Effect of Cryogenic Treatment on Microstructure and Tribological Property Evolution of Electron Beam Melted Ti6Al4V

Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated using electron beam melting(EBM),and their microstructure and tribological properties evolution were systematically analyzed by scanning electron microscopy(SEM),vickers hardness,and wear tests.The experimental results show that the as-fabricated specimen consists of lamellarαphase andβcolumnar crystal.While,the thickness of lamellarαphase decreased after cryogenic treatment.In addition,it can be found that the fineαphase was precipitated and dispersed between the lamellarαphase with the holding time increase.Vickers hardness shows a trend of first increasing and then decreasing.The wear rate of the specimen cryogenic treated for 24 h is the minimum and the average friction coefficient is 0.50,which is reduced by 14.61%compared with the as-fabricated.The wear mechanism of the as-fabricated specimen is severe exfoliation,adhesive,abrasive,and slight fatigue wear.However,the specimen cryogenic treated for 24 h shows slight adhesive and abrasive wear.It can be concluded that it is feasibility of utilizing cryogenic treatment to reduce the wear of EBMed Ti6Al4V.

Generation and Suppression of Pendant Droplet Oscillation in Electron Beam Directed Energy Deposition

Electron beam–directed energy deposition(EB–DED)has emerged as a promising wire-based metal additive manufacturing technique.However,the effects of EBs on pendant droplets at wire tips have not yet been determined.The aim of this study is to enhance the understanding of this action by analyzing the mechanism of droplet oscillation.The pendant droplet oscillation phenomenon hinders the stable transfer of droplets to the molten pool and limits the feasibility of manufacturing complex lattice structures by EB–DED.Hence,another aim of this study is to create an oscillation suppression method.An escalating asymmetric amplitude is the main characteristic of droplet oscillation.The primary oscillationinducing force is the recoil force generated from the EB-acted local surface of the droplet.The physical mechanism of this force is the rapid increase and uneven distribution of the local surface temperature caused by the partial action of the EB.The prerequisites for droplet oscillation include vacuum conditions,high power densities,and bypass wire feeding processes.The proposed EB–dynamic surrounding melting(DSM)method can be applied to conveniently and effectively suppress oscillations,enable the accurate transfer of droplets to the molten pool,and achieve stable processes for preparing the strut elements of lattice structures.Lowering the temperature and improving the uniformity of its distribution are the mechanisms of oscillation suppression in EB–DSM.In this study,the physical basis for interpreting the mechanism by which EBs act on droplets and the technical basis for using EB–DED to prepare complex lattice structure parts are provided.

Real-time generation of circular patterns in electron beam lithography

Electron beam lithography(EBL)involves the transfer of a pattern onto the surface of a substrate byfirst scanning a thin layer of organicfilm(called resist)on the surface by a tightly focused and precisely controlled electron beam(exposure)and then selectively removing the exposed or nonexposed regions of the resist in a solvent(developing).It is widely used for fabrication of integrated cir-cuits,mask manufacturing,photoelectric device processing,and otherfields.The key to drawing circular patterns by EBL is the graphics production and control.In an EBL system,an embedded processor calculates and generates the trajectory coordinates for movement of the electron beam,and outputs the corresponding voltage signal through a digital-to-analog converter(DAC)to control a deflector that changes the position of the electron beam.Through this procedure,it is possible to guarantee the accuracy and real-time con-trol of electron beam scanning deflection.Existing EBL systems mostly use the method of polygonal approximation to expose circles.A circle is divided into several polygons,and the smaller the segmentation,the higher is the precision of the splicing circle.However,owing to the need to generate and scan each polygon separately,an increase in the number of segments will lead to a decrease in the overall lithography speed.In this paper,based on Bresenham’s circle algorithm and exploiting the capabilities of afield-programmable gate array and DAC,an improved real-time circle-producing algorithm is designed for EBL.The algorithm can directly generate cir-cular graphics coordinates such as those for a single circle,solid circle,solid ring,or concentric ring,and is able to effectively realizes deflection and scanning of the electron beam for circular graphics lithography.Compared with the polygonal approximation method,the improved algorithm exhibits improved precision and speed.At the same time,the point generation strategy is optimized to solve the blank pixel and pseudo-pixel problems that arise with Bresenham’s circle algorithm.A complete electron beam deflection system is established to carry out lithography experiments,the results of which show that the error between the exposure results and the preset pat-terns is at the nanometer level,indicating that the improved algorithm meets the requirements for real-time control and high precision of EBL.

