Self-assembly of perovskite nanocrystals:From driving forces to applications

Self-assembly of metal halide perovskite nanocrystals(NCs)into superlattices can exhibit unique collective properties,which have significant application values in the display,detector,and solar cell field.This review discusses the driving forces behind the self-assembly process of perovskite NCs,and the commonly used self-assembly methods and different self-assembly structures are detailed.Subsequently,we summarize the collective optoelectronic properties and application areas of perovskite superlattice structures.Finally,we conclude with an outlook on the potential issues and future challenges in developing perovskite NCs.

Research on the Spatio-Temporal Evolution and Driving Forces of Green Spaces in the Central Urban Area of Zunyi City

Green space,as a medium for carrying out urban functions and guiding urban development,is becoming a scarce resource along with the urbanization process and the intensification of environmental problems.In the face of the spatial mismatch between high demand and low supply,it is of great significance to clarify the evolution mechanism of green space to undertake national spatial planning,protect the natural strategic resources in the urban fringe area,and promote the sustainable development of the“three living spaces.”The study focuses on the Zunyi City Center,selecting the 20 years of rapid development following its establishment as a city as the study period.It explores the dynamic evolution of green space and the main driving forces during different periods using remote-sensing image data.The study shows that from 2003 to 2023,the total scale of green space has an obvious decreasing trend along with the expansion of the urban built-up area.A large amount of arable land is being converted to construction land,resulting in a sudden decrease in arable land area.In the past 10 years,the comprehensive land use dynamics have accelerated.Still,the spatial difference has gradually narrowed,indicating that the overall development intensity of Zunyi City’s central urban area has increased.There is a gradual spread of the trend to the hilly areas.The limiting effect of the mountainous natural environment on the city’s development has gradually diminished under the superposition of external factors,such as economic development,industrial technological upgrading,and policy orientation so the importance of the effective protection and rational utilization of urban green space has become more prominent.

Driving forces and their relative contributions to hydrocarbon expulsion from deep source rocks: A case of the Cambrian source rocks in the Tarim Basin

To thoroughly understand the dynamic mechanism of hydrocarbon expulsion from deep source rocks,in this study,five types of hydrocarbon expulsion dynamics(thermal expansion,hydrocarbon diffusion,compaction,product volume expansion,and capillary pressure difference(CPD))are studied.A model is proposed herein to evaluate the relative contribution of different dynamics for hydrocarbon expulsion using the principle of mass balance,and the model has been applied to the Cambrian source rocks in the Tarim Basin.The evaluation results show that during hydrocarbon expulsion from the source rocks,the relative contribution of CPD is the largest(>50%),followed by compaction(10%-40%),product volume expansion(5%-30%),and thermal expansion(2%-20%).The relative contribution of diffusion to hydrocarbon expulsion is minimal(<10%).These results demonstrate that CPD plays an important role in the hydrocarbon expulsion process of deep source rocks.The hydrocarbon expulsion process of source rocks can be categorized into three stages based on the contribution of different dynamics to the process:the first stage is dominated by compaction and diffusion to expel hydrocarbons,the second stage is dominated by product volume expansion and CPD,and the third stage is dominated by product volume expansion and CPD.This research offers new insights into hydrocarbon exploration in tight oil and gas reservoirs.

Thermodynamic re-assessment of the Mg-Gd-Y ternary system coupling with the driving forces for phase precipitations during aging process

