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CO_(2)flooding in shale oil reservoir with radial borehole fracturing for CO_(2)storage and enhanced oil recovery
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作者 Jia-Cheng Dai Tian-Yu Wang +3 位作者 Jin-Tao Weng Kang-Jian Tian Li-Ying Zhu Gen-Sheng Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期519-534,共16页
This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume i... This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is conducted.The CO_(2)flooding process is divided into four stages.Reductions in layer spacing will significantly improve oil production rate and gas storage capacity.However,serious gas channeling can occur when the spacing is lower than 20 m.Increasing the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage rate.Sensitivity analysis shows that layer spacing and fracture height greatly influence gas storage and oil production.Research outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction. 展开更多
关键词 Shale oil Radial borehole fracturing Embedded discrete fracture model enhanced oil recovery Carbon storage
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Synergistic anionic/zwitterionic mixed surfactant system with high emulsification efficiency for enhanced oil recovery in low permeability reservoirs
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作者 Hai-Rong Wu Rong Tan +6 位作者 Shi-Ping Hong Qiong Zhou Bang-Yu Liu Jia-Wei Chang Tian-Fang Luan Ning Kang Ji-Rui Hou 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期936-950,共15页
Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant... Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs. 展开更多
关键词 Anionic/zwitterionic mixed surfactant system EMULSIFICATION Synergistic effect Low permeability reservoir enhanced oil recovery
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Experimental investigation on using CO_(2)/H_(2)O emulsion with high water cut in enhanced oil recovery
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作者 Xi-Dao Wu Peng Xiao +2 位作者 Bei Liu Guang-Jin Chen Jian-Hua Pang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期974-986,共13页
CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fractio... CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut. 展开更多
关键词 CO_(2)/H_(2)O emulsion High water cut CO_(2) mobility control enhanced oil recovery
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An overview of chemical enhanced oil recovery and its status in India
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作者 Ganesh Kumar Pothula Rakesh Kumar Vij Achinta Bera 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2305-2323,共19页
India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required t... India is currently producing crude oil from matured fields because of insufficient discoveries of new fields.Therefore,in order to control the energy crisis in India,enhanced oil recovery(EOR)techniques are required to reduce the import of crude from the OPEC(Organization of the Petroleum Exporting Countries).This review mentions chemical EOR techniques(polymers,surfactants,alkali,nanoparticles,and combined alkali-surfactant-polymer flooding)and operations in India.Chemical EOR methods are one of the most efficient methods for oil displacement.The efficiency is enhanced by interfacial tension(IFT)reduction using surfactants and alkali,and mobility control of injected water is done by adding a polymer to increase the volumetric sweep efficiency.This paper also reviews the current trend of chemical EOR,prospects of chemical EOR in Indian oilfields,the development of chemical EOR in India with their challenges raising with economics,and screening criteria for chemical EOR implementation on the field scale.Furthermore,the review gives a brief idea about chemical EOR implementation in Indian oilfields in future prospects to increase the additional oil recovery from existing depleted fields to reduce the import of crude oil.The outcome of this review depicts all chemical EOR operations and recovery rates both at the laboratory scale and field scale around the country.The additional recovery rates are compared from various chemical EOR methods like conventional chemical flooding methods and conventional chemicals combined with nanoparticles on a laboratory scale.The development of chemical EOR in the past few decades and the EOR policy given by the government of India has been mentioned in this review.The analysis provides an idea about enhanced recovery screening and implementation of chemical EOR methods in existing fields will significantly reduce the energy crisis in India. 展开更多
关键词 Chemical enhanced oil recovery Surfactant flooding Polymer flooding Indian oilfields enhanced oil recovery challenges in India Screening criteria
