Compared to cold drawing,dieless drawing has shown great potential for manufacturing biodegradable Mg alloy microtubes due to the large reduction in area acquired in a single pass.However,owing to the local heating an...Compared to cold drawing,dieless drawing has shown great potential for manufacturing biodegradable Mg alloy microtubes due to the large reduction in area acquired in a single pass.However,owing to the local heating and local deformation,the deformation mechanism during dieless drawing is not clear,and thus causing difficulties in controlling the microstructure of dieless drawn tubes.For the purpose of acquiring a desired microstructure.in this study the deformation mechanism of ZM21 Mg alloy tube was clarified by conducting continuous observation of the microstructural evolution during dieless drawing.The results show that both SRX and DRX occurred during dieless drawing.SRX occurred before the plastic deformation to soften dieless drawn tubes.With increase of feeding speed,the deformation mechanism changed accordingly:(1) At the low-speed of 0.02 mm/s,the deformation mechanism was dominated by twin-slip sliding,during which {10-12} tension twins were generated inside grains to accommodate the plastic deformation by changing the crystal orientation.(2) At the intermediate-speed of 2 mm/s,a twin-DRX process related to {10-12} tension twin was observed,which was characterized by the generation of abundant {10-12} tension twins and the evolution of misorientation angle of {10-12} tension twins.Moreover,the transformation from twin-DRX to CDRX can be observed at the late stage of plastic deformation,which was attributed to the inhomogeneous conditions of dieless drawing.(3) At the high-speed of 5 mm/s,a CDRX process was observed,during which grain boundary sliding and grain tilting were observed,in addition to the gradual rotation of subgrains.These results show that during dieless drawing,DRX is not only a temperature-dependent phenomenon,but also influenced by the variation of feeding speed.展开更多
Magnesium(Mg)alloy stents are expected to be the next generation of stents because of good biocompatibility and biodegradability.Compared with cold drawing,dieless drawing with local heating is an effective method for...Magnesium(Mg)alloy stents are expected to be the next generation of stents because of good biocompatibility and biodegradability.Compared with cold drawing,dieless drawing with local heating is an effective method for manufacturing the Mg alloy microtubes since a large reduction in area can be achieved in a single pass.However,the microstructure and properties of dieless drawn tubes have not been clarified,leading to the problems in practical application of dieless drawn tubes.In this study,the microstructure and performance of dieless drawn tubes are clarified.The results show that temperature and speed in the dieless drawing process are two factors in determining the grain size of dieless drawn tubes since decreasing the temperature or increasing the speed promotes the generation of fine-grained microstructure.Twins are also generated during the dieless drawing process,which 1)disintegrates grains leading to refinement and 2)causes Hall-Petch law effect on dieless drawn tubes.Tensile tests show that grain size is the main factor in determining the mechanical properties of dieless drawn tubes,namely,0.2%proof stress 135-180MPa,ultimate tensile strength(UTS)200-250MPa,and elongation 8-12%.In 0.9 wt%NaCl solution,localized corrosion is the key factor in initiating the corrosion of dieless drawn tubes,but refined grains and fewer twins can alleviate local corrosion.These results imply that dieless drawn tubes are promising in the clinical application of Mg alloy stents for cardiovascular disease.展开更多
Theoretical analyses show that the variation of wall thickness is in direct proportion to outer-diameter, inter-diameter, and (1+R_s)^(1/2) (Rs is sectional increase ratio of tube), the theoretical calculated results ...Theoretical analyses show that the variation of wall thickness is in direct proportion to outer-diameter, inter-diameter, and (1+R_s)^(1/2) (Rs is sectional increase ratio of tube), the theoretical calculated results of wall thickness during tube dieless upsetting are very approximate to the experimental one. As the width of deformation field increases, both the variation of wall thickness and the derivative of wall thickness variation to width of deformation field (to/tf) reduce.展开更多
