Local tetragonal distortion of Pt alloy catalysts for enhanced oxygen reduction reaction efficiency

Platinum-based alloy nanoparticles are the most attractive catalysts for the oxygen reduction reaction at present,but an in-depth understanding of the relationship between their short-range structural information and catalytic performance is still lacking.Herein,we present a synthetic strategy that uses transition-metal oxide-assisted thermal diffusion.PtCo/C catalysts with localized tetragonal distortion were obtained by controlling the thermal diffusion process of transition-metal elements.This localized structural distortion induced a significant strain effect on the nanoparticle surface,which further shortened the length of the Pt-Pt bond,improved the electronic state of the Pt surface,and enhanced the performance of the catalyst.PtCo/C catalysts with special short-range structures achieved excellent mass activity(2.27 Amg_(Pt)^(-1))and specific activity(3.34 A cm^(-2)).In addition,the localized tetragonal distortion-induced surface compression of the Pt skin improved the stability of the catalyst.The mass activity decreased by only 13%after 30,000 cycles.Enhanced catalyst activity and excellent durability have also been demonstrated in the proton exchange membrane fuel cell configuration.This study provides valuable insights into the development of advanced Pt-based nanocatalysts and paves the way for reducing noble-metal loading and increasing the catalytic activity and catalyst stability.

Linear magnetoresistance and structural distortion in layered SrCu_(4-x)P_(2) single crystals

We report a systematic study on layered metal SrCu_(4-x)P_(2) single crystals via transport, magnetization, thermodynamic measurements and structural characterization. We find that the crystals show large linear magnetoresistance without any sign of saturation with a magnetic field up to 30T. We also observe a phase transition with significant anomalies in resistivity and heat capacity at T_(p)~140 K. Thermal expansion measurement reveals a subtle lattice parameter variation near Tp, i.e.,?L_(c)/L_(c)~0.062%. The structural characterization confines that there is no structure transition below and above T_(p). All these results suggest that the nonmagnetic transition of SrCu_(4-x)P_(2) could be associated with structural distortion.

Engineering Thermoelectric Performance of α-GeTe by Ferroelectric Distortion

The rhombohedralα-GeTe can be approximated as a slightly distorted rock-salt structure along its[111]direction and possesses superb thermoelectric performance.However,the role of such a ferroelectric-like structural distortion on its transport properties remains unclear.Herein,we performed a systematic study on the crystal structure and electronic band structure evolutions of Ge_(1-x)Sn_(x)Te alloys where the degree of ferroelectric distortion is continuously tuned.It is revealed that the band gap is maximized while multiple valence bands are converged at x=0.6,where the ferroelectric distortion is the least but still works.Once undistorted,the band gap is considerably reduced,and the valence bands are largely separated again.Moreover,near the ferro-to-paraelectric phase transition Curie temperature,the lattice thermal conductivity reaches its minima because of significant lattice softening enabled by ferroelectric instability.We predict a peak ZT value of 2.6 at 673 K inα-GeTe by use of proper dopants which are powerful in suppressing the excess hole concentrations but meanwhile exert little influence on the ferroelectric distortion.

Bulging Distortion of Austenitic Stainless Steel Sheet on the Partially Penetrated Side of Non-Penetration Lap Laser Welding Joint

Non-penetration laser welding of lap joints in austenitic stainless steel sheets is commonly preferred in fields where the surface quality is of utmost importance.However,the application of non-penetration welded austenitic stainless steel parts is limited owing to the micro bulging distortion that occurs on the back surface of the partial penetration side.In this paper,non-penetration lap laser welding experiments,were conducted on galvanized and SUS304 austenitic stainless steel plates using a fiber laser,to investigate the mechanism of bulging distortion.A comparative experiment of DC01 galvanized steel-Q235 carbon steel lap laser welding was carried out,and the deflection and distortion profile of partially penetrated side of the sheets were measured using a noncontact laser interferometer.In addition,the cold-rolled SUS304 was subjected to heat holding at different temperatures and water quenching after bending to characterize its microstructure under tensile and compressive stress.The results show that,during the heating stage of the thermal cycle of laser lap welding,the partial penetration side of the SUS304 steel sheet generates compressive stress,which extrudes the material in the heat-affected zone to the outside of the back of the SUS304 steel sheet,thereby forming a bulge.The findings of these experiments can be of great value for controlling the distortion of the partial penetrated side of austenitic stainless steel sheet during laser non-penetration lap welding.

