Joint Noise Reduction and lp-Norm Minimization for Enhancing Time Delay Estimation in Colored Noise

Time delay estimation (TDE) is an important issue in signal processing. Conventional TDE algorithms are usually efficient under white noise environments. In this paper, a joint noise reduction and -norm minimization method is presented to enhance TDE in colored noise. An improved subspace method for colored noise reduction is first performed. Then the time delay is estimated by using an -norm minimization method. Because the clean speech signal form the noisy signal is well extracted by noise reduction and the -norm minimization method is robust, the TDE accuracy can be enhanced. Experiment results confirm that the proposed joint estimation method obtains more accurate TDE than several conventional algorithms in colored noise, especially in the case of low signal-to-noise ratio.

Low overhead design-for-testability for scan-based delay fault testing

An efficient design-for-testability （DFT） technique is proposed to achieve low overhead for scan-based delay fault testing. Existing techniques for delay test such as skewed-load or broadside make the test generation process complex and produce lower coverage for scan-based designs as compared with non-scan designs, whereas techniques such as enhanced-scan test can make the test easy but need an extra holding latch to add substantial hardware overhead. A new tri-state holding logic is presented to replace the common holding latch in enhanced-scan test to get a substantial low hardware overhead. This scheme can achieve low delay overhead by avoiding the holding latch on the critical timing scan path. What＇s more, this method can also keep the state and signal activity in the combinational circuit from the scan during data scan-in operation to reduce the power dissipation. Experiment results on a set of ISCAS89 benchmarks show the efficiency of the proposed scheme.

Stability and oscillations in a slow-fast flexible joint system with transformation delay

Flexible joints are usually used to transfer velocities in robot systems and may lead to delays in motion transformation due to joint flexibility. In this paper, a linkrotor structure connected by a flexible joint or shaft is firstly modeled to be a slow-fast delayed system when moment of inertia of the lightweight link is far less than that of the heavy rotor. To analyze the stability and oscillations of the slowfast system, the geometric singular perturbation method is extended, with both slow and fast manifolds expressed analytically. The stability of the slow manifold is investigated and critical boundaries are obtained to divide the stable and the unstable regions. To study effects of the transformation delay on the stability and oscillations of the link, two quantitatively different driving forces derived from the negative feedback of the link are considered. The results show that one of these two typical driving forces may drive the link to exhibit a stable state and the other kind of driving force may induce a relaxation oscillation for a very small delay. However, the link loses stability and undergoes regular periodic and bursting oscillation when the transformation delay is large. Basically, a very small delay does not affect the stability of the slow manifold but a large delay affects substantially.

Sixty-four MDCT achieves higher contrast in pancreas with optimization of scan time delay

AIM: To compare different multidetector computed tomography (MDCT) protocols to optimize pancreatic contrast enhancement. METHODS: Forty consecutive patients underwent contrast-enhanced biphasic MDCT (arterial and portalvenous phase) using a 64-slice MDCT. In 20 patients, the scan protocol was adapted from a previously used 40-channel MDCT scanner with arterial phase scanning initiated 11.1 s after a threshold of 150 HU was reached in the descending aorta, using automatic bolus tracking (Protocol 1). The 11.1-s delay was changed to 15 s in the other 20 patients to reflect the shorter scanning times on the 64-channel MDCT compared to the previous 40-channel system (Protocol 2). HU values were measured in the head and tail of the pancreas in the arterial and portal-venous phase. RESULTS: Using an 11.1-s delay, 74.2 HU (head) were measured on average in the arterial phase and 111.2 HU (head) were measured using a 15-s delay (P <0.0001). For the pancreatic tail, the average attenuation level was 76.73 HU (11.1 s) and 99.89 HU (15 s) respectively (P = 0.0002). HU values were also significantly higher in the portal-venous phase [pancreatic head: 70.5 HU (11.1 s) vs 84.0 HU (15 s) (P = 0.0014); pancreatic tail: 67.45 HU (11.1 s) and 77.18 HU (15 s) using Protocol 2 (P = 0.0071)]. CONCLUSION: Sixty-four MDCT may yield a higher contrast in pancreatic study with (appropriate) optimization of scan delay time.

Effects of information transmission delay and channel blocking on synchronization in scale-free Hodgkin-Huxley neuronal networks

In this paper,we investigate the evolution of spatiotemporal patterns and synchronization transitions in dependence on the information transmission delay and ion channel blocking in scale-free neuronal networks.As the underlying model of neuronal dynamics,we use the Hodgkin-Huxley equations incorporating channel blocking and intrinsic noise.It is shown that delays play a significant yet subtle role in shaping the dynamics of neuronal networks.In particular,regions of irregular and regular propagating excitatory fronts related to the synchronization transitions appear intermittently as the delay increases.Moreover,the fraction of working sodium and potassium ion channels can also have a significant impact on the spatiotemporal dynamics of neuronal networks.As the fraction of blocked sodium channels increases,the frequency of excitatory events decreases,which in turn manifests as an increase in the neuronal synchrony that,however,is dysfunctional due to the virtual absence of large-amplitude excitations.Expectedly,we also show that larger coupling strengths improve synchronization irrespective of the information transmission delay and channel blocking.The presented results are also robust against the variation of the network size,thus providing insights that could facilitate understanding of the joint impact of ion channel blocking and information transmission delay on the spatiotemporal dynamics of neuronal networks.

