The action mechanisms and structures designs of F-containing functional materials for high performance oxygen electrocatalysis

Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.

The Most Probable Mechanism Function and Kinetic Parameters of Gibbsite Dissolution in NaOH

Determination of probable mechanism function and kinetic parameters is important to hydrometallurgical kinetics.In this work,the most probable mechanism function and kinetic parameters of gibbsite dissolution in NaOH solution are studied.The sample,the mixture of synthetic gibbsite and sodium hydroxide solution,was scanned in high-pressure differential scanning calorimetry(DSC) equipment with the heating rate of 10 K·min-1. Integral equation and differential equation of non-isothermal kinetics were solved to fit the data related to DSC curve.According to the calculation results,the most probable mechanism function for pure synthetic gibbsite dissolution in sodium hydroxide solution is presented based on the optimum procedure in the database of the mechanism function.The apparent activation energy obtained is(75±1) kJ·mol-1,the frequency factor is 10 8±1mol·s-1,and the reaction is a second order reaction.

A PENALTY FUNCTION METHOD FOR THE PRINCIPAL-AGENT PROBLEM WITH AN INFINITE NUMBER OF INCENTIVE-COMPATIBILITY CONSTRAINTS UNDER MORAL HAZARD

In this paper,we propose an iterative algorithm to find the optimal incentive mechanism for the principal-agent problem under moral hazard where the number of agent action profiles is infinite,and where there are an infinite number of results that can be observed by the principal.This principal-agent problem has an infinite number of incentive-compatibility constraints,and we transform it into an optimization problem with an infinite number of constraints called a semi-infinite programming problem.We then propose an exterior penalty function method to find the optimal solution to this semi-infinite programming and illustrate the convergence of this algorithm.By analyzing the optimal solution obtained by the proposed penalty function method,we can obtain the optimal incentive mechanism for the principal-agent problem with an infinite number of incentive-compatibility constraints under moral hazard.

Multiple-response optimization for melting process of aluminum melting furnace based on response surface methodology with desirability function

To reduce the fuel consumption and emissions and also enhance the molten aluminum quality, a mathematical model with user-developed melting model and burning capacity model, were established according to the features of melting process of regenerative aluminum melting furnaces. Based on validating results by heat balance test for an aluminum melting furnace, CFD （computational fluid dynamics） technique, in association with statistical experimental design were used to optimize the melting process of the aluminum melting furnace. Four important factors influencing the melting time, such as horizontal angle between burners, height-to-radius ratio, natural gas mass flow and air preheated temperature, were identified by PLACKETT-BURMAN design. A steepest descent method was undertaken to determine the optimal regions of these factors. Response surface methodology with BOX-BEHNKEN design was adopted to further investigate the mutual interactions between these variables on RSD （relative standard deviation） of aluminum temperature, RSD of furnace temperature and melting time. Multiple-response optimization by desirability function approach was used to determine the optimum melting process parameters. The results indicate that the interaction between the height-to-radius ratio and horizontal angle between burners affects the response variables significantly. The predicted results show that the minimum RSD of aluminum temperature （12.13%）, RSD of furnace temperature （18.50%） and melting time （3.9 h） could be obtained under the optimum conditions of horizontal angle between burners as 64°, height-to-radius ratio as 0.3, natural gas mass flow as 599 m3/h, and air preheated temperature as 639 ℃. These predicted values were further verified by validation experiments. The excellent correlation between the predicted and experimental values confirms the validity and practicability of this statistical optimum strategy.

MODAL PARAMETERS EXTRACTION WITH CROSS CORRELATION FUNCTION AND CROSS POWER SPECTRUM UNDER UNKNOWN EXCITATION

In most of real operational conditions only response data are measurable while the actual excitations are unknown, so modal parameter must be extracted only from responses. This paper gives a theoretical formulation for the cross-correlation functions and cross-power spectra between the outputs under the assumption of white-noise excitation. It widens the field of modal analysis under ambient excitation because many classical methods by impulse response functions or frequency response functions can be used easily for modal analysis under unknown excitation. The Polyreference Complex Exponential method and Eigensystem Realization Algorithm using cross-correlation functions in time domain and Orthogonal Polynomial method using cross-power spectra in frequency domain are applied to a steel frame to extract modal parameters under operational conditions. The modal properties of the steel frame from these three methods are compared with those from frequency response functions analysis. The results show that the modal analysis method using cross-correlation functions or cross-power spectra presented in this paper can extract modal parameters efficiently under unknown excitation.

