Dynamic in situ reconstruction of NiSe_(2) promoted by interfacial Ce_(2)(CO_(3))_(2)O for enhanced water oxidation

Understanding and manipulating the structural evolution of water oxidation electrocatalysts lays the foundation to finetune their catalytic activity.Herein,we present a synthesis of NiSe_(2)-Ce_(2)(CO_(3))_(2)O heterostructure and demonstrate the efficacy of interfacial Ce_(2)(CO_(3))2O in promoting the formation of catalytically active centers to improve oxygen evolution activity.In-situ Raman spectroscopy shows that incorporation of Ce_(2)(CO_(3))2O into NiSe_(2) causes a cathodic shift of the Ni^(2+)→Ni~(3+) transition potential.Operando electrochemical impedance spectroscopy reveals that strong electronic coupling at heterogeneous interface accelerates charge transfer process.Furthermore,density functional theory calculations suggest that actual catalytic active species of NiOOH transformed from NiSe_(2),which is coupled with Ce_(2)(CO_(3))_(2)O,can optimize electronic structure and decrease the free energy barriers toward fast oxygen evolution reaction(OER) kinetics.Consequently,the resultant NiSe_(2)-Ce_(2)(CO_(3))_(2)O electrode exhibits remarkable electrocatalytic performance with low overpotentials(268/304 mV@50/100 mA cm^(-2)) and excellent stability(50 mA cm^(-2) for 120 h) in the alkaline electrolyte.This work emphasizes the significance of modulating the dynamic changes in developing efficient electrocatalyst.

Dynamic MmWave Channel Reconstruction of MIMO OTA Testing for Handover Scenarios

The evaluation of handover performance is essential for ensuring seamless user experience under innovative application scenarios in the fifth generation(5G)and beyond era,including autonomous driving,mobile augmented and virtual reality.However,due to the hardware constrains of a sectored multiprobe anechoic chamber(SMPAC),switching among multiple channel models is of low precision with a high cost in traditional over-the-air(OTA)test solutions.In this paper,we present an efficient and repeatable emulation strategy to reconstruct dynamic millimeter-wave(mm Wave)channels in laboratories for multiple-input multiple-output(MIMO)mobile devices.Firstly,we propose a novel evaluation metric,called average power angular spectrum similarity percentage(APSP),which minimizes the unexpected impact induced by the indefinite condition of adaptive antenna arrays in mm Wave terminals during handover process.Moreover,we propose a partitioned probe configuration strategy by designing a beam directivitybased switching circuit,which enables quick changes of probe configurations in SMPAC.Simulation results demonstrate the effectiveness of the proposed algorithms,thus providing a guideline for the reconstruction of the dynamic channel in different scenarios with resource limitation.

Exploring the role of iron in Fe_(5)Ni_(4)S_(8)toward oxygen evolution through modulation of electronic orbital occupancy

Ni-Fe-based catalysts are considered to be among the most active catalysts for the oxygen evolution reaction(OER)under alkaline conditions,with Fe playing a crucial role.However,Fe leaching occurs during the reaction due to thermodynamic instability,which has resulted in conflicting reports within the literature regarding its role.To clarify this point,we propose a strategy consisting of modulating the electronic orbital occupancy to suppress the extensive loss of Fe atoms during the OER process.Theoretical calculations,in-situ X-ray photoelectron spectroscopy,molecular dynamics simulations,and a series of characterization showed that the stable presence of Fe not only accelerates the electron transfer process but also optimizes the reaction barriers of the oxygen evolution intermediates,promoting the phase transition of Fe_(5)Ni_(4)S_(8)to highly active catalytic species.The modulated Fe_(5)Ni_(4)S_(8)-based pre-catalysts exhibit improved OER activity and long-term durability.This study provides a novel perspective for understanding the role of Fe in the OER process.

