The electrolytic codeposition of lanthanum-cobalt in the melt consisting of urea-NaCl-NaAc-CoCl2-LaCl3 was studied by means of cyclic voltammetry, electron probe analyser, X-ray diffraction. Cathodic potential, curren...The electrolytic codeposition of lanthanum-cobalt in the melt consisting of urea-NaCl-NaAc-CoCl2-LaCl3 was studied by means of cyclic voltammetry, electron probe analyser, X-ray diffraction. Cathodic potential, current density, La3+/Co2+ molar ratio in the melt and the electrode substrates all exercise influence on the content of lanthanum deposied. The deposites consist of cobalt and lanthanum, but they don't form any intermetallic compound.展开更多
The mechanism of the electrolytic codeposition of Y Al alloy in molten LiF AlF 3 Al 2O 3 YF 3, LiF YF 3 Y 2O 3 AlF 3 and LiF YF 3 Y 2O 3 Al 2O 3 systems was investigated by means of cyclic volta...The mechanism of the electrolytic codeposition of Y Al alloy in molten LiF AlF 3 Al 2O 3 YF 3, LiF YF 3 Y 2O 3 AlF 3 and LiF YF 3 Y 2O 3 Al 2O 3 systems was investigated by means of cyclic voltammetry. The electrodeposited products were analysed by X ray diffraction. The results show that the electrolytic codeposition of Y Al alloy in the LiF YF 3 Y 2O 3 Al 2O 3 system without AlF 3 can be achieved at the same potential for Y(Ⅲ) and Al(Ⅲ) which have great difference in deposition potential. It is beneficial to codeposition of Y(Ⅲ) and Al(Ⅲ) when temperature rises. The potential of beginning codeposition is about -0.85 V ( vs Pt reference electrode), but only at the potential of -0.95 V or more negative can Y based Al alloy containing a great amount of yttrium be obtained.展开更多
文摘The electrolytic codeposition of lanthanum-cobalt in the melt consisting of urea-NaCl-NaAc-CoCl2-LaCl3 was studied by means of cyclic voltammetry, electron probe analyser, X-ray diffraction. Cathodic potential, current density, La3+/Co2+ molar ratio in the melt and the electrode substrates all exercise influence on the content of lanthanum deposied. The deposites consist of cobalt and lanthanum, but they don't form any intermetallic compound.
文摘The mechanism of the electrolytic codeposition of Y Al alloy in molten LiF AlF 3 Al 2O 3 YF 3, LiF YF 3 Y 2O 3 AlF 3 and LiF YF 3 Y 2O 3 Al 2O 3 systems was investigated by means of cyclic voltammetry. The electrodeposited products were analysed by X ray diffraction. The results show that the electrolytic codeposition of Y Al alloy in the LiF YF 3 Y 2O 3 Al 2O 3 system without AlF 3 can be achieved at the same potential for Y(Ⅲ) and Al(Ⅲ) which have great difference in deposition potential. It is beneficial to codeposition of Y(Ⅲ) and Al(Ⅲ) when temperature rises. The potential of beginning codeposition is about -0.85 V ( vs Pt reference electrode), but only at the potential of -0.95 V or more negative can Y based Al alloy containing a great amount of yttrium be obtained.
