The paper presents ac impedance behaviours of phenyl iso-thiocyanate adsorbed on Pt electrode.Nyquist plots are analysed and simulated,and parameters of relative equivalent circuits are obtained.
The impedance diagram of hdrogen storage electrodes(AH electrodes )displayed twosemicircles.Thelow frequency one is affected by cycle number and composition of MH electrodes.
Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide（β-Ni（OH）2 ） was...Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide（β-Ni（OH）2 ） was prepared from nickel sulphate solution using potassium hydroxide as a precipitating agent. Pure β-phase of nickel hydroxide was confirmed from XRD and FT-IR studies. The effects of TiO2 additive on the β-Ni（OH）2 electrode performance are examined. The structure and property of the TiO2 added β-Ni（OH）2 were characterized by XRD, TG-DTA and SEM analysis. A pasted–type electrode is prepared using nickel hydroxide powder as the main active material on a nickel sheet as a current collector. Cyclic voltammetry and electrochemical impedance spectroscopy studies were performed to evaluate the electrochemical performance of the β-Ni（OH）2 and TiO2 added β-Ni（OH）2 electrodes in 6 M KOH electrolyte. Anodic（Epa） and cathodic（Epc）peak potentials are found to decrease after the addition of TiO 2 into β-Ni（OH）2 electrode material. Further,addition of TiO2 is found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current. Compared with pure β-Ni（OH）2 lectrode,TiO2 added β-Ni（OH）2 electrode is found to exhibit higher proton diffusion coefficient（D） and lower charge transfer resistance. These findings suggest that the TiO2 added β-Ni（OH）2 electrode possess improved electrochemical properties and thus can be recognized as a promising candidate for the battery electrode applications.展开更多
At present,electrode line impedance supervision(ELIS)based protection is widely used to detect faults on grounding electrode lines,which are indispensable elements of high-voltage direct current(HVDC)systems.The exist...At present,electrode line impedance supervision(ELIS)based protection is widely used to detect faults on grounding electrode lines,which are indispensable elements of high-voltage direct current(HVDC)systems.The existing theoretical analysis of measured impedance is based on lumped line model and the threshold value is generally set according to engineering experience,which have caused the dead zone problem and even accidents.Therefore,a study on measured impedance of ELIS-based protection and its threshold value selection method is carried out to solve this problem.In this study,the expressions of measured impedance under normal operation and fault conditions are deduced based on rigorous and accurate line model.Based on the expressions,the characteristics of the measured impedance are calculated and analyzed.With the characteristics of the measured impedance,the applicability of the protection with the traditional threshold value is further discussed and the distribution of the dead zone can be located.Then,the method to calculate the threshold value of ELIS-based protection is proposed.With a proper threshold value selected by the proposed method,the dead zone of ELIS-based protection is effectively eliminated,and the protection can identify all types of faults even with large transition resistances.Case studies on PSCAD/EMTDC have been conducted to verify the conclusion.展开更多
文摘The paper presents ac impedance behaviours of phenyl iso-thiocyanate adsorbed on Pt electrode.Nyquist plots are analysed and simulated,and parameters of relative equivalent circuits are obtained.
文摘The impedance diagram of hdrogen storage electrodes(AH electrodes )displayed twosemicircles.Thelow frequency one is affected by cycle number and composition of MH electrodes.
文摘Nickel hydroxide was used as the positive electrode material in rechargeable alkaline batteries, which plays a significant role in the field of electric energy storage devices. β-nickel hydroxide（β-Ni（OH）2 ） was prepared from nickel sulphate solution using potassium hydroxide as a precipitating agent. Pure β-phase of nickel hydroxide was confirmed from XRD and FT-IR studies. The effects of TiO2 additive on the β-Ni（OH）2 electrode performance are examined. The structure and property of the TiO2 added β-Ni（OH）2 were characterized by XRD, TG-DTA and SEM analysis. A pasted–type electrode is prepared using nickel hydroxide powder as the main active material on a nickel sheet as a current collector. Cyclic voltammetry and electrochemical impedance spectroscopy studies were performed to evaluate the electrochemical performance of the β-Ni（OH）2 and TiO2 added β-Ni（OH）2 electrodes in 6 M KOH electrolyte. Anodic（Epa） and cathodic（Epc）peak potentials are found to decrease after the addition of TiO 2 into β-Ni（OH）2 electrode material. Further,addition of TiO2 is found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current. Compared with pure β-Ni（OH）2 lectrode,TiO2 added β-Ni（OH）2 electrode is found to exhibit higher proton diffusion coefficient（D） and lower charge transfer resistance. These findings suggest that the TiO2 added β-Ni（OH）2 electrode possess improved electrochemical properties and thus can be recognized as a promising candidate for the battery electrode applications.
基金supported by the National Natural Science Foundation of China for Distinguished Young Scholars(No.52025071)the Joint Funds of the National Natural Science Foundation of China(No.U1866205)。
文摘At present,electrode line impedance supervision(ELIS)based protection is widely used to detect faults on grounding electrode lines,which are indispensable elements of high-voltage direct current(HVDC)systems.The existing theoretical analysis of measured impedance is based on lumped line model and the threshold value is generally set according to engineering experience,which have caused the dead zone problem and even accidents.Therefore,a study on measured impedance of ELIS-based protection and its threshold value selection method is carried out to solve this problem.In this study,the expressions of measured impedance under normal operation and fault conditions are deduced based on rigorous and accurate line model.Based on the expressions,the characteristics of the measured impedance are calculated and analyzed.With the characteristics of the measured impedance,the applicability of the protection with the traditional threshold value is further discussed and the distribution of the dead zone can be located.Then,the method to calculate the threshold value of ELIS-based protection is proposed.With a proper threshold value selected by the proposed method,the dead zone of ELIS-based protection is effectively eliminated,and the protection can identify all types of faults even with large transition resistances.Case studies on PSCAD/EMTDC have been conducted to verify the conclusion.
