Recent advances in experimental techniques and data processing allow in situ determination of mineral crystal structure and chemistry up to Mbar pressures in a laser-heated diamond anvil cell(DAC),providing the fundam...Recent advances in experimental techniques and data processing allow in situ determination of mineral crystal structure and chemistry up to Mbar pressures in a laser-heated diamond anvil cell(DAC),providing the fundamental information of the mineralogical constitution of our Earth's interior.This work highlights several recent breakthroughs in the field of high-pressure mineral crystallography,including the stability of bridgmanite,the single-crystal structure studies of post-perovskite and H-phase as well as the identification of hydrous minerals and iron oxides in the deep lower mantle.The future development of high-pressure crystallography is also discussed.展开更多
The thermal structure of the lower mantle plays a key role in understanding the dynamic processes of the Earth's evolution and mantle convection.Because intrinsic attenuation in the lower mantle is highly sensitiv...The thermal structure of the lower mantle plays a key role in understanding the dynamic processes of the Earth's evolution and mantle convection.Because intrinsic attenuation in the lower mantle is highly sensitive to temperature,determining of the attenuation of the lower mantle could help us determine its thermal state.We attempted to constrain the attenuation of the lower mantle by measuring the amplitude ratios of p to ScP on the vertical component and s to ScS on the tangential component at short epicentral distances for seismic wave data from deep earthquakes in Northeast China.We calculated the theoretical amplitude ratios of p to ScP and s to ScS by using ray theory and the axial-symmetric spectral element method AxiSEM,as well as by considering the effects of radiation patterns,geometrical spreading,and ScP reflection coefficients.By comparing the observed amplitude ratios with the synthetic results,we constrained the quality factors as Qα≈3,000 and Qβ≈1,300 in the lower mantle beneath Northeast China,which are much larger than those in the preliminary reference Earth model(PREM)model of Qα~800 and Qβ~312.We propose that the lower mantle beneath Northeast China is relatively colder than the average mantle,resulting in weaker intrinsic attenuation and higher velocity.We estimated the temperature of the lower mantle beneath Northeast China as approximately 300–700 K colder than the global average value.展开更多
It is generally believed a variation of 3He/4He isotopic ratios in the mantle is due to only the decay of U and Th,which produces4 He as well as heat.Here we show that not only3He/4He isotopic ratios but also helium c...It is generally believed a variation of 3He/4He isotopic ratios in the mantle is due to only the decay of U and Th,which produces4 He as well as heat.Here we show that not only3He/4He isotopic ratios but also helium contents can be fractionated by thermal diffusion in the lower mantle.The driving force for that fractionation is the adiabatic or convective temperature gradient,which always produces elemental and isotopic fractionation along temperature gradient by thermal diffusion with higher light/heavy isotopic ratio in the hot end.Our theoretical model and calculations indicate that the lower mantle is helium stratified,caused by thermal diffusion due to*400℃temperature contrast across the lower mantle.The highest3He/4He isotopic ratios and lowest He contents are in the lowermost mantle,which is a consequence of thermaldiffusion fractionation rather than the lower mantle is a primordial and undegassed reservoir.Therefore,oceanicisland basalts derived from the deepest lower mantle with high3He/4He isotopic ratios and less He contents—the long-standing helium paradox,is solved by our model.Because vigorous convection in the upper mantle had resulted in disordered or disorganized thermal-diffusion effects in He,Mid-ocean ridge basalts unaffected by mantle plume have a relatively homogenous and lower!3He/4He isotopic compositions.Our model also predicts that 3He/4He isotopic ratios in the deepest lower mantle of early Earth could be even higher than that of Jupiter,the initial He isotopic ratio in our solar system,because the temperature contrast across the lower mantle in the early Earth is the largest and less4 He had been produced by the decay of U and Th.Moreover,the early helium-stratified lower mantle owned the lowest He contents due to over-degassing caused by the largest temperature contrast.Consequently,succeeding evolution of the lower mantle is a He ingassed process due to secular cooling of the deepest mantle.This explains why significant amount of He produced by the decay of U and Th in the lower mantle were not released,another long-standing heat–helium paradox.展开更多