Based on the available experimental phase equilibrium relations and aging precipitation sequences,the Mg–Gd–Y ternary system has been thermodynamically re-assessed by means of CALPHAD technique.To simulate the experimentally reported aging precipitation sequence,α(Mg)_(SS)(supersaturated)→GP zones(D019-type,metastable)→β’-Mg_(7)Gd(c-bco,metastable)→β_(1)-Mg_(3)Gd(fcc,metastable)→β-Mg_(5)Gd(fcc,stable)near the Mg–Gd side,andα(Mg)SS(supersaturated)→β’-Mg_(7)Y(c-bco,metastable)→β-Mg_(24)Y_(5)(bcc,stable)near the Mg–Y side,the effective nucleation driving forces obtained by deducting the nucleation resistances from the thermodynamic driving forces are calculated and analyzed.Two metastable components,GP zones(D019-type)andβ’(c-bco)ordered fromα(Mg)_(SS),do not exist in the stable equilibrium phase diagram but appear in the annealing process of typical alloys.The Redlich–Kister equations are adopted to describe three solution phases,Liquid,HCP_A3 and BCC_A2.The intermediate compounds Mg_(2)Y,Mg_(24)Y_(5),Mg_(2)Gd,Mg_(3)Gd and Mg_(5)Gd are expressed by the formulas of(Mg,Y)_(2/3)(Gd,Mg,Y)_(1/3),Mg_(24/29)(Gd,Mg,Y)_(4/29)Y1/29,(Gd,Mg)_(2/3)(Gd,Mg,Y)_(1/3),(Gd,Mg)_(3/4)(Gd,Mg,Y)_(1/4)and Mg_(5/6)(Gd,Mg,Y)_(1/6),respectively.In particular,the two-sublattice models(Gd,Mg,Y)_(1/2)(Gd,Mg,Y)_(1/2),(Gd,Mg,Y)_(3/4)(Gd,Mg,Y)_(1/4)and(Gd,Mg,Y)_(7/8)(Gd,Mg,Y)_(1/8)have been respectively used to describe the stable Mg(Gd,Y)(BCC_B2)alloy compound as well as the metastable GP zones(D019-type)andβ’(c-bco)phase,in order to cope with the order-disorder transitions.A set of self-consistent thermodynamic parameters has been obtained to ensure the thermodynamic calculations well consistent with the reported experimental data,containing not only the stable equilibrium phase diagram but also the aging precipitation sequence.

Spatial patterns and driving forces of land use change in China during the early 21st century

Land use and land cover change as the core of coupled human-environment systems has become a potential field of land change science （LCS） in the study of global environmental change. Based on remotely sensed data of land use change with a spatial resolution of 1 km × 1 km on national scale among every 5 years, this paper designed a new dynamic regionalization according to the comprehensive characteristics of land use change including regional differentiation, physical, economic, and macro-policy factors as well. Spatial pattern of land use change and its driving forces were investigated in China in the early 21 st century. To sum up, land use change pattern of this period was characterized by rapid changes in the whole country. Over the agricultural zones, e.g., Huang-Huai-Hai Plain, the southeast coastal areas and Sichuan Basin, a great proportion of fine arable land were engrossed owing to considerable expansion of the built-up and residential areas, resulting in decrease of paddy land area in southern China. The development of oasis agriculture in Northwest China and the reclamation in Northeast China led to a slight increase in arable land area in northern China. Due to the ＂Grain for Green＂ policy, forest area was significantly increased in the middle and western developing regions, where the vegetation coverage was substantially enlarged, likewise. This paper argued the main driving forces as the implementation of the strategy on land use and regional development, such as policies of ＂Western Development＂, ＂Revitalization of Northeast＂, coupled with rapidly economic development during this period.

Understanding cultivated land dynamics and its driving forces in northern China during 1983-2001

Based on the long-term serial NOAA/NDVI dataset during 1983-1999 and SPOT/VGT dataset in 2001, the land use/cover change information in the 13 provinces of northern China was extracted based on the analysis of the cultivated landscape characteristics at first, then the effects of human activities on cultivated land process were explored by GIS and the driving forces of cultivated land change were investigated. The conclusions can be drawn as follows： （1） The constant increase of weak ecological function land as desert and cultivated land and the decrease of the ecological function land of forest and shrub were the main characteristics of the land use/cover change in the 13 provinces from 1983 to 1999, which showed the effects on the ecological adjustment fimction. However, such situations were changed to some extent in the 2000s because of the eco-construction policy of the government. （2） From 1983 to 2001, the Barycenter of cultivated land tended to move from northeast to southwest with the topography and transportation situations being the main influences on the cultivated land distribution. It is found that the cultivated land use intensity decreased noticably with the increase of distance from the main communication arteries. （3） The improvement of the people＇s living standard is closely related with the cultivated land change. The structural adjustment in the agricultural land caused by economic development and the improvement of the people＇s living standard ig an important factor affecting the cultivated land change in northern China from 1983 to 2001

