The screening dependence of superconducting state parameters (λ, μ*, Tc, α and NoV) of six alloys of aluminium doped MgB2 systems are studied in the BCS-Eliashberg-MeMillan framework by employing five forms of ...The screening dependence of superconducting state parameters (λ, μ*, Tc, α and NoV) of six alloys of aluminium doped MgB2 systems are studied in the BCS-Eliashberg-MeMillan framework by employing five forms of dielectric screening function, viz. random phase approximation (RPA), Harrison, Geldart and Vosko (GV), Hubbard and Overhauser in conjunction with Ashcroft's potential. It is observed that electron-phonon coupling strength and Coulomb pseudopotential μ* are quite sensitive to the form of dielectric screening, whereas transition temperature Tc, isotope effect exponent α and effective interaction strength NoV show weak dependence on the form of dielectric screening function. It is found that the RPA form of dielectric screening function yields the best results for transition temperature Tc for all alloys of the Mg-Al-B system. The results obtained using GV screening are much higher than the experimental results. This shows that all the four dielectric screenings used here almost describe superconductivity in all the alloys of the Mg-Al-B system, but the GV screening is not suitable for such an alloy system.展开更多
Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substi...Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substitution for Mg results in an increase of the lattice constant in both a and c directions. The super- conductivity of MgB2 is also suppressed by Hg substitution. The observed suppression of super- conductivity by Hg substitution is discussed in terms of the interband impurity scattering effect in two-band superconductors.展开更多
The discovery of superconductivity in magnesium diboride (MgB2) has opened up a new field in materials science research. It offers a possibility of a new class of high performance superconducting materials for practic...The discovery of superconductivity in magnesium diboride (MgB2) has opened up a new field in materials science research. It offers a possibility of a new class of high performance superconducting materials for practical applications because of the relatively low cost of fabrication, high critical current densities (Jc) and fields, large coherence length, absence of weak links, higher Tc(TC = 39K) compared with Nb3Sn and Nb-Ti alloys (two or four times that of Nb,,Sn and Nb-Ti alloys). However, the weak flux pinning in the magnetic field remains a major challenge. This paper reports the most interesting results on nanomaterial (SiC and Si) doping in magnesium diboride. The high density of nano-scale defects introduced by doping is responsible for the enhanced pinning. The fabrication method, critical current density, microstructures, flux pinning and cost for magnesium diboride bulks, wires and tapes are also discussed. It is believed that high performance SiC doped MgB2 will have a great potential for many practical applications at 5K to 25K up to 5T.展开更多
文摘The screening dependence of superconducting state parameters (λ, μ*, Tc, α and NoV) of six alloys of aluminium doped MgB2 systems are studied in the BCS-Eliashberg-MeMillan framework by employing five forms of dielectric screening function, viz. random phase approximation (RPA), Harrison, Geldart and Vosko (GV), Hubbard and Overhauser in conjunction with Ashcroft's potential. It is observed that electron-phonon coupling strength and Coulomb pseudopotential μ* are quite sensitive to the form of dielectric screening, whereas transition temperature Tc, isotope effect exponent α and effective interaction strength NoV show weak dependence on the form of dielectric screening function. It is found that the RPA form of dielectric screening function yields the best results for transition temperature Tc for all alloys of the Mg-Al-B system. The results obtained using GV screening are much higher than the experimental results. This shows that all the four dielectric screenings used here almost describe superconductivity in all the alloys of the Mg-Al-B system, but the GV screening is not suitable for such an alloy system.
基金This work was supported by the National Science Foundation of China under Grant No. 50372052, 50588201the National Basic Research Program of China (973 program) under Grant No. 2007CB616906+1 种基金the Program for Changjiang Scholars and Innovative Research Team in UniversityAustralian Research Council under Grant No. DP0559872, DP0881739.
文摘Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substitution for Mg results in an increase of the lattice constant in both a and c directions. The super- conductivity of MgB2 is also suppressed by Hg substitution. The observed suppression of super- conductivity by Hg substitution is discussed in terms of the interband impurity scattering effect in two-band superconductors.
文摘The discovery of superconductivity in magnesium diboride (MgB2) has opened up a new field in materials science research. It offers a possibility of a new class of high performance superconducting materials for practical applications because of the relatively low cost of fabrication, high critical current densities (Jc) and fields, large coherence length, absence of weak links, higher Tc(TC = 39K) compared with Nb3Sn and Nb-Ti alloys (two or four times that of Nb,,Sn and Nb-Ti alloys). However, the weak flux pinning in the magnetic field remains a major challenge. This paper reports the most interesting results on nanomaterial (SiC and Si) doping in magnesium diboride. The high density of nano-scale defects introduced by doping is responsible for the enhanced pinning. The fabrication method, critical current density, microstructures, flux pinning and cost for magnesium diboride bulks, wires and tapes are also discussed. It is believed that high performance SiC doped MgB2 will have a great potential for many practical applications at 5K to 25K up to 5T.