Reclassification and distribution patterns of discovered oils in theDongying Depression, Bohai Bay Basin, China

The Dongying Depression is an important petrolifeous province,with diverse source rocks and complex petroleum distribution patterns.A total of 32 crude oils were analyzed by the gas chromatographyemass spectrometry and isotopic compositions to better understanding the petroleum systems in the study area.Three oil types were classified by hierarchical cluster analyses.Type I and II oils have closely correlation with the discovered source rocks,which have been confirmed to be mainly derived from the lower third and upper forth member of the Eocene Shahejie Formation source rocks(Es3^(L) and Es4^(U)),respectively.Obviously,type III oils contain abundant gammacerane,tricyclic terpanes and C_(29) steranes and have lower values of δ13C than type I and II oils,indicating a completely different source rock and biological origins.Until recently,type III oils fail to match any of the discovered source rock,which contains main contribution of aquatic organism or/and bacteria inputs.In addition,the spacial distribution of these three oil types were discussed.Type I oils mainly distributed in the Es3 and Es4 reservoirs that closed to the generative kitchens.Type II oils occurred in the Es4 reservoirs in the sourthern slope of the depression,which probably caused by lateral migration along the horizontal fractures and sandstone layers within the Es4 interval.Differently,type III oils in the sourthern slope of the depression were mainly discovered in the Eocene Kongdian or Ordocician reservoirs,which suggests great exploration potential of deep underlying strata.

Sedimentary Processes and Depositional Characteristics of Coarse-grained Subaqueous Fans along Steep Slopes in a Lacustrine Rift Basin:A Case Study from the Dongying Depression,Bohai Bay Basin,China

Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.

The control of astronomical cycles on lacustrine fine-grained event Sedimentation——A case study of the Chunshang sub-member of the upper Es_(4) in the Dongying Sag

Fine-grained lacustrine sedimentation controlled by astronomical cycles remains a research weakness in sedimentology studies,as most studies have concentrated on how astronomical cycles affect the normal lacustrine fine-grained sedimentation,but how they affect the lacustrine fine-grained event sedimen-tation has been rarely studied.Therefore,this work researched the characteristics of event sedimentation by systematically observing the cores from 30 cored wells in the Shahejie Formation of the Dongying Sag at a depth of over 1800 m,with more than 4000 thin sections being authenticated and over 1000 whole rocks being analyzed by X-ray diffraction(XRD).The research object was the Chunshang Sub-member of Upper Es_(4) in the Fanye 1 well,as it had the most comprehensive analysis data and underwent the most continuous coring.We divided astronomical cycles into different orders and made corresponding curves using the gamma-ray(GR)curve,spectral analysis,power spectrum estimation,and module extreme values,there were 6 long eccentricity periods,22 short eccentricity periods,65.5 obliquity cycles,and 110.5 precession cycles in this sub-member.On this basis,this study analyzed the control of astronomical cycles on the lacustrine fine-grained event sedimentation,and the research shows deposits were developed by slide-slump,turbidities,hyperpycnites,and tempestites in the Chunshang Sub-member of the Upper Es_(4),with higher long eccentricity,the monsoon climate contributes to the formation of storm currents,while with lower long eccentricity,the surface deposits are severely eroded by rivers and rainfalls,thus developing the slide-slump,turbidities,and hyperpycnites.The relationship between the lacustrine fine-grained event sedimentation and astronomical cycles was studied in this case study,which can promote research on fine-grained sedimentary rocks in genetic dynamics and boost the theoretical and disciplinary development in fine-grained sedimentology.