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Molecular design and applications of a nanostructure green Tripodal surface active ionic liquid in enhanced oil recovery: Interfacial tension reduction, wettability alteration, and emulsification
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作者 Mona Kharazi Javad Saien +1 位作者 Morteza Torabi Mohammad Ali Zolfigol 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3530-3539,共10页
Surface active ionic liquids (SAILs) are considered as prominent materials in enhanced oil recovery thanks to their high interfacial activity. This study reports the preparation and applications of a nanostructure Tri... Surface active ionic liquids (SAILs) are considered as prominent materials in enhanced oil recovery thanks to their high interfacial activity. This study reports the preparation and applications of a nanostructure Tripodal imidazolium SAIL as an environmentally-friendly substitute to the conventional surfactants. The product has a star-like molecular structure centered by a triazine spacer, namely [(C_(4)im)_(3)TA][Cl_(3)], prepared by a one-step synthesis method and characterized with FT-IR, NMR, XRD, and SEM analysis methods. The interfacial tension of the system was decreased to about 78% at critical micelle concentration of less than 0.08 mol·dm^(−3). Increasing temperature, from 298.2 to 323.2 K, improved this capability. The solid surface wettability was changed from oil-wet to water-wet and 80% and 77% stable emulsions of crude oil–aqueous solutions were created after one day and one week, respectively. Compared to the Gemini kind homologous SAILs, the superior effects of the Tripodal SAIL were revealed and attributed to the strong hydrophobic branches in the molecule. The Frumkin adsorption isotherm precisely reproduced the generated IFT data, and accordingly, the adsorption and thermodynamic parameters were determined. 展开更多
关键词 Tripodal ionic liquids Green materials enhanced oil recovery Interfacial tension WETTABILITY EMULSIFICATION
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Nanoparticle-reinforced foam system for enhanced oil recovery(EOR):Mechanistic review and perspective
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作者 Xue-Chen Tang Yi-Qiang Li +1 位作者 Zhe-Yu Liu Ning Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2023年第4期2282-2304,共23页
Boosted by economic development and rising living standards,the world's carbon dioxide emissions remain high.Maintaining temperature rises below 1.5℃ by the end of the century requires rapid global carbon capture... Boosted by economic development and rising living standards,the world's carbon dioxide emissions remain high.Maintaining temperature rises below 1.5℃ by the end of the century requires rapid global carbon capture and storage implementation.The successful application of carbon capture,utilization,and storage(CCUS)technology in oilfields has become the key to getting rid of this predicament.Foam flooding,as an organic combination of gas and chemical flooding,became popular in the 1950s.Notwithstanding the irreplaceable advantages,as a thermodynamically unstable system,foam's stability has long restricted its development in enhanced oil and gas recovery.With special surface/interface effects and small-size effects,nanoparticles can be used as foam stabilizers to enhance foam stability,thereby improving foam seepage and oil displacement effects in porous media.In this paper,the decay kinetics and the stabilization mechanisms of nanoparticle-reinforced foams were systematically reviewed.The effects of nanoparticle characteristics,including particle concentration,surface wettability,particle size,and type,and reservoir environment factors,including oil,temperature,pressure,and salinity on the foam stabilization ability were analyzed in detail.The seepage and flooding mechanisms of nanoparticle-reinforced foams were summarized as:improving the plugging properties of foams,enhancing the interaction between foams and crude oil,and synergistically adjusting the wettability of reservoir rocks.Finally,the challenges in the practical application of nanoparticle-reinforced foams were highlighted,and the development direction was proposed.The development of nanoparticle-reinforced foam can open the way toward adaptive and evolutive EOR technology,taking one further step towards the high-efficiency production of the petroleum industry. 展开更多
关键词 NANOPARTICLE Foam stability Porous media oil displacement mechanism enhanced oil recovery
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Gas channeling control with an in-situ smart surfactant gel during water-alternating-CO_(2) enhanced oil recovery
