Secular variations of carbon isotopic composition of organic carbon can be used in the study of global environmental variation, the carbon cycle, stratigraphic delimitation, and biological evolution, etc. Organic carb...Secular variations of carbon isotopic composition of organic carbon can be used in the study of global environmental variation, the carbon cycle, stratigraphic delimitation, and biological evolution, etc. Organic carbon isotopic analysis of the Nangao and Zhalagou sections in eastern Gnizhou reveals a negative excursion near the Precambrian-Cambrian boundary that correlates with a distinct carbonate carbon isotopic negative excursion at this boundary globally. Our results also demonstrate that several alternating positive and negative shifts occur in the Meishucunian, and an obvious negative anomaly appears at the boundary between the Meishucunian and Qiongzhusian. The isotope values are stable in the middle and lower parts but became more positive in the upper part of the Qiongzhusian. Evolution of organic carbon isotopes from the two sections in the deepwater facies can be well correlated with that of the carbonate carbon isotopes from the section in the shallow water facies. Integrated with other stratigraphic tools, we can precisely establish a lower Cambrian stratigraphic framework from shallow sheff to deep basin of the Yangtze Platform.展开更多
The placement of the Ediacaran-Cambrian boundary in deep-water realm in South China and the high-precision temporal framework for the Ediacaran-Cambrian transition in this region have not yet been completely solved. R...The placement of the Ediacaran-Cambrian boundary in deep-water realm in South China and the high-precision temporal framework for the Ediacaran-Cambrian transition in this region have not yet been completely solved. Recently, we have found two K-bentonite beds in the top of the Liuchapo Formation at the Pingyin section, Guizhou Province. It provides an opportunity for constructing the temporal framework of the transitional strata on the Yangtze Platform in South China and for determining the Ediacaran-Cambrian boundary in this area. In this study, we conducted high-precision CA-ID-TIMS U-Pb dating on zircons from the two K-bentonites. The ages of the two K-bentonites were precisely constrained at 536.40±0.47/1.1/1.2 Ma(2σ, n=7, MSWD=0.92) and 541.48±0.46/1.1/1.2 Ma(2σ, n=8, MSWD=1.3). Combining the geochronological results with organic carbon isotope data of chert in the topmost Liuchapo Formation from the section, we suggest that the EdiacaranCambrian boundary should be consistent with a significant negative organic carbon isotope excursion between the two Kbentonites. The scheme of the Ediacaran-Cambrian boundary in this study is of great significance for global correlation, and further for unravelling the information of the terminal Ediacaran-early Cambrian ocean.展开更多
The Ediacaran–Cambrian succession in South China records dramatic biological,oceanic and geochemical changes,but it is not well constrained geochronologically.This study reports a new SIMS U-Pb date of 543.4±3.5...The Ediacaran–Cambrian succession in South China records dramatic biological,oceanic and geochemical changes,but it is not well constrained geochronologically.This study reports a new SIMS U-Pb date of 543.4±3.5 Ma(MSWD=1.2)from a tuffaceous layer in the Zhoujiaao Section,and carbonate C-O isotopes in both Zhoujiaao and Sixi sections,Three Gorges area.This tuffaceous layer is present in the Upper Dengying Formation(i.e.,the Baimatuo Member)which is characterized by a stableδ13Ccarb plateau and the beginning of a negativeδ13Ccarb shift near its upper boundary.In accordance with the existing biostratigraphic and chemostratigraphic data,this new date corroborates that the upper boundary of the Dengying Formation in South China is approximately equivalent to the Ediacaran-Cambrian boundary(ca.541 Ma).This age also provides the minimum age of the last appearance of the Shibantan biota in the Three Gorges area,indicating that the terminal Ediacaran index fossils(e.g.,Cloudina,Sinotubulites)are not reliable stratigraphic markers for further subdivision of the uppermost Ediacaran.展开更多