Diversity of depositional architecture and sandbody distribution of sublacustrine fans during forced regression: A case study of Paleogene Middle Sha 3 Member in Dongying Sag, Bohai Bay Basin, East China

Currently, the differences in gravity flow deposits within different systems tracts in continental lacustrine basins are not clear. Taking the middle submember of the third member of Paleogene Shahejie Formation(Sha 3 Member) in the Shishen 100 area of the Dongying Sag in the Bohai Bay Basin as an example, the depositional architecture of sublacustrine fans during forced regression and the impact of the fourth-order base-level changes on their growth were investigated using cores, well logs and 3D seismic data. Sublacustrine fans were mainly caused by hyperpycnal flow during the fourth-order base-level rise, while the proportion of slump-induced sublacustrine fans gradually increased during the late fourth-order base-level fall. From rising to falling of the fourth-order base-level, the extension distance of channels inside hyperpycnal-fed sublacustrine fans reduced progressively, resulting in the transformation in their morphology from a significantly channelized fan to a skirt-like fan. Furthermore, the depositional architecture of distributary channel complexes in sublacustrine fans changed from vertical aggradation to lateral migration, and the lateral size of individual channel steadily decreased. The lobe complex's architectural patterns evolved from compensational stacking of lateral migration to aggradational stacking, and the lateral size of individual lobe steadily grew. This study deepens the understanding of depositional features of gravity flow in high-frequency sequence stratigraphy and provides a geological foundation for the fine development of sublacustrine fan reservoirs.

Genetic mechanisms and control on hydrocarbon accumulation in transtensional structures: A case study of Gaoqing area, northern Dongying Sag, China

Broom-shaped structures are widely seen in transtensional basins, including those discovered in many sags of the Bohai Bay Basin. Broom-shaped transtensional structural zones are generally petroliferous and thus important targets for hydrocarbon exploration. This study analyzed the evolution and genetic mechanisms of the broom-shaped transtensional structures in the Gaoqing area of the Dongying Sag using the 3D seismic flattening technique and a physical simulation experiment. Furthermore, the control effects of the broom-shaped transtensional structures on hydrocarbon accumulation and distribution were discussed. The research results are as follows. The Gaoqing area is of a broom-shaped transtensional structure in planar view, composed of several arc-shaped secondary faults intersecting with high-level main fault in the same direction. On the seismic section, it appears as a typical semi-flower-like structure. In the early stage (that is, during the deposition of the Kongdian Formation to the lower submember of the 4th member of the Shahejie Formation, Es4(L)), single-fault pattern consisting of single or multiple faults in alignment was developed under extensional stress. While with the change of structural stress (that is, during the deposition of the Es4(U) to the Es2(L)), more secondary faults were formed, and came in a pattern of broom-shaped structure together with the major fault. In the late stage (that is, during the deposition of the Es1 to the Guantao Formation), the en echelon fault pattern was formed, as the major fault broke into multiple secondary faults. The divergent end of the broom-shaped transtensional structure has many secondary faults developed, the fault planes are gentle, and small-scale fan deltas are the predominant type of deposits. The hydrocarbon tends to laterally migrate far away and accumulate mianly in structural and lithologic-structural traps. On the other hand, in the convergent end, the fault planes are relatively steep, resulting in small-scale subaqueous fans or large-scale deltas deposited along the major fault, with hydrocarbon accumulating minaly in structural-lithologic traps proximal to the provenances.

Characteristics and origin of abnormally high porosity zones in buried Paleogene clastic reservoirs in the Shengtuo area, Dongying Sag, East China

