Influence of introducing Zr,Ti,Nb and Ce elements on externally solidified crystals and mechanical properties of high-pressure die-casting Al–Si alloy

High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.

Assessing efficacy of standard impregnation techniques on die-cast aluminum alloys using X-ray micro-CT

Utilizing lightweight Al alloys in various industrial applications requires achieving precise pressure tightness and leak requirements.Vacuum pressure impregnation(VPI)with thermosetting polymers is commonly used to address leakage defects in die-cast Al alloys.In this study,the efficacy of the VPI technique in sealing alloy parts was investigated using a combination of nondestructive micro X-ray computed tomography(micro XCT)and a standard leak test.The results demonstrate that the commonly used water leak test is insufficient for determining the sealing performance.Instead,micro XCT shows distinct advantages by enabling more comprehensive analysis.It reveals the presence of a low atomic number impregnates sealant within casting defects,which has low grey contrast and allows for visualizing primary leakage paths in 3D.The effective atomic number of impregnated resin is 6.75 and that of Al alloy is 13.69 by dual-energy X-ray CT.This research findings will contribute to enhancing the standard VPI process parameters and the properties of impregnating sealants to improve quality assurance for impregnation in industrial metals.

Effect of slow shot speed on externally solidified crystal,porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy

The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM)and laboratory computed tomography(CT).Results showed that the newly developed AlSi9MnMoV alloy exhibited improved mechanical properties when compared to the AlSi10MnMg alloy.The AlSi9MnMoV alloy,which was designed with trace multicomponent additions,displays a notable grain refining effect in comparison to the AlSi10MnMg alloy.Refining elements Ti,Zr,V,Nb,B promote heterogeneous nucleation and reduce the grain size of primaryα-Al.At a lower slow shot speed,the large ESCs are easier to form and gather,developing into the dendrite net and net-shrinkage.With an increase in slow shot speed,the size and number of ESCs and porosities significantly reduce.In addition,the distribution of ESCs is more dispersed and the net-shrinkage disappears.The tensile property is greatly improved by adopting a higher slow shot speed.The ultimate tensile strength is enhanced from 260.31 MPa to 290.31 MPa(increased by 11.52%),and the elongation is enhanced from 3.72%to 6.34%(increased by 70.52%).

“三创五育”背景下“双一流”高校本科人才培养的DIE模式初探及评价

针对新时代背景下“双一流”高校人才培养的发展需求,在“三创五育”理念指导下,解析基于产学研合作理论引入的DIE模式的内涵,系统阐述了DIE理念贯彻下的教学系统设计并付诸实践,旨在打破教学系、研究所、企业之间的壁垒,为学生学习、实践提供更多样化的渠道。问卷调查结果表明DIE模式在本科生团队协作、学术创造、自信心树立等方面有切实作用,为培养全面发展的高素质本科人才提供了参考。

Opportunities and challenges of Chinese die-casting market

The present status and perspectives of Chinese die-casting market were commented. In 2003, the total output of die castings in the whole country was 708000 tons, in which the outputs of Al-alloy, Zn-alloy, Mg-alloy, Cu-alloy die castings were 474600 tons, 222000 tons, 5800 tons, 5600 tons, respectively, each accounted for 67%, 31.35%, 0.85%, 0.8% of the total. The annual sale volume of die-casting machines was approximately 1800. And the gross output value of dies approached RMB 38 billion, in which die-casting dies accounted for about 10%. In the die-casting industry of the entire country, the foreign capital enterprises, public-run enterprises, township and village enterprises, private enterprises accounted for over 80% of the total die-casting enterprises. Super huge die-casting groups are forming.

Microstructure and mechanical properties of Mg-6Gd-3Y-0.5Zr alloy processed by high-vacuum die-casting

GW63K （Mg-6Gd-3Y-0.5Zr） magnesium alloys were prepared successfully by high-vacuum die-casting. Effects of fast shot speed and vacuum level on the grain size and mechanical properties of this alloy were studied. Microstructure of the alloys was analyzed by SEM, EDX and optical microscope （OM）. The effect of heat treatment on high vacuum die-casting （HVDC） GW63K alloy was also studied. The results indicate that with the increase of fast velocity, the tensile yield strength hardly changes, but the elongation first increases, then decreases. The optimum heat treatment process is solution treatment at 748 K for 2 h and aging at 473 K for 80 h. Under this condition, GW63K magnesium alloy exhibits a maximum tensile strength and elongation of 308 MPa and 9.45%. There is significant correlation between ductility and the presence of external solidified cells （ESCs）. The as-cast GW63K alloy consists ofα-Mg and Mg24（Gd,Y）5 particles. After heat treatment, Gd and Y atoms dissolve intoα-Mg matrix.