The Ediacaran-Cambrian(E-C) succession in South China records remarkable oceanic,biological and geochemical variations,but it was not well defined geochronologically,which hinders the interpretation of the spatio-temp...The Ediacaran-Cambrian(E-C) succession in South China records remarkable oceanic,biological and geochemical variations,but it was not well defined geochronologically,which hinders the interpretation of the spatio-temporal seawater chemical architecture during the time E-C interval.This study presents two Re-Os isochron ages of 520.2±6.1 and 561.7±8.5 Ma for the barite-rich black shales from the top Liuchapo and Doushantuo formations respectively in Tianzhu County,Guizhou Province.In combination with existing age data,the two new Re-Os isochron ages suggest that the Liuchapo Formation was deposited between 550 and 520 Ma.Moreover,like the polymetallic Ni-MoPGE layers of shelf margin(or platform) facies and V-rich horizons of transitional(or shelf slope) to deep-water facies,the barite deposits were likely formed due to differential mineralization.The timing offset likely resulted from differential elemental concentration related to certain local factors(i.e.,hydrothermal fluids,seawater redox and biological activity).The isochron-derived initial ^(187)Os/^(188)Os ratios of the top Liuchapo Formation(0.902 ± 0.048) and the Doushantuo Formation(0.740 ± 0.042) fall within the range of continental weathering flux(1.54) and oceanic crust(0.126),implying the involvement of marine hydrothermal fluids.Moreover,their difference of initial ^(187)Os/^(188)Os ratios may reflect variations of continental weathering intensity and uplift magnitude.展开更多
It has been an intense debate on the exact boundary between Ediacaran and Cambrian in the southwest Yangtze Block.The calibration of this critical boundary has a remarkable influence on the further investigation of th...It has been an intense debate on the exact boundary between Ediacaran and Cambrian in the southwest Yangtze Block.The calibration of this critical boundary has a remarkable influence on the further investigation of the break-up of the Rodinia Supercontinent,the early life evolution,and the mechanism of the phosphorite deposit.Ediacaran and Cambrian strata and fossils are widely distributed in Anning,Yunnan Province in China.In recent years,the Xiaowaitoushan Member from the Lower Yuhucun Formation has been studied.Through this interval with continuous collections,the first appearance datums(FADs)of the protoconodont(Fomitchella cf.inchoate Yang et He,Protohertzina cf.anabarica Missarzhevsky)and globular embryos fossil(Olivooides sp.)earlier than these in the Lower Cambrian strata of the Meishucun Formation were discovered.This discovery indicates that the Xiaowaitoushan Member has included more FADs than the previously discovered single FAD of Anabarites primitivus Qian et Jiang,and the Ediacaran–Cambrian boundary in southwest China should be replaced below the Point“A”of the Meishucun Formation in Yunnan Province.The Point“B”of the Meishucun Formation is younger than the suggested age 541 Ma of the Ediacaran–Cambrian boundary and can no longer reference the Global Boundary Stratotype Section and Point(GSSP)correlation in southwest China.It can be suggested based on the previous stratigraphy and palaeontology studies from northern Sichuan and southern Shaanxi and the FAD of the globular embryos fossils that the Ediacaran‒Cambrian boundary in the southwest Yangtze Block should be placed at the base of the Xiaowaitoushan Member;other phosphorite strata refer to Xiaowaitoushan Member.The discovery of the FADs of the shelly fossils in the Xiaowaitoushan Member provides new evidence for the global correlation of the Ediacaran–Cambrian boundary in the southwest Yangtze Block.The conodont discoloration index(CAI)of the specimens in Anning is between 2 and 3,which indicates that the organic matter in Xiaowaitoushan Member is matured and has high potential to form a shale gas reservoir.展开更多
The black shale series that formed in the Ediacaran–Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean,-climate,and-biology. In this study, we measured Re–Os isotopic comp...The black shale series that formed in the Ediacaran–Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean,-climate,and-biology. In this study, we measured Re–Os isotopic compositions of the black shale in the Niutitang Formation from the Gezhongwu section in Zhijin, Guizhou Province.The samples had high Re and Os contents, with Re ranging from 21.27 to 312.78 ng/g and Os ranging from 0.455 to7.789 ng/g. The Re–Os isotope isochron age of 522.9 ± 8.6 Ma implies deposition of the Niutitang black shale predated the Chengjiang Fauna, providing an age constraint for the expansion of oceanic anoxia in the study area. The initial ^(187)Os/^(188)Os ratio of 0.826 ± 0.026 indicates that enhanced continental weathering might have triggered the exansion of the oceanic anoxia.展开更多
