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Three-dimensional Modeling of Ore-forming Elements and Mineralization Prognosis for the Yechangping Mo Deposit,Henan Province,China
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作者 DING Gaoming JI Genyuan +5 位作者 YAN Guolong XU Yongzhong WANG Kunming XIAO Chun WANG Quanle GUO Dongbao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期736-752,共17页
Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-di... Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration. 展开更多
关键词 3D geochemical model ore-forming elements GEOSTATISTICS deep mineralization prediction Yechangping Mo deposit
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The abundance,distribution,and enrichment mechanism of harmful trace elements in coals from Guizhou,Southwestern China
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作者 Hui Hou Wei Cheng +1 位作者 Ruidong Yang Yan Zhang 《Acta Geochimica》 EI CAS CSCD 2024年第5期889-903,共15页
Coal seams can enrich a variety of harmful trace elements under specific geological conditions.The spatial distribution of harmful trace elements in coal is extremely uneven,and the distribution characteristics of eac... Coal seams can enrich a variety of harmful trace elements under specific geological conditions.The spatial distribution of harmful trace elements in coal is extremely uneven,and the distribution characteristics of each element content are different.The harmful elements released in the process of coal mining and utilization will cause serious harm to the environment and the human body.It is of great resource significance to study the geochemistry of coal that affects the enrichment and distribution characteristics of harmful trace elements.Based on the domestic and foreign literature on coal geochemistry in Guizhou published by previous investigators,this study counted 1097 sample data from 23 major coal-producing counties in Guizhou Province,systematically summarized the relevant research results of harmful trace elements in the coal of Guizhou,and revealed the overall distribution and enrichment characteristics of harmful trace elements in the coal of Guizhou.The results show that the average contents of Cd,Pb,Se,Cu,Mo,U,V,As,Hg,and Cr in coal of Guizhou are higher than those in Chinese coal and world coal.A variety of harmful trace elements in the coal of Guizhou have high background values,especially in Liupanshui,Xingyi and Qianbei coalfield.The enrichment of various harmful trace elements in the Late Permian coal in Guizhou is mainly related to the combined action of various geological and geochemical factors.The supply of terrigenous debris and sedimentary environment may be the basic background of the enrichment of harmful elements in western Guizhou,while low-temperature hydrothermal activity and volcanic ash deposition may be the main reasons for the enrichment of harmful elements in southwestern Guizhou. 展开更多
关键词 Harmful trace elements Distribution characteristics enrichment law Geological and geochemical features GUIZHOU
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Enriched Constant Elements in the Boundary Element Method for Solving 2D Acoustic Problems at Higher Frequencies
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作者 Zonglin Li Zhenyu Gao Yijun Liu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期2159-2175,共17页
The boundary element method(BEM)is a popular method for solving acoustic wave propagation problems,especially those in exterior domains,owing to its ease in handling radiation conditions at infinity.However,BEM models... The boundary element method(BEM)is a popular method for solving acoustic wave propagation problems,especially those in exterior domains,owing to its ease in handling radiation conditions at infinity.However,BEM models must meet the requirement of 6–10 elements per wavelength,using the conventional constant,linear,or quadratic elements.Therefore,a large storage size of memory and long solution time are often needed in solving higher-frequency problems.In this work,we propose two new types of enriched elements based on conventional constant boundary elements to improve the computational efficiency of the 2D acoustic BEM.The first one uses a plane wave expansion,which can be used to model scattering problems.The second one uses a special plane wave expansion,which can be used tomodel radiation problems.Five examples are investigated to showthe advantages of the enriched elements.Compared with the conventional constant elements,the new enriched elements can deliver results with the same accuracy and in less computational time.This improvement in the computational efficiency is more evident at higher frequencies(with the nondimensional wave numbers exceeding 100).The paper concludes with the potential of our proposed enriched elements and plans for their further improvement. 展开更多
关键词 enriched boundary elements constant elements 2D acoustic problems higher frequency
