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Green,Sustainable Architectural Bamboo with High Light Transmission and Excellent Electromagnetic Shielding as a Candidate for Energy-Saving Buildings 被引量:2
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作者 Jing Wang Xinyu Wu +5 位作者 Yajing Wang Weiying Zhao Yue Zhao Ming Zhou Yan Wu Guangbin Ji 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期209-224,共16页
Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose compo... Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose composite with excellent optical transmittance that retained the natural shape and fiber structure of bamboo.The modified whole bamboo possessed an impressive optical transmittance of approximately 60%at 6.23 mm,illuminance of 1000 luminance(lux),water absorption stability(mass change rate less than 4%),longitudinal tensile strength(46.40 MPa),and surface properties(80.2 HD).These were attributed to not only the retention of the natural circular hollow structure of the bamboo rod on the macro,but also the complete bamboo fiber skeleton template impregnated with UV resin on the micro.Moreover,a multilayered device consisting of translucent whole bamboo,transparent bamboo sheets,and electromagnetic shielding film exhibited remarkable heat insulation and heat preservation performance as well as an electromagnetic shielding performance of 46.3 dB.The impressive optical transmittance,mechanical properties,thermal performance,and electromagnetic shielding abilities combined with the renewable and sustainable nature,as well as the fast and efficient manufacturing process,make this bamboo composite material suitable for effective application in transparent,energy-saving,and electromagnetic shielding buildings. 展开更多
关键词 Electromagnetic interference shielding Biomass material TRANSMITTANCE energy-saving BAMBOO
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Scalable and flexible porous hybrid film as a thermal insulating subambient radiative cooler for energy-saving buildings
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作者 Tong Wang Shuhua Tu +7 位作者 Yinggang Chen Qian Zhu Yinan Zhang Zhiyi Ding Xue Mei Min Chen Min Gu Limin Wu 《National Science Open》 2023年第4期153-167,共15页
Passive daytime radiative cooling(PDRC)is one of the promising alternatives to electrical cooling and has a significant impact on worldwide energy consumption and carbon neutrality.Toward real-world applications,howev... Passive daytime radiative cooling(PDRC)is one of the promising alternatives to electrical cooling and has a significant impact on worldwide energy consumption and carbon neutrality.Toward real-world applications,however,the parasitic heat input and heat leakage pose crucial challenges to commercial and residential buildings cooling.The integrating of radiative cooling and thermal insulation properties represents an attractive direction in renewable energy-efficient building envelope materials.Herein,we present a hierarchically porous hybrid film as a scalable and flexible thermal insulating subambient radiative cooler via a simple and inexpensive inverse high internal phase emulsion strategy.The as-prepared porous hybrid film exhibits an intrinsic combination of high solar reflectance(0.95),strong longwave infrared thermal emittance(0.97),and low thermal conductivity(31 mW/(m K)),yielding a subambient cooling temperature of~8.4℃ during the night and~6.5℃ during the hot midday with an average cooling power of~94 W/m^(2) under a solar intensity of~900 W/m^(2).Promisingly,combining the superhydrophobicity,durability,superelasticity,robust mechanical strength,and industrial applicability,the film is favorable for large-scale,sustainable and energy-saving applications in a wide variety of climates and complicated surfaces,enabling a substantial reduction of energy costs,greenhouse gas emission and associated ozone-depleting from traditional cooling systems. 展开更多
关键词 radiative cooling thermal insulation energy-saving buildings SCALABILITY FLEXIBILITY
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Multi-subject and multi-objective integrated optimization system and implementation strategy for energy-saving renovation of the existing residential buildings
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作者 GUO Han-ding JIN Zhen-xing +1 位作者 QIAO Wan-zhen ZHANG Yin-xian 《Ecological Economy》 2023年第2期149-162,共14页
