A STUDY ON THE STRUCTURAL EFFECT OF DOUBLE BRIDGES CONJUGATED SYSTEMS I.CARBONYL-IMINO SYSTEM

The struetural effect of the conjugative system(C)with carbonyl-imino bridges has been studied.The results show that:In the conjugated system(C),there is no electronic absorption peak attributable to the whole system,but there are three π-π* bands each nt which displays chacactecistics of its own independently.These indicate that the two bridges-carbonyl-and-imino-can block the tlanSmlSSion of the conjngative polarization of the whole system,so as to form three segments,this is verified by means of chemical synthesis and degradation.

Effect of activation temperature on the properties of double layer capacitance of diatomite-templated carbon

1 Introduction In recent years porous carbons have been widely used in many fields such as energy storage(Mc Creery,2008;Liu et al,2009;Ho et al,2014;Yang et al,2015),adsorption,wastewater treatment,air purification

Fano Effect and Anti-Resonance Band in a Parallel-Coupled Double Quantum Dot System with Two Multi-Quantum Dot Chains

A parallel-coupled double quantum dot （PCDQD） system with two multi-quantum dot chains is designed. Conductance versus Fermi energy level is investigated utilizing the non-equilibrium Green＇s function approach. If two quantum dots are added on each side of the PCDQD system, additional Breit Wigner and Fano resonances occur in the conductance spectra. If quantum dots are added on one side of the system, small Fano resonances can be observed in the conductance spectra. Adjusting the number of side-coupled quantum dots, the anti-resonance bands emerge at different positions, which makes the system applicable as a quantum switching device. Moreover, the I-V characteristic curve presents the step characteristic and the width of the step decreases with increasing the number of side-coupled quantum dots.

Simulation of the relationship between roadway dynamic destruction and hypocenter parameters

Many factors can induce rock burst. Shock energy and shock distance are two key factors affecting rock burst. The 32101 roadway of the Xingcun coal mine, which has a tendency for rock burst, was used as an example. The dynamic module of Itasca’s FLAC (Fast Lagrangian Analysis of Continua) 2D explicit finite-difference software was used to simulate the roadway’s destruction. The vibration velocity and displacements of the rock surrounding the roadway were modeled for different shock energies and hypocenter distances. The simulation results indicate that the vibration velocity and displacement of rock surrounding the roadway have a quadratic relationship to the shock energy and a power law relationship to the distance of the hypocenter from the roadway. A dynamic view of the process was obtained from a series of "snap-shots" collected at 100 different time steps. This shows an isolating "river" is first formed at the hypocenter. The region above the "river" is a low stress zone while below the "river" a high stress zone exists. This high stress zone surrounds the ribs of the roadway in a "double ear" pattern. Continuous and repeated action of the high stress in the "double ear" shaped zone destroys the roadway.

Fluid Flow Past a Circular Cylinder with Tandem Rod and Staggered Rod at Low Reynolds Number

The flow past a primary cylinder with one tandem control rod and one staggered control rod is simulated in this paper through solving the Navier-Stokes equations. Two examples are simulated to validate the model, and the results matched well with those of previous researches. The Reynolds number based on the diameter of the primary cylinder is 500. The diameter ratio between the control rod and the primary cylinder （d/D） is 0.25. It was found that the effect of the combination of one upstream tandem control rod and one staggered control rod on the hydrodynamics of the primary cylinder is a linear superposition of the effect of a corresponding single control rod, and the effect of the upstream tandem control rod is dominant at larger spacing ratios such as G/D=2. For the combination of a downstream tandem control rod and a staggered control rod, the effect of the control rods is different from that of the corresponding single control rod in the region of 0.2〈G/D〈0.5 ＆ 30°〈a〈120° and 0.9〈G/D〈1.4 ＆ 30°〈a〈50°, where the additional effect is obvious. In this case, the effect of the downstream tandem control rod is dominant at small spacing ratios （such as G/D=0.1）. At moderate spacing ratios such as G/D=0.4, the effects of the tandem control rod and the staggered control rod are comparable in both cases.

Mechanism of Quantum Consciousness that Synchronizes Quantum Mechanics with Relativity—Perspective of a New Model of Consciousness

Synchronization of quantum mechanics with relativity has been considered differently from the present quantum gravity models. It is originated from the roots of philosophy of physics and the basic concepts of relativity & quantum mechanics. It emphasizes the fact that two conscious observers are necessary to experience one conscious moment. Various concepts of consciousness have been discussed and emphasized the necessity for the introduction of a new model of quantum consciousness. A quantum coordinate system has been introduced to explain the present understanding of the phenomena “observation” and “reality”. It has been elaborated that the observation defined by physics is confined to Lorentz space time coordinate system, Minkowski coordinate system and general relativity. But phenomena of observation cannot be completed without considering one more hidden transformation explaining quantum coordinate system which transforms the quantum states into relativistic coordinate system as an interaction between two conscious observers explained by an interactive mechanism of quantum states. A flow chart has been illustrated by a mechanism giving rise to conscious moment and proposed a new model of consciousness. It emphasizes on the fact that “reality” is different from “observation” defined by physics. It affects the relativistic factor of special relativity and suggests a modification for it. If this modified relativistic factor is proved experimentally, the results establish consciousness’s mechanism and a remarkable breakthrough in physics of consciousness studies.