Tin bronze wires were produced by dieless drawing. The effects of heating power, the distance between cooler and heater as well as feeding speed on the diameter, the temperature field, and the deformation region profi...Tin bronze wires were produced by dieless drawing. The effects of heating power, the distance between cooler and heater as well as feeding speed on the diameter, the temperature field, and the deformation region profile of the wires were investigated. The results indi-cated that each processing parameter exhibited both lower and upper limits of stable deformation based on the criterion of stable deformation with the diameter fluctuation of ±0.05 mm. Both the temperature and its gradient of the deformation region increased with increasing heating power under stable deformation, but decreased with an increase in feeding speed. As the distance between cooler and heater increased, the temperature of the deformation region increased and the slope of the deformation region profile decreased. The processing limit map of sta-ble deformation exhibited a closed curve and the unstable deformation consisted of wire breakage and diameter fluctuations.展开更多
The back-propagation neural (BPN) network was proposed to model the relationship between the parameters of the dieless draw- ing process and the microstrecmres of the QSi3-1 silicon bronze alloy. Combined with image...The back-propagation neural (BPN) network was proposed to model the relationship between the parameters of the dieless draw- ing process and the microstrecmres of the QSi3-1 silicon bronze alloy. Combined with image processing techniques, grain sizes and grain-boundary morphologies were respectively determined by the quantitative metallographic method and the flactal theory. The outcomes obtained show that the deformed microstructures exhibit typical fractal features, and the boundaries can be characterized quantitatively by ffactal dimensions. With the temperature of 600-800℃ and the drawing speed of 0.67-1.00 mm-s-1, either a lower temperature or a higher speed will cause a smaller grain size together with an elevated fractal dimension. The developed model can be capable for forecasting the microstructure evolution with a minimum error. The average relative errors between the predicted results and the experimental values of grain size and fractal dimension are 3.9% and 0.9%, respectively.展开更多
The microstructure and mechanical properties of Cu-12wt%Al alloy wires which are composed of continuous columnar crystals after dieless drawing forming at drawing speed of 1.0–1.4 mm/s and deformation temperature of ...The microstructure and mechanical properties of Cu-12wt%Al alloy wires which are composed of continuous columnar crystals after dieless drawing forming at drawing speed of 1.0–1.4 mm/s and deformation temperature of 600–900°C were analyzed, and deformation behavior of the alloy during dieless drawing forming was experimentally investigated. The results showed that in the above-mentioned conditions, recrystallization phenomenon was not found during dieless drawing forming. When a drawing speed of 1.0 mm/s was used, the grain boundaries were out of straight gradually with increasing deformation temperature from 600°C to 900°C, and tensile strength of the dieless drawn Cu-12wt%Al alloy wires increased while elongations decreased with increasing deformation temperature. At drawing speed of 1.1–1.2 mm/s and deformation temperature of 600°C, the effect of dieless drawing forming process on the microstructure of the alloy was inconspicuous, and when drawing speed was up to 1.3–1.4 mm/s, the grain boundaries of continuous columnar crystals became zigzag while there was little effect of drawing speed of 1.1–1.4 mm/s on the elongation and tensile strength of the alloy wires.展开更多
Since processing parameters have always been assumed to be stable in the current finite element numerical simulation of dieless drawing process, the simulation results for the product dimension tend to stabilize gradu...Since processing parameters have always been assumed to be stable in the current finite element numerical simulation of dieless drawing process, the simulation results for the product dimension tend to stabilize gradually. In fact, the dimension fluctuation exists in the forming process all the while. A mathematical model of Gauss distribution for processing parameters was employed and a finite element numerical model of dieless drawing process with non-steady processing parameters was established. Dieless drawing processing of Ni-Ti alloy wire was conducted for verifying the proposed model. The results indicated that the non-steady processing parameters model had higher simulation accuracy of the wire diameter than that given by the steady parameters model. Furthermore, the model could also be used to analyze the fluctuation characteristics in the whole dieless drawing process.展开更多