The lateral temperature anomalous structure of the lower mantle is reconstructed from the seismic tomographical model and high temperature and high pressure laboratory results. A significant correlation between the di...The lateral temperature anomalous structure of the lower mantle is reconstructed from the seismic tomographical model and high temperature and high pressure laboratory results. A significant correlation between the distribution of the cold anomaly and the location of past subduction belts shows that the shallower anomaly corresponds to the younger subduction sites, while the deeper anomaly to the older ones. This correlation also suggests that the cold anomaly may have come from the subduction slabs and the scale of mantle convection may have been completed. The coldest and largest anomaly is concentrated near the core mantle boundary (CMB). Few cold anomalies float in the shallower and middle parts of the lower mantle, suggesting that the downward migration of the subduction slabs, discontinuous and step like, may be divided into the following three stages: subduction, stagnation at the 670 km discontinuity due to the phase transition, and disintegration when the size exceeds the critical point.展开更多
Using the differences of sound velocity and temperature on the Hugoniot and isoentropic state,the temperature coefficients of sound velocity of perovskite-enstatite under high pressure were obtained.For compressional,...Using the differences of sound velocity and temperature on the Hugoniot and isoentropic state,the temperature coefficients of sound velocity of perovskite-enstatite under high pressure were obtained.For compressional,shear and bulk wave velocities,their temperature coefficients decrease from 0.386,0.251,0.255 m/(s·K)at 40 GPa to 0.197,0.131,0.162m/(S·K)at 140GPa,respectively.Extrapolating these to zero pressure results in(■K/■T)o=-0.0279 GPa·K^(-1),which is consistent very well with the value got by hydrostatic pressure experiment.On the basis of our data,we conclude that the compressional wave velocity anomaly of 0.1-0.2%in the deep lower mantle and 2%in the D″region would imply lateral thermal heterogeneity with amplitude of 53-106 K and 1066 K in these regions,respectively.展开更多
The temperature dependence of the Al2O3 solubility in bridgmanite has been determined in the system MgSiO3–Al_(2)O_(3)at temperatures of 2750–3000 K under a constant pressure of 27 GPa using a multi-anvil apparatus....The temperature dependence of the Al2O3 solubility in bridgmanite has been determined in the system MgSiO3–Al_(2)O_(3)at temperatures of 2750–3000 K under a constant pressure of 27 GPa using a multi-anvil apparatus.Bridgmanite becomes more aluminous with increasing temperatures.A LiNbO3-type phase with a pyrope composition(Mg_(3)Al_(2)Si_(3)O_(12))forms at 2850 K,which is regarded as to be transformed from bridgmanite upon decompression.This phase contains 30 mol%Al_(2)O_(3)at 3000 K.The MgSiO3 solubility in corundum also increases with temperatures,reaching 52 mol%at 3000 K.Molar volumes of the hypothetical Al_(2)O_(3)bridgmanite and MgSiO_(3)corundum are constrained to be 25.950.05 and 26.24±0.06 cm^(3)/mol,respectively,and interaction parameters of non-ideality for these two phases are 5.6±0.5 and 2.2±0.5 KJ/mol,respectively.The increases in Al^(2)O^(3)and MgSiO^(3)contents,respectively,in bridgmanite and corundum are caused by a larger entropy of Al_(2)O_(3)bridgmanite plus MgSiO_(3)corundum than that of MgSiO_(3)bridgmanite plus Al_(2)O_(3)corundum with temperature,in addition to the configuration entropy.Our study may help explain dynamics of the top lower mantle and constrain pressure and temperature conditions of shocked meteorites.展开更多
This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret. A set of research papers has been assembled, which broadly reflect his research interests over his 50 plus...This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret. A set of research papers has been assembled, which broadly reflect his research interests over his 50 plus year career. These papers Focus on the role that fluids play during the Formation and evolution of the Earth's crust. Below I provide a brief summary of the life of Jacques Touret, along with a select bibliography of his more important papers. This is then followed by a brief introduction to the papers assembled for this special issue.展开更多
The pyrite-type FeO_(2)and FeO_(2)H were synthesized at the pressure-temperature conditions relevant to Earth’s deep lower mantle.Through the water-iron reaction,the pyrite-phase is a good candidate to explain the ch...The pyrite-type FeO_(2)and FeO_(2)H were synthesized at the pressure-temperature conditions relevant to Earth’s deep lower mantle.Through the water-iron reaction,the pyrite-phase is a good candidate to explain the chemical heterogeneities and seismological anomalies at the bottom of the mantle.The solid solution of pyrite-type FeO_(2)and FeO_(2)H,namely the FeO_(2)Hx(0≤x≤1),is particularly interesting and introduces puzzling chemical states for both the O and H atoms in the deep mantle.While the role of H in the FeO_(2)–FeO_(2)H system has been primarily investigated,discrepancies remain.In this work,we summarize recent progress on the pyrite-phase,including FeO_(2),FeO_(2)H,and FeO_(2)Hx,which is critical for understanding the water cycling,redox equilibria,and compositional heterogenicities in the deep lower mantle.展开更多