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The effect of Fe-Mn minerals and seawater interface and enrich-ment mechanism of ore-forming elements of polymetallic crusts and nodules from the South China Sea 被引量:4
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作者 GUAN Yao SUN Xiaoming +7 位作者 IANG Xiaodong SA Rina ZHOU Li HUANG Yi LIU Yating LI Xiaojie LU Rongfei WANG Chi 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第6期34-46,共13页
Ferromanganese crusts and nodules are important submarine mineral resources that contain various metal elements with significant economic value. In this study, polymetallic crusts and nodules obtained from the South C... Ferromanganese crusts and nodules are important submarine mineral resources that contain various metal elements with significant economic value. In this study, polymetallic crusts and nodules obtained from the South China Sea (SCS) were determined by using X-ray power diffraction (XRD), Raman spectroscopy (RS), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) to systematically investigate and analyze the mineralogical and spectral characteristics of the Fe-Mn minerals. XRD measurements revealed that the SCS polymetallic crusts and nodules were composed of vernadite, quartz, and plagioclase. The nodules also contained todorokite. The Fe-phase minerals of the SCS crusts and nodules were composed of amorphous Fe oxide/hydroxide, and the Mn- and Fe-phases minerals exhibited relatively poor degrees of crystallization. FTIR results showed that the Fe-Mn minerals in the crusts and nodules included a large number of surface hydroxyl groups. These surface hydroxyl groups contained protons that could provide reactive sites for complexation of ore-forming elements in seawater. XPS results indicated that the surfaces of the Fe-Mn minerals mainly contained Fe, Mn, and O. Fe was present in the trivalent oxidation state, while Mn, which may contain several bivalent oxidation state, was present in the tetravalent and trivalent oxidation states. The SCS polymetallic crusts and nodules were compared with Pacific seamount crusts, and results showed that the surface hydroxyl (-OH) groups of the SCS crusts and nodules numbered more than the lattice oxygen (O^2-). But the lattice oxygen of Pacific seamount crusts numbered more than the surface hydroxyl groups. This characteristic indicated that the degree of crystallization of Fe-Mn minerals from the Pacific Ocean was higher than that of minerals from the South China Sea. Comprehensive studies showed that ore-forming elements in the interface between seawater and the Fe-Mn minerals in the submarine ferromanganese crusts and nodules employed the following enrichment mechanisms: (1) the metal ion complexed with the surface hydroxyl of Fe-Mn minerals to form hydroxyl complexes, which were connected by coordination bonds or stable inner-sphere complexes that exchanged protons on the mineral surfaces; (2) the charged surfaces of the minerals and metal cations formed outer-sphere complexes, which made up the electrostatic double layer, through electrostatic adsorption; and (3) the metal cations isomorphously exchanged the Mn and Fe ions of the mineral lattice structure. 展开更多
关键词 polymetallic crust and nodule mineralogy characteristic interface effect element enrichment surfacecomplexation
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Separation and Enrichment of Rare Earth Elements in Phosphorite in Xinhua,Zhijin,Guizhou 被引量:6
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作者 张杰 孙传敏 +1 位作者 杨国峰 谢飞 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第z2期413-414,共2页
The phosphorite ores-deposits rich in rare earth elements(REE) in Zhijin, Xinhua, Guizhuo occurs in the early Cambrian Meishucun and at the bottom part of Qiongzhusi stage (the upper layer of phosphorites), belonging ... The phosphorite ores-deposits rich in rare earth elements(REE) in Zhijin, Xinhua, Guizhuo occurs in the early Cambrian Meishucun and at the bottom part of Qiongzhusi stage (the upper layer of phosphorites), belonging to Yangzi stratum section. The living creature scraps was proved existent in dolomitic-phosphorites by experiments, The REE could be extracted to provide the worthy data for the further using. Adopting the HNO3 to extract REE, through the ion exchange method, the REE recovery rate could be reached 85.44% , having certain reference value. 展开更多
关键词 rare earth elements PHOSPHORITES separation and enrichment
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Enrichment and Release of Rare Earth Elements during Weathering of Sedimentary Rocks in Wujiang Catchments,Southwest China
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作者 宋照亮 刘丛强 +3 位作者 韩贵琳 王中良 朱兆洲 杨成 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第4期491-496,共6页