Ag-28Cu-8Sn(wt%)alloy is a widely used brittle silver-based brazing filler metal.The wire of brazing filler metal was prepared by continuous casting process and dieless drawing technology.The phase structure was measu...Ag-28Cu-8Sn(wt%)alloy is a widely used brittle silver-based brazing filler metal.The wire of brazing filler metal was prepared by continuous casting process and dieless drawing technology.The phase structure was measured by X-ray diffraction(XRD),and the microstructure of wetting interface,cast states,processing states and fracture morphologies were characterized by the optical microscopy(OM)and scanning electron microscopy(SEM),respectively.The electrical conductivity,hardness,tensile strength and elongation rate were tested as well.Furthermore,the solid-liquid phase temperature was measured by a differential scanning calorimeter(DSC),and the wettability of brazing filler metal was tested by spreading method.The outcomes obtained show that the as-cast microstructure is a typical three-zone structure,including region of surface fine grain,zone of columnar grain and region of center equiaxed crystal.Ag-28Cu-8Sn alloy is mainly composed of Ag-rich a-phase,Cu-rich pphase and intermediate compounds.Grain refinement appears in the cross section,as for grains of the longitudinal section,the shape is changed from ribbon to fiber to form a silk texture.The strength and hardness improve with the increase in the true strain,while the conductivity and elongation are reduced.Furthermore,the solid-phase temperature is 605.9℃,and the liquid-phase temperature is 725.1℃.The spreading area of Ag-28Cu-8Sn brazing filler metal is 174 mm^2,and the metallurgical bonding occurs between Ag-28Cu-8Sn brazing filler metal and Cu matrix.In addition,compared with cold drawing process,there are not any microcracks at the fracture morphology for the alloy fabricated by dieless drawing.The dieless drawing process overcomes some processing defects of traditional cold drawing,and the processing performance of Ag-28Cu-8Sn alloy is improved.展开更多
基金supported by JSTP KAKENHI Grant No. 19H02476The Light Meal Education Foundation, Inc.China Scholarship Council for the award of fellowship and funding (No. 201707040058)
文摘Compared to cold drawing,dieless drawing has shown great potential for manufacturing biodegradable Mg alloy microtubes due to the large reduction in area acquired in a single pass.However,owing to the local heating and local deformation,the deformation mechanism during dieless drawing is not clear,and thus causing difficulties in controlling the microstructure of dieless drawn tubes.For the purpose of acquiring a desired microstructure.in this study the deformation mechanism of ZM21 Mg alloy tube was clarified by conducting continuous observation of the microstructural evolution during dieless drawing.The results show that both SRX and DRX occurred during dieless drawing.SRX occurred before the plastic deformation to soften dieless drawn tubes.With increase of feeding speed,the deformation mechanism changed accordingly:(1) At the low-speed of 0.02 mm/s,the deformation mechanism was dominated by twin-slip sliding,during which {10-12} tension twins were generated inside grains to accommodate the plastic deformation by changing the crystal orientation.(2) At the intermediate-speed of 2 mm/s,a twin-DRX process related to {10-12} tension twin was observed,which was characterized by the generation of abundant {10-12} tension twins and the evolution of misorientation angle of {10-12} tension twins.Moreover,the transformation from twin-DRX to CDRX can be observed at the late stage of plastic deformation,which was attributed to the inhomogeneous conditions of dieless drawing.(3) At the high-speed of 5 mm/s,a CDRX process was observed,during which grain boundary sliding and grain tilting were observed,in addition to the gradual rotation of subgrains.These results show that during dieless drawing,DRX is not only a temperature-dependent phenomenon,but also influenced by the variation of feeding speed.
基金JSTP KAKENHI Grant Number 19H02476JKA and its promotion funds from KEIRIN RACE.Peihua Du thanks China Scholarship Council for the award of fellowship and funding(No.201707040058).