In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Netwo...In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Networks Center)in the study area.We adopted the double-difference seismic tomographic method(tomo DD)to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt(MLYB).A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography,which greatly reduced the inversion residual.Our results indicate that reliable velocity structure of th e uppermost mantle can be obtained when Pn is involved in the tomography.Our results show that:(1)the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning:a nearly E-W-trending low-velocity zone is present beneath the Dabie Orogen,in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen.They suggest the presence of thickened lower crust beneath the orogens in the study area.In contrast,the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies;(2)both the ultra-high-pressure(UHP)metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies.The upper crust in the Dabie Orogen is characterized by a low-velocity belt,sandwiched between two high velocity zones in a horizontal direction,with discontinuous low-velocity layers in the middle crust.The keel of the Dabie Orogen is mainly preserved beneath its northern section.We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen,which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there.Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks,forming the'sandwich'velocity structure there;(3)high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB.From the Anqing-Guichi ore field northeastward to the Luzong,Tongling,Ningwu and Ningzhen orefields,high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed.The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields,but the high-velocity anomalies are mainly stellate distributed.The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust,different from the velocity structure in the upper crust.The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones,in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field.The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian(Jurassic-Cretaceous)period,during which extensive magmatism occurred.The near mantle-crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust.The magmas may have ascended through major crustal faults,undergoing AFC(assimilation and fractional crystallization)processes,became emplaced in the fault-bounded basins or Paleozoic sequences,eventually forming the many Cu-Fe polymetallic deposits there.展开更多
Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the format...Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the formation of NieCueFe deposits. We describe sulphide inclusions from unique ultramafic clots within mafic xenoliths, from the mafic xenoliths themselves, and from the three silica-rich host plutons in Tongling, China. For the first time, we are able to propose a general framework model for the evolution of sulphide melts during the evolution of mafic to felsic magmas from the upper mantle to the upper crust. The model improves our understanding of the sulphide melt evolution in upper mantle to upper crust magmas, and provides insight into the formation of stratabound skarn-type FeeCu polymetallic deposits associated with felsic magmatism, thus promising to play an important role during prospecting for such deposits.展开更多
Two seismic refraction profiles which are perpendicular to each other, running through Xingtai earthquake region,reveal the anomalous variations of crust-mantle velocity structure and deep tectonics. Pg wave attenuate...Two seismic refraction profiles which are perpendicular to each other, running through Xingtai earthquake region,reveal the anomalous variations of crust-mantle velocity structure and deep tectonics. Pg wave attenuatesrapidly with distance in the earthquake region. A group of strong reflections from a depth of 21. 0 km can be identified along the section from Longyao to the piedmont of Taihang Mountain, but P. waves characterized generally by strong amplitude are not obvious. Under the earthquake region and its western neighboring region, thecrustal velocity structure features high and low velocities changed alternatively. From North China plain toShanxi plateau, the velocity at the top of the upper mantle decreases progressively, while crustal thickness increases by 11 km. Moho uplifts locally in the earthquake region. The crustal fault stretching deeply to Moho andthe discontinuous sections of Moho in the earthquake region are supposed to be the channels and zones for magmatic intrusion. The uplifting of upper mantle and magmatic intrusion are responsible for the formation ofanomalous crust-mantle structures and extending basins, and for the occurrence of Xingtai earthquake as well.展开更多
