For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraq...For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraquinone type） and C. I. disperse orange 25 （azo type） in supercritieal CO2 were carried out with a high-pressure dyeing apparatus at temperatures from 80 to 130℃ and pressure up to 31 MPa. The effect of operating conditions on color yield （K/S） was investigated in SFD experiment, and the optimum operating conditions for the above two disperse dyes were obtained as follows： the temperature 120℃, the pressure 25 MPa and the dyeing time 100 min. As compared with SFD, the conventional water dyeing （CWD） was carried out with the same dyes and textile. The results show that the better fastness, levelness and apparent color can be achieved in SFD and the SFD process has many significant advantages over the CWD process.展开更多
Some properties of nematic liquid crystal E7 doped with two disperse orange dyes used together and effect of addition of carbon nanoparticles （single walled carbon nanotube or fullerene C60） on them were studied. Tw...Some properties of nematic liquid crystal E7 doped with two disperse orange dyes used together and effect of addition of carbon nanoparticles （single walled carbon nanotube or fullerene C60） on them were studied. Two dyes （disperse orange 11 and 13） having high solubility and order parameter were used as co-dopants. A notable increase in order parameter was obtained comparing to that of liquid crystal doped with single dye. When carbon nanoparticles were used as dopant, a decrease in order parameter was observed at low temperatures while it increased at high temperatures. When applied voltage changed, the order parameter abruptly increased in its threshold value and saturated in higher voltages as expected. An appreciable change in textures was not observed with addition of dopants. This addition gave rise to an increase in nematic-isotropic phase transition temperatures compared with that of pure liquid crystal.展开更多
In this study,a series of Co_3O_4/ mildly oxidized graphite oxide(mGO) nanocatalysts(Co_3O_4/ mGO-l,Co_3O_4/ mGO-2 and Co_3O_4/mGO-3) were synthesized through solvothermal method and used as a mediator for the heterog...In this study,a series of Co_3O_4/ mildly oxidized graphite oxide(mGO) nanocatalysts(Co_3O_4/ mGO-l,Co_3O_4/ mGO-2 and Co_3O_4/mGO-3) were synthesized through solvothermal method and used as a mediator for the heterogeneous peroxymonosulfate(PMS)activation.The performance of CO_3O_4 / mGO/PMS system was investigated using acid orange 7(AO7).Results showed that Co_3O_4/mGO-3 had the best degradation efficiency of AO7 and the removal rate was above 90%in about 6 min.The phenomenon indicated the catalytic activity of Co_3O_4/mGO composites was related to the oxidation degree of graphite oxide(GO).In addition,experiments showed the content of Co_3O_4 had an effect on the catalytic activity.The composites were characterized with X-ray powder diffraction(XRD),FTIR,Raman,X-ray photoelectron spectroscopy(XPS) and transmission electron microscopy(TEM).According to the charactrization and synergistic catalytic mechanism,the generation of Co—OH complexes found to be the initial step to activate PMS in the heterogeneous system of Co_3O_4/mGO hybrid.展开更多
采用研磨分散法制备了超细液状分散橙30,研究了复合分散剂配比对超细液状分散橙30离心稳定性、尺寸稳定性的影响,并进行了染色试验。结果表明,当分散剂用量为60%(对染料质量),分散剂m(PEG1500)∶m(4080A)∶m(SL)=1∶0.5∶4.5时,所制备...采用研磨分散法制备了超细液状分散橙30,研究了复合分散剂配比对超细液状分散橙30离心稳定性、尺寸稳定性的影响,并进行了染色试验。结果表明,当分散剂用量为60%(对染料质量),分散剂m(PEG1500)∶m(4080A)∶m(SL)=1∶0.5∶4.5时,所制备的液状分散染料较佳。颗粒的平均粒径为271.1 nm,且粒径分布指数PDI为0.158,离心稳定性为96.2%,自然条件下贮存35天后,粒度变化ΔD仅为3.5 nm,Zeta电位变化ΔZP为0.5 m V;且具有良好的高、低温分散稳定性,上染百分率高于常规分散染料。展开更多
基金Supported by National Natural Science Foundation of China(No.20277004)
文摘For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraquinone type） and C. I. disperse orange 25 （azo type） in supercritieal CO2 were carried out with a high-pressure dyeing apparatus at temperatures from 80 to 130℃ and pressure up to 31 MPa. The effect of operating conditions on color yield （K/S） was investigated in SFD experiment, and the optimum operating conditions for the above two disperse dyes were obtained as follows： the temperature 120℃, the pressure 25 MPa and the dyeing time 100 min. As compared with SFD, the conventional water dyeing （CWD） was carried out with the same dyes and textile. The results show that the better fastness, levelness and apparent color can be achieved in SFD and the SFD process has many significant advantages over the CWD process.
文摘Some properties of nematic liquid crystal E7 doped with two disperse orange dyes used together and effect of addition of carbon nanoparticles （single walled carbon nanotube or fullerene C60） on them were studied. Two dyes （disperse orange 11 and 13） having high solubility and order parameter were used as co-dopants. A notable increase in order parameter was obtained comparing to that of liquid crystal doped with single dye. When carbon nanoparticles were used as dopant, a decrease in order parameter was observed at low temperatures while it increased at high temperatures. When applied voltage changed, the order parameter abruptly increased in its threshold value and saturated in higher voltages as expected. An appreciable change in textures was not observed with addition of dopants. This addition gave rise to an increase in nematic-isotropic phase transition temperatures compared with that of pure liquid crystal.
基金Innovation Program of Shanghai Municipal Education Commission,China(No.12ZZ069)Research Fund for the Doctoral Program of Higher Education,China(No.20130075110006)
文摘In this study,a series of Co_3O_4/ mildly oxidized graphite oxide(mGO) nanocatalysts(Co_3O_4/ mGO-l,Co_3O_4/ mGO-2 and Co_3O_4/mGO-3) were synthesized through solvothermal method and used as a mediator for the heterogeneous peroxymonosulfate(PMS)activation.The performance of CO_3O_4 / mGO/PMS system was investigated using acid orange 7(AO7).Results showed that Co_3O_4/mGO-3 had the best degradation efficiency of AO7 and the removal rate was above 90%in about 6 min.The phenomenon indicated the catalytic activity of Co_3O_4/mGO composites was related to the oxidation degree of graphite oxide(GO).In addition,experiments showed the content of Co_3O_4 had an effect on the catalytic activity.The composites were characterized with X-ray powder diffraction(XRD),FTIR,Raman,X-ray photoelectron spectroscopy(XPS) and transmission electron microscopy(TEM).According to the charactrization and synergistic catalytic mechanism,the generation of Co—OH complexes found to be the initial step to activate PMS in the heterogeneous system of Co_3O_4/mGO hybrid.
文摘采用研磨分散法制备了超细液状分散橙30,研究了复合分散剂配比对超细液状分散橙30离心稳定性、尺寸稳定性的影响,并进行了染色试验。结果表明,当分散剂用量为60%(对染料质量),分散剂m(PEG1500)∶m(4080A)∶m(SL)=1∶0.5∶4.5时,所制备的液状分散染料较佳。颗粒的平均粒径为271.1 nm,且粒径分布指数PDI为0.158,离心稳定性为96.2%,自然条件下贮存35天后,粒度变化ΔD仅为3.5 nm,Zeta电位变化ΔZP为0.5 m V;且具有良好的高、低温分散稳定性,上染百分率高于常规分散染料。
