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The mechanism of hydraulic fracturing assisted oil displacement to enhance oil recovery in low and medium permeability reservoirs
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作者 LIU Yikun WANG Fengjiao +8 位作者 WANG Yumei LI Binhui ZHANG Dong YANG Guang ZHI Jiqiang SUN Shuo WANG Xu DENG Qingjun XU He 《Petroleum Exploration and Development》 CSCD 2022年第4期864-873,共10页
Aiming at the technology of hydraulic fracturing assisted oil displacement which combines hydraulic fracturing,seepage and oil displacement,an experimental system of energy storage and flowback in fracturing assisted ... Aiming at the technology of hydraulic fracturing assisted oil displacement which combines hydraulic fracturing,seepage and oil displacement,an experimental system of energy storage and flowback in fracturing assisted oil displacement process has been developed and used to simulate the mechanism of percolation,energy storage,oil displacement and flowback of chemical agents in the whole process.The research shows that in hydraulic fracturing assisted oil displacement,the chemical agent could be directly pushed to the deeper area of the low and medium permeability reservoirs,avoiding the viscosity loss and adhesion retention of chemical agents near the pay zone;in addition,this technology could effectively enlarge the swept volume,improve the oil displacement efficiency,replenish formation energy,gather and exploit the scattered residual oil.For the reservoir with higher permeability,this measure takes effect fast,so to lower cost,and the high pressure hydraulic fracturing assisted oil displacement could be adopted directly.For the reservoir with lower permeability which is difficult to absorb water,hydraulic fracturing assisted oil displacement with surfactant should be adopted to reduce flow resistance of the reservoir and improve the water absorption capacity and development effect of the reservoir.The degree of formation energy deficit was the main factor affecting the effective swept range of chemical agents.Moreover,the larger the formation energy deficit was,the further the seepage distance of chemical agents was,accordingly,the larger the effective swept volume was,and the greater the increase of oil recovery was.Formation energy enhancement was the most important contribution to enhanced oil recovery(EOR),which was the key to EOR by the technology of hydraulic fracturing assisted oil displacement. 展开更多
关键词 hydraulic fracturing chemical flooding formation energy enhancement remaining oil distribution oil displacement mechanism enhancing oil recovery
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Using cyclic alternating water injection to enhance oil recovery for carbonate reservoirs developed by linear horizontal well pattern
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作者 LI Yong ZHAO Limin +5 位作者 WANG Shu SUN Liang ZHANG Wenqi YANG Yang HU Dandan CHEN Yihang 《Petroleum Exploration and Development》 CSCD 2021年第5期1139-1151,共13页
In view of high water cut and low oil recovery caused by the unidirectional flow in linear pattern of horizontal wells for the carbonate reservoirs in the Middle East,this paper provides a novel approach to improve oi... In view of high water cut and low oil recovery caused by the unidirectional flow in linear pattern of horizontal wells for the carbonate reservoirs in the Middle East,this paper provides a novel approach to improve oil recovery by converting linear water injection to cyclic alternating water injection patterns including cyclic alternating water injection with apparent inverted seven-spot pattern or apparent five-spot pattern and cyclic differential alternating water injection.The main advantage of using this strategy is that the swept efficiency is improved by changing injection-production streamlines and displacement directions,which means displacement from two different direction for the same region during a complete cycle.This technology is effective in increasing the swept efficiency and tapping the remaining oil,thus resulting in higher oil recovery.Field application with three new patterns in a carbonate reservoir in the Middle East is successful.By optimizing injection and production parameters based on the cyclic alternating well pattern,the test well group had a maximum increase of daily oil production per well of 23.84 m^(3) and maximum water cut drop of 18%.By further optimizing the distance(keep a long distance)between the heels of injection and production wells,the waterflooding performance could be better with water cut decreasing and oil production increasing. 展开更多