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作者 Xin-Jie Luo Bing Wei +6 位作者 Ke Gao Bo Jing Bo Huang Ping Guo Hong-Yao Yin Yu-Jun Feng Xi Zhang 《Petroleum Science》 SCIE EI CSCD 2023年第5期2835-2851,共17页
Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling... Undesirable gas channeling always occurs along the high-permeability layers in heterogeneous oil reservoirs during water-alternating-CO_(2)(WAG)flooding,and conventional polymer gels used for blocking the“channeling”paths usually suffer from either low injectivity or poor gelation control.Herein,we for the first time developed an in-situ high-pressure CO_(2)-triggered gel system based on a smart surfactant,N-erucamidopropyl-N,N-dimethylamine(UC22AMPM),which was introduced into the aqueous slugs to control gas channeling inWAG processes.The water-like,low-viscosity UC22AMPM brine solution can be thickened by high-pressure CO_(2) owing to the formation of wormlike micelles(WLMs),as well as their growth and shear-induced structure buildup under shear flow.The thickening power can be further potentiated by the generation of denser WLMs resulting from either surfactant concentration augmentation or a certain range of heating,and can be impaired via pressurization above the critical pressure of CO_(2) because of its soaring solvent power.Core flooding tests using heterogeneous cores demonstrated that gas channeling was alleviated by plugging of high-capacity channels due to the in-situ gelation of UC22AMPM slugs upon their reaction with the pre-or post-injected CO_(2) slugs under shear flow,thereupon driving chase fluids into unrecovered low-permeability areas and producing an 8.0% higher oil recovery factor than the conventional WAG mode.This smart surfactant enabled high injectivity and satisfactory gelation control,attributable to low initial viscosity and the combined properties of one component and CO_(2)-triggered gelation,respectively.This work could provide a guide towards designing gels for reducing CO_(2) spillover and reinforcing the CO_(2) sequestration effect during CO_(2) enhanced oil recovery processes. 展开更多
关键词 CO_(2)flooding enhanced oil recovery Gas channeling Water-alternating-CO_(2) Smart surfactant GEL
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Surface-functionalized cellulose nanocrystals(CNC)and synergisms with surfactant for enhanced oil recovery in low-permeability reservoirs
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作者 Zhe Li Wan-Li Kang +6 位作者 Meng-Lan Li Hong-Bin Yang Tong-Yu Zhu Ying-Qi He Hai-Zhuang jang Bo-Bo Zhou Ji-Ting Hao 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1572-1583,共12页
Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this stu... Nanocellulose,a natural polymeric nanomaterial,has attracted significant attention in enhanced oil recovery(EOR)applications due to its abundance,nanoscale,high oil-water interfacial adsorption ef-ficiency.In this study,surface-functionalized cellulose nanocrystals(SF-CNCs)were prepared via hy-drochloric acid hydrolysis and chemical modification,with adaptable nanosize and considerable dispersion stability in low-permeability reservoirs.The SF-CNCs were structurally characterized by FT-IR,Cryo-TEM,which have a diameter of 5-10 nm and a length of 100-200 nm.The SF-CNC dispersions possessed higher stability and stronger salt-tolerance than those of corresponding CNC dispersions,due to the strong hydrophilicity of the sulfonic acid group.It was synergistically used with a non-ionic surfactant(APG1214)to formulate a combined flooding system(0.1 wt%SF-CNC+0.2 wt%APG1214).The combined flooding system exhibits strong emulsification stability,low oil-water interfacial tension of o.03 mN/m,and the ability to alter the wettability for oil-wetting rocks.Furthermore,the combined system was_able to provide an optimum EOR efficiency of 20.2%in low-permeability cores with 30.13×10^(-3)μm^(2).Notably.it can enlarge the sweep volume and increase the displacement efficiency simultaneously.Overall,the newly formulated nanocellulose/surfactant combined system exhibits a remarkable EoR performance in low-permeability reservoirs. 展开更多
关键词 Low-permeability reservoirs enhanced oil recovery Cellulose nanocrystals(CNC) SURFACTANT Dispersion stability
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A novel nanofluid of modified carbon black nanoparticles for enhanced oil recovery in low permeability reservoirs
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作者 Guang Zhao Li-Hao Liang +3 位作者 Dong-Fang Lv Wen-Juan Ji Qing You Cai-Li Dai 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1598-1607,共10页