A study of pulsed high voltage driven hollow-cathode electron beam sources through synchronous optical trigger

In this study,a pulsed,high voltage driven hollow-cathode electron beam sources through an optical trigger is designed with characteristics of simple structure,low cost,and easy triggering.To validate the new design,the characteristics of hollow-cathode discharge and electron beam characterization under pulsed high voltage drive are studied experimentally and discussed by discharge characteristics and analyses of waveform details,respectively.The validation experiments indicate that the pulsed high voltage supply significantly improves the frequency and stability of the discharge,which provides a new solution for the realization of a high-frequency,high-energy electron beam source.The peak current amplitude in the high-energy electron beam increases from 6.2 A to 79.6 A,which indicates the pulsed power mode significantly improves the electron beam performance.Besides,increasing the capacitance significantly affects the highcurrent,lower-energy electron beam more than the high-energy electron beam.

Divergence angle consideration in energy spread measurement for high-quality relativistic electron beam in laser wakefield acceleration

The thorough exploration of the transverse quality represented by divergence angle has been lacking yet in the energy spread measurement of the relativistic electron beam for laser wakefield acceleration(LWFA). In this work, we fill this gap by numerical simulations based on the experimental data, which indicate that in a C-shape magnet, magnetic field possesses the beam focusing effect, considering that the divergence angle will result in an increase in the full width at half maxima(FWHM) of the electron density distribution in a uniformly isotropic manner, while the length-to-width ratio decreases. This indicates that the energy spread obtained from the electron deflection distance is smaller than the actual value, regardless of the divergence angle. A promising and efficient way to accurately correct the value is presented by considering the divergence angle(for instance, for an electron beam with a length-to-width ratio of 1.12, the energy spread correct from 1.2% to 1.5%), providing a reference for developing the high-quality electron beam source.

Controllable growth of wafer-scale PdS and PdS_(2) nanofilms via chemical vapor deposition combined with an electron beam evaporation technique

Palladium(Pd)-based sulfides have triggered extensive interest due to their unique properties and potential applications in the fields of electronics and optoelectronics.However,the synthesis of large-scale uniform PdS and PdS_(2)nanofilms(NFs)remains an enormous challenge.In this work,2-inch wafer-scale PdS and PdS_(2) NFs with excellent stability can be controllably prepared via chemical vapor deposition combined with electron beam evaporation technique.The thickness of the pre-deposited Pd film and the sulfurization temperature are critical for the precise synthesis of PdS and PdS_(2) NFs.A corresponding growth mechanism has been proposed based on our experimental results and Gibbs free energy calculations.The electrical transport properties of PdS and PdS_(2) NFs were explored by conductive atomic force microscopy.Our findings have achieved the controllable growth of PdS and PdS_(2) NFs,which may provide a pathway to facilitate PdS and PdS_(2) based applications for next-generation high performance optoelectronic devices.

Effects of anode material on the evolution of anode plasma and characteristics of intense electron beam diode

In this paper,three kinds of materials including graphite,titanium(Ti)and molybdenum(Mo)are used as anodes to figure out the influence factors of anode material on the characteristics of the intense electron beam diode.The results show that the characteristics of diode are mainly determined by the cathode plasma motion under a 15 mm diode gap,in which the typical electron beam parameters are 280 kV,3.5 kA.When the diode gap is reduced to 5 mm,the voltage of the electron beam reduces to about 200 kV,and its current increases to more than 8.2 kA.It is calculated that the surface temperatures of Ti and Mo anodes are higher than their melting points.The diode plasma luminescence images show that Ti and Mo anodes produce plasmas soon after the bombardment of electron beams.Ti and Mo lines are respectively found in the plasma composition of Ti and Mo anode diodes.Surface melting traces are also observed on Ti and Mo anodes by comparing the micromorphologies before and after bombardment of the electron beam.These results suggest that the time of anode plasma generation is closely related to the anode material.Compared with graphite,metal Ti and Mo anodes are more likely to produce large amounts of plasma due to their more significant temperature rise effect.According to the moment that anode plasma begins to generate,the average expansion velocities of cathode and anode plasma are estimated by fitting the improved space-charge limited flow model.This reveals that generation and motion of the anode plasma significantly affect the characteristics of intense electron beam diode.