关键词 carbonate reservoirs horizontal well pattern cyclic alternating water injection displacement direction enhanced oil recovery Middle East
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Synergistic anionic/zwitterionic mixed surfactant system with high emulsification efficiency for enhanced oil recovery in low permeability reservoirs 被引量:1
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作者 Hai-Rong Wu Rong Tan +6 位作者 Shi-Ping Hong Qiong Zhou Bang-Yu Liu Jia-Wei Chang Tian-Fang Luan Ning Kang Ji-Rui Hou 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期936-950,共15页
Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant... Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs. 展开更多
关键词 Anionic/zwitterionic mixed surfactant system EMULSIFICATION Synergistic effect Low permeability reservoir enhanced oil recovery
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CO_(2)flooding in shale oil reservoir with radial borehole fracturing for CO_(2)storage and enhanced oil recovery
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作者 Jia-Cheng Dai Tian-Yu Wang +3 位作者 Jin-Tao Weng Kang-Jian Tian Li-Ying Zhu Gen-Sheng Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期519-534,共16页
This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume i... This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is conducted.The CO_(2)flooding process is divided into four stages.Reductions in layer spacing will significantly improve oil production rate and gas storage capacity.However,serious gas channeling can occur when the spacing is lower than 20 m.Increasing the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage rate.Sensitivity analysis shows that layer spacing and fracture height greatly influence gas storage and oil production.Research outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction. 展开更多
关键词 Shale oil Radial borehole fracturing Embedded discrete fracture model enhanced oil recovery Carbon storage
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Experimental investigation on using CO_(2)/H_(2)O emulsion with high water cut in enhanced oil recovery
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作者 Xi-Dao Wu Peng Xiao +2 位作者 Bei Liu Guang-Jin Chen Jian-Hua Pang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期974-986,共13页
CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fractio... CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut. 展开更多
关键词 CO_(2)/H_(2)O emulsion High water cut CO_(2) mobility control enhanced oil recovery
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Molecular design and applications of a nanostructure green Tripodal surface active ionic liquid in enhanced oil recovery: Interfacial tension reduction, wettability alteration, and emulsification 被引量:1
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作者 Mona Kharazi Javad Saien +1 位作者 Morteza Torabi Mohammad Ali Zolfigol 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3530-3539,共10页
Surface active ionic liquids (SAILs) are considered as prominent materials in enhanced oil recovery thanks to their high interfacial activity. This study reports the preparation and applications of a nanostructure Tri... Surface active ionic liquids (SAILs) are considered as prominent materials in enhanced oil recovery thanks to their high interfacial activity. This study reports the preparation and applications of a nanostructure Tripodal imidazolium SAIL as an environmentally-friendly substitute to the conventional surfactants. The product has a star-like molecular structure centered by a triazine spacer, namely [(C_(4)im)_(3)TA][Cl_(3)], prepared by a one-step synthesis method and characterized with FT-IR, NMR, XRD, and SEM analysis methods. The interfacial tension of the system was decreased to about 78% at critical micelle concentration of less than 0.08 mol·dm^(−3). Increasing temperature, from 298.2 to 323.2 K, improved this capability. The solid surface wettability was changed from oil-wet to water-wet and 80% and 77% stable emulsions of crude oil–aqueous solutions were created after one day and one week, respectively. Compared to the Gemini kind homologous SAILs, the superior effects of the Tripodal SAIL were revealed and attributed to the strong hydrophobic branches in the molecule. The Frumkin adsorption isotherm precisely reproduced the generated IFT data, and accordingly, the adsorption and thermodynamic parameters were determined. 展开更多
