Three Ni（II） Coordination Polymers with Various Architectures Based on Asymmetric Bis-pyridyl-amide and Polycarboxylates： Syntheses, Structures and Properties

Three different dimensionalNi（II） coordination polymers, [Ni（3-pna）（HIP）（H2O）3]-H20（1）, [Ni（3-pna）- （1,3,5-HBTC）]（2） and [Ni2（H2O）（3-pna）2（1,4-CHDC）2]4（3）（3-pna=3-pyridylnicotinamide, H2HIP=5-hydroxyisoph- thalic acid, 1,3,5-H3BTC=l,3,5-benzenetricarboxylic acid, 1,4-H2CHDC=l,4-cyclohexanedicarboxylic acid）, were synthesized under hydrothermal conditions and characterized by means of infrared spectra（IR）, thermal gravimetric （TG） analyses, powder X-ray diffraction（PXRD） and single-crystal X-ray diffraction. Complex 1 has a structure of 1D single-stranded chain, which is further stretched by hydrogen-bond interactions to form a 2D supramolecular sheet. Complex 2 shows a 2D network, which is stretched to 3D supramolecular frameworks through hydrogen-bond interactions. Complex 3 reveals a 3D skeleton with a （3,3,6,6）-connected {3·72} {32·4 } {33·42·5·73·85·9 } {33·45·52·72·82·9} topology. The effects of different polycarboxylates on the ultimate architectures of the complexes 1--3 were dis- cussed. Furthermore, the fluorescent and photocatalytic properties of the title complexes were also investigated.

Syntheses, Structures and Properties of Three Transition Metal Coordination Polymers Based on Semi-rigid 3-Pyridylnicotinamide and S/N-Containing Dicarboxylate Mixed Ligands

Three new coordination complexes, [Co（L）（ADTZ）]·H2O（1）, [Cd（L）（ADTZ）]·H2O（2） and [Zn（L）（ADTZ）]·H2O（3）[L=3-pyridylnicotinamide, H2ADTZ=2,5-（s-acetic acid）dimercapto-1,3,4-thiadiazole], were synthesized under hydrothermal conditions. These complexes were structurally characterized by single-crystal X-ray diffraction analysis and further characterized by infrared spectroscopy（IR）, powder X-ray diffraction （PXRD） and thermogravimetric analysis（TGA）. Complexes 1-3 exhibit the similar 2D double-layer networks based on 1D [M-L], zigzag chains and 1D [M-ADTZ]2n double-chains with different distances between metal ions and with various conformations of ADTZ anions. In complexes 1 and 3, the 2D sheets are extended into a 3D supramolecular frameworks by hydrogen bonding interactions. The subtle effects of the central metal atoms on the structures of the title coordination polymers were discussed. The electrochemical properties of complex 1 and luminescent properties of complexes 2 and 3 were investigated. In addition, complexes 1-3 exhibit photocatalytic activity for dye methylene blue degradation under UV light and show good stability toward photoca- talysis.