Lifetime measurement of the 3d^(9) ^(2)D_(3/2) metastable level in Mo^(15+)at an electron beam ion trap

An experimental measurement of the lifetime of 3d^(9) ^(2)D_(3/2) metastable level in Mo^(15+)is reported in this work.The Mo^(15+)ions are produced and trapped in an electron beam ion trap with a magnetic field of 0.65 T.The decay photons emitted from 3d^(9) ^(2)D_(3/2) level are subsequently recorded via a cooled photomultiplier tube.Through meticulous scrutiny of potential systematic uncertainties affecting the measurement outcomes,we have determined the lifetime of Mo^(15+)3d^(9)2D_(3/2)metastable level to be 2.83(22)ms.The experimental result provides a clear distinguishment from existing calculations based on various theoretical approaches.

Electron beam pumping improves the conversion efficiency of low-frequency photons radiated by perovskite quantum dots

This research argues that using an electron beam with high kinetic energy to pump perovskite quantum dots can significantly boost the efficiency of the low-frequency photon radiation conversion.Firstly,we measure the random lasing threshold and luminescence threshold of CsPbX_(3)films pumped by an electron beam.Then,we simulate the spatial distribution of the electron beams in CsPbX_(3)films.Combined with the above data,a low-frequency photon radiation conversion model based on the electron pumped perovskite quantum dots is presented.This could be a way to create a terahertz source with a high-power output or to multiply the terahertz power.

Focused electron beam transport through a long narrow metal tube at elevated pressures in the forevacuum range

We present here our investigations of the features of focused electron beam transport in free space at elevated pressures of a few pascals.We have explored the effect of the beam accelerating voltage,operating gas pressure,and magnetic focusing upon the trajectory of beam electrons in the crossover region,in particular on the beam convergence and divergence angles.It is shown that for the forevacuum pressure range of 2-5 Pa explored,a distinctive feature of the propagation of a focused electron beam with a current of up to 20 mA at an accelerating voltage of 10-20 kV is the difference in the angles of convergence(before the focus)and divergence(after the focus).Whereas at a low pressure of 2 Pa the divergence angle is smaller than the convergence angle,as the pressure increases the divergence angle increases and for pressures greater than 5 Pa the divergence angle is greater than the convergence angle.The results obtained were used in experiments on electron beam transport through a long narrow metal tube with a diameter of 5.8-9.2 mm and length of 10-30 cm.We show that for a 30 cm long tube of 7.5 mm diameter,the focused beam transmission can exceed 70%.

Local wavelength evolution and Landau damping of electrostatic plasma wave driven by an ultra-relativistic electron beam in dense inhomogeneous plasma

Evolution of an electrostatic plasma wave driven by a low-density ultra-relativistic electron beam in dense inhomogeneous plasma is considered. In particular, the wavelength variation as observed at fixed locations in the plasma is analyzed in terms of the wave characteristics. It is shown that for a negative density gradient, the observed local wavelength decreases monotonically with time, but for a positive density gradient, it first increases and then decreases with time, accompanied by reversal of the wave phase. However, in both cases the local wavelength eventually decreases with time since Landau damping becomes significant as the wavelength becomes of the order of the plasma Debye length. Results from particle-in-cell simulations agree well with theoretical analyses of the wavelength variation.

Microstructure and defect of titanium alloy electron beam deep penetration welded joint

The microstructure, phase composition and cold shut defect of thick titanium alloy electron beam welded joint were studied. The results showed that the microstructure of weld zone was composed of α′ phase; the heat affected zone was divided into fine-grained zone and coarse-grained zone, the microstructure of fine-grained zone was primary α phase ＋ β phase ＋ equiaxed α phase, and the microstructure of coarse-grained zone was primary α phase ＋ acicular α′ phase; the microstructure of base metal zone basically consisted of primary α phase, and a small amount of residual β phase sprinkled. The forming. reason of cold shut was analyzed, and the precaution of cold shut was proposed.