A novel nanofluid of modified carbon black(MCB)nanoparticles was initially developed for enhanced oil recovery(EOR)in low permeability reservoirs.The MCB nanoparticles were obtained via a three-step reaction involving... A novel nanofluid of modified carbon black(MCB)nanoparticles was initially developed for enhanced oil recovery(EOR)in low permeability reservoirs.The MCB nanoparticles were obtained via a three-step reaction involving modification by oxidation,acyl chlorination,and activated grafting.MCB nano-particles were spherically dispersed,with an average size of 72.3 nm.Compared with carbon black(CB)nanoparticles,dispersed MCB nanoparticles can effectively reduce the oil-water interfacial tension(IFT)to 10^(-2)mN/m and change the surface wettability of sand particles.Based on the results of core flooding experiments,the MCB nanoparticles exhibited a better EOR capacity than surfactants and CB nano-particles,and the final oil recovery was significantly increased by 27.27%.The core scanning test showed that the MCB nanoparticles could plug high permeability channels by adsorbing onto the surfaces of sand particles and forming larger aggregates that bridge across pores or throats,resulting in a higher swept volume.The synergistic effects of improved swept volume and oil displacement efficiency were the EOR mechanisms of the MCB nanoparticles.The studies indicate that these MCB nanoparticles have excellent potential for EOR in low permeability reservoirs. 展开更多
关键词 Modified carbon black nanoparticles Interfacial tension reduction Displacement efficiency Synergistic effects enhanced oil recovery
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Investigation of the effect of diethylene triamine pentaacetic acid chelating agent as an enhanced oil recovery fluid on wettability alteration of sandstone rocks
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作者 PARHIZGAR KERADEH Mahsa TABATABAEI-NEZHAD Seyyed Alireza 《Petroleum Exploration and Development》 SCIE 2023年第3期675-687,共13页
This study used the diethylene triamine pentaacetic acid(DTPA)-seawater(SW)system to modify the sandstone rock wettability and enhance oil recovery.The investigation involved conducting wettability measurement,Zeta po... This study used the diethylene triamine pentaacetic acid(DTPA)-seawater(SW)system to modify the sandstone rock wettability and enhance oil recovery.The investigation involved conducting wettability measurement,Zeta potential measurement,and spontaneous imbibition experiment.The introduction of 5%DTPA-sW solution resulted in a significant decrease in the rock-oil contact angle from 143°to 23,along with a reduction in the Zeta potential from-2.29 mV to-13.06 mV,thereby altering the rock surface charge and shifting its wettability from an oil-wet state to a strongly water-wet state.The presence or absence of potential determining ions(Ca^(2+),Mg^(2+),SO_(4)^(2-))in the solution did not impact the effectiveness of DTPA in changing the rock wettability.However,by tripling the concentration of these ions in the solution,the performance of 5%DTPA-SW solution in changing wettability was impaired.Additionally,spontaneous imbibition tests demonstrated that the 5%DTPA-SW solution led to an increase in oil recovery up to 39.6%.Thus,the optimum mass fraction of DTPA for changing sandstone wettability was determined to be5%. 展开更多
关键词 wettability alteration DTPA chelating agent Zeta potential spontaneous imbibition enhanced oil recovery
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Adsorption of Natural Surfactant on Sandstone in Enhanced Oil Recovery: Isotherms and Kinetics Studies
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作者 Monday Obekpa Michael 《Open Journal of Applied Sciences》 2023年第7期1119-1144,共26页
In chemical enhanced oil recovery, surfactants are injected into the reservoir with the intention to lower interfacial tension (IFT) between the water and oil phases, and thereby bring about efficient displacement of ... In chemical enhanced oil recovery, surfactants are injected into the reservoir with the intention to lower interfacial tension (IFT) between the water and oil phases, and thereby bring about efficient displacement of oil. However, the adsorption of the surfactants to reservoir rock surfaces leads to the loss and reduction in concentration of the surfactants, which in turn reduces the overall efficiency of the oil recovery process, with attendant financial losses. In this work, the adsorption of Quillaja Saponaria (QS), a novel, natural, non-ionic surfactant, on crushed sandstone reservoir rock is investigated. X-ray diffraction (XRD) study of clean sandstone particles has been undertaken to determine the main components present in the sand particles. The conductivity method was used to measure CMC and the surfactant concentrations in aqueous solutions. Batch adsorption experiments were used to determine the amount of QS adsorbed on rock surface. Equilibrium conditions were reached after almost 5 days. From the results of the study, the Langmuir isotherm model is more suited for predicting the adsorption behaviour of QS on sandstone. The kinetic adsorption of QS obeys the pseudo-second order model. This study is particularly relevant in surfactant selection for chemical EOR processes. 展开更多
