Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Complete synchronization of double-delayed Rssler systems with uncertain parameters

In this paper, we investigate complete synchronization of double-delayed RSssler systems with uncertain parameters as the master system is in chaotic synchronization. The uncertain parameters can be nonlinearly expressed in the system. The analysis and proof are given by means of the Lyapunov stability theorem. Based on theoretical analysis, some sufficient conditions of complete synchronization are proved. In order to validate the proposed scheme, numerical simulations are performed and the numerical results show that our scheme is very effective.

Capacitive Model and S-Parameters of Double-Pole Four-Throw Double-Gate RF CMOS Switch

In this paper, we have analyzed the Double-Pole Four-Throw Double-Gate Radio-Frequency Complementary Metal-Oxide-Semiconductor (DP4T DG RF CMOS) switch using S-parameters for 1 GHz to 60 GHz of frequency range. DP4T DG RF CMOS switch for operation at high frequency is also analyzed with its capacitive model. The re-sults for the development of this proposed switch include the basics of the circuit elements in terms of capacitance, re-sistance, impedance, admittance, series equivalent and parallel equivalent of this network at different frequencies which are present in this switch whatever they are ON or OFF.

A strength reduction method based on double reduction parameters and its application

In the traditional strength reduction method,the cohesion and the friction angle adopt the same reduction parameter,resulting in equivalent proportional reduction.This method does not consider the different effects of the cohesion and friction angle on the stability of the same slope and is defective to some extent.Regarding this defect,a strength reduction method based on double reduction parameters,which adopts different reduction parameters,is proposed.The core of the double-parameter reduction method is the matching reduction principle of the slope with different angles.This principle is represented by the ratio of the reduction parameter of the cohesion to that of the friction angle,described as η.With the increase in the slopeangle,ηincreases; in particular,when the slope angle is 45°,tηis 1.0.Through the matching reduction principle,different safety margin factors can be calculated for the cohesion and friction angle.In combination with these two safety margin factors,a formula for calculating the overall safety factor of the slope is proposed,reflecting the different contributions of the cohesion and friction angle to the slope stability.Finally,it is shown that the strength reduction method based on double reduction parameters acquires a larger safety factor than the classic limit equilibrium method,but the calculation results are very close to those obtained by the limit equilibrium method.

CNOP-P-based parameter sensitivity for double-gyre variation in ROMS with simulated annealing algorithm

Reducing the error of sensitive parameters by studying the parameters sensitivity can reduce the uncertainty of the model,while simulating double-gyre variation in Regional Ocean Modeling System(ROMS).Conditional Nonlinear Optimal Perturbation related to Parameter(CNOP-P)is an effective method of studying the parameters sensitivity,which represents a type of parameter error with maximum nonlinear development at the prediction time.Intelligent algorithms have been widely applied to solving Conditional Nonlinear Optimal Perturbation(CNOP).In the paper,we proposed an improved simulated annealing(SA)algorithm to solve CNOP-P to get the optimal parameters error,studied the sensitivity of the single parameter and the combination of multiple parameters and verified the effect of reducing the error of sensitive parameters on reducing the uncertainty of model simulation.Specifically,we firstly found the non-period oscillation of kinetic energy time series of double gyre variation,then extracted two transition periods,which are respectively from high energy to low energy and from low energy to high energy.For every transition period,three parameters,respectively wind amplitude(WD),viscosity coefficient(VC)and linear bottom drag coefficient(RDRG),were studied by CNOP-P solved with SA algorithm.Finally,for sensitive parameters,their effect on model simulation is verified.Experiments results showed that the sensitivity order is WD>VC>>RDRG,the effect of the combination of multiple sensitive parameters is greater than that of single parameter superposition and the reduction of error of sensitive parameters can effectively reduce model prediction error which confirmed the importance of sensitive parameters analysis.

Resonance analysis of single DOF parameter-varying system of magnetic-liquid double suspension bearing

Magnetic-liquid double suspension bearing(MLDSB)is mainly supported by electromagnetic suspension and supplemented by hydrostatic supporting.Its bearing capacity and stiffness can be greatly improved,and then it is suitable for the occasions of medium speed,heavy load.When the bearing system is excited by periodic force,the flow q and current i regulated by the double-closed-loop control mechanism change periodically.Then the risk of parametric resonance in MLDSB is greatly aggravated by the change of the parameter system,which seriously affects its operation stabil-ity and reliability.Therefore,this paper intends to study the resonance characteristics of the parame-ter system of MLDSB.Firstly,Marshall-Duffing equation of the parametric system is established by taking the flow q and the current i as variables respectively.Then,by using the asymptotic method,the occurrence condition and variation rule of the principal,1/2 Harmonic and 1/3 Harmonic para-metric resonance are solved.The results show that only the 1/2 Harmonic resonance of the flow q parameter varying system occurs accompanied by the resonance condition of high frequency.The principal,1/2 Harmonic and 1/3 Harmonic parametric resonance of the current i occur accompanied by the resonance condition of high frequency.And the 1/2 Harmonic resonance of the current i oc-curs accompanied by the non-single value bifurcation and dynamic bifurcation.The paper can pro-vide theoretical reference for the parameter design and stable operation of MLDSB.