Carrier-envelope-phase effect in nonsequential double ionization of Ar atoms by few-cycle laser pulses

A classical ensemble method is used to investigate nonsequential double ionization（NSDI） of Ar atoms irradiated by linearly polarized few-cycle laser pulses. The correlated-electron momentum distribution（CMD） exhibits a strong dependence on the carrier-envelope phase（CEP）. When the pulse duration is four cycles, the CMD shows a cross-like structure, which is consistent with experimental results. The CEP dependence is more notable when the laser pulse duration is decreased to two cycles and a special L-shaped structure appears in CMD. Recollision time of returning electrons greatly depends on CEP, which plays a significant role in accounting for the appearance of this structure.

Effects of Doubled Carbon Dioxide on Rainfall Responses to Radiative Processes of Water Clouds

The effects of doubled carbon dioxide on rainfall responses to radiative processes of water clouds are investigated in this study.Two groups of two-dimensional cloud-resolving model sensitivity experiments with regard to pre-summer heavy rainfall around the summer solstice and tropical rainfall around the winter solstice are conducted and their five-day averages over the model domain are analyzed.In the presence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the decrease associated with the enhanced atmospheric cooling to the increase associated with the enhanced infrared cooling as a result of the exclusion of radiative effects of water clouds.Doubled carbon dioxide leads to the reduction in tropical rainfall,caused by the removal of radiative effects of water clouds through the suppressed infrared cooling.In the absence of radiative effects of ice clouds,doubled carbon dioxide changes pre-summer rainfall from the increase associated with the strengthened atmospheric warming to the decrease associated with the weakened release of latent heat caused by the elimination of radiative effects of water clouds.The exclusion of radiative effects of water clouds increases tropical rainfall through the strengthened infrared cooling,which is insensitive to the change in carbon dioxide.

Viscous Heating for Laminar Liquid Flow in Microtubes

Using de-ionized ultra-filtered water (DIUFW) as the working fluid, the effects of viscous dissipation in micro-tubes with inner diameters of 19.9μm and 44.2μm, respectively, have been studied by experiments, the theoretical analysis and the numerical simulation at laminar state. Based on thermal imaging technology of micro-area, the temperature rise resulted from the viscous dissipation in microtube is measured by employing IR camera with a specially magnifying lens at different Reynolds numbers. A 2-D model adapted to microtube is presented to simulate the viscous dissipation characteristic considering electric double layer effect (EDL). The investigation shows the calculating results are in rough agreement with the experimental data if removing the experimental uncertainties. Based on the experimental and the numerical simulation results, a viscous dissipation number which can describe the law of the viscous heating in microtube is summed up and it explains the abnormity of the flow resistance in microtubes.

Conductivity of Poly(methyl methacrylate)/Polystyrene/Carbon Black and Poly(ethyl methacrylate)/Polystyrene/Carbon Black Ternary Composite Films

Poly(methyl methacrylate)(PMMA)/polystyrene(PS)/carbon black(CB)and poly(ethyl methacrylate)(PEMA)/PS/CB ternary composite films were obtained using solution casting technique to investigate double percolation effect.In both PMMA/PS/CB and PEMA/PS/CB ternary composite films,the CB particles prefer to locate into PS phase based on the results of calculating wetting coefficient,which is also confirmed by SEM images.The conductivity of the films was investigated,and the percolation threshold(￠c)of both ternary composite films with different polymer blend ratios was determined by fitting the McLachlan GEM equation.Conductivity of PMMA/PS/CB ternary composite films showed a typical double percolation effect.However,due to the double emulsion structure of PEMA/PS polymer blends,the PEMA/PS/CB ternary composite films(PEMA/PS=50/50)showed a higher￠c,even CB only located in PS phase,which conflicts with the double percolation effect.A schematic diagram combined with SEM images was proposed to explain this phenomenon.

Photo-sensitive characteristics of negative resistance turn-around occurring in SIPTH

Influences of light irradiation on the negative resistance turn-around characteristics of static induction photosensitive thyristor （SIPTH） have been experimentally and theoretically studied. As the gate current of SIPTH is increased by the light irradiation, the potential barrier in the channel is reduced due to the increase in voltage drop across the gate series resistance. Therefore, SIPTH can be quickly switched from the blocking state to the conducting state by relatively low anode voltage. The optimal matching relation for controlling anode conducting voltage of SIPTH by light irradiation has also been represented.