关键词 enhanced oil recovery Critical Micelle Concentration Interfacial Tension Adsorption Kinetics SURFACTANT SAPONIN
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Review of surfactant-assisted chemical enhanced oil recovery for carbonate reservoirs: challenges and future perspectives 被引量:18
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作者 Sreela Pal M.Mushtaq +1 位作者 Fawzi Banat Ali M.Al Sumaiti 《Petroleum Science》 SCIE CAS CSCD 2018年第1期77-102,共26页
A significant fraction of the conventional oil reserves globally is in carbonate formations which contain a substantial amount of residual oil. Since primary and secondary recovery methods fail to yield above 20%-40%o... A significant fraction of the conventional oil reserves globally is in carbonate formations which contain a substantial amount of residual oil. Since primary and secondary recovery methods fail to yield above 20%-40%of original oil in place from these reserves, the need for enhanced oil recovery(EOR) techniques for incremental oil recovery has become imperative. With the challenges presented by the highly heterogeneous carbonate rocks,evaluation of tertiary-stage recovery techniques including chemical EOR(c EOR) has been a high priority for researchers and oil producers. In this review, the latest developments in the surfactant-based c EOR techniques applied in carbonate formations are discussed, contemplating the future direction of existing methodologies. In connection with this, the characteristics of heterogeneous carbonate reservoirs are outlined. Detailed discussion on surfactant-led oil recovery mechanisms and related processes, such as wettability alteration, interfacial tension reduction, microemulsion phase behavior, surfactant adsorption and mitigation, and foams and their applications is presented. Laboratory experiments, as well as field study data obtained using several surfactants, are also included.This extensive discussion on the subject aims to help researchers and professionals in the field to understand the current situation and plan future enterprises accordingly. 展开更多
关键词 oil reserves Original oil in place Carbonateformations SURFACTANTS Chemical enhanced oil recovery
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Surfactant induced reservoir wettability alteration:Recent theoretical and experimental advances in enhanced oil recovery 被引量:14
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作者 Wang Yefei XU Huaimin +3 位作者 Yu Weizhao Bai Baojun Song Xinwang Zhang Jichao 《Petroleum Science》 SCIE CAS CSCD 2011年第4期463-476,共14页
Reservoir wettability plays an important role in various oil recovery processes.The origin and evolution of reservoir wettability were critically reviewed to better understand the complexity of wettability due to inte... Reservoir wettability plays an important role in various oil recovery processes.The origin and evolution of reservoir wettability were critically reviewed to better understand the complexity of wettability due to interactions in crude oil-brine-rock system,with introduction of different wetting states and their influence on fluid distribution in pore spaces.The effect of wettability on oil recovery of waterflooding was then summarized from past and recent research to emphasize the importance of wettability in oil displacement by brine.The mechanism of wettability alteration by different surfactants in both carbonate and sandstone reservoirs was analyzed,concerning their distinct surface chemistry,and different interaction patterns of surfactants with components on rock surface.Other concerns such as the combined effect of wettability alteration and interfacial tension (IFT) reduction on the imbibition process was also taken into account.Generally,surfactant induced wettability alteration for enhanced oil recovery is still in the stage of laboratory investigation.The successful application of this technique relies on a comprehensive survey of target reservoir conditions,and could be expected especially in low permeability fractured reservoirs and forced imbibition process. 展开更多
关键词 Wettability alteration RESERVOIR enhanced oil recovery (EOR) SURFACTANT
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Enhanced oil recovery by nonionic surfactants considering micellization, surface, and foaming properties 被引量:8
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作者 Achinta Bera Ajay Mandal +1 位作者 Hadi Belhaj Tarkeswar Kumar 《Petroleum Science》 SCIE CAS CSCD 2017年第2期362-371,共10页