Luminescent properties of thermally activated delayed fluorescence molecule with intramolecular π-π interaction between donor and acceptor

Influence of intramolecular π-π interaction on the luminescent properties of thermally activated delayed fluorescence（TADF） molecule（3, 5-bis（3,6-di-tert-butyl-9 H-carbazol-9-yl）-phenyl）（pyridin-4-yl） methanone（DTCBPY） is theoretically studied by using the density functional theory（DFT） and time-dependent density functional theory（TD-DFT）.Four conformations（named as A, B, C, and D） of the DTCBPY can be found by relax scanning, and the configuration C corresponds to the luminescent molecule detected experimentally. Besides, we calculate the proportion of each conformation by Boltzmann distribution, high configuration ratios（44% and 52%） can be found for C and D. Moreover, C and D are found to exist with an intramolecular π-π interaction between one donor and the acceptor; the intramolecular interaction brings a smaller Huang-Rhys factor and reduced reorganization energy. Our work presents a rational explanation for the experimental results and demonstrates the importance of the intramolecular π-π interaction to the photophysical properties of TADF molecules.

Time-resolution enhanced multi-path OTD measurement using an adaptive filter based incoherent OFDR

High accuracy and time resolution optical transfer delay(OTD)measurement is highly desired in many multi-path applications,such as optical true-time-delay-based array systems and distributed optical sensors.However,the time resolution is usually limited by the frequency range of the probe signal in frequency-multiplexed OTD measurement techniques.Here,we proposed a time-resolution enhanced OTD measurement method based on incoherent optical frequency domain reflectometry(I-OFDR),where an adaptive filter is designed to suppress the spectral leakage from other paths to break the resolution limitation.A weighted least square(WLS)cost function is first established,and then an iteration approach is used to minimize the cost function.Finally,the appropriate filter parameter is obtained according to the convergence results.In a proof-of-concept experiment,the time-domain response of two optical links with a length difference of 900 ps is successfully estimated by applying a probe signal with a bandwidth of 400 MHz.The time resolution is improved by 2.78times compared to the theoretical resolution limit of the inverse discrete Fourier transform(iDFT)algorithm.In addition,the OTD measurement error is below±0.8 ps.The proposed algorithm provides a novel way to improve the measurement resolution without applying a probe signal with a large bandwidth,avoiding measurement errors induced by the dispersion effect.

有线-无线网络中TFRC丢包区法算法研究

TCP-Friendly Rate Control(TFRC)是一种专门针对多媒体流在Internet中传输的拥塞控制方案,而无线环境中存在的链路质量以及切换等问题严重影响该机制的性能。本文针对此问题,提出了利用有线-无线网络的AP动态地标记分组来区分丢包,并基于此设计了适合有线-无线网络的TFRC-enhance协议。通过NS的模拟验证,相对于其他的端到端丢包区分算法,本文提出的算法准确性更高,并能取得很好的性能。

CO_2-triggered gelation for mobility control and channeling blocking during CO_2 flooding processes

CO2 flooding is regarded as an important method for enhanced oil recovery （EOR） and greenhouse gas control. However, the heterogeneity prevalently dis- tributed in reservoirs inhibits the performance of this technology. The sweep efficiency can be significantly reduced especially in the presence of ＂thief zones＂. Hence, gas channeling blocking and mobility control are important technical issues for the success of CO2 injection. Normally, crosslinked gels have the potential to block gas channels, but the gelation time control poses challenges to this method. In this study, a new method for selectively blocking CO2 channeling is proposed, which is based on a type of CO2-sensitive gel system （modified polyacry- lamide-methenamine-resorcinol gel system） to form gel in situ. A CO2-sensitive gel system is when gelation or solidification will be triggered by CO2 in the reservoir to block gas channels. The CO2-sensitivity of the gel system was demonstrated in parallel bottle tests of gel in N2 and CO2 atmospheres. Sand pack flow experiments were con- ducted to investigate the shutoff capacity of the gel system under different conditions. The injectivity of the gel system was studied via viscosity measurements. The results indi- cate that this gel system was sensitive to CO2 and had good performance of channeling blocking in porous media. Advantageous viscosity-temperature characteristics were achieved in this work. The effectiveness for EOR in heterogeneous formations based on this gel system was demonstrated using displacement tests conducted in double sand packs. The experimental results can provide guideli- nes for the deployment of theCO2-sensitive gel system for field applications.