Thirteen weathering profiles of sedimentary rocks such as limestone, dolomitic limestone, dolomite, sillicalite, black shale and purple sandrock from Wujiang catchments were selected for study on enrichment and releas... Thirteen weathering profiles of sedimentary rocks such as limestone, dolomitic limestone, dolomite, sillicalite, black shale and purple sandrock from Wujiang catchments were selected for study on enrichment and release behavior of rare earth elements (REE) during weathering, and its impact on plant growth and riverine REE distribution in the catchments with methods of hierachical cluster analysis and mass balance calculation in order to set a basis for riverine material source research and agricultural production. The results show that the enrichment degree of REE in calcareous soils from the Wujiang catchments is much higher than that of limestone, yellow soil, upper continental crust (UCC), China soil (CS) and world soil (WS). The ability of enrichment and release of REE is partly controlled by distribution of REE in bedrocks, contents and adsorption ability of organic matters, clay minerals and Fe-oxides/hydroxides in weathering profiles. The REE released from weathering of carbonate rocks and clastic rocks can be absorbed and utilized by local plants. The results also reveal that release of REE and Fe mainly from weathering of carbonate rocks and partly from clastic rocks exerts an important control on riverine REE distribution. 展开更多
关键词 rare earth elements enrichment RELEASE WEATHERING sedimentary rocks
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Upper Mantle Heterogeneity in Ore-Forming Elements and Its Bearing on Metallogenesis in Qinling Belt and East China
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作者 Han Yinwen Zheng Haifei Ouyang Jianping Zhang BenrenChina University of Geosciences , Wuhan 430074 《Journal of Earth Science》 SCIE CAS CSCD 1992年第1期34-42,共9页
This paper presents the results of our recent studies on the upper mantle composition in the Qinling Belt and East China . It discusses the methods of estimating the upper mantle composition, its selected elements and... This paper presents the results of our recent studies on the upper mantle composition in the Qinling Belt and East China . It discusses the methods of estimating the upper mantle composition, its selected elements and its constitution characteristics .The results indicate that ore-forming elements on ore types and their distribution in this area are strongly controlled by the upper mantle heterogeneity . 展开更多
关键词 regional upper mantle partial melting ore-forming elements chemical heterogeneity regional ore distribution .
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STUDY ON ENRICHMENT AND SEPARATION OF TRACE ELEMENTS WITH SILICA GELS MODIFIED BY HETEROCYCLIC AZO DYES
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作者 Ke An LI~2, Feng LIU, Shen Yang TONG (Department of Chemistry, Peking University, Beijing 100871) 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第8期633-636,共4页
Two types of modified silica gels were prepared by adsorption method and bonding method respectively. Enrichment and separation of trace metal ions have been done by using the column packed with modified silica gels.
关键词 HCI Br SG STUDY ON enrichment AND SEPARATION OF TRACE elements WITH SILICA GELS MODIFIED BY HETEROCYCLIC AZO DYES AZO TAH
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Enrichment Characteristics, Occurrence and Origin of Valuable Trace Elements in Lignite from Linchang Coal Mine, Guangxi, China
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作者 De’e Qi Shihao Wu +5 位作者 Shenyong Li Gui Zhao Jingkai Xing Shuai Kang Qian Wang Wenyue Gao 《Journal of Geoscience and Environment Protection》 2021年第12期133-150,共18页
To evaluate the comprehensive exploitation and utilization values of coal resources in Baise basin of Guangxi, the Paleogene coal of Linchang coal mine were sampled and studied. The enrichment characteristics, occurre... To evaluate the comprehensive exploitation and utilization values of coal resources in Baise basin of Guangxi, the Paleogene coal of Linchang coal mine were sampled and studied. The enrichment characteristics, occurrence modes, and geochemical origin of valuable trace elements in coal were studied by using X-ray diffraction (XRD), scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS), polarizing microscope, X-ray fluorescence spectrometry (XRF), inductively coupled plasma mass spectrometry (ICP-MS) and atomic fluorescence spectrometry (AFS). The results reveal that Linchang coal is ultra-low calorific value lignite with high ash, medium sulfur, medium-high moisture and medium volatilization. The minerals are mainly composed of illite, kaolinite, quartz, pyrite, siderite, bassanite, anhydrite and magnesium-containing calcite. Compared with average values for world low-rank coals, the contents of valuable trace elements in Linchang coal are higher on the whole, which is characterized by the high enrichment o<span>f U, the