Surfactants for enhanced oil recovery are important to study due to their special characteristics like foam generation,lowering interfacial tension between oleic and aqueous phases,and wettability alteration of reserv... Surfactants for enhanced oil recovery are important to study due to their special characteristics like foam generation,lowering interfacial tension between oleic and aqueous phases,and wettability alteration of reservoir rock surfaces.Foam is a good mobility control agent in enhanced oil recovery for improving the mobility ratio.In the present work,the foaming behavior of three nonionic ethoxylated surfactants,namely Tergitol 15-S-7,Tergitol 15-S-9,and Tergitol 15-S-12,was studied experimentally.Among the surfactants,Tergitol 15-S-12 shows the highest foamability.The effect of Na Cl concentration and synthetic seawater on foaming behavior of the surfactants was investigated by the test-tube shaking method.The critical micelle concentrations of aqueous solutions of the different nonionic surfactants were measured at 300 K.It was found that the critical micelle concentrations of all surfactants also increased with increasing ethylene oxide number.Dynamic light scattering experiments were performed to investigate the micelle sizes of the surfactants at their respective critical micelle concentrations.Core flooding experiments were carried out in sand packs using the surfactant solutions.It was found tha t22% additional oil was recovered in the case of all the surfactants over secondary water flooding.Tergitol 15-S-12exhibited the maximum additional oil recovery which is more than 26%after water injection. 展开更多
关键词 enhanced oil recovery Ethylene oxide number Foaming properties Surfactant flooding Micellization
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Co-optimization of carbon dioxide storage and enhanced oil recovery in oil reservoirs using a multi-objective genetic algorithm(NSGA-Ⅱ) 被引量:6
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作者 SAFARZADEH Mohammad Amin MOTAHHARI Seyyed Mahdia 《Petroleum Science》 SCIE CAS CSCD 2014年第3期460-468,共9页
Climate researchers have observed that the carbon dioxide (CO2) concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas (GHG... Climate researchers have observed that the carbon dioxide (CO2) concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas (GHG) emissions for Annex B (Developed) countries, and over 60% of global emissions. Because of impermeable cap rocks hydrocarbon reservoirs are able to sequester CO〉 In addition, due to high-demand for oil worldwide, injection of CO2 is a useful way to enhance oil production. Hence, applying an efficient method to co-optimize CO2 storage and oil production is vital. Lack of suitable optimization techniques in the past led most multi-objective optimization problems to be tackled in the same way as a single objective optimization issue. However, there are some basic differences between the multi and single objective optimization methods. In this study, by using a non- dominated sorting genetic algorithm (NSGA-II) for an oil reservoir, some appropriate scenarios are proposed based on simultaneous gas storage and enhanced oil recovery optimization. The advantages of this method allow us to amend production scenarios after implementing the optimization process, by regarding the variation of economic parameters such as oil price and CO2 tax. This leads to reduced risks and time duration of making new decisions based on upcoming situations. 展开更多
关键词 Greenhouse gas emission carbon dioxide enhanced oil recovery multi-objective optimization decision making
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Emerging applications of nanomaterials in chemical enhanced oil recovery:Progress and perspective 被引量:6
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作者 Najeebullah Lashari Tarek Ganat 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第8期1995-2009,共15页
In enhanced oil recovery,different chemicalmethods utilization improves hydrocarbon recovery due to their fascinating abilities to alter some critical parameters in porous media,such as mobility control,the interactio... In enhanced oil recovery,different chemicalmethods utilization improves hydrocarbon recovery due to their fascinating abilities to alter some critical parameters in porous media,such as mobility control,the interaction between fluid to fluid,and fluid to rock surface.For decades the use of surfactant and polymer flooding has been used as tertiary recovery methods.In the current research,the inclusion of nanomaterials in enhanced oil recovery injection fluids solely or in the presence of other chemicals has got colossal interest.The emphasis of this review is on the applicability of nanofluids in the chemical enhanced oil recovery.The