Temperature and stress fields in electron beam welded Ti-15-3 alloy to 304 stainless steel joint with copper interlayer sheet

Electron beam welding of Ti-15-3 alloy to 304 stainless steel （STS） using a copper filler metal was carried out. The temperature fields and stress distributions in the Ti/Fe and Ti/Cu/Fe joint during the welding process were numerically simulated and experimentally measured. The results show that the rotated parabola body heat source is fit for the simulation of the electron beam welding. The temperature distribution is asymmetric along the weld center and the temperature in the titanium alloy plate is higher than that in the 304 STS plate. The thermal stress also appears to be in asymmetric distribution. The residual tensile stress mainly exists in the weld at the 304 STS side. The copper filler metal decreases the peak temperature and temperature grade in the joint as well as the residual stress. The longitudinal and lateral residual tensile strengths reduce by 66 MPa and 31 MPa, respectively. From the temperature and residual stress, it is concluded that copper is a good filler metal candidate for the electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel.

Electron beam welding of 304 stainless steel to QCr0.8 copper alloy with copper filler wire

Electron beam welding （EBW） of 304 stainless steel to QCr0.8 copper alloy with copper filler wire was carried out. Orthogonal experiment was performed to investigate the effects of process parameters on the tensile strength of the joints, and the process parameters were optimized. The optimum process parameters are as follows：beam current of 30 mA, welding speed of 100 mm/min, wire feed rate of 1 m/min and beam offset of-0.3 mm. The microstructures of the optimum joint were studied. The results indicate that the weld is mainly composed of dendriticαphase with little globularεphase, and copper inhomogeneity only occurs at the top of the fusion zone. In addition, a melted region without mixing exists near the weld junction of copper side. This region with a coarser grain size is the weakest section of the joints. It is found that the microhardness of the weld decreases with the increase of the copper content in solid solution. The highest tensile strength of the joint is 276 MPa.

Fatigue behavior of AZ31B magnesium alloy electron beam welded joint based on infrared thermography

Fatigue behavior of AZ31B magnesium alloy electron beam welded joint undergoing cyclic loading was investigated by infrared thermography. Temperature evolution throughout a fatigue process was presented and the mechanism of heat generationwas discussed. Fatigue limit of the welded joint was predicted and the fatigue damage was also assessed based ontheevolution of the temperatureand hotspot zone on the specimen surfaceduring fatigue tests. The presented results show that infrared thermography can not onlyquicklypredict the fatigue behavior of the welded joint, but also qualitatively identify the evolution of fatigue damage in real time. It is found that the predicted fatigue limit agrees well with the conventionalS-Nexperimental results. The evolution of the temperatureand hotspot zone on the specimen surface can be an effectivefatigue damage indicatorfor effectiveevaluationof magnesium alloy electron beam welded joint.

Structure and mechanical properties of aluminum alloy/Ag interlayer/steel non-centered electron beam welded joints

Electron beam welding was carried out between aluminum alloy and steel with Ag interlayer. Seam morphology, structure and mechanical properties of the joints were investigated with different action positions of the electron beam spot. The results show that with the increment of the beam offset to the silver side from the interface between silver and steel, the seam morphology was improved, and the porosity in the Ag interlayer vanished. A transition layer mainly composed of Ag2Al and Al eutectic was formed at the interface between silver and aluminum, and became thin and spiccato as the beam offset increased. When the beam offset was too large, two IMC layers composed of FeAl and FeAl3 respectively were formed at the interface between steel and Ag interlayer. The optimal beam offset was 0.2 mm, and the maximum tensile strength of the joint was 193 MPa, 88.9% that of the aluminum alloy, and the fracture occurred at the interface between steel and Ag interlayer.