关键词 Tripodal ionic liquids Green materials enhanced oil recovery Interfacial tension WETTABILITY EMULSIFICATION
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Nanoparticle-reinforced foam system for enhanced oil recovery(EOR):Mechanistic review and perspective 被引量:1
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作者 Xue-Chen Tang Yi-Qiang Li +1 位作者 Zhe-Yu Liu Ning Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2282-2304,共23页
Boosted by economic development and rising living standards,the world's carbon dioxide emissions remain high.Maintaining temperature rises below 1.5℃ by the end of the century requires rapid global carbon capture... Boosted by economic development and rising living standards,the world's carbon dioxide emissions remain high.Maintaining temperature rises below 1.5℃ by the end of the century requires rapid global carbon capture and storage implementation.The successful application of carbon capture,utilization,and storage(CCUS)technology in oilfields has become the key to getting rid of this predicament.Foam flooding,as an organic combination of gas and chemical flooding,became popular in the 1950s.Notwithstanding the irreplaceable advantages,as a thermodynamically unstable system,foam's stability has long restricted its development in enhanced oil and gas recovery.With special surface/interface effects and small-size effects,nanoparticles can be used as foam stabilizers to enhance foam stability,thereby improving foam seepage and oil displacement effects in porous media.In this paper,the decay kinetics and the stabilization mechanisms of nanoparticle-reinforced foams were systematically reviewed.The effects of nanoparticle characteristics,including particle concentration,surface wettability,particle size,and type,and reservoir environment factors,including oil,temperature,pressure,and salinity on the foam stabilization ability were analyzed in detail.The seepage and flooding mechanisms of nanoparticle-reinforced foams were summarized as:improving the plugging properties of foams,enhancing the interaction between foams and crude oil,and synergistically adjusting the wettability of reservoir rocks.Finally,the challenges in the practical application of nanoparticle-reinforced foams were highlighted,and the development direction was proposed.The development of nanoparticle-reinforced foam can open the way toward adaptive and evolutive EOR technology,taking one further step towards the high-efficiency production of the petroleum industry. 展开更多
关键词 NANOPARTICLE Foam stability Porous media oil displacement mechanism enhanced oil recovery
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Gas channeling control with an in-situ smart surfactant gel during water-alternating-CO_(2) enhanced oil recovery 被引量:1
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作者 Xin-Jie Luo Bing Wei +6 位作者 Ke Gao Bo Jing Bo Huang Ping Guo Hong-Yao Yin Yu-Jun Feng Xi Zhang 《Petroleum Science》 SCIE EI CSCD 2023年第5期2835-2851,共17页
Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling... Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes. 展开更多
关键词 CO_(2)flooding enhanced oil recovery Gas channeling Water-alternating-CO_(2) Smart surfactant GEL
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An overview of chemical enhanced oil recovery and its status in India
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作者 Ganesh Kumar Pothula Rakesh Kumar Vij Achinta Bera 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2305-2323,共19页
India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required t... India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required to reduce the import of crude from the OPEC(Organization of the Petroleum Exporting Countries).This review mentions chemical EOR techniques(polymers,surfactants,alkali,nanoparticles,and combined alkali-surfactant-polymer flooding)and operations in India.Chemical EOR methods are one of the most efficient methods for oil displacement.The efficiency is enhanced by interfacial tension(IFT)reduction using surfactants and alkali,and mobility control of injected water is done by adding a polymer to increase the volumetric sweep efficiency.This paper also reviews the current trend of chemical EOR,prospects of chemical EOR in Indian oilfields,the development of chemical EOR in India with their challenges raising with economics,and screening criteria for chemical EOR implementation