There are three abnormally high porosity zones developed in buried Paleogene nearshore subaqueous fan and sublacustrine fan clastic＇reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900- 4,400 m, respectively, within the Shengtuo area of the Dongying Sag. Here the porosity of reservoirs buried deeper than 4,000 m can still be greater than 20%. Investigation of these three abnormally high porosity （AHP） zones in the 3rd to 4th member of the Paleogene Shahejie Formation in the Shengtuo area was carried out with utilization of core observation, thin section identification, SEM observation, image analysis, core physical property testing and other technical methods. The results show that, the AHP zones in 2,800-3,200 m and 3,250-3,700 m are visible pores primary AHP zones dominated by significant primary intergranular pores （more than 50% of the total porosity）, while secondary pores and micropores in authigenic clays may develop in some reservoirs. AHP reservoirs in the AHP zone of 3,900-4,400 m are dominated by micropores in matrix, visible pores are mainly grain dissolution pores but with low absolute content （〈 1%）, so this zone belongs to the micropores primary AHP zone. The genesis of the three AHP zones was studied to distinguish between porosity enhancement and porosity preservation. Our research shows that, in deeply buried clastic reservoirs in the Shengtuo area, mineral dissolution occurred in a relatively closed diagenetic system with high temperature and high salinity. Reservoir rocks underwent extensive feldspar dissolution, while detrital carbonate grains and carbonate cements show no evidence of extensive dissolution. Although significant feldspar dissolution pores developed, feldspar dissolution enhanced porosity only a little due to the precipitation of almost isovolumetric dissolution products in the nearby primary intergranular pores in forms of authigenic clays and quartz cements. Net enhanced porosity originating from feldspar dissolution is generally less than 0.25%. Thus, the subsurface dissolution has little impact on the mid-deep buried high porosity reservoirs. Reservoirs in braided channels of middle fans in sublacustrine fans and reservoirs in the middle-front of fan bodies of nearshore subaqueous fans provide the basis for the development of AHP zones. The shallow development of fluid overpressure and early hydrocarbon emplacement have effectively retarded compaction and carbonate cementation, so that the high porosity in the superficial layers is preserved in the mid-deep layers. These are the main controlling factors in the development of AHP zones.

Depositional Patterns and Oil／Gas Accumulation Features of Sha-3 Member Turbidites in Dongying Depression, Bohai Bay Basin

Recent exploration results indicate that a significant exploration potential remains in the Dongying Depression of the Bohai Bay Basin and the undiscovered oil and gas are largely reservoired in subtle traps including turbidite litholigcal traps of the Sha-3 Member. In order to effectively guide the exploration program targeting turbidites, this study will focus on the depositional models of the Sha-3 Member turbidites and oil/gas accumulation characteristics in these turbidites. Two corresponding relationships were found. One is that the East African Rift Valley provides a modern analog for the depositional systems in the Dongying Depression. The other is that the depositional models of line-sourced slope aprons, single point-source submarine fan and multiple source ramp turbidite, established for deep-sea turbidites, can be applied to interpret the depositional features of the turbidite fans of three different origins: slope turbidite aprons, lake floor turbidite fans and delta-fed turbidite fans in the Sha-3 Member. Updip sealing integrity is the key factor determining whether oil/gas accumulates or not in the slope aprons and lake floor fans. The factors controlling oil/gas migration and accumulation in the delta-fed turbidite fans are not very clear. Multiple factors rather than a single factor probably played significant roles in these processes.

Diagenetic Evolution and Formation Mechanisms of High-Quality Reservoirs under Multiple Diagenetic Environmental Constraints:An Example from the Paleogene Beach-Bar Sandstone Reservoirs in the Dongying Depression,Bohai Bay Basin

The diagenetic environment, diagenetic responses, diagenetic transformation model and formation mechanisms of high-quality reservoirs（beach-bar sandstones of the Paleogene fourth member） in the Dongying depression were studied through the analysis of fluid inclusions, thin section and burial evolution history. The diagenetic fluids of the beach-bar sandstone reservoirs evolved from early high salinity and weak alkalinity to low salinity and strong acidity, late high salinity and strong alkalinity and late low salinity and acidity, which were accompanied by two stages of oil and gas filling. The fluids at the margins of the sandbodies were continuously highly saline and strongly alkaline. The western（eastern） reservoirs experienced early open（closed）, middle open, and late closed diagenetic environments during their burial history. The flow pattern was characterized by upwelling during the majority of the diagenesis（in the east, a non-circulating pattern transitioned into an upwelling current）. Due to the evolution of the diagenetic fluids, the diagenetic sequence of the beach-bar reservoirs was as follows： early weak carbonate cementation; feldspar and carbonate cement dissolution and authigenic quartz cementation; late carbonate and anhydrite cementation, authigenic feldspar cementation, and late quartz dissolution; and late carbonate cementation, feldspar dissolution, and authigenic quartz cementation. The diagenetic strength during these stages varied or was absent altogether in different parts of the reservoirs. Due to the closeness of the diagenetic environment and the flow pattern of the diagenetic fluids, the diagenetic products are variably distributed in the sandstones interbedded with mudstones and in the fault blocks. The evolution of multiple alternating alkaline and acidic diagenetic environments controlled the distribution patterns of the reservoir diagenesis and reservoir space, and the reservoir quality index, RQI, increased gradually from the margins to the centers of the sandstones. The closeness of the diagenetic environment and the flow patterns of the diagenetic fluids controlled the differences in the reservoir properties among the fault blocks. With increasing distance from the oil-source faults, the RQI values in the west gradually decreased and in the east initially increased and then decreased.