文摘Magnesium(Mg)alloy stents are expected to be the next generation of stents because of good biocompatibility and biodegradability.Compared with cold drawing,dieless drawing with local heating is an effective method for manufacturing the Mg alloy microtubes since a large reduction in area can be achieved in a single pass.However,the microstructure and properties of dieless drawn tubes have not been clarified,leading to the problems in practical application of dieless drawn tubes.In this study,the microstructure and performance of dieless drawn tubes are clarified.The results show that temperature and speed in the dieless drawing process are two factors in determining the grain size of dieless drawn tubes since decreasing the temperature or increasing the speed promotes the generation of fine-grained microstructure.Twins are also generated during the dieless drawing process,which 1)disintegrates grains leading to refinement and 2)causes Hall-Petch law effect on dieless drawn tubes.Tensile tests show that grain size is the main factor in determining the mechanical properties of dieless drawn tubes,namely,0.2%proof stress 135-180MPa,ultimate tensile strength(UTS)200-250MPa,and elongation 8-12%.In 0.9 wt%NaCl solution,localized corrosion is the key factor in initiating the corrosion of dieless drawn tubes,but refined grains and fewer twins can alleviate local corrosion.These results imply that dieless drawn tubes are promising in the clinical application of Mg alloy stents for cardiovascular disease.
基金Sponsored by Ministry of Education of China and Natural Science Foundation of Liaoning Province
文摘Theoretical analyses show that the variation of wall thickness is in direct proportion to outer-diameter, inter-diameter, and (1+R_s)^(1/2) (Rs is sectional increase ratio of tube), the theoretical calculated results of wall thickness during tube dieless upsetting are very approximate to the experimental one. As the width of deformation field increases, both the variation of wall thickness and the derivative of wall thickness variation to width of deformation field (to/tf) reduce.
基金supported by the National Basic Research Priorities Program of China (No.2006CB605200)the National Natural Science Foundation of China (No.50634010, 50674008)+1 种基金the Program for New Century Excellent Talents in Chinese Universities (No.NCET-06-0083)the Universities Fundamental Research Foundation of MOE (No FRF-TP-10-002B)
文摘Tin bronze wires were produced by dieless drawing. The effects of heating power, the distance between cooler and heater as well as feeding speed on the diameter, the temperature field, and the deformation region profile of the wires were investigated. The results indi-cated that each processing parameter exhibited both lower and upper limits of stable deformation based on the criterion of stable deformation with the diameter fluctuation of ±0.05 mm. Both the temperature and its gradient of the deformation region increased with increasing heating power under stable deformation, but decreased with an increase in feeding speed. As the distance between cooler and heater increased, the temperature of the deformation region increased and the slope of the deformation region profile decreased. The processing limit map of sta-ble deformation exhibited a closed curve and the unstable deformation consisted of wire breakage and diameter fluctuations.
基金supported by the National Basic Research Priorities Program of China (No.2006CB605200)the National Natu-ral Science Foundation of China (Nos.50674008 and 50634010)+1 种基金the Program for New Century Excellent Talents in Chinese Universities (No.NCET-06-0083)the Foundation of State Key Laboratory for Advanced Metals and Materials (No.2008Z-15)
文摘The back-propagation neural (BPN) network was proposed to model the relationship between the parameters of the dieless draw- ing process and the microstrecmres of the QSi3-1 silicon bronze alloy. Combined with image processing techniques, grain sizes and grain-boundary morphologies were respectively determined by the quantitative metallographic method and the flactal theory. The outcomes obtained show that the deformed microstructures exhibit typical fractal features, and the boundaries can be characterized quantitatively by ffactal dimensions. With the temperature of 600-800℃ and the drawing speed of 0.67-1.00 mm-s-1, either a lower temperature or a higher speed will cause a smaller grain size together with an elevated fractal dimension. The developed model can be capable for forecasting the microstructure evolution with a minimum error. The average relative errors between the predicted results and the experimental values of grain size and fractal dimension are 3.9% and 0.9%, respectively.