Remarkable mechanochromism and force-induced thermally activated delayed fluorescence enhancement from white-light-emitting organic luminogens with aggregation-induced emission

The development of organic materials with white-light emission and thermally activated delayed fluorescence(TADF)properties in the solid state remain a challenge.Herein,a series of white-light-emitting organic luminogens have been developed and are found to show aggregation-induced delayed fluorescence(AIDF)characteristics.The AIDF emitters present dual-emission consisted of prompt fluorescence and TADF in the crystalline state.Their white-light emissions can be easily tuned by altering the chemical structure and connecting position of the heterocyclic aromatic substituent.Under the stimuli of mechanical force and solvent vapor,the compounds exhibit remarkable and reversible mechanochromism,in which their emission colors are switchable between white and yellow.Upon grinding,they also display linearly tunable luminescence colors,as well as force-induced TADF enhancement,which may be associated with the more compact molecular packing and the restriction of intramolecular motions.The results from time-resolved emission scanning and theoretical calculation suggest that the dual-emission of the AIDF luminogens likely results from the twisted intramolecular charge transfer transitions of the molecules,and the reversible mechanochromism properties probably stem from the interconversion of the quasi-axial and the quasi-equatorial conformations.

时延QoS保证的D2D-based V2V车载通信功率分配方案

OFDMA蜂窝网络中采用Underlay模式的基于终端直通技术的车-车(D2D-based V2V)通信能够提高频谱利用率、增大系统吞吐量,但随之产生的同频干扰问题严重影响通信质量。为了解决该问题,同时满足车辆通信的低时延服务质量(QoS)需求,提出一种基于时延QoS保证的D2D-based V2V车载通信功率分配方案。该方案同时考虑了蜂窝用户和D2D-based V2V用户所受到的干扰,并采用有效容量提供QoS保障,通过拉格朗日对偶分解法求解优化问题。数值仿真表明,相比于其他方案,该方案能够很好地提高系统有效容量。

6-(N,N-Dimethylamino)-2-naphthoylacryl Acid:a Highly Selective and Sensitive Fluorescent Sensor of Copper(Ⅱ)

A novel fluorescent probe,6-（N,N-dimethylamino）-2-naphthoylacryl acid（ACADAN） was designed and synthesized as a fluorescent sensor for Cu^2＋ in aqueous media.Significant amplification of fluorescence signals without causing any discernible change of maximum fluorescence emission wavelength（λ max） was observed upon the addition of Cu^2＋.Importantly,ACADAN is capable of recognizing Cu^2＋ selectively in aqueous media in the presence of various biologically relevant metal ions and the prevalent toxic metal ions in the environment with high sensitivity（detection limit was 0.1 μmol/L）.

Regulated CO adsorption by the electrode with OH^(-) repulsive property for enhancing C–C coupling

Electrochemical CO_(2) reduction driven by renewable electricity is one of the promising strategies to store sus-tainable energy as fuels.However,the selectivity of value-added multi-carbon products remains poor for further application of this process.Here,we regulate CO adsorption by forming a Nafion layer on the copper(Cu)electrode that is repulsive to OH^(-),contributing to enhanced selectivity of CO_(2) reduction to C_(2) products with the suppression of C 1 products.The operando Raman spectroscopy indicates that the local OH^(-)would adsorb on part of active sites and decrease the adsorption of CO.Therefore,the electrode with repulsive to OH^(-)can adjust the concentration of OH^(-),leading to the increased adsorption of CO and enhanced C–C coupling.This work shows that electrode design could be an effective strategy for improving the selectivity of CO_(2) reduction to multi-carbon products.

Small-Space Microphone Array Fractional Delay Algorithm Based on FIR Filter for Cochlear Implant

Directional speech enhancement of signals from microphone arrays is an effective way to improve speech recognition for cochlear implant users. The strict implant size limitation results in a short distance between microphones. The fractional delay problem due to the short distance between microphones is solved by a maximal flat （Maxflat） finite impulse response （FIR） filter, using the Maxflat error criteria at a low frequency containing most of the speech information and energy. The fractional Maxfiat FIR filter approximates the ideal digital fractional filter at the magnitude response, phase response, and phase delay characteristics, and is also very low order. The results demonstrate that the Maxflat FIR filter accurately and effectively solves the fractional digital delay and is very suitable for real-time speech processing in practical cochlear implant products.