Hydrocarbon accumulation characteristics of beachbar sandstones in the southern slope of the Dongying Sag, Jiyang Depression, Bohai Bay Basin, China

A number of beach-bar sandstone reservoir beds are developed in the upper fourth member of the Eocene Shahejie Formation （Es4s） on the southern slope of the Dongying Sag.Based on the analysis of seismic and logging data,with characterization and petrographic studies of core and cutting samples,this paper analyzes the hydrocarbon accumulation characteristics in two typical blocks of the Boxing and Wangjiagang oilfields,especially reservoir bed heterogeneity and migration conditions that influence oil and gas distribution,calculates the index of reservoir bed quality （IRQ） with a mathematical method,and discusses the relationship between driving force and resistance of hydrocarbon accumulation.Taking into account the characteristics of thin interbeds in beach-bar sandstones,an experimental model simulated the characteristics of hydrocarbon migration and accumulation in thin interbedded sandstones with reservoir bed heterogeneity.The results showed that hydrocarbon distribution and properties were extremely non-uniform.Reservoir bed and migration conditions controlled hydrocarbon accumulation in beach-bar sandstones.IRQ is above 0.4 in the main hydrocarbon region.Sand body distribution,structural configuration and fault systems controlled the direction of regional migration and location of hydrocarbon accumulation.Simulation experiments indicated that the change of driving force for hydrocarbon migration affected selective accumulation mechanisms.Hydrocarbon moved vertically along fault zones to the reservoir and resulted in the distribution of hydrocarbon in the reservoir.Two kinds of hydrocarbon accumulation models exist in the study area.One is a hydrocarbon accumulation model controlled by reservoir bed heterogeneity and the second is a hydrocarbon accumulation model controlled by a complex migration system with faults connecting sandbodies.Finally,different exploration strategies should be adopted for the detailed exploration for beach-bar sandstone reservoirs according to different geological backgrounds.

Formation Dynamics and Quantitative Prediction of Hydrocarbons of the Superpressure System in the Dongying Sag

Based on the theory of formation dynamics of oil/gas pools, the Dongying sag can be divided into three dynamic systems regarding the accumulation of oil and gas： the superpressure closed system, the semi-closed system and the normal pressure open system. Based on the analysis of genesis of superpressure in the superpressure closed system and the rule of hydrocarbon expulsion, it is found that hydrocarbon generation is related to superpressure, which is the main driving factor of hydrocarbon migration. Micro fractures formed by superpressure are the main channels for hydrocarbon migration. There are three dynamic patterns for hydrocarbon expulsion： free water drainage, hydrocarbon accumulation and drainage through micro fissures. In the superpressure closed system, the oil-driving-water process and oil/gas accumulation were completed in lithologic traps by way of such two dynamic patterns as episodic evolution of superpressure systems and episodic pressure release of faults. The oil-bearing capacity of lithologic traps is intimately related to reservoir-forming dynamic force. Quantitative evaluation of dynamic conditions for pool formation can effectively predict the oil-bearing capability of traps.