Dynamic Visualization Approach of the Multiphase Flow Using Electrical Capacitance Tomography

Identifying the flow patterns is vital for understanding the complicated physical mechanisms in multiphase flows.For this purpose,electrical capacitance tomography(ECT) technique is considered as a promising visualization method for the flow pattern identification,in which image reconstruction algorithms play an important role.In this paper,a generalized dynamic reconstruction model,which integrates ECT measurement information and physical evolution information of the objects of interest,was presented.A generalized objective functional that simultaneously considers the spatial constraints,temporal constraints and dynamic evolution information of the objects of interest was proposed.Numerical simulations and experiments were implemented to evaluate the feasibility and efficiency of the proposed algorithm.For the cases considered in this paper,the proposed algorithm can well reconstruct the flow patterns,and the quality of the reconstructed images is improved,which indicates that the proposed algorithm is competent to reconstruct the flow patterns in the visualization of multiphase flows.

Dynamic Reconstruction of Total-cross-tied Photovoltaic Array Based on Arrays Using an Improved Dung Beetle Algorithm

A dynamic reconfiguration method for photovoltaic(PV)arrays based on an improved dung beetle algorithm(IDBO)to address the issue of PV array mismatch loss caused by partial shading conditions(PSCs)is proposed.To establish the output power-current(P-I)segmentation function for the total-cross-tied(TCT)PV array and the constraint function for the electrical switches,the IDBO algorithm was used to optimize both the P-I segmentation function and the electrical switch constraint function.IDBO is compared with algorithm-free reconfiguration and five other heuristic algorithms using two evaluation criteria:mismatch loss and power enhancement percentage,across six shading scenarios for 6x6 PV arrays.The irradiation distribution of PV arrays reconfigured by IDBO is also presented.The results show that IDBO effectively increases the output power of PV arrays and reduces mismatch loss.The output PV curves tend to exhibit a single peak,and the reconstruction results are superior to those obtained with the other methods.

Principle and key technology of generalized high precision simulation of TT&C channel

A generalized simulation method of the tracking,telemetry and control（TT＆C） channel,which is applicable to wideband and arbitrary radio frequency（RF） signal,is proposed.It can accurately simulate the dynamic transmission delay of the arbitrary RF signal in channels,especially regardless of any prior knowledge including signal form,signal parameters,and so on.The proposed method orthogonally demodulates the wideband and arbitrary RF signal to complex baseband by a known local oscillator（LO） signal.Whereafter,it takes measures to obtain the delay reconstruction signal of baseband signals based on the dynamic transmission delay between a ground station and a responder.Meanwhile,it manages to obtain the delay reconstruction signal of LO signals.The simulation output signal（the delayed RF signal） can be achieved through the synthesis of the two delay reconstruction signals mentioned above.The principle and its related key technology are described in detail,and the realizable system architecture is given.

Active site identification and engineering during the dynamic evolution of copper-based catalysts for electrocatalytic CO_(2) reduction

To date,copper-based catalysts are one of the most prominent catalysts that can electrochemically reduce CO_(2)towards highvalue fuels or chemicals,such as ethylene,ethanol,and acetic acid.However,the chemically active feature of Cu-based catalysts hinders the understanding of the intrinsic catalytic active sites during the initial and the operative processes of electrochemical CO_(2)reduction(CO_(2)RR).The identification and engineering of active sites during the dynamic evolution of catalysts are thereby vital to further improve the activity,selectivity,and durability of Cu-based catalysts for high-performance CO_(2)RR.In this regard,four triggers for the dynamic evolution of catalysts were introduced in detail.Afterward,three typical active-site theories during the dynamic reconstruction of catalysts were discussed.In addition,the strategies in catalyst design were summarized according to the latest reports of Cu-based catalysts for CO_(2)RR,including the tuning of electronic structure,controlling of the external potential,and regulation of local catalytic environment.Finally,the conclusions and perspectives were provided to inspire more investigations and studies on the intrinsic active sites during the dynamic evolution of catalysts,which could promote the optimization of the catalyst system to further improve the performance of CO_(2)RR.