enrichment of elements Li, V and Ag, and the slight enrichment of</span> elements Be, Ga and Se. Lithium, V, Ga and Ag mainly occur in clay minerals including illite and kaolinite, and part of V is related to organic matter. Th<span>e carriers of Be in coal are clay minerals and organic matter. Selenium is </span>mainly combined with organic matter and a small amount exists in pyrite. Uranium is primarily organically bound in coal. The enrichment of valuable trace elements in Linchang coal is influenced by the sedimentary source, coal<span>-forming environment, underground circulating water and geological structure. The sedimentary environment of the coal seam is an acid-reduced terrestrial peat swamp, and the source is Triassic sedimentary rocks weathered f</span>rom feldspathic volcanic rocks around Baise basin. 展开更多
关键词 LIGNITE Valuable Trace elements enrichment Characteristics Occurrence Modes Geochemical Origin
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Super-Enrichment of Dispersed Elements and Associated Ore Deposits
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作者 高振敏 姚林波 《Chinese Journal Of Geochemistry》 EI CAS 2004年第1期46-51,共6页
Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-e... Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-enrichment of the four dispersed elements Tl, Ge, Se, and Te under favorable geological conditions, where their enrichment coefficients are so high that their abundances can reach n×10+3-n×10+4, sometimes even up to n×10+6 times (e.g. Te) those of the crust. As a result, they can form their independent ore deposits. Studies have shown that such independent ore deposits are mostly distributed in the southwestern part of China, most of which belong to low-temperature ore deposits, ranging in age from Yanshanian to Himalayan (Cretaceous to Cenozoic), with a significant time gap with the host strata. Moreover, this paper also deals with the existing forms (as independent minerals, occurring isomorphously and being adsorbed) of the dispersed elements in those independent ore deposits. The discovery of independent ore deposits of dispersed elements is a great breakthrough in the study of dispersed element metallogenesis. 展开更多
关键词 沉积物 地质条件 元素富集 地壳 喜马拉雅山
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Separation and enrichment of elemental sulfur and mercury from hydrometallurgical zinc residue using sodium sulfide 被引量:2
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作者 王子阳 蔡晓兰 +3 位作者 张泽彪 张利波 王仕兴 彭金辉 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第2期640-646,共7页
The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipit... The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipitating. The results show that the leaching rate of elemental sulfur is more than 98%, and 98.13% of mercury is enriched in the residue, under the optimized conditions of sodium sulfide concentration 1.5 mol/L, liquid/solid ratio 6:1 and leaching time 30 min at room temperature. In addition, the content of mercury is enriched 5.23 times that in the leaching residue. The elemental sulfur is precipitated from leaching solution under conditions of carbon dioxide flow rate 200 mL/min and blowing time 150 min, while solution is stirred adequately. The recovery efficiency of elemental sulfur reaches 97.67%, and the purity of elemental sulfur is 99.75%, meeting the requirements of industrial first-rate product standard according to the national standard of GB/T 2449-2006 (PRC). 展开更多
关键词 flotation sulfur concentrate sodium sulfide leaching carbon dioxide precipitating mercury enrichment elemental sulfurrecovery
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The enhanced element enrichment in the supercritical states of granite–pegmatite systems 被引量:12
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作者 Rainer Thomas Paul Davidson Karen Appel 《Acta Geochimica》 EI CAS CSCD 2019年第3期335-349,共15页
In this paper, we show that supercritical fluids have a greater significance in the generation of pegmatites,and for ore-forming processes related to granites than is usually assumed. We show that the supercritical me... In this paper, we show that supercritical fluids have a greater significance in the generation of pegmatites,and for ore-forming processes related to granites than is usually assumed. We show that the supercritical melt or fluid is a silicate phase in which volatiles; principally H_2O are completely miscible in all proportions at magmatic temperatures and pressures. This phase evolves from felsic melts and changes into hydrothermal fluids, and its unique properties are particularly important in sequestering and concentrating low abundance elements, such as metals. In our past research, we have focused on processes observed at upper crustal levels, however extensive work by us and other researchers have demonstrated that supercritical melt/fluids should be abundant in melting zones at deep-crustal levels too. We propose that these fluids may provide a connecting link between lower and upper crustal magmas,and a highly efficient transport mechanism for usually melt incompatible elements. In this paper, we explore the unique features of this fluid which allow the partitioning of variouselements and compounds, potentially up to extreme levels,and may explain various features both of mineralization and the magmas that produced them. 展开更多