Petrological and geochemical studies on some volcanic and sub-volcanic rocks from the Lower Benue rift indicate that they are basalts, basaltic and doleritic sills, trachybasalt and trachyte which generally belong to ...Petrological and geochemical studies on some volcanic and sub-volcanic rocks from the Lower Benue rift indicate that they are basalts, basaltic and doleritic sills, trachybasalt and trachyte which generally belong to the alkali basalt series. The alkaline affinity is clearly evident in both their normative and modal mineral compositions, as well as their chemical compositions. The generally high fractionation indices [(La/Yb)N] are 7.06 to 17.65 for the basaltic rocks and 23.59 to 135. 35 for the trachytic rocks, against low values commonly seen in subalkaline (tholeiitic) series, with strong enrichments in the incompatible elements. All this strongly supports their alkaline affinity. The basaltic rocks are generally fine-grained and porphyritic, consisting of phenocrysts of clinopyroxene and olivine in the groundmass of the same minerals together with plagioclase. The clinopyroxene is either diopside or clinoenstatite. The trachyte consists of oligoclase, orthoclase, biotite, quartz and exhibits typical trachytic, flow structure. The basaltic and doleritic sills are commonly altered, with calcite and epidote as common alteration prod-ucts. This alteration, which is reflected in the erratic behaviour of K2O, MnO and P2O5 on Harker variation diagrams, high values of LOI, strong depletions in the more mobile LILE (Rb, K, Ba and Sr) and high Th/Ta ratios, is attributed to the effects of an aqueous fluid phase and crustal contamination. On the whole, the mineralogical, as well as major-, trace-elements and REE data suggest that the rocks are co-genetic and most likely derived from differentiation of an alkali olivine-basalt magma, generating through variable low degrees of partial melting of probably an enriched lithospheric (upper) mantle following an asthenospheric uplift (mantle plume or intumescence) with HIMU signa-tures in a within-plate continental rift tectonic setting. This corroborates earlier results obtained for the intrusive rocks in the region.展开更多
基金The authors acknowledge the support from the Foundation of President of China Academy of Engineering Physics(Grant No:201402032)National Natural Science Foundation of China(Grant No:41574080 and U1530402).
文摘Recent advances in experimental techniques and data processing allow in situ determination of mineral crystal structure and chemistry up to Mbar pressures in a laser-heated diamond anvil cell(DAC),providing the fundamental information of the mineralogical constitution of our Earth's interior.This work highlights several recent breakthroughs in the field of high-pressure mineral crystallography,including the stability of bridgmanite,the single-crystal structure studies of post-perovskite and H-phase as well as the identification of hydrous minerals and iron oxides in the deep lower mantle.The future development of high-pressure crystallography is also discussed.
基金supported by funding from the National Natural Science Foundation of China (grant no. 41904061)China Postdoctoral Science Foundation (grant no. 2018M640742)
文摘The thermal structure of the lower mantle plays a key role in understanding the dynamic processes of the Earth's evolution and mantle convection.Because intrinsic attenuation in the lower mantle is highly sensitive to temperature,determining of the attenuation of the lower mantle could help us determine its thermal state.We attempted to constrain the attenuation of the lower mantle by measuring the amplitude ratios of p to ScP on the vertical component and s to ScS on the tangential component at short epicentral distances for seismic wave data from deep earthquakes in Northeast China.We calculated the theoretical amplitude ratios of p to ScP and s to ScS by using ray theory and the axial-symmetric spectral element method AxiSEM,as well as by considering the effects of radiation patterns,geometrical spreading,and ScP reflection coefficients.By comparing the observed amplitude ratios with the synthetic results,we constrained the quality factors as Qα≈3,000 and Qβ≈1,300 in the lower mantle beneath Northeast China,which are much larger than those in the preliminary reference Earth model(PREM)model of Qα~800 and Qβ~312.We propose that the lower mantle beneath Northeast China is relatively colder than the average mantle,resulting in weaker intrinsic attenuation and higher velocity.We estimated the temperature of the lower mantle beneath Northeast China as approximately 300–700 K colder than the global average value.