The core of the healthy and orderly operation of the existing residential building energy-saving renovation market lies in the exploration of the implementation mechanism of multi-subject and multi-objective integrate... The core of the healthy and orderly operation of the existing residential building energy-saving renovation market lies in the exploration of the implementation mechanism of multi-subject and multi-objective integrated optimization.The multi-agent and multi-objective integrated optimization system framework is a powerful tool to guide the scientific decision-making of the market core structural entities in the future market practice. This paper analyzes the practical dilemma of energy-saving renovation of theexisting residential buildings in China, summarizes the practical experience of multi-subject and multi-objective integrated optimization of energy-saving renovation of the existing residential buildings in foreign countries, and puts forward beneficial practical enlightenment on the basis of comparison at home and abroad;The design principles of the target integrated optimization system have established a multi-subject and multi-objective integrated optimization system framework for the energy-saving renovation of the existing residential buildings, from six aspects: government guidance, trust consensus, value co-creation, risk sharing, revenue sharing, and social responsibility sharing. This paper proposes a multi-subject and multi-objective integrated practice strategy, in order to promote the efficient and orderly development of China's existing residential building energy-saving renovation market. 展开更多
关键词 the existing residential buildings energy-saving renovation win-win cooperation multi-objective integration hierarchical optimization
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Energy-Saving Distributed Flexible Job Shop Scheduling Optimization with Dual Resource Constraints Based on Integrated Q-Learning Multi-Objective Grey Wolf Optimizer
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作者 Hongliang Zhang Yi Chen +1 位作者 Yuteng Zhang Gongjie Xu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第8期1459-1483,共25页
The distributed flexible job shop scheduling problem(DFJSP)has attracted great attention with the growth of the global manufacturing industry.General DFJSP research only considers machine constraints and ignores worke... The distributed flexible job shop scheduling problem(DFJSP)has attracted great attention with the growth of the global manufacturing industry.General DFJSP research only considers machine constraints and ignores worker constraints.As one critical factor of production,effective utilization of worker resources can increase productivity.Meanwhile,energy consumption is a growing concern due to the increasingly serious environmental issues.Therefore,the distributed flexible job shop scheduling problem with dual resource constraints(DFJSP-DRC)for minimizing makespan and total energy consumption is studied in this paper.To solve the problem,we present a multi-objective mathematical model for DFJSP-DRC and propose a Q-learning-based multi-objective grey wolf optimizer(Q-MOGWO).In Q-MOGWO,high-quality initial solutions are generated by a hybrid initialization strategy,and an improved active decoding strategy is designed to obtain the scheduling schemes.To further enhance the local search capability and expand the solution space,two wolf predation strategies and three critical factory neighborhood structures based on Q-learning are proposed.These strategies and structures enable Q-MOGWO to explore the solution space more efficiently and thus find better Pareto solutions.The effectiveness of Q-MOGWO in addressing DFJSP-DRC is verified through comparison with four algorithms using 45 instances.The results reveal that Q-MOGWO outperforms comparison algorithms in terms of solution quality. 展开更多
关键词 Distributed flexible job shop scheduling problem dual resource constraints energy-saving scheduling multi-objective grey wolf optimizer Q-LEARNING
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Controllable thermal rectification design for buildings based on phase change composites
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作者 Hengbin Ding Xiaoshi Li +2 位作者 Tianhang Li Xiaoyong Zhao He Tian 《Journal of Semiconductors》 EI CAS CSCD 2024年第2期40-45,共6页
Phase-change material(PCM)is widely used in thermal management due to their unique thermal behavior.However,related research in thermal rectifier is mainly focused on exploring the principles at the fundamental device... Phase-change material(PCM)is widely used in thermal management due to their unique thermal behavior.However,related research in thermal rectifier is mainly focused on exploring the principles at the fundamental device level,which results in a gap to real applications.Here,we propose a controllable thermal rectification design towards building applications through the direct adhesion of composite thermal rectification material(TRM)based on PCM and reduced graphene oxide(rGO)aerogel to ordinary concrete walls(CWs).The design is evaluated in detail by combining experiments and finite element analysis.It is found that,TRM can regulate the temperature difference on both sides of the TRM/CWs system by thermal rectification.The difference in two directions reaches to 13.8 K at the heat flow of 80 W/m^(2).In addition,the larger the change of thermal conductivity before and after phase change of TRM is,the more effective it is for regulating temperature difference in two directions.The stated technology has a wide range of applications for the thermal energy control in buildings with specific temperature requirements. 展开更多