on the field scale.Furthermore,the review gives a brief idea about chemical EOR implementation in Indian oilfields in future prospects to increase the additional oil recovery from existing depleted fields to reduce the import of crude oil.The outcome of this review depicts all chemical EOR operations and recovery rates both at the laboratory scale and field scale around the country.The additional recovery rates are compared from various chemical EOR methods like conventional chemical flooding methods and conventional chemicals combined with nanoparticles on a laboratory scale.The development of chemical EOR in the past few decades and the EOR policy given by the government of India has been mentioned in this review.The analysis provides an idea about enhanced recovery screening and implementation of chemical EOR methods in existing fields will significantly reduce the energy crisis in India. 展开更多
关键词 Chemical enhanced oil recovery Surfactant flooding Polymer flooding Indian oilfields enhanced oil recovery challenges in India Screening criteria
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Surface-functionalized cellulose nanocrystals(CNC)and synergisms with surfactant for enhanced oil recovery in low-permeability reservoirs
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作者 Zhe Li Wan-Li Kang +6 位作者 Meng-Lan Li Hong-Bin Yang Tong-Yu Zhu Ying-Qi He Hai-Zhuang jang Bo-Bo Zhou Ji-Ting Hao 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1572-1583,共12页
Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this stu... Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this study,surface-functionalized cellulose nanocrystals(SF-CNCs)were prepared via hy-drochloric acid hydrolysis and chemical modification,with adaptable nanosize and considerable dispersion stability in low-permeability reservoirs.The SF-CNCs were structurally characterized by FT-IR,Cryo-TEM,which have a diameter of 5-10 nm and a length of 100-200 nm.The SF-CNC dispersions possessed higher stability and stronger salt-tolerance than those of corresponding CNC dispersions,due to the strong hydrophilicity of the sulfonic acid group.It was synergistically used with a non-ionic surfactant(APG1214)to formulate a combined flooding system(0.1 wt%SF-CNC+0.2 wt%APG1214).The combined flooding system exhibits strong emulsification stability,low oil-water interfacial tension of o.03 mN/m,and the ability to alter the wettability for oil-wetting rocks.Furthermore,the combined system was_able to provide an optimum EOR efficiency of 20.2%in low-permeability cores with 30.13×10^(-3)μm^(2).Notably.it can enlarge the sweep volume and increase the displacement efficiency simultaneously.Overall,the newly formulated nanocellulose/surfactant combined system exhibits a remarkable EoR performance in low-permeability reservoirs. 展开更多
关键词 Low-permeability reservoirs enhanced oil recovery Cellulose nanocrystals(CNC) SURFACTANT Dispersion stability
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A novel nanofluid of modified carbon black nanoparticles for enhanced oil recovery in low permeability reservoirs
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作者 Guang Zhao Li-Hao Liang +3 位作者 Dong-Fang Lv Wen-Juan Ji Qing You Cai-Li Dai 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1598-1607,共10页
A novel nanofluid of modified carbon black(MCB)nanoparticles was initially developed for enhanced oil recovery(EOR)in low permeability reservoirs.The MCB nanoparticles were obtained via a three-step reaction involving... A novel nanofluid of modified carbon black(MCB)nanoparticles was initially developed for enhanced oil recovery(EOR)in low permeability reservoirs.The MCB nanoparticles were obtained via a three-step reaction involving modification by oxidation,acyl chlorination,and activated grafting.MCB nano-particles were spherically dispersed,with an average size of 72.3 nm.Compared with carbon black(CB)nanoparticles,dispersed MCB nanoparticles can effectively reduce the oil-water interfacial tension(IFT)to 10^(-2)mN/m and change the surface wettability of sand particles.Based on the results of core flooding experiments,the MCB nanoparticles exhibited a better EOR capacity than surfactants and CB nano-particles,and the final oil recovery was significantly increased by 27.27%.The core scanning test showed that the MCB nanoparticles could plug high permeability channels by adsorbing onto the surfaces of sand particles and forming larger aggregates that bridge across pores or throats,resulting in a higher swept volume.The synergistic effects of improved swept volume and oil displacement efficiency were the EOR mechanisms of the MCB nanoparticles.The studies indicate that these MCB nanoparticles have excellent potential for EOR in low permeability reservoirs. 展开更多