基金Funding for this study comes from the Strategic Priority Research Program (B) of CAS (XDB18010100)the Chinese NSF projects (41490635, 41530210, 41225012, 41573040)
文摘It is generally believed a variation of 3He/4He isotopic ratios in the mantle is due to only the decay of U and Th,which produces4 He as well as heat.Here we show that not only3He/4He isotopic ratios but also helium contents can be fractionated by thermal diffusion in the lower mantle.The driving force for that fractionation is the adiabatic or convective temperature gradient,which always produces elemental and isotopic fractionation along temperature gradient by thermal diffusion with higher light/heavy isotopic ratio in the hot end.Our theoretical model and calculations indicate that the lower mantle is helium stratified,caused by thermal diffusion due to*400℃temperature contrast across the lower mantle.The highest3He/4He isotopic ratios and lowest He contents are in the lowermost mantle,which is a consequence of thermaldiffusion fractionation rather than the lower mantle is a primordial and undegassed reservoir.Therefore,oceanicisland basalts derived from the deepest lower mantle with high3He/4He isotopic ratios and less He contents—the long-standing helium paradox,is solved by our model.Because vigorous convection in the upper mantle had resulted in disordered or disorganized thermal-diffusion effects in He,Mid-ocean ridge basalts unaffected by mantle plume have a relatively homogenous and lower!3He/4He isotopic compositions.Our model also predicts that 3He/4He isotopic ratios in the deepest lower mantle of early Earth could be even higher than that of Jupiter,the initial He isotopic ratio in our solar system,because the temperature contrast across the lower mantle in the early Earth is the largest and less4 He had been produced by the decay of U and Th.Moreover,the early helium-stratified lower mantle owned the lowest He contents due to over-degassing caused by the largest temperature contrast.Consequently,succeeding evolution of the lower mantle is a He ingassed process due to secular cooling of the deepest mantle.This explains why significant amount of He produced by the decay of U and Th in the lower mantle were not released,another long-standing heat–helium paradox.
文摘The lateral temperature anomalous structure of the lower mantle is reconstructed from the seismic tomographical model and high temperature and high pressure laboratory results. A significant correlation between the distribution of the cold anomaly and the location of past subduction belts shows that the shallower anomaly corresponds to the younger subduction sites, while the deeper anomaly to the older ones. This correlation also suggests that the cold anomaly may have come from the subduction slabs and the scale of mantle convection may have been completed. The coldest and largest anomaly is concentrated near the core mantle boundary (CMB). Few cold anomalies float in the shallower and middle parts of the lower mantle, suggesting that the downward migration of the subduction slabs, discontinuous and step like, may be divided into the following three stages: subduction, stagnation at the 670 km discontinuity due to the phase transition, and disintegration when the size exceeds the critical point.
基金Supported by National Natural Science Foundation of China under Grant No.19672058the Science and Technology Foundation of Chinese Academy of Engineering Physics under Grant No.960103.
文摘Using the differences of sound velocity and temperature on the Hugoniot and isoentropic state,the temperature coefficients of sound velocity of perovskite-enstatite under high pressure were obtained.For compressional,shear and bulk wave velocities,their temperature coefficients decrease from 0.386,0.251,0.255 m/(s·K)at 40 GPa to 0.197,0.131,0.162m/(S·K)at 140GPa,respectively.Extrapolating these to zero pressure results in(■K/■T)o=-0.0279 GPa·K^(-1),which is consistent very well with the value got by hydrostatic pressure experiment.On the basis of our data,we conclude that the compressional wave velocity anomaly of 0.1-0.2%in the deep lower mantle and 2%in the D″region would imply lateral thermal heterogeneity with amplitude of 53-106 K and 1066 K in these regions,respectively.
基金Z.L.was financially supported by the Bayerisches Geoinstitut Visitor’s Program and the Fundamental Research Funds for the Central Universities of Ministry of Education of China(Grant No.45119031C037)This project has received funding from the European Research Council(ERC)under the European Union’s Horizon 2020 research and innovation programme(Proposal No.787527)+2 种基金It is also supported by research grants to T.K.(BMBF:05K13WC2,05K16 WC2DFG:KA3434/3–1,KA3434/7–1,KA3434/8–1,KA3434/9–1)Z.L.(the National Science Foundation of China Grant No.41902034).