Changes in cultivated land patterns and driving forces in the Three Gorges Reservoir area, China, from 1992 to 2015

Changes of cultivated land patterns caused by major water conservation projects are rarely reported. We selected the Three Gorges Reservoir area in China to study the change in area and landscape pattern of the cultivated land in the head,central, and tail areas of the reservoir that took place between 1992 and 2015;we then studied the spatial distribution of the cultivated land in the three parts of the reservoir;finally, we studied the driving forces behind the changes in the cultivated land. The results derived are as follows.(1) During the construction of the Three Gorges Project(TGP, 1992–2015), the area of cultivated land around the reservoir decreased by30.23 million ha. This reduction occurred in phases:the most severe change in cultivated land occurred during the later stage of the project(2002–2010);only 0.62 million ha of cultivated land did not change between 1992 and 2015.(2) Spatial pattern analysis showed that the cultivated land in the three parts of the reservoir changed from a northern distribution to a southern distribution;thus, the area of cultivated land in the north decreased over the time period. The area of cultivated land in the head and tail areas decreased by varying degrees, while it increased in the central area over the 23 years, indicating that the change in cultivated land showed regional differences.(3) The TGP, the policy of reverting farmland to forest,and urbanization were the main driving factors for the change of cultivated land, but there were differences in their impacts at different stages.(4) According to the patch dynamics of the land cover change, the degree of change gradually intensified during the early and later stages of the project and then stabilized during the operational period. Our research provides scientific support for the protection of cultivated land resources and food security in the reservoir area and for the coordination of social and economic development, which is of great significance to sustainable development in the reservoir area.

Analysis of Major Driving Forces of Ecological Footprint Based on the STRIPAT Model and RR Method:A Case of Sichuan Province,Southwest China

The Ecological Footprint(EF) equation provides useful accounting to analyze the relationship between human activities and the environment.Knowledge of the specific forces driving EF is not fully understood but the STIRPAT model provides a simple framework for decomposing the impact of human activities on environment.We applied the EF model in Sichuan Province,China to assess the impact of human activities.The per capita EF increased by 2 fold in the 14 years between 1995 and 2008,but ecological capacity decreased in the same period,suggesting that the biologically productive area of Sichuan Province is inadequate to sustain human activities.According to the refined STIRPAT model,the hypothesized driving forces of EF include population size(P),GDP per capita(A1),quadratic term of GDP per capita(A2),percentage of GDP from industry(T1) and urbanization rate(T2).However,the multi-collinearity among these drivers could be a substantial problem which may reveal negative effect in the final results.Application of the Ridge Regression(RR) method to fit the STIRPAT model had the advantage of being able to avoid the collinearity among independent variables.The results showed that population is the principal driving force of EF variation in Sichuan Province and that urbanization and industrialization also have a positive association with the EF.Analysis of affluence elasticity(EEA) showed that the relationship betweenEF and economic growth was not curvilinear,suggesting that variation of EF does not follow an Environmental Kuznets Curve relative to economic growth in Sichuan Province.

