The inhibition effect of three azole compounds, 2-aminobenzimidazole（ABM）, 2-aminothiazole（AT） and 2-aminobenzothiazole（ABT）, on the corrosion of mild steel in a 1 mol/L HCI solution was investigated by means of...The inhibition effect of three azole compounds, 2-aminobenzimidazole（ABM）, 2-aminothiazole（AT） and 2-aminobenzothiazole（ABT）, on the corrosion of mild steel in a 1 mol/L HCI solution was investigated by means of potentiodynamic polarization measurement, electrochemical impedance spectroscopy（EIS） and scanning electron microscopy（SEM）. The correlation between inhibition efficiency and molecular structure of inhibitor was theoretically studied via quantum chemical calculations. The results show that the inhibition efficiency（η） of the inhibitors follows the order of ηABT〉ηAT〉ηABM. Moreover, ABM, AT and ABT belong to mixed-type inhibitors. The adsorption of the inhibitors on the steel surface follows the Langmuir adsorption isotherm, with both physisorption and chemisorption.展开更多
This paper mainly clarified the dispersion mechanism of three typical chemical dispersants which are polyethylene glycol octylphenyl ether(Triton X-100,T-100),polyethylene pyrrolidone(PVP)and carboxymethyl cellulose(C...This paper mainly clarified the dispersion mechanism of three typical chemical dispersants which are polyethylene glycol octylphenyl ether(Triton X-100,T-100),polyethylene pyrrolidone(PVP)and carboxymethyl cellulose(CMC)within lithium-ion battery(LIB)slurry.Initially,the optimum amounts of T-100,PVP and CMC are selected from 0%,0.5%,1.5%and 2.5%by evaluating the impedance of LIB slurry in the case of adding each typical chemical dispersant with EIS method.Moreover,the impedance spectrum of three different slurry samples which are PVDF-NMP solution,LiCoO_(2) slurry and Carbon Black(CB)slurry with the optimum amount of each dispersant are also investigated.After using SEM and C element distribution images of LIB slurry to verify the correctness of the dispersion mechanism of each dispersant,it is concluded that the dispersion CMC with its optimum amount 1.5%is the best one to promote the formation of conductive paths and CB-coated LiCoO_(2) network structure within LIB slurry,which has the considerably potential to improve the performance of LIB.展开更多
由于油气管道敷设于地下,在敷设过程中管道会经过不同的地区,从而遭受不同程度的腐蚀,严重的可能导致管道开裂,造成巨大的人员伤亡和经济损失。因此,开展管道钢在模拟土壤环境中的电化学腐蚀行为研究,对于保证油气管道的安全运行具有重...由于油气管道敷设于地下,在敷设过程中管道会经过不同的地区,从而遭受不同程度的腐蚀,严重的可能导致管道开裂,造成巨大的人员伤亡和经济损失。因此,开展管道钢在模拟土壤环境中的电化学腐蚀行为研究,对于保证油气管道的安全运行具有重要的意义。为此,采用电化学阻抗技术(EIS)和动电位极化测试技术,研究了X90管道钢直缝焊管母材和焊缝在近中性模拟土壤溶液(NS4)中的电化学腐蚀行为。结果表明:1在NS4溶液中,X90管道钢具有典型的阳极溶解特征,没有钝化现象;2母材的热力学稳定性高于焊缝的热力学稳定性;3在-850 m V极化电位下对母材和焊缝试样进行不同时间的极化,随着极化时间的延长,材料的极化电阻增加,腐蚀电流密度下降,材料的耐蚀性增加且母材的耐蚀性优于焊缝。展开更多
基金Supported by the National Natural Science Foundation of China（No.51171094）.
文摘The inhibition effect of three azole compounds, 2-aminobenzimidazole（ABM）, 2-aminothiazole（AT） and 2-aminobenzothiazole（ABT）, on the corrosion of mild steel in a 1 mol/L HCI solution was investigated by means of potentiodynamic polarization measurement, electrochemical impedance spectroscopy（EIS） and scanning electron microscopy（SEM）. The correlation between inhibition efficiency and molecular structure of inhibitor was theoretically studied via quantum chemical calculations. The results show that the inhibition efficiency（η） of the inhibitors follows the order of ηABT〉ηAT〉ηABM. Moreover, ABM, AT and ABT belong to mixed-type inhibitors. The adsorption of the inhibitors on the steel surface follows the Langmuir adsorption isotherm, with both physisorption and chemisorption.
基金support from National Natural Science Foundation of China(grant No.52006176,51876175,and 62101438)the Key Research and Development Project of Shaanxi Province(grant No.2022kw-18).
文摘This paper mainly clarified the dispersion mechanism of three typical chemical dispersants which are polyethylene glycol octylphenyl ether(Triton X-100,T-100),polyethylene pyrrolidone(PVP)and carboxymethyl cellulose(CMC)within lithium-ion battery(LIB)slurry.Initially,the optimum amounts of T-100,PVP and CMC are selected from 0%,0.5%,1.5%and 2.5%by evaluating the impedance of LIB slurry in the case of adding each typical chemical dispersant with EIS method.Moreover,the impedance spectrum of three different slurry samples which are PVDF-NMP solution,LiCoO_(2) slurry and Carbon Black(CB)slurry with the optimum amount of each dispersant are also investigated.After using SEM and C element distribution images of LIB slurry to verify the correctness of the dispersion mechanism of each dispersant,it is concluded that the dispersion CMC with its optimum amount 1.5%is the best one to promote the formation of conductive paths and CB-coated LiCoO_(2) network structure within LIB slurry,which has the considerably potential to improve the performance of LIB.
文摘由于油气管道敷设于地下,在敷设过程中管道会经过不同的地区,从而遭受不同程度的腐蚀,严重的可能导致管道开裂,造成巨大的人员伤亡和经济损失。因此,开展管道钢在模拟土壤环境中的电化学腐蚀行为研究,对于保证油气管道的安全运行具有重要的意义。为此,采用电化学阻抗技术(EIS)和动电位极化测试技术,研究了X90管道钢直缝焊管母材和焊缝在近中性模拟土壤溶液(NS4)中的电化学腐蚀行为。结果表明:1在NS4溶液中,X90管道钢具有典型的阳极溶解特征,没有钝化现象;2母材的热力学稳定性高于焊缝的热力学稳定性;3在-850 m V极化电位下对母材和焊缝试样进行不同时间的极化,随着极化时间的延长,材料的极化电阻增加,腐蚀电流密度下降,材料的耐蚀性增加且母材的耐蚀性优于焊缝。