文摘The temperature dependence of the Al2O3 solubility in bridgmanite has been determined in the system MgSiO3–Al_(2)O_(3)at temperatures of 2750–3000 K under a constant pressure of 27 GPa using a multi-anvil apparatus.Bridgmanite becomes more aluminous with increasing temperatures.A LiNbO3-type phase with a pyrope composition(Mg_(3)Al_(2)Si_(3)O_(12))forms at 2850 K,which is regarded as to be transformed from bridgmanite upon decompression.This phase contains 30 mol%Al_(2)O_(3)at 3000 K.The MgSiO3 solubility in corundum also increases with temperatures,reaching 52 mol%at 3000 K.Molar volumes of the hypothetical Al_(2)O_(3)bridgmanite and MgSiO_(3)corundum are constrained to be 25.950.05 and 26.24±0.06 cm^(3)/mol,respectively,and interaction parameters of non-ideality for these two phases are 5.6±0.5 and 2.2±0.5 KJ/mol,respectively.The increases in Al^(2)O^(3)and MgSiO^(3)contents,respectively,in bridgmanite and corundum are caused by a larger entropy of Al_(2)O_(3)bridgmanite plus MgSiO_(3)corundum than that of MgSiO_(3)bridgmanite plus Al_(2)O_(3)corundum with temperature,in addition to the configuration entropy.Our study may help explain dynamics of the top lower mantle and constrain pressure and temperature conditions of shocked meteorites.
文摘This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret. A set of research papers has been assembled, which broadly reflect his research interests over his 50 plus year career. These papers Focus on the role that fluids play during the Formation and evolution of the Earth's crust. Below I provide a brief summary of the life of Jacques Touret, along with a select bibliography of his more important papers. This is then followed by a brief introduction to the papers assembled for this special issue.
基金NSAF(Grant Nos.U1530402 and U1930401)National Natural Science Foundation of China(NSFC,Grant No.17N1051-0213)+2 种基金the National Science Foundation-Earth Sciences(EAR-1128799)the Department of Energy-Geosciences(DE-FG02-94ER14466)HPCAT operations are supported by DOE-NNSA’s Office of Experimental Sciences.APS is supported by DOEBES,under contract No.DE-AC02-06CH11357.
文摘The pyrite-type FeO_(2)and FeO_(2)H were synthesized at the pressure-temperature conditions relevant to Earth’s deep lower mantle.Through the water-iron reaction,the pyrite-phase is a good candidate to explain the chemical heterogeneities and seismological anomalies at the bottom of the mantle.The solid solution of pyrite-type FeO_(2)and FeO_(2)H,namely the FeO_(2)Hx(0≤x≤1),is particularly interesting and introduces puzzling chemical states for both the O and H atoms in the deep mantle.While the role of H in the FeO_(2)–FeO_(2)H system has been primarily investigated,discrepancies remain.In this work,we summarize recent progress on the pyrite-phase,including FeO_(2),FeO_(2)H,and FeO_(2)Hx,which is critical for understanding the water cycling,redox equilibria,and compositional heterogenicities in the deep lower mantle.
基金funded by grants from the Key Project of the National Natural Science Foundation of China(No.41630320)the National Key Research and Development Program of China(No.2016YFC0600200)the Hefei Postdoctoral Science Foundation。
文摘In this study,we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events.These events(M≥2.0)occurred from 1980 s to June 2019 and were recorded at 319 seismic stations(Chinese Earthquake Networks Center)in the study area.We adopted the double-difference seismic tomographic method(tomo DD)to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt(MLYB).A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography,which greatly reduced the inversion residual.Our results indicate that reliable velocity structure of th e uppermost mantle can be obtained when Pn is involved in the tomography.Our results show that:(1)the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning:a nearly E-W-trending low-velocity zone is present beneath the Dabie Orogen,in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen.They suggest the presence of thickened lower crust beneath the orogens in the study area.In contrast,the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies;(2)both the ultra-high-pressure(UHP)metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies.The upper crust in the Dabie Orogen is characterized by a low-velocity belt,sandwiched between two high velocity zones in a horizontal direction,with discontinuous low-velocity layers in the middle crust.The keel of the Dabie Orogen is mainly preserved beneath its northern section.We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen,which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there.Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks,forming the'sandwich'velocity structure there;(3)high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB.From the Anqing-Guichi ore field northeastward to the Luzong,Tongling,Ningwu and Ningzhen orefields,high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed.The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields,but the high-velocity anomalies are mainly stellate distributed.The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust,different from the velocity structure in the upper crust.The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones,in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field.The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian(Jurassic-Cretaceous)period,during which extensive magmatism occurred.The near mantle-crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust.The magmas may have ascended through major crustal faults,undergoing AFC(assimilation and fractional crystallization)processes,became emplaced in the fault-bounded basins or Paleozoic sequences,eventually forming the many Cu-Fe polymetallic deposits there.