关键词 phase change composites controllable thermal rectification building applications
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A Stroke-Limitation AMD Control System with Variable Gain and Limited Area for High-Rise Buildings
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作者 Zuo-Hua Li Qing-Gui Wu +1 位作者 Jun Teng Chao-Jun Chen 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第1期865-884,共20页
Collisions between a moving mass and an anti-collision device increase structural responses and threaten structural safety.An active mass damper(AMD)with stroke limitations is often used to avoid collisions.However,a ... Collisions between a moving mass and an anti-collision device increase structural responses and threaten structural safety.An active mass damper(AMD)with stroke limitations is often used to avoid collisions.However,a strokelimited AMD control system with a fixed limited area shortens the available AMD stroke and leads to significant control power.To solve this problem,the design approach with variable gain and limited area(VGLA)is proposed in this study.First,the boundary of variable-limited areas is calculated based on the real-time status of the moving mass.The variable gain(VG)expression at the variable limited area is deduced by considering the saturation of AMD stroke.Then,numerical simulations of a stroke-limited AMD control system with VGLA are conducted on a high-rise building structure.These numerical simulations show that the proposed approach has superior strokelimitation performance compared with a stroke-limited AMD control system with a fixed limited area.Finally,the proposed approach is validated through experiments on a four-story steel frame. 展开更多
关键词 High-rise buildings active control stroke limitations variable gain variable limited area
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A novel control strategy for reproducing the floor motions of high-rise buildings by earthquake-simulating shake tables
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作者 Yuteng Cao Zhe Qu Xiaodong Ji 《Earthquake Research Advances》 CSCD 2024年第1期67-75,共9页
To enable the experimental assessment of the seismic performance of full-scale nonstructural elements with multiple engineering parameters(EDPs),a three-layer testbed named Nonstructural Element Simulator on Shake Tab... To enable the experimental assessment of the seismic performance of full-scale nonstructural elements with multiple engineering parameters(EDPs),a three-layer testbed named Nonstructural Element Simulator on Shake Table(NEST)has been developed.The testbed consists of three consecutive floors of steel structure.The bottom two floors provide a space to accommodate a full-scale room.To fully explore the flexibility of NEST,we propose a novel control strategy to generate the required shake table input time histories for the testbed to track the target floor motions of the buildings of interest with high accuracy.The control strategy contains two parts:an inverse dynamic compensation via simulation of feedback control systems(IDCS)algorithm and an offline iteration procedure based on a refined nonlinear numerical model of the testbed.The key aspects of the control strategy were introduced in this paper.Experimental tests were conducted to simulate the seismic responses of a full-scale office room on the 21^(st)floor of a 42-story high-rise building.The test results show that the proposed control strategy can reproduce the target floor motions of the building of interest with less than 20%errors within the specified frequency range. 展开更多
关键词 Shake table test Nonstructural element High-rise building Open-loop IDCS algorithm Off-line iteration
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Low-Cost Insulation for Energy Efficient Buildings in Terai Region of Nepal
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作者 Abhishek Karn 《Journal of Civil Engineering and Architecture》 2024年第1期38-50,共13页
There is a huge amount of energy savings potential in public building sector that has yet to be realized.By prioritizing energy efficiency in its own buildings and thus promoting the development of required knowledge ... There is a huge amount of energy savings potential in public building sector that has yet to be realized.By prioritizing energy efficiency in its own buildings and thus promoting the development of required knowledge in terms of new technology and construction methods,the public sector will lead the way in efforts to increase the rate of renovations.The low-cost insulation strategies and a comparison of cost with existing insulation materials has been described in this study.We have repeatedly faced energy crises and will continue to do so in the future if appropriate action is not taken in a timely manner.Properly implementing energy-saving initiatives in for achieving thermal comfort in buildings as well as reducing the energy costs would undoubtedly inspire the residential sector,resulting in significant reductions in energy usage.Simulations were carried out to study insulation layers on various building components like exterior walls,floor and roofs,generating different scenarios for a building as a base model,which were then compared and analysed to verify the literature used to develop the cases.The proposed recommendations,which have been validated,are certain to increase building energy efficiency,achieve thermal comfort in low cost than what is currently being used. 展开更多