responsiblemechanisms are an increment in the viscosity of injection fluid,decrement in oil viscosity,reduction in interfacial and surface tension,and alteration of wettability in the rock formation.In this review,important parameters are presented,which may affect the desired behavior of nanoparticles,and the drawbacks of nanofluid and polymer flooding and the need for a combination of nanoparticles with the polymer are discussed.Due to the lack of literature in defining the mechanism of nanofluid in a reservoir,this paper covers majorly all the previous work done on the application of nanoparticles in chemical enhanced oil recovery at home conditions.Finally,the problems associatedwith the nano-enhanced oil recovery are outlined,and the research gap is identified,which must be addressed to implement polymeric nanofluids in chemical enhanced oil recovery. 展开更多
关键词 Chemical enhanced oil recovery MECHANISMS Nanoparticles POLYMERIC Nanofluids
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Advances in enhanced oil recovery technologies for low permeability reservoirs 被引量:5
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作者 Wan-Li Kang Bo-Bo Zhou +1 位作者 Miras Issakhov Marabek Gabdullin 《Petroleum Science》 SCIE CAS CSCD 2022年第4期1622-1640,共19页
Low permeability oil and gas resources are rich and have great potential all over the world, which has gradually become the main goal of oil and gas development. However, after traditional primary and secondary exploi... Low permeability oil and gas resources are rich and have great potential all over the world, which has gradually become the main goal of oil and gas development. However, after traditional primary and secondary exploitation, there is still a large amount of remaining oil that has not been recovered.Therefore, in recent years, enhanced oil recovery(EOR) technologies for low permeability reservoirs have been greatly developed to further improve crude oil production. This study presents a comprehensive review of EOR technologies in low permeability reservoirs with an emphasis on gas flooding, surfactant flooding, nanofluid flooding and imbibition EOR technologies. In addition, two kinds of gel systems are introduced for conformance control in low permeability reservoirs with channeling problems. Finally,the technical challenges, directions and outlooks of EOR in low permeability reservoirs are addressed. 展开更多
关键词 enhanced oil recovery Low permeability reservoir Gas flooding Surfactant flooding Nanofluid flooding IMBIBITION Conformance control
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A review of fluid displacement mechanisms in surfactant-based chemical enhanced oil recovery processes:Analyses of key influencing factors 被引量:5
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作者 Ahmed Bashir Amin Sharifi Haddad Roozbeh Rafati 《Petroleum Science》 SCIE CAS CSCD 2022年第3期1211-1235,共25页
Surfactant-based oil recovery processes are employed to lower the interfacial tension in immiscible displacement processes,change the wettability of rock to a more water-wet system and emulsify the oil to displace it ... Surfactant-based oil recovery processes are employed to lower the interfacial tension in immiscible displacement processes,change the wettability of rock to a more water-wet system and emulsify the oil to displace it in subsurface porous media.Furthermore,these phenomena can reduce the capillary pressure and enhance spontaneous imbibition.The key factors affecting such immiscible displacement process are temperature,salinity and p H of the fluids,surfactant concentration and adsorption.Therefore,before any surfactant flooding process is applied,extensive studies of fluid-fluid and rock-fluid interactions are needed.The use of other chemicals along with surfactants in chemical enhanced oil recovery(c EOR)processes have been widely considered to exploit the synergy of individual chemicals and complement the weakness arises from each of them during immiscible displacement of fluids in porous media.Therefore,such combinations of chemicals lead to alkaline-surfactant(AS),surfactantpolymer(SP),alkaline-surfactant-polymer(ASP),and nanoparticle-surfactant(NS)flooding processes,among others.In this review study,we categorised the role and displacement mechanisms of surfactants and discussed the key factors to be considered for analysing the fluid displacement in porous media. 展开更多
关键词 Alkaline surfactant(AS)flooding Alkaline-surfactant-polymer(ASP)flooding enhanced oil recovery(EOR) Interfacial tension(IFT) Nanoparticle-surfactant(NS)flooding Surfactant adsorption Surfactant-polymer(SP)flooding Wettability alteration
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Enhanced oil recovery from carbonate reservoirs by spontaneous imbibition of low salinity water 被引量:4