文摘Secular variations of carbon isotopic composition of organic carbon can be used in the study of global environmental variation, the carbon cycle, stratigraphic delimitation, and biological evolution, etc. Organic carbon isotopic analysis of the Nangao and Zhalagou sections in eastern Gnizhou reveals a negative excursion near the Precambrian-Cambrian boundary that correlates with a distinct carbonate carbon isotopic negative excursion at this boundary globally. Our results also demonstrate that several alternating positive and negative shifts occur in the Meishucunian, and an obvious negative anomaly appears at the boundary between the Meishucunian and Qiongzhusian. The isotope values are stable in the middle and lower parts but became more positive in the upper part of the Qiongzhusian. Evolution of organic carbon isotopes from the two sections in the deepwater facies can be well correlated with that of the carbonate carbon isotopes from the section in the shallow water facies. Integrated with other stratigraphic tools, we can precisely establish a lower Cambrian stratigraphic framework from shallow sheff to deep basin of the Yangtze Platform.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41673061, 41462001 & 41688103)the Chinese Academy of Sciences Instrument and Equipment Function Development Project (Grant No. IGG201803)。
文摘The placement of the Ediacaran-Cambrian boundary in deep-water realm in South China and the high-precision temporal framework for the Ediacaran-Cambrian transition in this region have not yet been completely solved. Recently, we have found two K-bentonite beds in the top of the Liuchapo Formation at the Pingyin section, Guizhou Province. It provides an opportunity for constructing the temporal framework of the transitional strata on the Yangtze Platform in South China and for determining the Ediacaran-Cambrian boundary in this area. In this study, we conducted high-precision CA-ID-TIMS U-Pb dating on zircons from the two K-bentonites. The ages of the two K-bentonites were precisely constrained at 536.40±0.47/1.1/1.2 Ma(2σ, n=7, MSWD=0.92) and 541.48±0.46/1.1/1.2 Ma(2σ, n=8, MSWD=1.3). Combining the geochronological results with organic carbon isotope data of chert in the topmost Liuchapo Formation from the section, we suggest that the EdiacaranCambrian boundary should be consistent with a significant negative organic carbon isotope excursion between the two Kbentonites. The scheme of the Ediacaran-Cambrian boundary in this study is of great significance for global correlation, and further for unravelling the information of the terminal Ediacaran-early Cambrian ocean.
基金funded by the National Natural Science Foundation of China(Nos.41472089,91755210)
文摘The Ediacaran–Cambrian succession in South China records dramatic biological,oceanic and geochemical changes,but it is not well constrained geochronologically.This study reports a new SIMS U-Pb date of 543.4±3.5 Ma(MSWD=1.2)from a tuffaceous layer in the Zhoujiaao Section,and carbonate C-O isotopes in both Zhoujiaao and Sixi sections,Three Gorges area.This tuffaceous layer is present in the Upper Dengying Formation(i.e.,the Baimatuo Member)which is characterized by a stableδ13Ccarb plateau and the beginning of a negativeδ13Ccarb shift near its upper boundary.In accordance with the existing biostratigraphic and chemostratigraphic data,this new date corroborates that the upper boundary of the Dengying Formation in South China is approximately equivalent to the Ediacaran-Cambrian boundary(ca.541 Ma).This age also provides the minimum age of the last appearance of the Shibantan biota in the Three Gorges area,indicating that the terminal Ediacaran index fossils(e.g.,Cloudina,Sinotubulites)are not reliable stratigraphic markers for further subdivision of the uppermost Ediacaran.
基金jointly supported by the National Natural Science Foundation of China(Nos.41763006,42063009,U1812402)the Talent Base Project of Guizhou Province(No.RCJD2018-21)。
文摘The Ediacaran-Cambrian(E-C) succession in South China records remarkable oceanic,biological and geochemical variations,but it was not well defined geochronologically,which hinders the interpretation of the spatio-temporal seawater chemical architecture during the time E-C interval.This study presents two Re-Os isochron ages of 520.2±6.1 and 561.7±8.5 Ma for the barite-rich black shales from the top Liuchapo and Doushantuo formations respectively in Tianzhu County,Guizhou Province.In combination with existing age data,the two new Re-Os isochron ages suggest that the Liuchapo Formation was deposited between 550 and 520 Ma.Moreover,like the polymetallic Ni-MoPGE layers of shelf margin(or platform) facies and V-rich horizons of transitional(or shelf slope) to deep-water facies,the barite deposits were likely formed due to differential mineralization.The timing offset likely resulted from differential elemental concentration related to certain local factors(i.e.,hydrothermal fluids,seawater redox and biological activity).The isochron-derived initial ^(187)Os/^(188)Os ratios of the top Liuchapo Formation(0.902 ± 0.048) and the Doushantuo Formation(0.740 ± 0.042) fall within the range of continental weathering flux(1.54) and oceanic crust(0.126),implying the involvement of marine hydrothermal fluids.Moreover,their difference of initial ^(187)Os/^(188)Os ratios may reflect variations of continental weathering intensity and uplift magnitude.