关键词 buildings ENERGY energy efficient thermal comfort
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The Effect of Core Eccentricity on the Structural Behavior of Concrete Tall Buildings
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作者 Tarek Anwar Taha Awida 《Journal of Civil Engineering and Architecture》 2024年第3期112-117,共6页
The main purpose of this paper is to investigate the effect of core eccentricity on the structural behavior of concrete tall buildings.Concrete buildings of 55 floors with plan dimensions 48.0×48.0 m2 were invest... The main purpose of this paper is to investigate the effect of core eccentricity on the structural behavior of concrete tall buildings.Concrete buildings of 55 floors with plan dimensions 48.0×48.0 m2 were investigated.Three cases of main core locations are studied:centric(A),eccentric by one sixth(B)and one third(C)of building width.The three-dimensional finite element method has been used in conducting structural analysis through ETABS software.Gravity and lateral(wind and seismic)loadings are applied to all building cases.It has been concluded that the core location is the prime parameter governing the structural behavior of tall buildings.Although the first two cases(A,B)have acceptable and similar structural behaviors conforming to code limits,in the third case(C),the building behavior came beyond code limits.The author introduced remedial action by adding two secondary cores in the opposite direction of the main core(C-R)to restore the building behavior to the code limits.The results of this action were satisfactory. 展开更多
关键词 Concrete tall buildings core eccentricity structural behavior GRAVITY WIND seismic loadings
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Post-war Sustainability-Driven School Buildings: A Review of the Literature
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作者 Asayehgn Desta 《Management Studies》 2024年第1期58-65,共8页
The Safe Schools Declaration of 2015 is an inter-governmental political agreement signed by several countries designed to protect the schooling of the school-aged population during armed conflicts.Yet,in countries whe... The Safe Schools Declaration of 2015 is an inter-governmental political agreement signed by several countries designed to protect the schooling of the school-aged population during armed conflicts.Yet,in countries where civil war erupted,schools were demolished.Several school-aged children were either forcibly recruited by governments or coerced by rebel groups to serve in armed fights.As a result,several children were deprived of their education and have remained suffering from deep psychological scars.The central question of the study is:What kind of sustainability-driven school buildings can be initiated in countries that are now enduring peace so that the learning environments are more comfortable and improve the well-being of the war-impacted children and school employees?After reviewing the literature,a strategic conceptual framework that incorporated the synergistic relationship between economic,social,and environmental aspects of sustainability was initiated to map out sustainable school buildings.In short,the conceptual framework proposed to construct school buildings in some of the war-affected developing countries includes assembling cost-efficiency and eco-effectiveness inputs,using renewable energy sources powered by natural sunlight,collecting rainwater in mud cisterns,reducing emissions of carbon oxides,and empowering the local community to be the main actors to design sustainable buildings during the preconstruction,construction,and post-construction stages to serve as learning spaces for the war-affected occupants and their neighborhoods. 展开更多
关键词 war-affected countries continuous cycle sustainable school buildings COST-EFFICIENCY renewable energy involvement of local community
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Research and Application of Deep Learning Technology in Prefabricated Buildings
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作者 Rong Guo 《Journal of World Architecture》 2024年第2期134-139,共6页
Prefabricated buildings have become an important development trend in the field of modern architecture because of their high efficiency and environmental friendliness. Artificial intelligence and deep learning technol... Prefabricated buildings have become an important development trend in the field of modern architecture because of their high efficiency and environmental friendliness. Artificial intelligence and deep learning technology have been increasingly applied in prefabricated buildings. Deep learning technology provides comprehensive optimization of building design, construction, quality control, and cost and schedule management through the learning and analysis of large amounts of data. This paper aims to explore the application of deep learning technology in prefabricated buildings, analyze the revolutionary changes it brings in different stages, and discuss the problems faced when implementing this technology. 展开更多
