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Dissipative particle dynamics simulation of wettability alternation phenomena in the chemical flooding process 被引量:4
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作者 Xiaobo Li Yuewu Liu +1 位作者 Jianfei Tang Shujiao Li 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2009年第5期583-587,共5页
Wettability alternation phenomena is considered one of the most important enhanced oil recovery (EOR) mechanisms in the chemical flooding process and induced by the adsorption of surfactant on the rock surface. Thes... Wettability alternation phenomena is considered one of the most important enhanced oil recovery (EOR) mechanisms in the chemical flooding process and induced by the adsorption of surfactant on the rock surface. These phenomena are studied by a mesoscopic method named as dissipative particle dynamics (DPD). Both the alteration phenomena of water-wet to oil-wet and that of oil-wet to water-wet are simulated based on reasonable definition of interaction parameters between beads. The wetting hysteresis phenomenon and the process of oil-drops detachment from rock surfaces with different wettability are simulated by adding long-range external forces on the fluid particles. The simulation results show that, the oil drop is liable to spread on the oil-wetting surface and move in the form of liquid film flow, whereas it is likely to move as a whole on the waterwetting surface. There are the same phenomena occuring in wettability-alternated cases. The results also show that DPD method provides a feasible approach to the problems of seepage flow with physicochemical phenomena and can be used to study the mechanism of EOR of chemical flooding. 展开更多
关键词 Wettability alternation dissipative particledynamics - enhanced oil recovery Chemical flooding -Mesoscopic mechanics
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低浓度表面活性剂-聚合物二元复合驱油体系的分子模拟与配方设计 被引量:25
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作者 曹绪龙 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2008年第6期682-688,共7页
采用耗散颗粒动力学(DPD)方法在介观层次上模拟了表面活性剂烷基苯磺酸盐在油-水界面的排布行为,考察了分子结构、油相等因素对界面密度和界面效率的影响,探讨了利用表面活性剂复配协同效应提高界面活性的机理。实验研究了表面活性剂类... 采用耗散颗粒动力学(DPD)方法在介观层次上模拟了表面活性剂烷基苯磺酸盐在油-水界面的排布行为,考察了分子结构、油相等因素对界面密度和界面效率的影响,探讨了利用表面活性剂复配协同效应提高界面活性的机理。实验研究了表面活性剂类型、油相、表面活性剂复配等对油-水界面张力的影响。结果表明,"阴+非"表面活性剂复配可使油-水界面张力降低1个数最级。根据分子模拟和实验研究结果,结合孤东七区试验区原油特点,提出了"0.3%石油磺酸盐+0.1%表面活性剂1~#+0.15%聚合物"的二元复合驱配方,可使油-水界面张力降低至2.95×10^(-3)mN/m,物理模拟实验提高采收率高达18.1%。 展开更多
关键词 表面活性剂聚合物二元复合驱油体系 耗散颗粒动力学模拟 烷基苯磺酸钠 石油磺酸盐 界面张力 提高采收率
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Numerical simulation of pore-scale flow in chemical flooding process 被引量:3
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作者 Xiaobo Li,~(1,a) Shuhong Wu,~1 Jie Song,~1 Hua Li,~1 and Shuping Wang~2 1.Research Institute of Petroleum Exploration & Development of Petrochina,Beijing 100083,China 2)Petroleum Exploration & Production Research Institute of Sinopec,Beijing 100083,China 《Theoretical & Applied Mechanics Letters》 CAS 2011年第2期68-72,共5页
Chemical flooding is one of the effective technologies to increase oil recovery of petroleum reservoirs after water flooding.Above the scale of representative elementary volume(REV), phenomenological modeling and nume... Chemical flooding is one of the effective technologies to increase oil recovery of petroleum reservoirs after water flooding.Above the scale of representative elementary volume(REV), phenomenological modeling and numerical simulations of chemical flooding have been reported in literatures,but the studies alike are rarely conducted at the pore-scale,at which the effects of physicochemical hydrodynamics are hardly resolved either by experimental observations or by traditional continuum-based simulations.In this paper,dissipative particle dynamics(DPD),one of mesoscopic fluid particle methods,is introduced to simulate the pore-scale flow in chemical flooding processes.The theoretical background,mathematical formulation and numerical approach of DPD are presented.The plane Poiseuille flow is used to illustrate the accuracy of the DPD simulation,and then the processes of polymer flooding through an oil-wet throat and a water-wet throat are studies, respectively.The selected parameters of those simulations are given in details.These preliminary results show the potential of this novel method for modeling the physicochemical hydrodynamics at the pore scale in the area of chemical enhanced oil recovery. 展开更多
关键词 chemical flooding pore-scale flow dissipative particle dynamics mesoscopic simulation enhanced oil recovery
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乳化和润湿反转现象的耗散粒子动力学研究 被引量:7
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作者 李小波 刘曰武 +1 位作者 李树皎 唐剑斐 《石油学报》 EI CAS CSCD 北大核心 2009年第2期259-262,266,共5页
利用耗散粒子动力学方法,研究了化学驱过程中乳化和润湿反转两个重要的物理化学现象。通过合理划分流体粒子和定义粒子之间相互作用参数,模拟了十二烷基苯磺酸钠、正十二烷和水三组分体系的自发乳化现象;通过附加固壁条件,模拟了在水动... 利用耗散粒子动力学方法,研究了化学驱过程中乳化和润湿反转两个重要的物理化学现象。通过合理划分流体粒子和定义粒子之间相互作用参数,模拟了十二烷基苯磺酸钠、正十二烷和水三组分体系的自发乳化现象;通过附加固壁条件,模拟了在水动力作用下吸附在岩石表面的油珠发生破裂的非自发乳化过程,以及由于表面活性剂在岩石表面吸附而引起的润湿反转现象,比较了润湿反转前后残余油珠的运动情况。模拟结果表明:作为介观力学的离散粒子动力学方法,耗散粒子动力学方法可作为研究包含物理化学现象的化学驱渗流问题的重要手段。 展开更多
关键词 强化采油 化学驱 乳化 润湿反转 耗散粒子动力学 介观力学
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模拟化学驱微观渗流的介观方法
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作者 李小波 吴淑红 +2 位作者 宋杰 李华 孟照娟 《大庆石油学院学报》 CAS 北大核心 2011年第5期49-53,117,共5页
针对基于连续性假设模拟方法难以处理化学驱微观渗流的多尺度物理现象,引入耗散粒子动力学的介观模拟手段,将流体处理成为一个大量粒子构成的体系,通过统计粒子之间相互运动而得到流体的宏观表现;建立模型参数与可测物理量之间的联系,... 针对基于连续性假设模拟方法难以处理化学驱微观渗流的多尺度物理现象,引入耗散粒子动力学的介观模拟手段,将流体处理成为一个大量粒子构成的体系,通过统计粒子之间相互运动而得到流体的宏观表现;建立模型参数与可测物理量之间的联系,开发相应的模拟程序,研究经典泊肃叶流动、聚合物分子构象、聚合物溶液流变性、聚合物链条刚性对链条构象和溶液黏度的影响、以及聚合物溶液的微观驱替过程.结果表明:部分模拟结果与经典流体理论和试验结果预测接近,为化学驱微观渗流研究提供一种处理物理化学变化与流动之间耦合关系的途径. 展开更多
关键词 化学驱 微观渗流 介观理论 耗散粒子动力学 提高采收率
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