Computational Quantification of Map Projection Distortion by Fractal Dimension of Coastlines

Maps, essential tools for portraying the Earth’s surface, inherently introduce distortions to geographical features. While various quantification methods exist for assessing these distortions, they often fall short when evaluating actual geographic features. In our study, we took a novel approach by analyzing map projection distortion from a geometric perspective. We computed the fractal dimensions of different stretches of coastline before and after projection using the divide-and-conquer algorithm and image processing. Our findings revealed that map projections, even when preserving basic shapes, inevitably stretch and compress coastlines in diverse directions. This analysis method provides a more realistic and practical way to measure map-induced distortions, with significant implications for cartography, geographic information systems (GIS), and geomorphology. By bridging the gap between theoretical analysis and real-world features, this method greatly enhances accuracy and practicality when evaluating map projections.

DISTORTION THEOREMS FOR CLASSES OF g-PARAMETRIC STARLIKE MAPPINGS OF REAL ORDER IN C^(n)

In this paper,we define the class S_(g)^(BX)of g-parametric starlike mappings of real order γ on the unit ball BX in a complex Banach space X,where g is analytic and satisfies certain conditions.By establishing the distortion theorem of the Fr´echet-derivative type of S_(g)^(BX)with a weak restrictive condition,we further obtain the distortion results of the Jacobi-determinant type and the Fr´echet-derivative type for the corresponding classes(compared with S_(g)^(BX))defined on the unit polydisc(resp.unit ball with the arbitrary norm)in the space of n-dimensional complex variables,n≥2.Our results extend the classic distortion theorem of holomorphic functions from the case in one-dimensional complex space to the case in the higher dimensional complex space.The main theorems also generalize and improve some recent works.

Out-of-plane weak ferromagnetism at room temperature in lattice-distortion non-collinear antiferromagnet of single-crystal Mn_(3)Sn

Out-of-plane weak ferromagnetic(OWFM)spin arrangements with topological properties can realize a series of interesting physical properties.However,this spin structure tends to exist at low temperatures.The OWFM structure can also be induced at room temperature by hydrostatic pressure,whereas this isotropic approach tends to form helical AFM structures.We report the OWFM spin arrangement in single crystal Mn_(3)Sn by an anisotropic strategy of high-stressconstrained compression deformation at room temperature.Both experimental and theoretical simulation results show that the alignment of the OWFM spin structure is due to the distortion of the atomic scale caused by the strain energy during deformation.The OWFM spin arrangement can significantly change the magnetic property of Mn_(3)Sn.As a result,the remanent magnetization M_(r)for the deformed sample(0.056μ_(B)/f.u.)is about eleven times that for the pre-deformed sample(0.005μ_(B)/f.u.),and the coercivity(H_(c))increases from 0 k Oe(pre-deformed sample)to 6.02 k Oe(deformed sample).Our findings provide a way to generate the OWFM spin structure at room temperature and may give fresh ideas for creating antiferromagnetic materials with excellent physical properties.