基金financially supported by the China Geological Survey (Grant No. 12120113069900)the National Natural Science Foundation of China (Grant No. 40672045)
文摘Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the formation of NieCueFe deposits. We describe sulphide inclusions from unique ultramafic clots within mafic xenoliths, from the mafic xenoliths themselves, and from the three silica-rich host plutons in Tongling, China. For the first time, we are able to propose a general framework model for the evolution of sulphide melts during the evolution of mafic to felsic magmas from the upper mantle to the upper crust. The model improves our understanding of the sulphide melt evolution in upper mantle to upper crust magmas, and provides insight into the formation of stratabound skarn-type FeeCu polymetallic deposits associated with felsic magmatism, thus promising to play an important role during prospecting for such deposits.
文摘Two seismic refraction profiles which are perpendicular to each other, running through Xingtai earthquake region,reveal the anomalous variations of crust-mantle velocity structure and deep tectonics. Pg wave attenuatesrapidly with distance in the earthquake region. A group of strong reflections from a depth of 21. 0 km can be identified along the section from Longyao to the piedmont of Taihang Mountain, but P. waves characterized generally by strong amplitude are not obvious. Under the earthquake region and its western neighboring region, thecrustal velocity structure features high and low velocities changed alternatively. From North China plain toShanxi plateau, the velocity at the top of the upper mantle decreases progressively, while crustal thickness increases by 11 km. Moho uplifts locally in the earthquake region. The crustal fault stretching deeply to Moho andthe discontinuous sections of Moho in the earthquake region are supposed to be the channels and zones for magmatic intrusion. The uplifting of upper mantle and magmatic intrusion are responsible for the formation ofanomalous crust-mantle structures and extending basins, and for the occurrence of Xingtai earthquake as well.
基金Financial support for field work and thin-section preparation,which are parts of the Ph.D. thesis of the author,was provided by the Shell Professorial Chair in Geology,University of Nigeria,Nsukka under Late Umeji A.C.
文摘Petrological and geochemical studies on some volcanic and sub-volcanic rocks from the Lower Benue rift indicate that they are basalts, basaltic and doleritic sills, trachybasalt and trachyte which generally belong to the alkali basalt series. The alkaline affinity is clearly evident in both their normative and modal mineral compositions, as well as their chemical compositions. The generally high fractionation indices [(La/Yb)N] are 7.06 to 17.65 for the basaltic rocks and 23.59 to 135. 35 for the trachytic rocks, against low values commonly seen in subalkaline (tholeiitic) series, with strong enrichments in the incompatible elements. All this strongly supports their alkaline affinity. The basaltic rocks are generally fine-grained and porphyritic, consisting of phenocrysts of clinopyroxene and olivine in the groundmass of the same minerals together with plagioclase. The clinopyroxene is either diopside or clinoenstatite. The trachyte consists of oligoclase, orthoclase, biotite, quartz and exhibits typical trachytic, flow structure. The basaltic and doleritic sills are commonly altered, with calcite and epidote as common alteration prod-ucts. This alteration, which is reflected in the erratic behaviour of K2O, MnO and P2O5 on Harker variation diagrams, high values of LOI, strong depletions in the more mobile LILE (Rb, K, Ba and Sr) and high Th/Ta ratios, is attributed to the effects of an aqueous fluid phase and crustal contamination. On the whole, the mineralogical, as well as major-, trace-elements and REE data suggest that the rocks are co-genetic and most likely derived from differentiation of an alkali olivine-basalt magma, generating through variable low degrees of partial melting of probably an enriched lithospheric (upper) mantle following an asthenospheric uplift (mantle plume or intumescence) with HIMU signa-tures in a within-plate continental rift tectonic setting. This corroborates earlier results obtained for the intrusive rocks in the region.