the Sc-bearing red mud.The addition of coke and CaO enhances the transformation of hematite(Fe_(2)O_(3))to metallic iron(Fe~0)and magnetite(Fe_(3)O_(4))as well as the transformation of ferrosilite into metallic iron(Fe~0).The test results show that utilizing the new process a Fe concentrate with a TFe content of 81.22 wt%and Fe recovery of 92.96%was obtained.Furthermore,magnetic separation tailings with Sc content of 0.0062 wt%and Sc recovery of 98.65%were also obtained.The test results were achieved under the following process conditions:roasting temperature of 1373 K,roasting time of 45 min,calcium oxide dosage of 20 wt%,coke dosage of 25 wt%,grinding fineness of90%<0.04 mm,and magnetic field intensity of 0.24 T.The major minerals in the Fe concentrate are metallic iron(Fe~0)and magnetite(Fe_(3)O_(4)).The main minerals in the magnetic separation tailings with a low TFe content of 2.62%are CaO·SiO_(2),Na_(2)O·SiO_(2),FeO·SiO_(2),Ca_(3)Fe_(2)Si_(3)O_(12),CaAl_(2)SiO_6 and CaFe(SiO_(3))_(2).
基金financially supported by the Technology Program of Henan Province(No.202102210207)the National Key Research and Development Plan(No.2017YFB0305401)+2 种基金the National Natural Science Foundation of China(Nos.51422403 and 51774078)the Fundamental Research Funds for the Central Universities(Nos.N162505002,N172506009 and N170908001)the Key Science and Shenyang Science and Technology Project(No.17-500-8-01)。
文摘High ferrotitanium is used as a deoxidizer and alloying agent in steelmaking processes and is mainly produced using high-cost remelting processes.The thermite method is a simple and low-cost method for preparing low ferrotitanium.However,the high levels of S,Al,and O residues in the product severely restrict its applicability in the low-cost preparation of good-quality high ferrotitanium.In this study,a novel multistage deep reduction method for preparing high-quality high ferrotitanium is proposed,and the multistage desulfurization mechanism is systematically investigated.The results indicate that multistage desulfurization is an effective method for reducing the S content of high ferrotitanium prepared via the thermite method.During the strong desulfurization stage,Ti_(2)S reacts with CaO at the slag-metal interface and produces CaS.The S content decreases,while the O content increases,with the increase of CaO in the CaO-Al_(2)O_(3)-based slag.During the deep desulfurization,Ti_(2)S is deeply reduced by the Ca and produces CaS,thus further reducing the S content.The S content decreases with the incremental addition of Ca and can be reduced to 0.035 wt%after multistage desulfurization.