Relationship between salt diapirism and faulting in the central structural belt of the Dongying sag,Bohai Gulf basin,China

Many growth faults developed in the Dongying sag of the Jiyang depression of the Bohai Gulf basin, China. These normal growth faults consist of flower-like grabens in the hanging walls of the major faults, accompanied by reverse dragging. The central structural belt is an important structural unit in the Dongying sag, and is divided into a series of small blocks by these faults. These internal blocks can be classified into five structural classes, including parallel blocks, arc-shape blocks, plume-like blocks, ring-radial blocks, and splay blocks. It is shown that these complicated block classes and the 'negative flower-like' fault associations in the central structural belt resulted from regional NNW-SSE extension accompanying local salt diapirism and related reverse dragging, rather than strike-slip faulting. On the basis of the diapirism strength, diapers in the central structural belt can be divided into lower salt ridges and pillows, and blind piercing structures. Diapirs are mainly composed of some salts with a little soft mudstone and gypsum. These structures began forming during deposition of the Sha 3 member and terminated during deposition of the Guangtao formation.

Formation and Accumulation of Hydrocarbons in the Central Uplift,Dongying Depression

A large number of crude oil and rock samples from various oil pools of the Central Uplift in Dongying Depression were investigated to reveal the origin and accumulation of hydrocarbons. The results showed that the composition and areal distribution of hydrocarbons vary with the location of the oil pools. An increasing trend of gammacerane/C30-hopane and steranes/hopanes but a decreasing trend of prystane/phytane （Pr/Ph） and 18（H）-/17（H）- trisnorhopane （Ts/Tm） ratios were observed from southwest to northeast. This indicates a variation of source rocks and hydrocarbon properties. An increasing trend of water salinity with much more input of algae-rich microorganisms in the deposition environment of the source rock was observed from southwest to northeast. However, the thermal maturity of the source rocks showed a decreasing trend in the same direction. Oil-to-oil and oil-to-source rock correlations showed that most oils were sourced from Es3 and Es4 members with a burial depth of more than 3,000-3,150 m and 2,700 m respectively. The oils in the Shinan and Ying 11 sand bodies, which were generally mixed with the Es4 sourced oils, came mostly from Es3 mudstones. It is quite significant that the Es4 derived oils migrated vertically for hundreds of meters and accumulated in an overlying lithologic pool of the Es3^m, i.e., Ying 11 synclinal lithologic pool, which suggests that the mechanisms of migration and accumulation for subtle oil pools in the Dongying Depression are more complex than that of the previously expected.

Distribution of sterane maturity parameters in a lacustrine basin and their control factors:A case study from the Dongying Sag,East China

Fifty samples from the source rocks in Member 3 and Member 4 of the Paleogene Shahejie Formation in the Bohai Bay Basin, East China, were analyzed to investigate the distribution, evolution of the molecular maturity ratios C29ββ/（ββ＋αα） and C2920S/（20S＋20R） and their control factors in the natural geological profile and sequence. The results showed that progressive changes in molecular maturity parameters are associated with major changes in thermal evolution of related biomarkers. Increases in the C29ββ/（ββ＋αα） and C2920S/（20S＋20R） ratios result from the difference in the relative rate between generation and thermal degradation of isomers involved. The samples from a hyper-saline environment below 3.5 km in which evaporitic rocks deposited shows high response of Sr/Ba, Sr/Ca, Fe/ Mn, Pr/n-C17, Ph/n-C18 and gammacerane and low response of Pr/Ph. There presents negative reversal of biomarker maturity C29ββ/（ββ＋αα, C29ββ/（ββ＋αα） and Ts/（Ts＋Ym） in the samples from hypersaline environment, reflecting that the gypsum- halite have negative effect on the isomerization of biomarker and thermal evolution of organic matter. The minerals in evaporites also retard the conventional thermal indicators including vitrinite reflectance （Ro） and pyrolysis peak temperature Tmax at the depth below 3.4 km （i.e. 〉3.4 km）, and these parameters also show the inhibition from overpressure in the range of 2.4-3.4 kin. This result will be helpful in the interpretation and application of molecular maturity parameters for similar saline lacustrine basins.