Effect of hot working on microstructure and mechanical properties of TC11/Ti_2AlNb dual-alloy joint welded by electron beam welding process

The influence of hot working on the microstructures of TC11/Ti2 Al Nb dual-alloy joints welded by electron beam welding(EBW) process was investigated. The tensile tests were performed at room temperature for specimens before and after thermal exposure. The results show that the fusion zone of TC11/Ti2 Al Nb dual-alloy joint welded by EBW is mainly composed of β phase. After deformation and heat treatment, the grain boundaries of the as-cast alloy are broken and the fusion zone mainly consists of β, α2and α phases. The fusion zone performs poor property in the tensile test. Specimens before and after thermal exposure all fail in this area under different deformation conditions. The ultimate tensile strength of specimens after heat treatment is up to 1190 MPa at room temperature. The joints by water quenching after deformation have better plasticity with an elongation up to 4.4%. After thermal exposure at 500 °C for 100 h, the tensile strength of the specimen slightly rises while the ductility changes a little. SEM observation shows that the fracture mechanism is predominantly transgranular under different deformation conditions.

Surface modification of Cu-25Cr alloy induced by high current pulsed electron beam

A Cu-25Cr alloy prepared by vacuum induction melting method was treated by the high current pulsed electron beam （HCPEB） with pulse numbers ranging from 1 to 100. Surface morphologies and microstructures of the alloy before and after the treatment were investigated by scanning electron microscopy and X-ray diffraction. The results show that significant surface modification can be induced by HCPEB with the pulse number reaching 10. Craters with typical morphologies on the Cu-25Cr alloy surface are formed due to the dynamic thermal field induced by the HCPEB. Micro-cracks, as a unique feature, are well revealed in the irradiated Cu-25Cr specimens and attributed to quasi-static thermal stresses accumulated along the specimen surface. The amount of cracks is found to increase with the pulse number and a preference of these cracks to Cr phases rather than Cu phases is also noted. Another characteristic produced by the HCPEB is the fine Cr spheroids, which are determined to be due to occurrence of liquid phase separation in the Cu-25Cr alloy. In addition, an examination on surface roughness of all specimens reveals that more pulses will produce a roughened surface, as a result of compromising the above features.

Research on degradation of 2, 4 dichlorophenol and pentachlorophenol in water by electron beam irradiation

Electron beam was successfully used for the degradation of 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in water. The effects of radiation doses on substrate degradation and dechlorination of solutions with concentrations of 50 mg/L for both chlorophenols were investigated. The effects of initial concentration, pH and absence of oxygen on the degradation were also investigated. The concentrations of 2,4-DCP and PCP remaining in solution after irradiation were measured by high-performance liquid chromatograph (HPLC). The results showed that an increased radiation dose led to increased degradation of the chlorophenols and increased Cl- yields. In all cases, the rate of degradation was found to be higher than the corresponding inorganic chloride yield from the parent compound. Deoxygenation was also found to increase the rate of degradation of the chlorophenols in water while degradation under alkaline condition was lower than at low to neutral pH.

Effects of Electron Beam Local Postweld Heat Treatment on Microstructure and Properties of 30CrMnSiNi2A Steel Welded Joints

To improve the microstructure and properties of the electron beam welded joints, the vacuum or furnace whole post weld heat treatment (FWPWHT) usually should be done on it. The electron beam local post weld heat treatment (EBLPWHT) is a rather new heat treatment procedure that provides the advantages of high precision, flexibility and efficiency, energy saving and higher productivity. In this paper, the microstructure, mechanical properties, fracture toughness and fatigue properties of electron beam welded joints of 30CrMnSiNi2A steel in as-welded (AW) and EBLPWHT conditions have been investigated respectively. The results show that the microstructures of different zones of joints in as-welded condition are changed by EBLPWHT procedure, in which the welds from coarse needle martensite into lath-shaped martensite; the main structures of heat affected zones (HAZ) from lath-shaped martensite into lower bainite. The properties of welded joints can be improved by the EBLPWHT in some extent, especially the fracture toughness of the welds and the fatigue crack resistance of welded joints can be sufficiently improved. However, more appropriate heat treatment parameters of the EBLPWHT have to be studied in order to increase the mechanical properties of base metal near by the HAZ.