Distortion Evaluation of EMP Sensors Using Associated-Hermite Functions

Electromagnetic pulse(EMP)is a kind of transient electromagnetic phenomenon with short rise time of the leading edge and wide spectrum,which usually disrupts communications and damages electronic equipment and system.It is challenging for an EMP sensor to measure a wideband electromagnetic pulse without distortion for the whole spectrum.Therefore,analyzing the distortion of EMP measurement is crucial to evaluating the sensor distortion characteristics and correcting the measurement results.Waveform fidelity is usually employed to evaluate the distortion of an antenna.However,this metric depends on specific signal waveforms,thus is unsuitable for evaluating and analyzing the distortion of EMP sensors.In this paper,an associated-hermite-function based distortion analysis method including system transfer matrices and distortion rates is proposed,which is general and independent from individual waveforms.The system transfer matrix and distortion rate can be straightforwardly calculated by the signal orthogonal transformation coefficients using associated-hermite functions.Distortion of a sensor vs.frequency is then visualized via the system transfer matrix,which is convenient in quantitative analysis of the distortion.Measurement of a current probe,a coaxial pulse voltage probe and a B-field sensor were performed,based on which the feasibility and effectiveness of the proposed distortion analysis method is successfully verified.

Distortion product otoacoustic emissions in newborn babies with and without late-term maternal iron deficiency anaemia

Background:Studies on animals have demonstrated that maternal iron deficiency anaemia(IDA)could result in decreased cochlear sensory hair cells and reduced amplitudes of distortion-product otoacoustic emissions(DPOAEs)of young guinea pigs.Thus,it is essential to study the functioning of cochlear hair cells using DPOAEs in human newborn babies with maternal IDA.The current study explores maternal IDA’s effect on DPOAEs in newborn babies.Method:A total of 110 newborn babies with gestational age≥34 weeks were considered and a‘betweensubjects’design was used.The participants were divided into 3 groups-“Normal”(61 babies without maternal IDA),“Mild”(28 babies with mild maternal IDA)and“Moderate”(21 babies with moderate maternal IDA).The cord blood was collected and the DPOAEs were recorded for each baby for a range of frequencies(1 k 8 kHz)and a range of intensities(7040 dB SPL in 10 dB steps).Results:The analysis of both DP-gram and DP input-output(I/O)function showed that there was no significant difference(p>0.05)across the normal,mild,and moderate groups in the overall presence of DPOAEs as well as the amplitude across frequencies or intensities(7040 dB SPL).Also,the overall correlation of RBC indices with DPOAE amplitude across frequencies as well as the slope of the I/O function showed no relationship.Conclusion:The current study concludes that there is no effect of late-term maternal IDA on the DPOAEs of newborn babies.

水稻内稃扭曲突变体palea distortion 1(pd1)的鉴定与基因定位

在对籼稻缙恢10进行EMS(ethyl methane sulfonate)处理后的群体中,发现一个花器官突变体,主要表现为内稃扭曲并呈现外稃化特征,浆片数目增加且呈现稃状特征,雄蕊数目减少至1～4个,部分雄蕊的花丝呈现浆片化特征,暂将其命名为水稻颖壳扭曲突变体palea distortion 1(pd1)。遗传分析表明该突变性状受一个隐形单基因控制。利用群体分离分析法(bulked segregation analysis,BSA),将PD1基因定位在第2染色体的RM13693和RM13936之间,遗传距离分别为3.25cM和3.90cM。该研究结果为PD1基因的图位克隆奠定了基础。

Application of the Delaunay triangulation interpolation in distortion XRII image

To alleviate the distortion of XRII X-ray image intensifier images in the C-arm CT computer tomography imaging system an algorithm based on the Delaunay triangulation interpolation is proposed.First the causes of the phenomenon the classical correction algorithms and the Delaunay triangulation interpolation are analyzed.Then the algorithm procedure is explained using flow charts and illustrations. Finally experiments are described to demonstrate its effectiveness and feasibility. Experimental results demonstrate that the Delaunay triangulation interpolation can have the following effects.In the case of the same center the root mean square distances RMSD and standard deviation STD between the corrected image with Delaunay triangulation interpolation and the ideal image are 5.760 4 ×10 -14 and 5.354 2 ×10 -14 respectively.They increase to 1.790 3 2.388 8 2.338 8 and 1.262 0 1.268 1 1.202 6 after applying the quartic polynomial model L1 and model L2 to the distorted images respectively.The RMSDs and STDs between the corrected image with the Delaunay triangulation interpolation and the ideal image are 2.489 × 10 -13 and 2.449 8 ×10 -13 when their centers do not coincide. When the quartic polynomial model L1 and model L2 are applied to the distorted images they are 1.770 3 2.388 8 2.338 8 and 1.269 9 1.268 1 1.202 6 respectively.