关键词 Modified carbon black nanoparticles Interfacial tension reduction Displacement efficiency Synergistic effects enhanced oil recovery
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Temperature/salt tolerance and oil recovery of xanthan gum solution enhanced by surface-modified nanosilicas
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作者 Long Xu Xu Liu +5 位作者 Hong-Yu Ding Huan Zhang Lei Liu Jing-Hui Li Hou-Jian Gong Ming-Zhe Dong 《Petroleum Science》 SCIE EI CAS CSCD 2023年第1期577-589,共13页
Amide-and alkyl-modified nanosilicas(AANPs)were synthesized and introduced into Xanthan gum(XG)solution,aiming to improve the temperature/salt tolerance and oil recovery.The rheological behaviors of XG/AANP hybrid dis... Amide-and alkyl-modified nanosilicas(AANPs)were synthesized and introduced into Xanthan gum(XG)solution,aiming to improve the temperature/salt tolerance and oil recovery.The rheological behaviors of XG/AANP hybrid dispersions were systematically studied at different concentrations,temperatures and inorganic salts.At high temperature(75C)and high salinity(10,000 mg,L1 NaCl),AANPs increase the apparent viscosity and dynamic modulus of the XG solution,and XG/AANP hybrid dispersion exhibits elastic-dominant properties.The most effective concentrations of XG and AANP interacting with each other are 1750 mg·L^(-1) and 0.74 wt%,respectively.The temperature tolerance of XG solution is not satisfactory,and high temperature further weakens the salt tolerance of XG.However,the AANPs significantly enhance the viscoelasticity the XG solution through hydrogen bonds and hydrophobic effect.Under reservoir conditions,XG/AANP hybrid recovers approximately 18.5%more OOIP(original oil in place)than AANP and 11.3%more OOIP than XG.The enhanced oil recovery mechanism of the XG/AANP hybrid is mainly increasing the sweep coefficient,the contribution from the reduction of oil-water interfacial tension is less. 展开更多
关键词 Temperature/salt tolerance RHEOLOGY Surface-modified nanosilicas Xanthan gum enhanced oil recovery SYNERGY
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Assessment of Nanoparticle-Enriched Solvents for Oil Recovery Enhancement
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作者 Muayad M.Hasan Firas K.Al-Zuhairi +1 位作者 Anfal H.Sadeq Rana A.Azeez 《Fluid Dynamics & Materials Processing》 EI 2023年第11期2827-2835,共9页
Solvents are generally used to reduce the viscosity of heavy crude oil and ultimately enhance oil recovery.Recently,a new method has been introduced where nanoparticles(NPs)are exploited to induce enhanced oil recover... Solvents are generally used to reduce the viscosity of heavy crude oil and ultimately enhance oil recovery.Recently,a new method has been introduced where nanoparticles(NPs)are exploited to induce enhanced oil recovery owing to their ability to improve the mobility ratio,dampen the interfacial tension,and alter rock wett-ability.This study investigated the integration of nano-alumina(Al_(2)O_(3))NPs with an n-hexane solvent.In parti-cular,a Brookfield viscometer has been used to measure the crude oil viscosity and it has been found that NPs can effectively lead to a significant decrease in the overall oil viscosity(70 cp using the solvent only,45 cp when NPs are added). 展开更多
关键词 NANOTECHNOLOGY viscosity reduction organic solvents degree of viscosity reduction(DVR) enhanced oil recovery(EOR)
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Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
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作者 PARHIZGAR KERADEH Mahsa TABATABAEI-NEZHAD Seyyed Alireza 《Petroleum Exploration and Development》 SCIE 2023年第3期675-687,共13页