Parallel Minimax Searching Algorithm for Extremum of Unimodal Unbounded Function

In this paper we consider a parallel algorithm that detects the maximizer of unimodal function f(x) computable at every point on unbounded interval (0, ∞). The algorithm consists of two modes: scanning and detecting. Search diagrams are introduced as a way to describe parallel searching algorithms on unbounded intervals. Dynamic programming equations, combined with a series of liner programming problems, describe relations between results for every pair of successive evaluations of function f in parallel. Properties of optimal search strategies are derived from these equations. The worst-case complexity analysis shows that, if the maximizer is located on a priori unknown interval (n-1], then it can be detected after cp(n)=「2log「p/2」+1(n+1)」-1 parallel evaluations of f(x), where p is the number of processors.

In-Plane and Out-of-Plane Mechanical Properties of Zero Poisson’s Ratio Cellular Structures for Morphing Application

Intelligent structures like zero Poisson’s ratio(ZPR)cellular structures have been widely applied to the engineering fields such as morphing wings in recent decades,owing to their outstanding characteristics including light weight and low effective modulus. In-plane and out-of-plane mechanical properties of ZPR cellular structures are investigated in this paper. A theoretical method for calculating in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus of ZPR cellular structures is proposed,and the impacts of the unit cell geometrical configurations on in-plane tensile modulus,in-plane shear modulus and out-of-plane bending modulus are studied systematically based on finite element(FE)simulation. Experimental tests validate the feasibility and effectiveness of the theoretical and FE analysis. And the results show that the in-plane and out-of-plane mechanical properties of ZPR cellular structures can be manipulated by designing cell geometrical parameters.

OPTIMIZING THE DESIGN PARAMETER OF MINE DYNAMIC SYSTEM

The main contests of mire optimization design includes: mine field size, borizon and level height, mumber, shaft form and development disposal and so on. In this paper, based on mine dynamic analysis, the index function model of mine different development stage is built up,applying dynamic programming method to find the solution of system’s optimum value,which makes the optimized result of mine dynamic design parameter more comprehensive, sysematical and reasonable. Through theory analysis research and practical validation, the obtained design parameters are reasonable and accurate.

Establishment of Knowledge Base Management System and the Type Selection of Mechanism for Mechanism Kinematic Scheme

Firstly data standardization technology and combined classification method have been applied to carry out classification of kinematic behaviors and mechanisms in the mapping field between the kinematic behavior level and the mechanism level of conceptual design.The principle of computer coding and storing have been built to give a fast and broad selection of mechanisms that meets the requirements of basic motion characters.Then on the basis of mentioned above,the heuristic matching propagation principle (HMPP) of kinematic behaviors and its true table serves as a guide to perform mechanism types selection.Finally an application is given to indicate its practicability and effectiveness.

Source Characteristics of the 2012 Ahar-Varzaghan Earthquake

The August 11, 2012 Mw 6.4 earthquakes in northwestern Iran occurred as a result of oblique strike-slip faulting in the shallow crust of the Eurasia plate, approximately 300 kilometer east of the plate boundary between the Eurasia and Arabia plates. The seismotectonics of this region is controlled by the collision of the Arabia and Eurasia plates;at the latitude of the earthquakes, the Arabia plate moves almost due north with respect to the Eurasia plate at a rate of approximately 26 millimeter per year. Over the past forty years, seven earthquakes of Mw 6 or greater have occurred within 300 kilometer of today’s events. The nearest was a Mw 6.1 earthquake in February of 1997, approximately 100 kilometer to the east, which caused 1100 fatalities. The studied area encourage the authors to determine the focal mechanism, source time function and sub events’ features which can guide us to reliable judges.