A New Inversion Method of Sedimentary Strata For Deriving Double Parameters and Its Applications

The inverse problem of wave equation is the importance of study not only in seismic prospecting but also in applied mathematics. With the development of the research, the inverse methods of 1 - D wave equations have been trending towards the multiple parameters inversion . We have obtained an inverse method with double -parameter, in which medium density and wave velocity can be derived simultaneously. In this paper, to increase the inverse accuracy, the method is improved as follows. Firstly, the formula in which the Green Function is omitted are derived and used. Secondly, the regularizing method is reasonable used by choosing the stable function. With the new method, we may derive elastic parameter and medium density or medium density and wave velocity. Thus, lithology parameters for seismic prospecting may be obtained.After comparing the derived values from the new method with that from previous method, we obtain the new method through which substantially improve the derived accuracy . The new method has been applied to real depths inversion for sedimentary strata and volcanic rock strata in Chaoyanggou Terrace of Songliao Basin in eastern China. According to the inverse results,the gas - bearing beds are determlned.

A New Approach to Calculate Parameters of Induction Generator with Double Windings

The accuracy prediction for the performance of an induction generator depends much on the parameters of the equivalent circuit. This paper presented a new way for calculating these parameters of induction generator with double windings. The method is based on 2D time-dependent magnetic field coupled with electric circuit. An application example of a 12-phase self-excited induction generator (SEIG) was provided to demonstrate the effectiveness of the presented approach. Some of the calculated results show good coincidence with the experiment values.

Dependence of Plasma Parameters on Plate Separation and Filament Location in a Double Plasma Device

A pair of stainless steel (ss) plates separates the source and target regions of a double plasma device. Two sets of tungsten filaments, placed at different distances from the ss plates, are then used to produce plasma alternately and the plasma parameters in the source and target regions for different discharge voltage, discharge current and plate separation are measured using Langmuir probes. It is found that plasma density and electron temperature are considerably affected and respond differently to changes in the plate separations and the position of the filaments.

Parametric sensitivity analysis of bearing characteristics of single DOF autonomous system of magnetic-liquid double suspension bearing

The mathematical model of single degree of freedom(DOF)nonlinear autonomous bearing system under constant flow supporting model is deduced.The single DOF nonlinear autonomous bearing system is transformed with the method of linear and nonlinear treatment,the mathematical expression and parameters sensitivity of relative error of stiffness and damping are presented.Finally,the main factors of magnetic-liquid double suspension bearing(MLDSB)are analyzed,and the influence on bearing performance indicators of single DOF nonlinear autonomous bearing system of main factors is revealed.The results show that linear stiffness/damping is the first part of equivalent stiffness/damping,and the second and third parts are high order minor term of Tayor series transform.The film thickness,the magnetic-liquid proportionality coefficient,the mass of rotor are the major influence factor of the bearing performance.The research can provide the theoretical reference for the design and nonlinear analysis of MLDSB.

An Optimal Double Inequality among the One-Parameter, Arithmetic and Geometric Means

In the present paper, we answer the question: for 0a what are the greatest value p(a) and the least value q(a) such that the double inequality Jp(a,b)aA(a,b)+ (1-a)G(a,b)Jq(a,b) holds for all a,b>0 with a is not equal to?b ?

A Novel Fault Location Algorithmfor Double-Circuit Transmission Lines based on Distributed Parameter

Anewfault location algorithmfor double-circuit transmissionlines is described inthis paper.Theproposed method uses data extractedfromtwo ends of the transmissionlines andthus eliminates the effects ofthe source impedance andthe fault resistance.The distributed parameter model and the modal transformationare also employed.Depending on modal transformation,the coupled equations of the lines are converted intodecoupled ones.Inthis way,the mutual coupling effects between adjacent circuits of the lines are eliminatedandtherefore an accurate fault location can be achieved.The proposed methodis tested via digital simulationusing EMTP in conjunction with MATLAB.The test results corroborate the high accuracy of the proposedmethod.

Double设计在对称化L_2-偏差下的均匀性

二水平部分因子设计在工农业生产、科学实验等领域得到广泛应用,因此有关二水平部分因子设计的研究一直是热点问题.最近,一种称为doubling的方法被用来构造二水平部分因子设计,特别是在构造分辨度为Ⅳ的设计时,这种方法是非常简单但很实用的方法,本文从均匀性的角度来研究double设计,进一步讨论doubling方法的实用性,利用对称化L_2-偏差作为均匀性的测度,发现double设计D(X)的均匀性与初始设计X的均匀性有着密切的联系,给出了double设计在对称化L_2-偏差下的下界.