关键词 Deep learning Prefabricated building APPLICATION
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Behavior characteristics and market operation problems of existing building energy-saving renovation market
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作者 GUO Han-ding WANG Ming-yu +1 位作者 MA Xing-neng ZHANG Yin-xian 《Ecological Economy》 2023年第3期271-283,共13页
The long-term and effective implementation of the existing building energy efficiency renovation depends on the development of the existing building energy efficiency renovation market.The key to the development of th... The long-term and effective implementation of the existing building energy efficiency renovation depends on the development of the existing building energy efficiency renovation market.The key to the development of the existing building energy efficiency renovation market is the joint role of the market players.Starting with the analysis of the externalities and information asymmetry of the existing building energy efficiency renovation market,this paper analyzes the behavioral characteristics and influencing factors of the existing building energy efficiency renovation market entities(central government,local government,owners,energy conservation service enterprises,third-party evaluation institutions,and other market entities),and reveals the problems of the existing building energy efficiency renovation market,such as the absence of government,the lack of main power,and the lack of financing channels,Thus,it lays a platform foundation for the research on the behavior strategy and security system of the existing building energy-s aving renovation market. 展开更多
关键词 the existing buildings energy-saving transformation subjective behavior EXTERNALITY information asymmetry
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Research and Application of Recycled Concrete Technology in Prefabricated Buildings
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作者 Shanshan DENG Gang SHI +3 位作者 Chao SHANG Fuchuan ZHOU Masabo Gasper Masiko M.Kaziana 《Research and Application of Materials Science》 2024年第1期33-36,共4页
The utilization of waste concrete as a raw material for recycled concrete in the domain of prefabricated components is garnering greater interest.This paper delineates and examines the concept,categorization,methodolo... The utilization of waste concrete as a raw material for recycled concrete in the domain of prefabricated components is garnering greater interest.This paper delineates and examines the concept,categorization,methodologies of preparation,applicable sectors,and evaluative metrics of recycled concrete technology,highlighting its prospective benefits.Nonetheless,for the successful integration of recycled concrete technology into prefabricated component applications,it is imperative to systematically enhance its physical,mechanical,and attributes,as well as its environmental efficacy.Moreover,to foster the continued advancement of recycled concrete technology,innovative initiatives,standardization,educational programs,demonstration projects,and collaborative efforts are crucial to promote broader adoption and realize improved outcomes within the realm of prefabricated components.In conclusion,recycled concrete technology is poised to play a pivotal role in prefabricated construction,offering robust support for propelling the construction industry towards a sustainable future. 展开更多
关键词 recycled concrete prefabricated buildings Environmental performance assessment
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Weathering Characterization and Degradation Analysis of Landscape Wooden Buildings in Semi-Arid and Sandy Area
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作者 Zhefeng Li Huijuan Zhong 《Journal of Architectural Research and Development》 2024年第1期26-31,共6页
Wooden buildings play a very important role in China’s construction and landscape architecture industry.In order to explore the weathering characteristics of the surface layer of landscape wooden buildings,the main c... Wooden buildings play a very important role in China’s construction and landscape architecture industry.In order to explore the weathering characteristics of the surface layer of landscape wooden buildings,the main causes of weathering were analyzed on the basis of summarizing the common types of weathering characterization.The results showed that the weathering characterization was mainly reflected in the surface defects of wood structures,such as cracking,discoloration,peeling,wind erosion wear,and so on.The coating technology on the surface of constructions was the main artificial factor affecting the surface defects of constructions.In the case of similar surface decoration conditions,sunlight and moisture were the main natural factors affecting the weathering of wooden buildings,which will promote the process of weathering. 展开更多