关键词 GRANITES PEGMATITES Supercritical state Extreme element enrichment
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Rare earth elements-rich phase and enriching mechanism in sediments from CC area, the Pacific Ocean 被引量:2
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作者 Meng Xianwei, Chen Zhihua, Wang Xiangqin, Liu Na (1. First Institute of Oceanography, State Oceanic Administration, Qingdao 266003, China 2. Key Lab. of Marine Science and Numerical Modelling, State Oceanic Administration, Qingdao 266003, China) 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2001年第2期209-214,共6页
Compared to North American shale composition (NASC), REE contents of sediments from the CC area in the Pacific Ocean are obviously high except that cerium has equal content to that of NASC. Three-valence rare earth el... Compared to North American shale composition (NASC), REE contents of sediments from the CC area in the Pacific Ocean are obviously high except that cerium has equal content to that of NASC. Three-valence rare earth elements were completely enriched in phosphate-phase and cerium in iron-phase. Rare earth elements in the sediments were originally derived from seawater. During lithi- genic and minerogenic processes of metalliferous nodules, three-valence rare earth elements in sediments mobilized and incorporated into sediments as authigenous biogenic-apatite, while cerium had change from Ce3+ to Ce4+ and directly precipitated from seawater and entered metalliferous nodules and caused Ce anomalies in REE pattern in sediments. 展开更多
关键词 CC area of the Pacific Ocean SEDIMENTS rare earth elements REE- rich phase enriching mechanism
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Sources, enrichment mechanisms, and resource effects of rare metal elements-enriched geothermal springs in Xizang, China
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作者 Fei XUE Hongbing TAN +1 位作者 Xiying ZHANG Jinbao SU 《Science China Earth Sciences》 SCIE EI CAS CSCD 2024年第11期3476-3499,共24页
Rare metals such as lithium(Li), rubidium(Rb), and cesium(Cs) are strategically crucial mineral resources for the development of emerging industries in China. Ensuring a stable long-term supply of these resources is e... Rare metals such as lithium(Li), rubidium(Rb), and cesium(Cs) are strategically crucial mineral resources for the development of emerging industries in China. Ensuring a stable long-term supply of these resources is essential. The geothermal systems in Xizang, China are well-developed, with a wide distribution of various types. Most high-temperature geothermal systems in Xizang are exceptionally enriched in rare metal elements(RMEs) and have the potential to become a new source of rare metals to secure China's strategic mineral resource supply in the future. A close relationship also exists between the geothermal system and the special salt lake resources on the Tibetan Plateau. Geothermal springs thus play a key role in the migration and enrichment of RMEs from deep to shallow parts of the crust, in the transition between endogenous and exogenous mineralization, and source-to-sink processes. However, the mechanisms of element enrichment and evolution in these springs have not been systematically discussed, and many theoretical issues remain to be investigated. Based on summarizing and analyzing previous research, this study employs hydrochemical and isotopic geochemistry methods to investigate typical geothermal springs across Xizang and explore the anomalous enrichment mechanism of RMEs, and the resource effects of geothermal springs. Comprehensive analysis shows that the total dissolved solids(TDS) and hydrochemical types of geothermal springs are similar to those of major geothermal fields worldwide, but the Tibetan springs are abnormally rich in Li(averaging5.48 mg/L), Rb(averaging 0.75 mg/L), and Cs(averaging 3.58 mg/L), which are hundreds to thousands of times more concentrated than natural waters. The distribution of these enriched geothermal springs is controlled by the Yarlung Zangbo suture zone and the extended N-S trending rifts, especially in the intersection zone of the two, where the geothermal springs are the most enriched. Based on the spatial distribution, isotopic, and elemental geochemistry, the RMEs enriched in Tibetan geothermal springs are mainly derived from the magmatic-hydrothermal fluids generated by the partial melting of the subducted Indian plate under the Eurasian continent. These fluids not only maintain geothermal