Development of vacuum die-casting process

The vacuum die-casting process,started 25 years ago in Japan,has been widely applied.This technology contributes very much to improvement of castings quality.The main factor causing the defects of die castings is the trapped air in the mold cavity,while the key technology of vacuum die-casting process is to avoid the trapped air effectively by evacuating the cavity before casting.At the same time,due to the shot speed and the casting pressure reduced in half,the service life of the die is prolonged and the productivity is enhanced,as well.Vacuum die-casting process is of great signif icance in improving the die castings quality and making up the shortcomings of super-high-speed shot casting.

A review of magnesium die-castings for closure applications

Vehicle mass reduction in the automotive industry has become an industry-wide objective.Increasing fuel efficiency and greenhouse gas emission targets for engine-powered vehicles,and ambitions for extended range electric vehicles have motivated these reductions in vehicle mass.Mass reduction opportunities in structural automotive applications are increasingly realized through lightweight alloy castings,such as magnesium,primarily due to the ease of component substitution.The traditional benefits of magnesium die-castings including lightweighting and associated compounded mass savings,excellent strength-to-weight ratio,part consolidation,near net-shape forming,dimensional repeatability,and integration of additional components can be realized in closure applications.One recent example is the application of a magnesium die-casting for the structural inner of the liftgate in the 2017 Chrysler Pacifica,replacing nine parts in the previous generation and resulting in a liftgate assembly weight reduction of nearly 50%.The work presented here reviews past and current developments of magnesium die-castings in closure applications and discusses the benefits and challenges of magnesium alloys for these applications,including casting design,corrosion and fastening strategies,and the manufacturing design and assembly methodologies.

Numerical simulation of low pressure die-casting aluminum wheel

The FDM numerical simulation software,ViewCast system,was employed to simulate the low pressure die casting(LPDC)of an aluminum wheel.By analyzing the mold-filling and solidification stage of the LPDC process,the distribution of liquid fraction,temperature field and solidification pattern of castings were studied.The potential shrinkage defects were predicted to be formed at the rim/spoke junctions,which is in consistence with the X-ray detection result.The distribution pattern of the defects has also been studied.A solution towards reducing such defects has been presented.The cooling capacity of the mold was improved by installing water pipes both in the side mold and the top mold.Analysis on the shrinkage defects under forced cooling mode proved that adding the cooling system in the mold is an effective method for reduction of shrinkage defects.

Simulation of α-Al grain formation in high vacuum die-casting Al-Si-Mg alloys with multi-component quantitative cellular automaton method

Al-Si-Mg alloys are the most commonly used material in high vacuum die-casting(HVDC),in which the morphology and distribution ofα-Al grains have important effect on mechanical properties.A multi-component quantitative cellular automaton(CA)model was developed to simulate the microstructure and microsegregation of HVDC Al-Si-Mg alloys with different Si contents(7%and 10%)and cooling rates during solidification.The grain number and average grain size with electron backscatter diffraction(EBSD)analysis were used to verify the simulation.The relationship between grain size and nucleation order as well as nuclei density was investigated and discussed.It is found that the growth of grains will be restrained in the location with higher nuclei density.The influence of composition and cooling rate on the solute transport reveals that for AlSi7Mg0.3 alloy the concentration of solute Mg in liquid is higher at the beginning of eutectic solidification.The comparison between simulation and experiment results shows that externally solidified crystals(ESCs)have a significant effect for samples with high cooling rate and narrow solidification interval.