This study used the diethylene triamine pentaacetic acid(DTPA)-seawater(SW)system to modify the sandstone rock wettability and enhance oil recovery.The investigation involved conducting wettability measurement,Zeta po... This study used the diethylene triamine pentaacetic acid(DTPA)-seawater(SW)system to modify the sandstone rock wettability and enhance oil recovery.The investigation involved conducting wettability measurement,Zeta potential measurement,and spontaneous imbibition experiment.The introduction of 5%DTPA-sW solution resulted in a significant decrease in the rock-oil contact angle from 143°to 23,along with a reduction in the Zeta potential from-2.29 mV to-13.06 mV,thereby altering the rock surface charge and shifting its wettability from an oil-wet state to a strongly water-wet state.The presence or absence of potential determining ions(Ca^(2+),Mg^(2+),SO_(4)^(2-))in the solution did not impact the effectiveness of DTPA in changing the rock wettability.However,by tripling the concentration of these ions in the solution,the performance of 5%DTPA-SW solution in changing wettability was impaired.Additionally,spontaneous imbibition tests demonstrated that the 5%DTPA-SW solution led to an increase in oil recovery up to 39.6%.Thus,the optimum mass fraction of DTPA for changing sandstone wettability was determined to be5%. 展开更多
关键词 wettability alteration DTPA chelating agent Zeta potential spontaneous imbibition enhanced oil recovery
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Adsorption of Natural Surfactant on Sandstone in Enhanced Oil Recovery: Isotherms and Kinetics Studies
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作者 Monday Obekpa Michael 《Open Journal of Applied Sciences》 2023年第7期1119-1144,共26页
In chemical enhanced oil recovery, surfactants are injected into the reservoir with the intention to lower interfacial tension (IFT) between the water and oil phases, and thereby bring about efficient displacement of ... In chemical enhanced oil recovery, surfactants are injected into the reservoir with the intention to lower interfacial tension (IFT) between the water and oil phases, and thereby bring about efficient displacement of oil. However, the adsorption of the surfactants to reservoir rock surfaces leads to the loss and reduction in concentration of the surfactants, which in turn reduces the overall efficiency of the oil recovery process, with attendant financial losses. In this work, the adsorption of Quillaja Saponaria (QS), a novel, natural, non-ionic surfactant, on crushed sandstone reservoir rock is investigated. X-ray diffraction (XRD) study of clean sandstone particles has been undertaken to determine the main components present in the sand particles. The conductivity method was used to measure CMC and the surfactant concentrations in aqueous solutions. Batch adsorption experiments were used to determine the amount of QS adsorbed on rock surface. Equilibrium conditions were reached after almost 5 days. From the results of the study, the Langmuir isotherm model is more suited for predicting the adsorption behaviour of QS on sandstone. The kinetic adsorption of QS obeys the pseudo-second order model. This study is particularly relevant in surfactant selection for chemical EOR processes. 展开更多
关键词 enhanced oil recovery Critical Micelle Concentration Interfacial Tension Adsorption Kinetics SURFACTANT SAPONIN
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2D Janus polymer nanosheets for enhancing oil recovery:From material ppreparation to property evaluation
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作者 Hao Shen Zi-Hao Yang +6 位作者 Guan-Zhong Wang Yi-Lin Xiong Qi-Chao Lv Qi Cao Qi-Qi Niu Yi-Bo Wang Zhao-xia Dong 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1584-1597,共14页
Janus amphiphilic polymer nanosheets(JAPNs)with anisotropic morphology and distinctive perfor-mance have aroused widespread interest.However,due to the difficulty in synthesis and poor dispersion stability,JAPNs have ... Janus amphiphilic polymer nanosheets(JAPNs)with anisotropic morphology and distinctive perfor-mance have aroused widespread interest.However,due to the difficulty in synthesis and poor dispersion stability,JAPNs have been scarcely reported in the field of enhancing oil recovery(EOR).Herein,a kind of organic-based flexible JAPNs was prepared by paraffin emulsion methods.The lateral sizes of JAPNs were ranging from hundreds of nanometers to several micrometers and the thickness was about 3 nm.The organic-based nanosheets were equipped with remarkably flexible structures,which could improve their injection performance.The dispersion and interfacial properties of JAPNs were studied systematically.By modification of crosslinking agent containing multiple amino groups,the JAPNs had excellent hydro-philicity and salt resistance compared with conventional inorganic or composite nanosheets.The settling time of nanosuspension with NaCl and CaCl_(2) at a low salinity of 1000 mg/L was over 240 h.The value could also remain 124 h under the