Distribution and controls of petroliferous plays in subtle traps within a Paleogene lacustrine sequence stratigraphic framework, Dongying Depression, Bohai Bay Basin, Eastern China

The characteristics of petroliferous plays in subtle traps within a sequence stratigraphic framework in the Dongying Depression are investigated in this study.Sand bodies within lowstand systems tracts(LSTs)of sequences,comprising incisedchannel fills,sublacustrine fans,deltas in LSTs,controlled by syndepositional normal faults,and sand bodies within transgressive systems tracts(TSTs)to early highstand systems tracts(HSTs),consisting of beach bars,and turbidites,controlled by the prodelta slope,paleorelief,and syndepositional normal faults,are good subtle reservoirs.Mudstones and shale of deep lake subfacies in TSTs to early HSTs of sequences are source and cap rocks.Abnormal overpressure is the dominant dynamic factor for hydrocarbon migration from source rock to the subtle traps.Normal faults,sand bodies,and unconformities function as conduit systems.Sand bodies distributed in the abnormal overpressure source rocks within LSTs to early HSTs are petroliferous plays in lithologic traps.The petroliferous plays in stratigraphic traps are controlled by unconformities at margins of the Depression.

Sequence Stratigraphic Delineation and Correlation of the Dongying Formation in the Nearshore and Adjacent Sea Areas, Bohai Bay Basin

Based on the analysis of well logs, seismic data, core studies, the Dongying （东营） Formation along the nearshore and adjacent sea areas, Bohai （渤海） Bay basin has been subdivided into three third-order sequences from base to top： namely, sequences SQ1, SQ2 and SQ3. The three sequences have different wireline （SP） log responses, showing triple-section characteristics with SQ1 being characterized by primarily flat baseline with intercalation of relatively low spontaneous potential, SQ2 generally exhibiting weak or moderate amplitude spontaneous potential with finger-shaped peaks, and SQ3 having relatively high spontaneous potential with funnel-shaped log curves. On the basis of the triple-section characteristics, the stratigraphic sequences can be correlated consistently throughout the entire study area. A stratigraphic and sedimentary model for sequences SQ1 to SQ3 of the Dongying Formation in the study area has been proposed. The accommodation space change in the two sides of the asymmetrical basin was examined and the asymmetrical basin has the feature of the asymmetrical accommodation space change. The asymmetrical physiography is a vital factor to influence the accommodation changes in additional to the lake level change, tectonism and sediment supply. This may have important implications to similar basins in other parts of China or elsewhere.

The comprehensive evaluation on resource environmental bearing capacity of central cities in the Yellow River Delta-A case study on Dongying City

Dongying City, which is the most important central city in the Yellow River Delta, is located in the estuary of the Yellow River. With a short land formation time, ecological environment is very weak in this area. To realize the sustainable economic development of the Yellow River Delta, resource environment and resource environmental bearing capacity(REBC) must be improved. This study builds assessment system of regional REBC through resource and economic characteristics in Yellow River Delta and uses principal component analysis(PCA) method to evaluate REBC of five counties and districts in Dongying City in 2011-2015 on the dimensions of time and space. Results show that, on the time dimension, Guangrao County is ranked first, Dongying district second for four years and Hekou and Kenli districts with lower ranks in 2012-2015, indicating that more attention needs to be paid to REBC of Hekou and Dongying districts and these two districts should be included into key monitoring areas. From space scale, REBC in five counties and districts has been gradually improving. In order to further develop REBC in Dongying City, measures such as intensifying protection of urban ecological environment and developing circular economy, etc. should be implemented.

Effects of Network Closure on Cooperative Innovation: Evidence from Dongying's Petroleum Equipment Industry in China

There are two opposing viewpoints on which kind of network configuration provides a more competitive advantage, namely,network closure or structural holes, with the latter occupying the dominant position in the literature. Using social network analysis and negative binomial regression methods, we graph the co-patent network of Dongying's petroleum equipment industry in China and explore its impact on enterprise innovation. The analysis is based on 17 face-to-face interviews, 31 enterprise questionnaires, and 354 co-patent records from the China State Intellectual Property Office identifying cooperative innovation for the years 1988–2013. We find that this network is closed, controlled by state-owned enterprises, and its closure has positive effects on enterprise innovation performance. This may be related to China's unique industrial development history, state system and policies, regional culture and circumstances, and enterprise characteristics. Therefore, for some industries in specific regions, the advantages usually attributed to structural holes and open innovation may not necessarily apply.