A Novel Segregation Distortion in Intraspecific Population of Asian Cotton(Gossypium arboretum L.)Detected by Molecular Markers

The segregation ratio of markers in an F2 population derived from Rudongjijiaoyaguo （Rdjjyg） and Zhongmian971 （Zm971） was studied using 3 morphological markers, 20 SSR markers, and ll SRAP markers. Totally, 24 markers （77.42%） showed a distorted segregation and all of them skewed toward the female genotype, which was peculiar in recent cotton research. All the three types of SSR markers and SRAP marker showed distorted segregation, but the morphological markers （Purple stem, Okra leaf, and Red spot color） were normally segregated. This indicated that such a novel segregation distortion phenomenon resulted from interior genetic factors, The allele frequency and the distribution of different genotype frequencies in the F2 population were analyzed in codominant markers, to find out factors attributed to distorted segregation. Most of them implied distorted allele frequency, but it was normal genotype frequency, which showed that these markers were influenced at the gamete level.

The anti-correlation method for removing harmonic distortion in vibroseis slip-sweep data

The slip-sweep technique is one of the high-efficiency, high-fidelity, and environmental vibroseis seismic prospecting techniques which consists of a vibrator group sweeping without waiting for the previous group＇s sweep to terminate. The cycle time can be reduced drastically and hence the production efficiency can be increased significantly but harmonic distortion of one sweep will leak into the record of the other sweep. In this paper, we propose an anti-correlation method for removing harmonic distortion in vibroseis data. This method is based on decomposition of the ground force signal into fundamental and harmonic components. Then the corresponding anti-correlation operator can be computed to estimate the energy of each harmonic after correlating the vibroseis data with the corresponding harmonic component. Finally, the vibroseis harmonic noise to be removed can be obtained by subtracting the extracted harmonic noise from the traces of the previous group＇s sweep. The advantage of the proposed method is that it can process both uncorrelated and correlated vibroseis seismic data. Moreover, the algorithm is simple, stable, and computationally fast. Especially, the significant contribution of this method is a considerable reduction in the harmonic without any alteration of the desired signals. The method was tested on both synthetic and field data sets to validate the good harmonic noise suppression results.

Cascade Kalman filter for gravity anomaly distortion correction based on second order potential model

Using a gravity anomaly covariance function based on the second-order Ganssian Markov gravity anomaly potential model, the state equation of a gravity anomaly signal is obtained in marine gravimetry. Combined with the system state equation and the measurement equation, a new method of the cascade Kalman filter is proposed and applied to the correction of gravity anomaly distortion. In the signal processing procedure, an inverse Kalman filter is used to restore the gravity anomaly signal and high frequency noises first. Then an adaptive Kalman filter, which uses the gravity anomaly state equation as the system equation, is set to estimate the actual gravity anomaly data. Emulations and experiments indicate that both the cascade Kalman filter method and the single inverse Kalman filter method are effective in alleviating the distortion of the gravity anomaly signal, but the performance of the cascade Kalman filter method is better than that of the single inverse Kalman filter method.

RESEARCH ON NONLINEAR DISTORTION IN AMPLIFIERS

Transistors are nonlinear devices, which can produce nonlinear distortion in amplifier while amplifying signals. For weak nonlinear distortion, the expressions of total harmonic distortion (THD), the second order intermodulation distortion(IM2 ), the third order intermodulation distortion(IM 3) and intercept point(IP 3) are deduced. With the aid of software Multisim, we simulate transistor common emitter amplifier, transistor common emitter amplifier with resistor in emitter, differential amplifier and differential amplifier with resistor between emitters. The simulational results and theoretical analyses are almost the same.