关键词 Wood structure building Weathering phenomenon Landscape vision Landscape architecture
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A Review of Innovative Design Strategies for Prefabricated Green Buildings
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作者 Yajuan Liu 《Journal of World Architecture》 2024年第1期91-96,共6页
Prefabricated green buildings are becoming a trend in the construction industry of China.The prefabricated components are made using modern technologies like green materials,artificial intelligence,and low-carbon and ... Prefabricated green buildings are becoming a trend in the construction industry of China.The prefabricated components are made using modern technologies like green materials,artificial intelligence,and low-carbon and energy-saving techniques.This makes them an important aspect of the development of the construction industry in China,representing modernization and sustainable development.This article presents a study on the innovative design of prefabricated green buildings.This article serves to promote sustainable development on a macro level. 展开更多
关键词 Green prefabricated building Monolithic residence Waterproof and anti-seepage Bathroom caisson
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Optimization and implementation strategy of ESCO driving force in the development of energy-saving transformation market of existing buildings
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作者 GUO Han-ding DU Zhuang +1 位作者 LI Bai-tong ZHANG Yin-xian 《Ecological Economy》 2021年第4期301-314,共14页
The development of the existing building energy-saving transformation market is inseparable from the internal driving force of ESCO.Giving full play to the driving role of ESCO scientifically is the internal requireme... The development of the existing building energy-saving transformation market is inseparable from the internal driving force of ESCO.Giving full play to the driving role of ESCO scientifically is the internal requirement to promote the healthy and orderly operation of the existing building energy-saving transformation market.This paper summarizes the practical experience of developing ESCO driving force operation in foreign existing building energy-saving transformation market,analyzes the bottleneck of developing ESCO driving force operation in China’s existing building energy-saving transformation market,and puts forward useful practical enlightenment based on the comparison between home and abroad;According to the optimization principle of ESCO driving force operation in the development of existing building energy-saving transformation market,the optimization design framework of ESCO driving force is proposed,and the implementation strategy of ESCO driving force optimization in the development of existing building energy-saving transformation market is planned.In order to optimize and improve the effectiveness of the operation and development of the energy-saving transformation market of existing buildings with the internal driving force of ESCO. 展开更多
关键词 energy-saving transformation of existing buildings market development ESCO driving force optimization design implementation strategy
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The path and countermeasures of increasing government’s governance capacities in energy-saving renovation of existing buildings
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作者 GUO Han-ding WANG Feng-hui +1 位作者 WU Hong-min ZHANG Yin-xian 《Ecological Economy》 2021年第1期48-59,共12页
The dual functions of government participation and governance in the development of the existing building energy-saving renovation market determine the importance of the government’s scientific and effective actions.... The dual functions of government participation and governance in the development of the existing building energy-saving renovation market determine the importance of the government’s scientific and effective actions.Continuously improving the government’s role is to promote the effective operation of the existing building energy-saving renovation market.Based on the inherent requirements of improving the government governance capacity in the development of the existing building energy-saving renovation market,this paper constructs the implementation path for the development of the existing building’s energy-saving renovation market from the three dimensions of practical concept,practical process and practical methods.From the four aspects of improving the legal and regulatory system,building a market information sharing platform,establishing a sound market supervision mechanism,and consolidating and improving the market accountability system,we will structure the existing building energysaving renovation market development to improve the government’s ability to restrain and implement