基金Supported by the National Basic Research Program of China (Grant No. 2006CB605200)the National High Technology Research and Development Program of China (Grant No. 2006AA03Z506)+1 种基金the National Natural Science Foundation of China (Grant Nos. 50674008 and 50634010)the Program for New Century Excellent Talents in University of China (Grant No. NCET-06-0083)
文摘The microstructure and mechanical properties of Cu-12wt%Al alloy wires which are composed of continuous columnar crystals after dieless drawing forming at drawing speed of 1.0–1.4 mm/s and deformation temperature of 600–900°C were analyzed, and deformation behavior of the alloy during dieless drawing forming was experimentally investigated. The results showed that in the above-mentioned conditions, recrystallization phenomenon was not found during dieless drawing forming. When a drawing speed of 1.0 mm/s was used, the grain boundaries were out of straight gradually with increasing deformation temperature from 600°C to 900°C, and tensile strength of the dieless drawn Cu-12wt%Al alloy wires increased while elongations decreased with increasing deformation temperature. At drawing speed of 1.1–1.2 mm/s and deformation temperature of 600°C, the effect of dieless drawing forming process on the microstructure of the alloy was inconspicuous, and when drawing speed was up to 1.3–1.4 mm/s, the grain boundaries of continuous columnar crystals became zigzag while there was little effect of drawing speed of 1.1–1.4 mm/s on the elongation and tensile strength of the alloy wires.
基金National Basic Research Program of China (2006CB605200)National Natural Science Foundation of China (50634010, 50674008)Program for New Century Excellent Talents in University (NCET-06-0083)
文摘Since processing parameters have always been assumed to be stable in the current finite element numerical simulation of dieless drawing process, the simulation results for the product dimension tend to stabilize gradually. In fact, the dimension fluctuation exists in the forming process all the while. A mathematical model of Gauss distribution for processing parameters was employed and a finite element numerical model of dieless drawing process with non-steady processing parameters was established. Dieless drawing processing of Ni-Ti alloy wire was conducted for verifying the proposed model. The results indicated that the non-steady processing parameters model had higher simulation accuracy of the wire diameter than that given by the steady parameters model. Furthermore, the model could also be used to analyze the fluctuation characteristics in the whole dieless drawing process.
基金financially supported by the National Natural Science Foundation of China(Nos.U1602271 and U1302272).
文摘Ag-28Cu-8Sn(wt%)alloy is a widely used brittle silver-based brazing filler metal.The wire of brazing filler metal was prepared by continuous casting process and dieless drawing technology.The phase structure was measured by X-ray diffraction(XRD),and the microstructure of wetting interface,cast states,processing states and fracture morphologies were characterized by the optical microscopy(OM)and scanning electron microscopy(SEM),respectively.The electrical conductivity,hardness,tensile strength and elongation rate were tested as well.Furthermore,the solid-liquid phase temperature was measured by a differential scanning calorimeter(DSC),and the wettability of brazing filler metal was tested by spreading method.The outcomes obtained show that the as-cast microstructure is a typical three-zone structure,including region of surface fine grain,zone of columnar grain and region of center equiaxed crystal.Ag-28Cu-8Sn alloy is mainly composed of Ag-rich a-phase,Cu-rich pphase and intermediate compounds.Grain refinement appears in the cross section,as for grains of the longitudinal section,the shape is changed from ribbon to fiber to form a silk texture.The strength and hardness improve with the increase in the true strain,while the conductivity and elongation are reduced.Furthermore,the solid-phase temperature is 605.9℃,and the liquid-phase temperature is 725.1℃.The spreading area of Ag-28Cu-8Sn brazing filler metal is 174 mm^2,and the metallurgical bonding occurs between Ag-28Cu-8Sn brazing filler metal and Cu matrix.In addition,compared with cold drawing process,there are not any microcracks at the fracture morphology for the alloy fabricated by dieless drawing.The dieless drawing process overcomes some processing defects of traditional cold drawing,and the processing performance of Ag-28Cu-8Sn alloy is improved.