salinity of 10,000 mg/L NaCl.With the dual functionalities of Janus amphiphilic nature and nanoparticles'Pickering effect,JAPNs could change rock wettability and form emulsions as"colloidal surfactants",In particular,a new technology called optical microrheology was pioneered to explore the destabilization state of nanosuspensions for the first time.Since precipitation lagged behind aggregation,especially for stable suspension systems,the onset of the unstable behavior was difficult to be detected by conventional methods,which should be the indicator of reduced effec-tiveness for nanofluid products.In addition,the oil displacement experiments demonstrated that the JAPNs could enhance oil recovery by 17.14%under an ultra-low concentration of 0.005%and were more suitable for low permeability cores.The findings can help for a better understanding of the material preparation of polymer nanosheets.We also hope that this study could shed more light on the nano-flooding technology for EOR. 展开更多
关键词 2D materials Polymer nanosheets enhance oil recovery Janus nature Amphiphilic property
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Study of steam heat transfer enhanced by CO_(2) and chemical agents: In heavy oil production 被引量:1
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作者 Ya-Li Liu Chao Zhang +1 位作者 Song-Yan Li Zhao-Min Li 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1030-1043,共14页
Steam flooding with the assistance of carbon dioxide (CO_(2)) and chemicals is an effective approach for enhancing super heavy oil recovery. However, the promotion and application of CO_(2) and chemical agent-assisted... Steam flooding with the assistance of carbon dioxide (CO_(2)) and chemicals is an effective approach for enhancing super heavy oil recovery. However, the promotion and application of CO_(2) and chemical agent-assisted steam flooding technology have been restricted by the current lack of research on the synergistic effect of CO_(2) and chemical agents on enhanced steam flooding heat transfer. The novel experiments on CO_(2)–chemicals cooperate affected steam condensation and seepage were conducted by adding CO_(2) and two chemicals (sodium dodecyl sulfate (SDS) and the betaine temperature-salt resistant foaming agent ZK-05200).According to the experimental findings, a “film” formed on the heat-transfer medium surface following the co-injection of CO_(2) and the chemical to impede the steam heat transfer, reducing the heat transfer efficiency of steam, heat flux and condensation heat transfer coefficient. The steam seepage experiment revealed that the temperature at the back end of the sandpack model was dramatically raised by 3.5–12.8 °C by adding CO_(2) and chemical agents, achieving the goal of driving deep-formation heavy oil. The combined effect of CO_(2) and SDS was the most effective for improving steam heat transfer, the steam heat loss was reduced by 6.2%, the steam condensation cycle was prolonged by 1.3 times, the condensation heat transfer coefficient was decreased by 15.5%, and the heavy oil recovery was enhanced by 9.82%. Theoretical recommendations are offered in this study for improving the CO_(2)–chemical-assisted steam flooding technique. 展开更多
关键词 Steam flooding Heavy oil Carbon dioxide Chemical agent enhanced oil recovery(EOR) Heat transfer
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Review of surfactant-assisted chemical enhanced oil recovery for carbonate reservoirs: challenges and future perspectives 被引量:18
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作者 Sreela Pal M.Mushtaq +1 位作者 Fawzi Banat Ali M.Al Sumaiti 《Petroleum Science》 SCIE CAS CSCD 2018年第1期77-102,共26页
A significant fraction of the conventional oil reserves globally is in carbonate formations which contain a substantial amount of residual oil. Since primary and secondary recovery methods fail to yield above 20%-40%o... A significant fraction of the conventional oil reserves globally is in carbonate formations which contain a substantial amount of residual oil. Since primary and secondary recovery methods fail to yield above 20%-40%of original oil in place from these reserves, the need for enhanced oil recovery(EOR) techniques for incremental oil recovery has become imperative. With the challenges presented by the highly heterogeneous carbonate rocks,evaluation of tertiary-stage recovery techniques including chemical EOR(c EOR) has been a high priority for researchers and oil producers. In this review, the latest developments