On arable land changes in Shandong Province and their driving forces

The decrease of total cultivated area and the lower per capita available arable land resource are now serious problems in Shandong Province, a major agricultural province in China. These problems will become more serious along with the further development of economy. In this paper, based on the statistical information at provincial and county levels, the changes of arable land in Shandong Province and their driving forces during the last 50 years are analyzed. The general changing trends of arable land and per capita available arable land are reducing, and the trends of decrease will continue when the economy is developing. The result of GIS spatial analysis shows that the change of the arable land use in Shandong Province has a regional difference. Eight variables having influences on cultivated land change are analyzed by principal component analysis. The results show that the dynamic development of economy, pressure of social system and progress of scientific techniques in agriculture are the main causes for cultivated land reduction. The principal factors which can be considered as driving forces for arable land change include per capita net living space, total population and per ha grain yield. By using regressive equation, along with analysis on population growth and economic development, cultivated areas in Shandong Province in 2005 and 2010 are predicted respectively. The predicted cultivated areas in Shandong will be 6435.47 thousand hain 2005 and 6336.23 thousand ha in 2010 respectively.

Land use and land cover change and its driving forces in Maqu County, China in the past 25 years

Maqu County is located in the northeast Qinghai-Tibetan Plateau, and it is the main watershed for the Yellow River. The ecosystem there is extremely vulnerable and sensitive to climate change and human activities, which have caused significant deterioration of the eco-environment in this region. In order to restore the ecological environment, a government project to restore the grazing areas to grassland was implemented in Maqu County in early 2004. This study evaluates the effects of that restoration project on land use and land cover change （LUCC）, and explores the driving forces of LUCC in Maqu County. In the study we used Landsat images obtained in 1989, 2004, 2009, and 2014 to establish databases of land use and land cover. Then we derived LUCC information by overlaying these layers using GIS software. Finally, we analyzed the main forces responsible for LUCC. The results showed that forests, high-coverage grasslands, and marshes experienced the most significant decreases during 1989–2004, by 882.8 ha, 35,250.4 ha, and 2,753.4 ha, respectively. However, moderate- and low-coverage grasslands and sand lands showed the opposite trend, increasing by 12,529.7 ha, 25,491.0 ha, and 577.5 ha, respectively. LUCC in 2004–2009 showed that ecological degradation slowed compared with 1989？2004. During 2009–2014, high- and moderate-coverage grasslands increased obviously, but low-coverage grasslands, marshes, unused lands, sand lands, and water areas showed the opposite trend. These results suggested that the degradation of the eco-environment was obvious before 2009, showing a decrease in the forests, grasslands, and water areas, and an increase in unused lands. The ecological degradation was reversed after 2009, as was mainly evidenced by increases in high- and mod-erate-coverage grasslands, and the shrinkage rate of marshes decreased obviously. These results showed that the project of restoring grazing lands to grassland had a positive effect on the LUCC. Other major factors that influence the LUCC include increasing temperature, variation in the seasonal frozen soil environment, seasonal overgrazing, and pest and rodent damage.

Spatio-temporal Pattern and Driving Forces of Comprehensive Agricultural Productivity in Jilin Province,China

Improving comprehensive agricultural productivity is an important measure to realize agricultural modernization.Based on the data from Jilin Statistical Yearbook,this study analyzed the spatial and temporal characteristics of comprehensive agricultural productivity discrepancy in the main agricultural production areas of Jilin Province,China.The comprehensive agricultural productivity of 25 county-level administrative units were evaluated by a comprehensive index system based on five aspects which included 20 indicators from 2004 to 2017.The pattern of the discrepancy was analyzed by the spatial differentiation indices and spatial convergence theory.The results were as follows:1) the overall comprehensive agricultural productivity was in a ’W-type’ rising trend;2) the discrepancy was in’inverted W-type’ trend;3) the spatial distribution characteristics were mainly discrete plaque and ’inverted V-type’;4) the formation of differences was forced by a combination of internal and external driving forces.Our study demonstrates the effectiveness of rising agricultural productivity and the level of economic and social developments in different counties in Jilin Province.