Application of stiffness matrix of a beam element considering section distortion effect

According to the stationary principle of potential energy and the generalized coordinate method, a stiffness matrix of a beam element considering distortion effects is derived. Using the stiffness matrix of the beam element, a finite element program for computing thin-walled box steel beams is developed. And the program can take the section distortion and warping effects into account. The influences of diaphragm spacing on the mechanical behavior of thin-walled box beams are analyzed by the program. The numerical analysis shows that setting diaphragms have the greatest influence on the distortion normal stress, while there is very little influence on the bending normal stress. Only when the distance of adjacent diaphragms decreases to a certain value, will the distortion normal stress in the thin-walled box beam obviously reduce under the distortion load. Finally, a distortion-warping coefficient γ is introduced for simplifying the calculation of the longitudinal normal stress of thin-walled box beams. When the ratio of diaphragms adjacent space L to the maximum section dimension H is less than 2, the distortion-warping coefficient γ tends to one, which means that the distortion normal stress of the thin-walled box beam tends to zero, and the effect of the section distortion can be ignored.

Distortion Behavior for SOI MOSFET

Distortion analysis of SOI MOS transistor is presented.By the power series method,the distortion behaviors of FD (fully depleted) and RC (recessed channel) SOI MOS transistor configurations are investigated.It is shown that the distortion figures deteriorate with the scaling down of channel length,and the RC SOI device shows better distortion performance than the FD SOI device.At the same time,the experimental data show that the ineffective body contact can lead to an increase of the harmonic amplitude due to the bulk resistance.The presented results give an intuitive knowledge for the design of low distortion mixed signal integrated system.

The Third-Order Intermodulation Distortion in the AlGaAs/GaAs HBT Amplifier

An accurate circuit model of the microwave small signal characteristics of AlGaAs/GaAs HBT (heterojunction bipolar transistor) is extremely useful for microwave linear applications of the device. This paper presents a small signal AlGaAs/GaAs HBT equivalent circuit, based on the DC characteristics and S parameter of the device. Using Volterra series, we have calculated the third order intermodulation distortion in a linear AlGaAs/GaAs HBT amplifier. The calculations are well concordant with the measurements from two tone signals intermodulation distortion test, and its excellent third order intermodulation performance shows that AlGaAs/GaAs HBT is a very attractive candidate for linear amplification.

Rate-distortion理论在H.264编码器中的应用

编码模式的选择是视频编码器控制的一个重要功能,它直接决定了编码器的性能和效率。新的视频压缩协议H.264协议比其它视频压缩协议提出了更多的编码模式,这就决定了H.264编码器不能像H.263编码器一样,通过比较某个门限值来简单地决定采用哪种编码模式。另一方面,根据Rate-distortion理论,在失真度与比特率之间存在一个最佳折衷点。如果确定了合适的拉各朗日(Lagrangian)参数,就能利用拉各朗日公式找到这个最佳折衷点。把这一理论作为H.264编码器的模式选择算法,将会使H.264编码器根据图像内容自适应地选择最佳的编码模式,达到最佳的压缩效果。

Correction of buckling distortion by ultrasonic shot peening treatment for 5A06 aluminum alloy welded structure

Ultrasonic shot peening treatment （USPT） was proposed to correct welding buckling distortion. The residual stress distribution along the depth direction of the peened zone was measured by an X-ray diffractometer. The microstructure of the treated specimens was investigated by scanning electron microscopy （SEM）. The Vickers microhardness was measured in different areas of welded joint before USPT and along the depth direction of the weld after USPT. The experimental results indicated that the welding buckling distortion of 5A06 aluminum alloy butt joint can be essentially corrected by USPT; the average correction rate reached 90.8% in this study. Furthermore, USPT enhanced specimens by work hardening. The microstructure of the peened zone was improved; moreover, the distribution of the precipitates and grains presented an apparent orientation.