Full-field dynamic strain reconstruction of an aero-engine blade from limited displacement responses

Blade strain distribution and its change with time are crucial for reliability analysis and residual life evaluation in blade vibration tests.Traditional strain measurements are achieved by strain gauges(SGs)in a contact manner at discrete positions on the blades.This study proposes a method of full-field and real-time strain reconstruction of an aero-engine blade based on limited displacement responses.Limited optical measured displacement responses are utilized to reconstruct the full-field strain.The full-field strain distribution is in-time visualized.A displacement-to-strain transformation matrix is derived on the basis of the blade mode shapes in the modal coordinate.The proposed method is validated on an aero-engine blade in numerical and experimental cases.Three discrete vibrational displacement responses measured by laser triangulation sensors are used to reconstruct the full-field strain over the whole operating time.The reconstructed strain responses are compared with the results measured by SGs and numerical simulation.The high consistency between the reconstructed and measured results demonstrates the accurate strain reconstructed by the method.This paper provides a low-cost,real-time,and visualized measurement of blade full-field dynamic strain using displacement response,where the traditional SGs would fail.

Specification of Initial Shapes for Dynamic Implicit Curve/Surface Reconstruction

The dynamic implicit curve/surface reconstruction demands no special requirement on the initial shapes in general. In order to speed up the iteration in the reconstruction, we discuss how to specify the initial shapes so as to reflect the geometric information and the topology structure of the given data. The basic idea is based on the combination of the distance function and the generalized eigenvector fitting model. Keywords Sampson distance, generalized eigenvector fitting, dynamic implicit surface reconstruction

HDR-Net-Fusion:Real-time 3D dynamic scene reconstruction with a hierarchical deep reinforcement network

Reconstructing dynamic scenes with commodity depth cameras has many applications in computer graphics,computer vision,and robotics.However,due to the presence of noise and erroneous observations from data capturing devices and the inherently ill-posed nature of non-rigid registration with insufficient information,traditional approaches often produce low-quality geometry with holes,bumps,and misalignments.We propose a novel 3D dynamic reconstruction system,named HDR-Net-Fusion,which learns to simultaneously reconstruct and refine the geometry on the fly with a sparse embedded deformation graph of surfels,using a hierarchical deep reinforcement(HDR)network.The latter comprises two parts:a global HDR-Net which rapidly detects local regions with large geometric errors,and a local HDR-Net serving as a local patch refinement operator to promptly complete and enhance such regions.Training the global HDR-Net is formulated as a novel reinforcement learning problem to implicitly learn the region selection strategy with the goal of improving the overall reconstruction quality.The applicability and efficiency of our approach are demonstrated using a large-scale dynamic reconstruction dataset.Our method can reconstruct geometry with higher quality than traditional methods.

A STUDY OF DYNAMIC SYSTEM ESTABLISHMENT IN EOF-CONTINUATION PHASE SPACE

For the EOF decomposition continuation phase space, the least square method is applied under the condition of orthogonal basis to find coefficients of all quadratic nonlinear terms of a state evo- lution equation such that a dynamic system that indicates the evolution features of a weather/cli- mate system in a limited area can be formulated. The scheme is compared with that for phase space continuation by time series drift. Results show that the dynamic system established in terms of the present method is likely to give more precise and realistic description of evolution of the weather/ climate system.

Adaptive speed of sound correction with photoacoustic tomography for imaging quality optimization

This work proposes a method to concurrently calibrate multiple acoustic speeds in different mediums with a photoacoustic（PA） and ultrasound（US） dual-modality imaging system. First, physical infrastructure information of the target is acquired through a US image. Then, we repeatedly build PA images around a special target to yield the best focused result by dynamically updating the acoustic speeds in a different medium of the target.With these correct acoustic propagation velocities in the according mediums, we can effectively optimize the PA image quality as the experiments proved, which might benefit future research in biomedical imaging science.