activities as a heat source but also participate in the material cycle of the geothermal spring as a material source. Against the background of regional crustal enrichment in RMEs,incompatible elements such as Li, Rb, and Cs are gradually enriched in magmatic-hydrothermal processes including partial melting in the source, magmatic differentiation, and hydrothermal fluid exsolution, and some ore-forming elements are further extracted from surrounding rocks through deep high-temperature water-rock interactions. Eventually, an eruption occurs, and these fluids move to the surface to form a geothermal spring rich in RMEs. With the drainage of geothermal springs, the RMEs are continuously transported to the lake basin by surface runoff and continue to concentrate and evolve into salt lake brines under an extremely arid climate environment, constituting an endogenous source and exogenous accumulation salt lake metallogenic model. This comprehensive explanation of the sources, migration, enrichment mechanisms, and resource effects of geothermal springs will deepen the understanding of rare metal mineralization processes, and aid in the advancement of theoretical models for key rare metal mineral resources in various geological bodies of the Tibetan Plateau, significantly expanding exploration scopes and accurately assessing the resource potential of RMEs. 展开更多
关键词 Geothermal springs Rare metal elements enrichment mechanisms Salt lakes Tibetan Plateau
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Origin of the Dashuigou Independent Tellurium Deposit at the Southeastern Qinghai-Tibet Plateau:Based on the Abundances of Trace Elements in the Country Rocks
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作者 Jianzhao Yin Shoupu Xiang +2 位作者 Haoyu Yin Hongyun Shi Yuhong Chao 《Advances in Geological and Geotechnical Engineering Research》 2023年第4期41-55,共15页
Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,a... Through a detailed study of the abundances and spatial-temporal distribution patterns of Te,Bi,As,Se,Cu,Pb,Zn,Au,and Ag in the rock types of different geological epochs in the Dashuigou independent tellurium deposit,and in combination with other research findings of previous researchers in this area,the authors conclude as follows:Abundances of the main ore-forming elements Te,Bi,As,Se,Au,and Ag are not high in the regional geological background,generally lower or close to their respective crustal Clark values,but almost all altered country rocks contain high levels of ore-forming elements.This indicates that the deposit’s ore-forming elements do not come from the country rocks.This also indicates that the geological thermal events that cause alteration and mineralization originate from depths and may be related to mantle plumes.Considering the distribution pattern of these ore-forming elements in the ore bodies’hanging wall and footwall,the metallogenic mechanism may be as follows:Mineralization is not achieved through lateral secretion in the horizontal or near horizontal direction,but rather through the upward movement and emplacement of deep ore-forming elements driven by geological processes such as mantle plumes.In addition,the migration of deep ore-forming elements is not achieved through dispersed infiltration between overlying rock particles,but through non widespread concentrated penetrating channels.This type of channel is likely to be the expansion structures where faults from different directions intersect,or where linear faults intersect with circular structures. 展开更多
关键词 Origin of ore-forming elements The Dashuigou independent tellurium deposit Trace element abundance The country rocks The mantle plume
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In, Sn, Pb and Zn Contents and Their Relationships in Ore-forming Fluids from Some In-rich and In-poor Deposits in China 被引量:16
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作者 ZHANG Qian ZHU Xiaoqing +1 位作者 HE Yuliang ZHU Zhaohui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2007年第3期450-462,共13页
All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn... All the indium-rich deposits with indium contents in ores more than 100×10^-6 seems to be of cassiterite-sulfide deposits or Sn-bearing Pb-Zn deposits, e.g., in the Dachang Sn deposit in Guangxi, the Dulong Sn-Zn deposit in Yunnan, and the Meng'entaolegai Ag-Pb-Zn deposit in Inner Mongolia, the indium contents in ores range from 98×10^-6 to 236×10^-6 and show a good positive correlation with contents of zinc and tin, and their correlation coefficients are 0.8781 and 0.7430, respectively. The indium contents from such Sn-poor deposits as the Fozichong Pb-Zn deposit in Guangxi and the Huanren Pb-Zn deposit in Liaoning are generally lower than 10×10^-6, i.e., whether tin is present or not in a deposit implies the enrichment extent of indium in ores. Whether the In enrichment itself in the ore -forming fluids or the ore-forming