An Analysis on Driving Forces of Arable Land Resource Change in Jieshou City

By the qualitative and quantitative analysis method,we analyze the driving forces of arable land resource change in Jieshou City and find that the arable land resource change in Jieshou City arises mainly from social and economic driving forces. Based on the social and economic indicator data about arable land resource in Jieshou City,we use principal component analysis to establish evaluation index system,and analyze the driving forces of dynamic arable land resource change in Jieshou City during 2006-2015. It is concluded that Jieshou's arable land change is mainly affected by economic and social factors.

Tier Ⅲ and Ⅳ cities Will Be the Main Driving Forces for Future E-business

Recently,the China E-Business Research Center(100EC.CN)released the'2015 Monitoring Report of China E-business Market'.The report says that the China E-business transaction volume amounted to 18.3 trillion yuan in 2015,up by 36.5%from a year ago,and marking an increase of 5.1 percentage points in growth rate.Meanwhile,the B2B E-business trade value totaled 13.9 trillion yuan,up

Spatial-temporal Dynamics and Driving Forces of Land Development Intensity in the Western China from 2000 to 2015

The change in land development intensity is an important perspective to reflect the variation in regional social and economic development and spatial differentiation.In this paper,spatial statistical analysis,Ordinary Least Squares(OLS),and Geographically weighted regression(GWR)methods are used to systematically analyse the spatial-temporal characteristics and driving forces of land development intensity for 131 spatial units in the western China from 2000 to 2015.The findings of the study are as follows:1)The land development intensity in the western China has been increasing rapidly.From 2000 to 2015,land development intensity increased by 3.4 times on average.2)The hotspot areas have shifted from central Inner Mongolia,northern Shaanxi and the Beibu Gulf of Guangxi to the Guanzhong Plain and the Chengdu-Chongqing urban agglomeration.The areas of cold spots were mainly concentrated in the Qinghai-Tibet Plateau,Yunnan,and Xinjiang.3)Investment intensity and the natural environment have always been the main drivers of land development intensity in the western China.Investment played a powerful role in promoting land development intensity,while the natural and ecological environment distinctly constrained such development.The effect of the economic factors on land development intensity in the western China has changed,which is reflected in the driving factor of construction land development shifting from economic growth in 2000 to economic structure,especially industrial structure,in 2015.

Spatial Patterns of LULC and Driving Forces in the Transnational Area of Tumen River:A Comparative Analysis of the Sub-regions of China,the DPRK,and Russia

Understanding the spatial patterns of land-use and land-cover(LULC)and their driving forces in transnational areas is important for the sustainable development of these regions.However,the spatial patterns of LULC and their driving forces across multiple scales are poorly understood in transnational areas.In this study,we analyzed the spatial patterns of LULC and driving forces in the transnational area of Tumen River(TATR)in 2016 across two scales:the entire region and the sub-regions of China,the Democratic People’s Republic of Korea(DPRK),and Russia.Results showed that the LULC was dominated by broadleaf forest and dry farmland in the TATR in 2016,which accounted for 66.86%and 13.60%of the entire region,respectively.Meanwhile,the LULC in the three sub-regions exhibited noticeable differences.In the Chinese and the DPRK’s sub-regions,the area of broadleaf forest was greater than those for the other LULC types,while the Russian sub-region was dominated by broadleaf forest and grassland.The spatial patterns of LULC were mainly influenced by topography,climate,soil properties,and human activities.In addition,the driving forces of the spatial patterns of LULC in the TATR had an obvious scaling effect.Therefore,we suggest that effective policies and regulations with cooperation among China,the DPRK,and Russia are needed to plan the spatial patterns of LULC and improve the sustainable development of the TATR.