基金The authors appreciate the comments given by the reviewers and editors.The work was financially supported by projects of“1∶50000 Regional Geological Survey of Samaki,Yinmin,Guicheng”and“Shugu Sheets in Yunnan Province by Land and Resources Department of Yunnan Province”(D201905)project of“1∶50000 Regional Geological Survey of Erjie,Yimen,Mingyihe,and Shangpubei Sheets in Yunnan Province”(DD20160017)“Regional Geological Survey Area Summary and Service Product Development in Yunnan Province”by China Geological Survey(121201102000150012-02,DD20190008)).
文摘It has been an intense debate on the exact boundary between Ediacaran and Cambrian in the southwest Yangtze Block.The calibration of this critical boundary has a remarkable influence on the further investigation of the break-up of the Rodinia Supercontinent,the early life evolution,and the mechanism of the phosphorite deposit.Ediacaran and Cambrian strata and fossils are widely distributed in Anning,Yunnan Province in China.In recent years,the Xiaowaitoushan Member from the Lower Yuhucun Formation has been studied.Through this interval with continuous collections,the first appearance datums(FADs)of the protoconodont(Fomitchella cf.inchoate Yang et He,Protohertzina cf.anabarica Missarzhevsky)and globular embryos fossil(Olivooides sp.)earlier than these in the Lower Cambrian strata of the Meishucun Formation were discovered.This discovery indicates that the Xiaowaitoushan Member has included more FADs than the previously discovered single FAD of Anabarites primitivus Qian et Jiang,and the Ediacaran–Cambrian boundary in southwest China should be replaced below the Point“A”of the Meishucun Formation in Yunnan Province.The Point“B”of the Meishucun Formation is younger than the suggested age 541 Ma of the Ediacaran–Cambrian boundary and can no longer reference the Global Boundary Stratotype Section and Point(GSSP)correlation in southwest China.It can be suggested based on the previous stratigraphy and palaeontology studies from northern Sichuan and southern Shaanxi and the FAD of the globular embryos fossils that the Ediacaran‒Cambrian boundary in the southwest Yangtze Block should be placed at the base of the Xiaowaitoushan Member;other phosphorite strata refer to Xiaowaitoushan Member.The discovery of the FADs of the shelly fossils in the Xiaowaitoushan Member provides new evidence for the global correlation of the Ediacaran–Cambrian boundary in the southwest Yangtze Block.The conodont discoloration index(CAI)of the specimens in Anning is between 2 and 3,which indicates that the organic matter in Xiaowaitoushan Member is matured and has high potential to form a shale gas reservoir.
基金supported by the China Geological Survey (DD20160346)the National Natural Science Foundation of China (41472089)the Guizhou Geological Prospecting Fund (2016091)
文摘The black shale series that formed in the Ediacaran–Cambrian transition are important stratigraphic records of the co-evolution of the paleo-ocean,-climate,and-biology. In this study, we measured Re–Os isotopic compositions of the black shale in the Niutitang Formation from the Gezhongwu section in Zhijin, Guizhou Province.The samples had high Re and Os contents, with Re ranging from 21.27 to 312.78 ng/g and Os ranging from 0.455 to7.789 ng/g. The Re–Os isotope isochron age of 522.9 ± 8.6 Ma implies deposition of the Niutitang black shale predated the Chengjiang Fauna, providing an age constraint for the expansion of oceanic anoxia in the study area. The initial ^(187)Os/^(188)Os ratio of 0.826 ± 0.026 indicates that enhanced continental weathering might have triggered the exansion of the oceanic anoxia.