Spatial Organization of Innovation in the Oil Equipment Manufacturing Industry: Case of Dongying, China

As innovation and technological change have become increasingly important for the competitiveness and sustainable growth of firms,cooperative innovation is now crucial for traditional industries in the context of globalization.This paper proposes a framework for analyzing the spatial pattern of cooperative innovation for traditional industries in developing countries.Based on in-depth interviews with 35 firms in the oil equipment manufacturing industry in Dongying City,China,this study argues that different firms in the innovation pyramid have various innovation activity preferences and spatial patterns.Firms with high innovation abilities tend to cooperate with various partners that are geographically dispersed and continuously expanding,while firms with inferior abilities usually cooperate with nearby fixed partners.Due to the differences in innovation environment and actor locations,firms tend to make different choices regarding innovation types and models,which highlight the importance of personnel training and basic scientific research at the global scale and practical product research and development at the national scale.Additionally,talent flow is the most important way to realize relationships for firm innovation activity.

Depositional Environment of Es_4~u and Es_3~l Shales Based on Biomarkers from the Boxing Sag of Dongying Depression, East China

The Boxing Sag is located in the southwest of Dongying Depression, southern Bohai Bay Basin of East China. It is one of the main petroliferous sags in the Dongying Depression, and has two major source rocks, namely the upper 4th Member （Es4u） and lower 3rd Member （Es31） shales of Eocene Shahejie Formation, which are the new exploration targets in recent years. In this study, 16 core samples were collected from Es4u and Es31 shales in the Boxing Sag, and the saturate hydrocarbons were analyzed by gas chromatography （GC） and gas chromatography-mass spectrometry （GC-MS）, respectively. The results show that Es4u shale has obvious phytane and gammacerane predominance, higher concentration of tricyclic terpanes and regular steranes, and very low concentration of 4- methly steranes; Es31 shale has pristane predominance, lower concentration of tricyclic terpanes, gammacerane and regular steranes, and higher concentration of 4-methly steranes. The Es4u shale can be further divided into two types based on the distribution of n-alkanes in gas chromatograms： normal distribution and double peak pattern. The biomarker characteristics and sedimentary facies distribution show that Es4u shale was deposited in the saline-hypersaline semi-deep （Type A Es4u shale, sag center） to shallow （Type B Es4u shale, sag edge） lacustrine environments, Es31 shale was deposited in the freshwater-brackish semi-deep-deep lacustrine environments, and the former sedimentary facies maps of Es4u and Es31 in the Boxing Sag are further modified.

Distribution Patterns of Calcite Cement in the Turbidite Sandstones of the Shahejie Formation in the Dongying Depression,Eastern China

Calcite cements are volumetrically dominant among the most diagenetic constituents in turbidite sandstones of the Paleogene Shahejie Formation in the Dongying Depression.The results show carbonate cements mainly occur in three phases:Calcite I(pre-compaction),Calcite II(post-compaction)and ankerite in the turbidite sandstone.The isotopic composition of Calcite I and Calcite II range from−4.3‰to 4.4‰,−3.5‰to 4.3‰PDB,respectively,suggesting that the calcite cements are mainly derived from the interbedded shales.The early calcite cement precipitated from the mixing of lacustrine and meteoric waters at 38-69℃.The late-phase calcite precipitated from pore waters modified by water-rock interactions at 64-126℃.Two distribution patterns of calcite cements can be identified,depending on their position within the sandstone.The peripheral cementation of the sandstones is near the sand-shale contact.The development of cement is controlled by sandstone thickness and the properties of the interbedded shale.For scattered cementation,the distribution of the calcite cement is not controlled by the sand-shale contact.Calcite cement was preferentially distributed in coarse-grained sandstones,indicating that sandstones with high original permeability are the preferred pathway for the migration of early diagenetic fluids.