Re-evaluation of the mechanical properties and creep resistance of commercial magnesium die-casting alloy AE44

This paper presents a re-evaluation of the room temperature mechanical properties and high temperature creep resistance of magnesium die-casting alloy AE44(Mg-4Al-4RE)in light of the influence of minor Mn addition.It is shown that the Mn-containing AE44 exhibits distinct age hardening response upon direct ageing(T5)due to the precipitation of nanoscale Al-Mn particles,as reported previously in a similar alloy.The T5 ageing leads to a significant improvement in strength with similar ductility.Consequently,the T5-aged AE44 has a remarkably better strength-ductility combination than most Mg die-casting alloys and even the Al die-casting alloy A380.Minor Mn addition is also shown to be critical for the creep resistance of AE44 whereas the influence of the RE constituent is not as significant as previously thought,which reaffirms that precipitation hardening of theα-Mg matrix is more important than grain boundary reinforcement by intermetallic phases for the creep resistance of die-cast Mg alloys.The findings in this work could provide new application perspectives for AE44,particularly in the automotive industry.

Mold Filling and Prevention of Gas Entrapment in High-pressure Die-casting

This paper presents some results of direct observation of mold filling in a specially designed die-casting by X-ray diffraction, including comparison with numerical simulation. Based on such work the authors discuss how to prevent gas entrapment and propose new methods.

Thin-Wall Aluminum Die-Casting Technology for Development of Notebook Computer Housing

Silicon-based aluminum casting alloys are known to be one of the most widely used alloy systems mainly due to their superior casting characteristics and unique combination of mechanical and physical properties. However,manufacturing of thin-walled aluminum die-casting components,less than 1.0 mm in thickness,is generally known to be very difficult task to achieve aluminum casting alloys with high fluidity.Therefore,in this study,the optimal die-casting conditions for producing 297 mm×210 mm×0.7 mm thin-walled aluminum component was examined experimentally by using 2 different gating systems,tangential and split type,and vent design.Furthermore,computational solidification simulation was also conducted.The results showed that split type gating system was preferable gating design than tangential type gating system at the point of view of soundness of casting and distortion generated after solidification.It was also found that proper vent design was one of the most important factors for producing thin-wall casting components because it was important for the fulfillment of the thin-wall cavity and the minimization of the casting distortion.

Effect of different processing parameters on interfacial heat-transfer behavior in high-pressure die-casting process

Vacuum die casting can reduce the'air entrapment'phenomenon during casting process.Based on the temperature measurements at metal-die interface with different processing parameters,such as slow shot speed(VL),high shot speed(VH),pouring temperature(Tp)and initial die temperature(Tm),inverse method was developed to determine the interfacial heat transfer coefficient(IHTC).The results indicate that a closer contact between the casting and die could be achieved when the vacuum system is used.It is found that the vacuum could strongly increase the values of IHTC and decrease the grain size in castings.The IHTC could have a higher peak value with increasing the Tp from680to720℃or the VL from0.1to0.4m/s.In addition,the influence of the VH and Tm on IHTC could be negligible.

Effect of Adding Extruded Mg-Mischmetal Intermediate Alloy on Microstructure and Properties of Die-Casting Magnesium Alloy AZ91D

The preparation techniques of Mg-mischmetal intermediate alloy and the effects of the mischmetal addition ranging from 0.45% to 1.04% on the microstructure and properties of AZ91D alloy prepared by die casting were investigated. The Mg-MM intermediate alloy was prepared by permanent mold casting and then was extruded into the bars. The microstructure and analytical studies were carried out using optical microscopy and differential scanning calorimetry (DSC). Testing results shows the Mg-MM intermediate alloy could melt easily down at die casting temperature of 680 ℃ that was lower than the melting point of lanthanum (918 ℃) and that of cerium (798 ℃). This was propitious to protection the alloy from the oxidation at high temperatures. Then magnesium alloy test bars were produced under conventional cold chamber die casting condition with addition of different weight of the Mg-MM intermediate alloy. Observation and analysis indicated that the microstructures of the alloy were refined and RE containing Al phase was formed with increasing RE addition. The data obtained by tensile tests showed that alloying with mischmetal improved the tensile property of the AZ91D magnesium die casting alloy at ambient temperature.

Different aging behaviors at surface layer and central region of a die-casting A380 alloy during heat treatment

Microstructural and hardness evolutions of a vacuum-assistant die-cast A380(Al-8.67 wt.%Si-3.27 wt.%Cu) alloy during heat treatment were investigated. Isothermal DSC test at 200 °C revealed that the precipitation reaction in the surface layer was faster than that in the central region. This corresponded with the hardness evolution that the surface layer hardened faster. The hardness increment in the surface layer was higher than that in the central region. Further experimental evidences indicated that the differences were due to the different amounts of heterogeneous nucleation sites for precipitation in the two parts. The influence of the characteristic as-cast microstructure on the artificial aging process is analyzed and discussed in detail.