measures.From the four levels of improving the market incentive mechanism,optimizing the market financing environment,clarifying the position of market resource allocation,and building a social operation platform,design measures to improve government incentives in the development of the existing building energy conservation renovation market.From the shaping of governance yuan organizational roles,governance capacity and responsibilities of departments at all levels to define boundaries,to build four main interactive platform governance perspective,the main parties demand balance the interests of both the governance capacity development planning in the government market,building energy-saving market to enhance the implementation of countermeasures.In order to promote the healthy and sustainable development of the existing building energy-saving renovation market based on the enhancement of government governance capacity. 展开更多
关键词 energy-saving renovation of existing buildings market development government’s governance capacity path selection implementation countermeasures
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Energy-saving Planning and Design of Urban Residential Buildings in Hanzhong Area
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作者 LI Xueping 《Journal of Landscape Research》 2017年第2期47-48,54,共3页
Energy-saving design of residential building is an important part of energy-saving architectural design. Planning and design of residential buildings in Hanzhong area should pay more attention to the building orientat... Energy-saving design of residential building is an important part of energy-saving architectural design. Planning and design of residential buildings in Hanzhong area should pay more attention to the building orientation, sunshine, summer ventilation and wind resistance in winter and so on, so as to create favorable conditions for energy-saving design of single buildings. The geographical location, climatic characteristics, residents living habits and indoor and outdoor thermal environment situation were analyzed in this paper, and combined with the existing problems of energy conservation in the planning and layout of residential buildings in Hanzhong area. Based on the investigation, this paper drew some conclusions to provide references for the energy-saving planning and design of urban residential buildings in the local area. 展开更多
关键词 Hanzhong area TOWN Residential building energy-saving planning and design
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Research on Modem Passive Integrated Energy-saving Technology of the Residential Buildings under Green Building Background
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作者 Xiao Lai 《International Journal of Technology Management》 2017年第4期25-27,共3页
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Low-content Pt-triggered the optimized d-band center of Rh metallene for energy-saving hydrogen production coupled with hydrazine degradation 被引量:1
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作者 Qiqi Mao Wenxin Wang +6 位作者 Kai Deng Hongjie Yu Ziqiang Wang You Xu Xiaonian Li Liang Wang Hongjing Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期58-66,I0004,共10页
Utilizing the hydrazine-assisted water electrolysis for energy-efficient hydrogen production shows a promising application, which relies on the development and design of efficient bifunctional electrocatalysts. Herein... Utilizing the hydrazine-assisted water electrolysis for energy-efficient hydrogen production shows a promising application, which relies on the development and design of efficient bifunctional electrocatalysts. Herein, we reported a low-content Pt-doped Rh metallene(Pt-Rhene) for hydrazine-assisted water electrolysis towards energy-saving hydrogen(H_(2)) production, where the ultrathin metallene is constructed to provide enough favorable active sites for catalysis and improve atom utilization.Additionally, the synergistic effect between Rh and Pt can optimize the electronic structure of Rh for improving the intrinsic activity. Therefore, the required overpotential of Pt-Rhene is only 37 mV to reach a current density of-10 mA cm^(-2) in the hydrogen evolution reaction(HER), and the Pt-Rhene exhibits a required overpotential of only 11 mV to reach a current density of 10 mA cm^(-2) in the hydrazine oxidation reaction(HzOR). With the constructed HER-HzOR two-electrode system, the Pt-Rhene electrodes exhibit an extremely low voltage(0.06/0.19/0.28 V) to achieve current densities of 10/50/100 mA cm^(-2) for energy-saving H_(2) production, which greatly reduces the electrolysis energy consumption. Moreover,DFT calculations further demonstrate that the introduction of Pt modulates the electronic structure of Rh and optimizes the d-band center, thus enhancing the adsorption and desorption of reactant/intermediates in the electrocatalytic reaction. 展开更多
关键词 Pt-Rhene Synergistic effect Hydrogen evolution reaction Hydrazine oxidation reaction energy-saving H_(2)production
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