Extraction of Echo Characteristics of Underwater Target Based on Cepstrum Method

The analysis and characteristic extraction of target echo characteristics are important in underwater target detection and recognition. Rigid acoustic scattering components are generally used as major echo contributors with relatively stable characteristic information. Previous studies focus on echo characteristics from a single angle, thereby limiting the amount of extracted characteristic information. This paper aims to establish a full-angle rigid echo components model and overcome the difficulty of the extraction of time delay characteristics of narrow-band acoustic scattering echoes. On the basis of the analysis of the target echo highlight model, the echo characteristics of rigid acoustic scattering components are extracted in the cepstrum domain, and a wavelet process is proposed to enhance the effect of time delay estimation. Experimental data indicate that the extracted time delay characteristics accord with the rigid echo characteristics of underwater target, thereby validating the effectiveness of the cepstrum method.

Dissipative particle dynamics simulation of wettability alternation phenomena in the chemical flooding process

Wettability alternation phenomena is considered one of the most important enhanced oil recovery （EOR） mechanisms in the chemical flooding process and induced by the adsorption of surfactant on the rock surface. These phenomena are studied by a mesoscopic method named as dissipative particle dynamics （DPD）. Both the alteration phenomena of water-wet to oil-wet and that of oil-wet to water-wet are simulated based on reasonable definition of interaction parameters between beads. The wetting hysteresis phenomenon and the process of oil-drops detachment from rock surfaces with different wettability are simulated by adding long-range external forces on the fluid particles. The simulation results show that, the oil drop is liable to spread on the oil-wetting surface and move in the form of liquid film flow, whereas it is likely to move as a whole on the waterwetting surface. There are the same phenomena occuring in wettability-alternated cases. The results also show that DPD method provides a feasible approach to the problems of seepage flow with physicochemical phenomena and can be used to study the mechanism of EOR of chemical flooding.

STABILITY OF THE STOCHASTIC θ-METHOD FOR SUPER-LINEAR STOCHASTIC DIFFERENTIAL EQUATIONS WITH UNBOUNDED DELAY

This paper deals with numerical stability properties of super-linear stochastic differential equations with unbounded delay. Sufficient conditions for mean square and almost sure decay stability of the above system and its stochastic θ-method approximation are investigated in this paper. The author establishes numerical stability under a monotone-type condition in unbounded delay setting. An example is presented to illustrate the result.

Development and analysis of a novel AF11-2 aptamer capable of enhancing the fluorescence of aflatoxin B1

Aflatoxin B1(AFB1)is one of the most common mycotoxins that threatens human health.As singlestranded oligonucleotides with high affinity and specificity,aptamers have incomparable effect on the targeted detection of AFB1.Herein,after 11 rounds of selection and analysis using a modified affinity chromatography-based SELEX strategy,the truncated 37 nt aptamer AF11-2 was successfully obtained.The aptamer shows good detection performance for AFB1,and can sensitively detect AFB1 in the range of 100-1000 nmol/L,with a detection limit of 42 nmol/L.In the detection of pretreated edible peanut oil samples,AF11-2 aptamer also showed a high recovery rate and good stability for AFB1,and achieved satisfactory results.In addition,AF11-2 aptamer can significantly enhance the fluorescence ability of AFB1,which is not available in traditional Afla17-2-3 aptamer.After molecular docking analysis,it was found that AF11-2 and Afla17-2-3 had different nucleotide binding sites for AFB1.Afla17-2-3 binds to the carbonyl O of AFB1,while AF11-2 binds to the pyrrolic O of AFB1,which may be the main reason that AF11-2 can enhance the fluorescence of AFB1.

Enhanced adsorption behavior of Nd(III) onto D113-III resin from aqueous solution

An enhanced adsorption and desorption procedure of Nd（Ⅲ） onto D113-Ⅲ resin were prepared with various chemical methods. Batch studies were carried out with various pH, contact time, temperature and initial concentrations, and then column studies were conducted. The results showed that the optimal adsorption condition was at pH value of 6.90. The process was fast initially and arrived equilibrium within 60 h. The resin exhibited a high Nd（Ⅲ） uptake as 232.56 mg/g at 298 K. The adsorption data fitted well with pseudo-second-order kinetic model. Thermodynamic parameters were studied, which indicated that the adsorption process was spontaneous and endothermic. Thomas model was delineated here to predict the breakthrough curves based on the experimental column study data. In the elution test, 1 mol/L HCl solution could achieve a satisfactory elution rate, which indicated that D113-1/1 resin could be regenerated and reused. Finally, the IR spectroscopic technique was undertaken, and a novel adsorption mechanism was proposed.

W^(1,2)(Ω)-and X^(1,2)(Ω)-stability of reactiondiffusion cellular neural networks with delay

With Poincare＇s inequality and auxiliary function applied in a class of retarded cellular neural networks with reaction-diffusion, the conditions of the systems＇ W^1,2（Ω）-exponential and X^1,2（Ω）-asmptotic stability are obtained. The stability conditions containing diffusion term are different from those obtained in the previous papers in their exponential stability conditions. One example is given to illustrate the feasibility of this method in the end.