考虑锚杆预应力作用下隧道围岩力学分析及参数设计

隧道工程中锚杆设计多依靠经验法和类比法,为研究预应力锚杆支护体系下围岩的力学效应,建立预应力锚杆与围岩力学耦合模型,考虑围岩开挖损伤效应,通过弹塑性力学理论推导出隧道开挖后围岩应力分布及径向位移解析表达式,采用有限差分软件FLAC3D进行算例验证并分析预应力锚杆参数对围岩状态的影响。研究结果表明:理论解析和数值模拟中最大切向应力和围岩塑性区半径分别为4.77 MPa、15 m和4.49 MPa、15.86 m,理论解析与数值模拟所计算隧道围岩应力分布、位移基本一致,在Ⅳ、Ⅴ级围岩地层中验证了理论解析解的合理性;随着预紧力增大,处于塑性区的围岩径向位移及塑性区半径逐渐减小,弹性区基本不受影响;当锚杆自由段长度位于塑性区时,随着锚杆长度增加,围岩塑性区径向位移及塑性区半径逐渐减小。在实际工程中应尽量增大锚杆预紧力,锚杆长度增加对围岩位移以及塑性区的发展控制效果有限,应控制锚杆自由段长度在塑性区内。

The Principle of Square Hole Machining and It＇s Tooling Structure Design

In order to meet the rapid needs of processing square hole in mechanical equipment, the paper expounds the square hole processing method： planetary wheel method, and analyze the principle of tooling structure and process with computer graphics parameters design. The results that, as long as the appropriate parameters, using the above method not only can punch the square hole, can also be processed triangle, the five angle and hexagonal regular polygon holes. The square hole processing method can provide theoretical basis and engineering reliable reference for related engineering and technical personnel.

基于热分解的舰用复合材料S2/430LV热工参数

为了研究S2/430LV在热分解前后的热工参数,首先利用热重分析仪对氮气环境中S2/430LV复合材料和430LV树脂进行30~800℃环境下热重试验,分析了两种材料在不同升温速率下热分解响应特征;然后,基于阿伦尼乌斯方程,采用微分法与积分法相结合的方法,确定了S2/430LV热分解动力学参数。研究结果表明:430LV树脂和S2/430LV复合材料在氮气环境中均呈现单一热分解过程,纤维织物会促进430LV树脂基体热分解反应;采用Kissinger方程和Flynm-Wall-Ozawa方程确定S2/430LV活化能取值范围;利用Coats-Redfern方程确定S2/430LV最优热分解机理函数和指前因子,从而建立分解率和温度的函数关系式;采用混合定律,建立了考虑材料分解的热工参数模型。研究结果可为舰艇复合材料结构耐火传热性能研究提供有效数据支撑。

楔横轧齿轮轴轴齿一体化成形机理研究

为实现齿轮轴短流程高效精确制造,本文创新了楔横轧齿轮轴一体化成形方法。在分析齿形塑性成形原理基础上,综合出加工模具的主要参数,得出了满足分齿条件的参数公式,设计出齿轮轴楔横轧模具;通过Deform软件对齿形模具进入加工过程的阶段进行了仿真,得到齿形模具于阶梯轴第1阶段展宽段进入加工成品质量最佳。在此基础上进行仿真,分析其应力场、应变场以及温度场,进而阐明齿轴一体化楔横轧成形机理。仿真与实验结果比较表明:误差在8.2%以下,验证了仿真结果的可靠性。本文研究结果为实现齿轴一体化精确短流程成形奠定了理论基础。