Double设计在对称化L_2-偏差下两个下界的比较

从列平衡的角度出发,将设计的中心化L2-偏差、对称化L2-偏差、可卷L2-偏差分别用二次型和均衡模式表示,可分别得到两个下界,它们都适合用来评价正交设计的均匀性。以double设计的对称化L2-偏差为例,证明了这两种方法算出的下界是相等的。

Double设计在对称化L_2-偏差下的广义字长型

在工农业生产、科学实验等领域都广泛应用到二水平部分因子设计.最近,在构造二水平部分因子设计时一种称为doubling的方法被使用.特别是在构造分辨度为IV的设计时,doubling是非常简单但很实用的方法.本文利用对称化L2-偏差作为均匀性的测度,得到了double设计D(X)的对称化L2-偏差值与初始设计X的广义字长型之间的关系.利用上述关系,我们断定对于具有广义较小低阶混杂的初始设计X,其对应的double设计D(X)也应该具有较小的对称化L2-偏差值,也就是说,D(X)应该具有较好的均匀性.

基于WOA-BP算法的氟金云母钻削工艺参数优化

通过氟金云母陶瓷钻削实验,测试了在不同加工参数下的材料去除量和刀具磨损量。利用WOA算法优化BP神经网络,并基于单因素实验值和WOA-BP网络预测值,利用最小二乘法拟合,建立了材料去除率和刀具磨损率关于工艺参数的一元模型,以相关系数检验了模型的精确度。在一元模型的基础上提出了多元模型,基于正交实验值和WOA算法对多元模型进行求解,模型误差在合理范围内。以材料去除率最大和刀具磨损率最小为优化目标,基于WOA算法进行了工艺参数双目标优化,得到了一组最优参数。基于最优工艺参数进行验证实验,实验结果表明得到的最优参数是合理的。

Dynamics and adaptive control of a dual-arm space robot with closed-loop constraints and uncertain inertial parameters

A dynamics-based adaptive control approach is proposed for a planar dual-arm space robot in the presence of closed-loop constraints and uncertain inertial parameters of the payload. The controller is capable of controlling the po- sition and attitude of both the satellite base and the payload grasped by the manipulator end effectors. The equations of motion in reduced-order form for the constrained system are derived by incorporating the constraint equations in terms of accelerations into Kane＇s equations of the unconstrained system. Model analysis shows that the resulting equations perfectly meet the requirement of adaptive controller design. Consequently, by using an indirect approach, an adaptive control scheme is proposed to accomplish position/attitude trajectory tracking control with the uncertain parameters be- ing estimated on-line. The actuator redundancy due to the closed-loop constraints is utilized to minimize a weighted norm of the joint torques. Global asymptotic stability is proven by using Lyapunov＇s method, and simulation results are also presented to demonstrate the effectiveness of the proposed approach.

In situ growth process of Mg-Fe layered double hydroxide conversion film on MgCa alloy

In this study,an environment-friendly layered double hydroxide(LDH)film has been deposited on Mg Ca alloy by a two-step technique.To improve the chemical conversion technique and control the film properties,batch studies have been carried out to address various process parameters such as pH value,treatment temperature and immersion time.The chemical composition was determined by X-ray diffractometry and energy dispersive X-ray spectroscopy.The morphology was characterized by scanning electron microscopy.The corrosion resistance of the samples with various films was compared by polarization curves and immersion test.It is found that the transformation duration of Mg-Fe LDH is long.Too high pH value and temperature has harmful effect on the purity of the film composition.The corrosion resistance of the films formed at low value of pH or high temperature or short treatment time is deteriorative.The optimum process is as follows:the sample is first immersed in the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH value of 5 at a temperature of 55℃for 1 h to form a precursor film,and then this precursor film is immersed into the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH of 11 at 55℃for 24 h to obtain the Mg-Fe LDH conversion film.

Local Measurement of Gas-Liquid Bubbly Flow with a Double-Sensor Probe

A double-sensor probe was used to measure local interfacial parameters of a gas-liquid bubbly flow in a horizontal tube. The parameters included void fraction, interfacial concentration, bubble size distribution, bubble frequency and bubble interface velocity. The authors paid special attention to the probe design and construction for minimizing measurement errors. Measures were also taken in the design of sensor ends for preventing corrosions in the flow. This is an effort to improve the current double-sensor probe technique to meet the ever-increasing needs to local parameter measurements in gas-liquid two-phase flows.

Double perovskite oxides Sr_2Mg_(1-x)Fe_xMoO(6-δ) for catalytic oxidation of methane

The double perovskite oxides Sr2Mg1-xF exMoO6-δ were investigated as catalysts for the methane oxidation.The structural properties of catalysts were characterized in detail by X-ray diffraction,X-ray photoelectron spectroscopy and X-ray absorption spectroscopy.The catalytic property was strongly influenced by the Fe substitution.The relation between catalytic performance and the degree of Fe substitution was examined with regard to the structure and surface characteristics of the mixed oxides.The Fe-containing catalysts exhibited higher activity attributable to the possible（Fe2＋,Mo6＋） and （Fe3＋,Mo5＋）valency pairs,and the highest activity was observed for Sr2Mg0.2Fe0.8MoO6-δ.The enhancement of the catalytic activity may be correlated with the Fe-relating surface lattice oxygen species and was discussed in view of the presence of oxygen vacancies.