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作者 Mohammad Reza Zaeri Rohallah Hashemi +1 位作者 Hamidreza Shahverdi Mehdi Sadeghi 《Petroleum Science》 SCIE CAS CSCD 2018年第3期564-576,共13页
An experimental study was performed to investigate the impact of low salinity water on wettability alteration in carbonate core samples from southern Iranian reservoirs by spontaneous imbibition. In this paper, the ef... An experimental study was performed to investigate the impact of low salinity water on wettability alteration in carbonate core samples from southern Iranian reservoirs by spontaneous imbibition. In this paper, the effect of temperature, salinity,permeability and connate water were investigated by comparing the produced hydrocarbon curves. Contact angle measurements were taken to confirm the alteration of surface wettability of porous media. Oil recovery was enhanced by increasing the dilution ratio of sea water, and there existed an optimum dilution ratio at which the highest oil recovery was achieved. In addition, temperature had a very significant impact on oil recovery from carbonate rocks. Furthermore, oil recovery from a spontaneous imbibition process was directly proportional to the permeability of the core samples. The presence of connate water saturation inside the porous media facilitated oil production significantly. Also, the oil recovery from porous media was highly dependent on ion repulsion/attraction activity of the rock surface which directly impacts on the wettability conditions. Finally, the highest ion attraction percentage was measured for sodium while there was no significant change in pH for all experiments. 展开更多
关键词 enhanced oil recovery Spontaneous imbibition Low salinity water Wettability alteration Carbonate rocks
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Experimental study on the mechanism of adsorption-improved imbibition in oil-wet tight sandstone by a nonionic surfactant for enhanced oil recovery 被引量:3
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作者 Yong-Peng Sun Yan Xin +1 位作者 Fang-Tao Lyu Cai-Li Dai 《Petroleum Science》 SCIE CAS CSCD 2021年第4期1115-1126,共12页
In recent years,production from tight oil reservoirs has increasingly supplemented production from conventional oil resources.Oil-wet formations account for a considerable proportion of tight oil reservoirs.Surfactant... In recent years,production from tight oil reservoirs has increasingly supplemented production from conventional oil resources.Oil-wet formations account for a considerable proportion of tight oil reservoirs.Surfactant can change wettability and reduce interfacial tension,thus resulting in a better oil recovery.In this manuscript,a nonionic surfactant was introduced for tight oil-wet reservoirs.The oil recovery in the oil-wet sandstone due to spontaneous imbibition was 8.59%lower than that of the waterwet sandstone due to surfactant.The 0.1%surfactant solution corresponded to the highest imbibition recovery rate of 27.02%from the oil-wet sample.With the surfactant treatment,the treated core quickly changed from weakly oil-wet to weakly water-wet.The capillary force acted as the driving force and promoted imbibition.The optimal surfactant adsorption quantity in the oil-wet sandstone was observed in the sample at concentrations ranging from 0.1%to 0.3%,which also corresponded to the highest oil recovery.Analysis of the inverse Bond number NB-1 suggested that the driving force was gravity for brine imbibition in the oil-wet cores and that it was capillary force for surfactant imbibition in the oil-wet cores.When the surfactant concentration was lower than the critical micelle concentration,the surfactant concentration was negatively correlated with the inverse Bond number and positively correlated with the oil recovery rate.When the surfactant concentration was higher than the critical micelle concentration,the oil recovery increased with a smaller interfacial tension.Nuclear magnetic resonance suggested that the movable pore and pore throat size in the oil-wet sample decreased from 0.363 mm in the untreated rock to 0.326 mm with the surfactant treatment,which indicated that the surfactant improved the flow capacity of the oil.The findings of this study can help to better understand the adsorption impact of surfactants on the characteristics of the oil/water and solid/liquid interfaces.The imbibition mechanism in oil-wet tight sandstone reservoirs was further revealed.These systematic approaches help to select appropriate surfactants for better recovery in oil-wet tight sandstone reservoirs through imbibition. 展开更多
关键词 Tight oil reservoir ADSORPTION enhanced oil recovery SURFACTANT WETTABILITY Interfacial tension
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