面向充电桩时间分配的在线双边拍卖机制设计

随着新能源汽车的快速发展,充电时间分配问题成为关注的焦点。现有研究主要集中在根据预先规划的驾驶路线选择充电桩,但对于车主的动态需求却没有提供即时解决方案。为解决该问题,文章首先根据车主的需求量、地理位置以及充电完成度等因素设计了一种需求者优先级函数,然后将充电桩的时间分配问题建模为密封竞价在线双边拍卖,在此基础上,提出了一种真实的交易机制。理论分析证明了该机制不仅满足个体理性、预算平衡,还能够引导供需双方报告真实的到达离开时间以及物品估值。最后通过具体的实验证明了该拍卖机制的实用性和有效性。所提出拍卖机制满足双边市场中交易个体的属性偏好和在线环境的交易特征,为当前的在线充电平台提供了有益的参考。

基于机理仿真的抽油机有杆泵举升系统生产参数优化设计

基于传统经验法和预测模型法的抽油机有杆泵举升系统设计方法在实际应用中要么过于简单要么过于复杂,设计方案的可靠性还有待提升。因此,应用大数据驱动技术从海量抽油机井举升系统设计方案中探索规律,推荐以提高产量和节能降耗为目标的抽汲参数优化设计最优方案,将提升抽油机井举升系统设计方法的科学性和可操作性。文章分析了抽油机井产量主控因素,将软件仿真和现场获取的抽油机井举升系统设计样本进行聚类分析融合得到新的样本库,建立了抽油机井举升系统设计方案的深度学习模型,研究了基于匹配算法的方案相似度模型,开发了抽油机井有杆泵举升系统生产参数设计推荐系统。根据实例计算验证,该系统能够根据待设计井的地质特征和开发特征,从海量样本中匹配到与地质油藏条件相似度高且运行效果良好的举升设计方案,推荐方案的举升参数及举升效果与原有方案相比有较大的提升,证明了计算模型的实际可行性,为抽油机举升系统优化设计提供了新思路及方法。

开采沉陷动态预测时间函数参数变化规律研究——以Weibull为例

针对开采沉陷动态预测模型中时间函数参数主要以最大下沉点的下沉时间序列为基础反演获取,在工作面上方空间位置变化规律研究不足的问题;依据工作面推进过程中覆岩受力、垮落情况,在平面方向上将采空区分为竖向整体受压区、中间区、动态完全区3个区间;以Weibull时间函数为例,分析了动态预测m、k 2个参数的含义、空间分布规律及特点,并构建2个参数的分区数学模型及选取准则;分别以实测最终值、概率积分法预测值为基准,通过实例验证了其正确性,丰富了开采沉陷动态预测参数研究。

2-DOF并联行程放大机构结构参数优化

为研制一种能实现快速行走、运动灵活性好的仿生四足机器人,对一种能够实现机构末端位置行程放大的2自由度并联机构进行运动性能分析与结构参数优化,并将优化结果应用到仿生四足机器人的腿部机构,研制出样机。首先,推导2自由度并联行程放大机构位置反解,建立机构的线速度雅克比矩阵,对机构的工作空间进行分析。其次,建立机构运动灵活性能评价指标,揭示主要结构参数对灵活性能指标的影响规律。然后,采用容限加权法确定一组合理的结构参数,使运动灵活性能指标达到最优。最后,根据优化的结构参数设计出仿生四足机器人腿部机构和整体的虚拟样机,并进行虚拟样机运动仿真。仿真结果表明:并联行程放大机构各驱动参数变化平稳,理论速度和仿真速度误差在±1.6×10-6m/s范围内,验证仿生四足机器人腿部机构设计方案和结构参数的合理性及理论推导的正确性,为该仿生四足机器人的进一步研究奠定了基础。

振荡浮子式波能装置的功率计算分析及参数设计

波浪能是重要的可再生资源之一,提高波浪能装置的能量捕获率是波浪能规模化利用的关键。本文对波浪能的能量转换装置进行了研究,针对装置于不同摇荡条件下的最大平均输出功率、最优阻尼系数及相关参数进行演化分析及求解。利用牛顿定律及质心系、转动惯量等建立二自由度、四自由度波浪能转换装置耦合运动模型,基于时间离散化的差分原理求解,同时采用模拟退火算法降低时间复杂度,提出了改良的粒子群算法,得到较为准确的结果,为实际工程中波浪能的高效采集提供思路和途径。