in the surfactant-based c EOR techniques applied in carbonate formations are discussed, contemplating the future direction of existing methodologies. In connection with this, the characteristics of heterogeneous carbonate reservoirs are outlined. Detailed discussion on surfactant-led oil recovery mechanisms and related processes, such as wettability alteration, interfacial tension reduction, microemulsion phase behavior, surfactant adsorption and mitigation, and foams and their applications is presented. Laboratory experiments, as well as field study data obtained using several surfactants, are also included.This extensive discussion on the subject aims to help researchers and professionals in the field to understand the current situation and plan future enterprises accordingly. 展开更多
关键词 oil reserves Original oil in place Carbonateformations SURFACTANTS Chemical enhanced oil recovery
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Surfactant induced reservoir wettability alteration:Recent theoretical and experimental advances in enhanced oil recovery 被引量:14
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作者 Wang Yefei XU Huaimin +3 位作者 Yu Weizhao Bai Baojun Song Xinwang Zhang Jichao 《Petroleum Science》 SCIE CAS CSCD 2011年第4期463-476,共14页
Reservoir wettability plays an important role in various oil recovery processes.The origin and evolution of reservoir wettability were critically reviewed to better understand the complexity of wettability due to inte... Reservoir wettability plays an important role in various oil recovery processes.The origin and evolution of reservoir wettability were critically reviewed to better understand the complexity of wettability due to interactions in crude oil-brine-rock system,with introduction of different wetting states and their influence on fluid distribution in pore spaces.The effect of wettability on oil recovery of waterflooding was then summarized from past and recent research to emphasize the importance of wettability in oil displacement by brine.The mechanism of wettability alteration by different surfactants in both carbonate and sandstone reservoirs was analyzed,concerning their distinct surface chemistry,and different interaction patterns of surfactants with components on rock surface.Other concerns such as the combined effect of wettability alteration and interfacial tension (IFT) reduction on the imbibition process was also taken into account.Generally,surfactant induced wettability alteration for enhanced oil recovery is still in the stage of laboratory investigation.The successful application of this technique relies on a comprehensive survey of target reservoir conditions,and could be expected especially in low permeability fractured reservoirs and forced imbibition process. 展开更多
关键词 Wettability alteration RESERVOIR enhanced oil recovery (EOR) SURFACTANT
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Advances in enhanced oil recovery technologies for low permeability reservoirs 被引量:8
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作者 Wan-Li Kang Bo-Bo Zhou +1 位作者 Miras Issakhov Marabek Gabdullin 《Petroleum Science》 SCIE CAS CSCD 2022年第4期1622-1640,共19页
Low permeability oil and gas resources are rich and have great potential all over the world, which has gradually become the main goal of oil and gas development. However, after traditional primary and secondary exploi... Low permeability oil and gas resources are rich and have great potential all over the world, which has gradually become the main goal of oil and gas development. However, after traditional primary and secondary exploitation, there is still a large amount of remaining oil that has not been recovered.Therefore, in recent years, enhanced oil recovery(EOR) technologies for low permeability reservoirs have been greatly developed to further improve crude oil production. This study presents a comprehensive review of EOR technologies in low permeability reservoirs with an emphasis on gas flooding, surfactant flooding, nanofluid flooding and imbibition EOR technologies. In addition, two kinds of gel systems are introduced for conformance control in low permeability reservoirs with channeling problems. Finally,the technical challenges, directions and outlooks of EOR in low permeability reservoirs are addressed. 展开更多
关键词 enhanced oil recovery Low permeability reservoir Gas flooding Surfactant flooding Nanofluid flooding IMBIBITION Conformance control
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