Study on the Driving Forces of Rocky Desertification in Guizhou Province Based on Variation Coefficient Method

[Objective] The aim was to study the driving forces of rocky desertification in Guizhou Province. [Method] Based on GIS and RS technology, the main driving forces of rocky desertification in Guizhou Province were analyzed by means of correlation analysis and variation coefficient method, and then the distribution of rocky desertification in Guizhou Province was assessed synthetically. [Result] The main driving forces of rocky desertification in Guizhou Province were vegetation cover, rainfall, peasant income and gradient which were obviously correlative with rocky desertification; from theoretical distribution, rocky desertification was the most serious in Bijie, southwest Guizhou, southern Guizhou and northeastern Guizhou, and the theoretical distribution of rocky desertification in Bijie was severer than its current situation, which showed that construction of ecological function area in Bijie restrained the development of rocky desertification effectively; the good consistency between theoretical and current distribution of rocky desertification revealed that the study method was feasible. [Conclusion] The study could provide theoretical references for the practical control of rocky desertification.

Shape gradient and classical gradient of curvatures:driving forces on micro/nano curved surfaces

Recent experiments and molecule dynamics simulations have shown that adhesion droplets on conical surfaces may move spontaneously and directionally. Besides, this spontaneous and directional motion is independent of the hydrophilicity and hydrophobicity of the conical surfaces. Aimed at this important phenomenon, a gen- eral theoretical explanation is provided from the viewpoint of the geometrization of micro/nano mechanics on curved surfaces. In the extrinsic mechanics on micro/nano soft curved surfaces, we disclose that the curvatures and their extrinsic gradients form the driving forces on the curved spaces. This paper focuses on the intrinsic mechanics on micro/nano hard curved surfaces and the experiment on the spontaneous and directional motion. Based on the pair potentials of particles, the interactions between an isolated particle and a micro/nano hard curved surface are studied, and the geometric foundation for the interactions between the particle and the hard curved surface is analyzed. The following results are derived： （a） Whatever the exponents in the pair potentials may be, the potential of the particle/hard curved surface is always of the unified curvature form, i.e., the potential is always a unified function of the mean curvature and the Gaussian curvature of the curved surface. （b） On the basis of the curvature-based potential, the geometrization of the micro/nano mechanics on hard curved surfaces may be realized. （c） Similar to the extrinsic mechanics on micro/nano soft curved surfaces, in the intrinsic mechanics on micro/nano hard curved surfaces, the curvatures and their intrinsic gradi- ents form the driving forces on the curved spaces. In other words, either on soft curved surfaces or hard curved surfaces and either in the extrinsic mechanics or the intrinsic mechanics, the curvatures and their gradients are all essential factors for the driving forces on the curved spaces. （d） The direction of the driving force induced by the hard curved surface is independent of the hydrophilieity and hydrophobicity of the curved surface, explaining the experimental phenomenon of the spontaneous and directional motion.

Analysis on Driving Forces behind Community Participation in Heritage Site Protection and Tourism Development

This paper applied literature research, model analysis, considered current community-participated tourism development, established a four driving forces model on the basis of analyzing the driving forces for community participation in heritage site protection and tourism development. The driving forces and applicability of community participation in heritage site protection and tourism development from the perspectives of interests drive, government pushing, tourism development attraction and environmental protection pressure.

Recent progress in polymerization-induced self-assembly:From the perspective of driving forces

Polymerization-induced self-assembly(PISA)enables the simultaneous growth and self-assembly of block copolymers in one pot and therefore has developed into a high-efficiency platform for the preparation of polymer assemblies with high concentration and excellent reproducibility.During the past decade,the driving force of PISA has extended from hydrophobic interactions to other supramolecular interactions,which has greatly innovated the design of PISA,enlarged the monomer/solvent toolkit,and endowed the polymer assemblies with intrinsic dynamicity and responsiveness.To unravel the important role of driving forces in the formation of polymeric assemblies,this review summarized the recent development of PISA from the perspective of driving forces.Motivated by this goal,here we give a brief overview of the basic principles of PISA and systematically discuss the various driving forces in the PISA system,including hydrophobic interactions,hydrogen bonding,electrostatic interactions,andπ-πinteractions.Furthermore,PISA systems that are driven and regulated by crystallization or liquid crystalline ordering were also highlighted.