Development and Application of Die-Casting High Speed Steel Rolls

Due to its high hardness,good red hardness and excellent wear resistance at high temperature,high speed steel(HSS)is fit for the roll manufacture.In order to overcome the segregation of centrifugal casting of HSS roll,die-cast processes were developed and its effects on the properties of the HSS roll were investigated.It was found that pressure,pressing time and speed are three important factors affecting shrinkage cavity.For pouring temperature of 1 400-1 450 ℃,pressure of 150-160 MPa,pressing time of 120-150 sand pressing speed of 14-16mm/s,a compact HSS roll was obtained,which has no segregation and small working allowance.In the high speed wire rod rolling mill,service life of the HSS roll is 5to 8times longer than that of high nickel chromium infinite chilled cast iron roll.

Thin-walled and large-sized magnesium alloy die castings for passenger car cockpit:Application,materials,and manufacture

In order to effectively reduce energy consumption and increase range mile,new energy vehicles represented by Tesla have greatly aroused the application of integrated magnesium(Mg)alloy die casting technology in automobiles.Previously,the application of Mg alloys in automobiles,especially in automotive cockpit components,is quite extensive,while it has almost disappeared for a period of time due to its relatively high cost,causing a certain degree of information loss in the application technology of Mg alloy parts in automobiles.The rapid development of automotive technology has led to a higher requirement for the automotive components compared with those traditional one.Therefore,whatever the components themselves,or the Mg alloy materials and die casting process have to face an increasing challenge,needing to be upgraded.In addition,owing to its high integration characteristics,the application of Mg alloy die casting technology in large-sized and thin-walled automotive parts has inherent advantages and needs to be expanded urgently.Indeed,it necessitates exploring advance Mg alloys and new product structures and optimizing die casting processes.This article summarizes and analyzes the development status of thin-walled and large-sized die casting Mg alloy parts in passenger car cockpit and corresponding material selection methods,die casting processes as well as mold design techniques.Furthermore,this work will aid researchers in establishing a comprehensive understanding of the manufacture of thin-walled and large-sized die casting Mg alloy parts in automobile cockpit.It will also assist them in developing new Mg alloys with improved comprehensive performance and new processes to meet the high requirements for die casting automotive components.

Compression properties of cost-efficient porous expanded clay reinforced AA7075 syntactic foams fabricated by industrial-oriented die casting technology

In today’s manufacturing industries,hard competition between rival firms makes it compulsory for researchers to design lighter and cheaper machine components due to the megatrends of cost-effectiveness and anti-pollution.At this point,aluminum syntactic foams(ASFs)are new-generation engineering composites and come into the upfront as a problem-solver.Owing to their features like low density,sufficient elongation,and perfect energy absorption ability,these advanced foams have been considerably seductive for many industrial sectors nowadays.In this study,an industrial-oriented automatic die casting technology was used for the first time to manufacture the combination of AA7075/porous expanded clay(PEC).Micro evaluations(optical and FESEM)reveal that there is a homogenous particle distribution in the foam samples,and inspections are compatible with the other ASF studies.Additionally,T6 aging heat treatment was operated on one half of the produced foams to explore the probable impact of aging on the compressive responses.Attained results show that PEC particles can be an alternative to expensive hollow spheres used in the previous works.Besides,a favorable relationship is ascertained between the aging treatment and mechanical properties such as compression strength and plateau strength.

Characteristics and distribution of microstructures in high pressure die cast alloys with X-ray microtomography:A review

Al and Mg alloy high pressure die castings(HPDC)are increasingly used in automotive industries.The microstructures in the castings have decisive effect on the casting mechanical properties,in which the microstructure characteristics are fundamental for the investigation of the microstructure-property relation.During the past decade,the microstructure characteristics of HPDC Al and Mg alloys,especially micro-pores andα-Fe,have been investigated from two-dimensional(2D)to threedimensional with X-ray micro-computed tomography(μ-CT).This paper provides an overview of the current understanding regarding the 3D characteristics and formation mechanisms of microstructures in HPDC alloys,their spatial distributions,and the impact on mechanical properties.Additionally,it outlines future research directions for the formation and control of heterogeneous microstructures in HPDC alloys.