conditions has actually caused the enrichment/depletion of indium in the deposits? After studying the fluid inclusions in quartz crystallized at the main stage of mineralization of several In-rich and In-poor deposits in China, this paper analyzed the contents and studied the variation trend of In, Sn, Pb and Zn in the ore-forming fluids. The results show that the contents of lead and zinc in the ore-forming fluids of In-rich and -poor deposits are at the same level, and the lead contents range from 22×10^-6 to 81×10^-6 and zinc from 164×10^-6 to 309×10^-6, while the contents of indium and tin in the ore-forming fluids of In-rich deposits are far higher than those of Inpoor deposits, with a difference of 1-2 orders of magnitude. Indium and tin contents in ore-forming fluid of In-rich deposits are 1.9×10^-6-4.1×10^-6 and 7×10^-6-55×10^-6, and there is a very good positive correlation between the two elements, with a correlation coefficient of 0.9552. Indium and tin contents in ore-forming fluid of In-poor deposits are 0.03×10^-6-0.09×10^-6 and 0.4×10^-6-2.0×10^-6, respectively, and there is no apparent correlation between them. This indicates, on one hand, that In-rich oreforming fluids are the material basis for the formation of In-rich deposits, and, on the other hand, tin probably played a very important role in the transport and enrichment of indium. 展开更多
关键词 In-rich deposit In-poor deposit ore-forming fluid fluid inclusion ore-forming elements
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Rare earth elements distribution in marine sediments of Malaysia coasts 被引量:11
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作者 Rezaee Ebrahim Saraee Khadijeh Saion B.Elias +1 位作者 Abdul Khalik Wood Abdi Mohammad Reza 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第6期1066-1071,共6页
In the east coast Peninsular Malaysia region,sediments are transported by several rivers from the east Malaysia into the South China Sea estuary.In the vicinity of the five river estuaries core sediments were collecte... In the east coast Peninsular Malaysia region,sediments are transported by several rivers from the east Malaysia into the South China Sea estuary.In the vicinity of the five river estuaries core sediments were collected in order to investigate rare earth elements(REEs) profile.Core sediments were divided into strata of between 2 to 4 cm intervals and prepared for analyzing by ICP-AES.REE concentrations of 54.3 μg/gr at 24–26 cm in EC4 increased to 114.1 μg/gr at 20–22 cm in EC5.The measured concentration of ... 展开更多
关键词 enrichment factor rare earth elements marine sediments South China Sea shale average
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Enrichment characteristics and sources of the critical metal yttrium in Zhijin rare earth-containing phosphorites, Guizhou Province, China 被引量:4
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作者 Xingxiang Gong Shengwei Wu +8 位作者 Yong Xia Zhengwei Zhang Shan He Zhuojun Xie Jiafei Xiao Haiying Yang Qingping Tan Yi Huang Yuhong Yang 《Acta Geochimica》 EI CAS CSCD 2021年第3期441-465,共25页
Yttrium(Y)is a critical metallic element that is used widely in modern scientific,technological,and industrial applications.Phosphorites in the Zhijin area of Guizhou Province,China,are famous for Y enrichment,but the... Yttrium(Y)is a critical metallic element that is used widely in modern scientific,technological,and industrial applications.Phosphorites in the Zhijin area of Guizhou Province,China,are famous for Y enrichment,but the enrichment characteristics and sources remain unclear.Previous studies suggested that the sources of rare earth elements(REEs,La-Lu)and Y(REYs,La-Lu+Y)were related to hydrothermal deposition.However,this study presents evidence refuting that hypothesis,with major and trace elemental data collected with quadrupoleinductively coupled plasma-mass spectrometry(Q-ICPMS)analysis.These data show that Y in Zhijin REYscontaining phosphorites has a normal distribution and is particularly enriched relative to other REYs.The Y enrichment degree is different at different∑REY intervals.Specifically,the Y enrichment degree is higher at lower∑REY values and lower at higher∑REY values.The REYs-containing phosphorites show features of primary phosphorites.Both REEs and Y have good correlations with P2 O5 in the phosphorites with low REYs contents(total REYs<535 ppm),whereas at high REYs contents(total REYs>535 ppm),REEs have a good correlation with P2 O5 but Y does not.Inconsistent enrichment processes of REYs are suggestive of complex sources of Y.Thus,seafloor hydrothermal fluids were not the direct source of Y.Normal seawater mixed with terrestrial sources might have contributed to the origin of Y here.This study could lead to improvements in Y mineral resource explorations and the situation involving the global REYs supply crisis. 展开更多
关键词 YTTRIUM PHOSPHORITES Rare earth elements Trace elements enrichment processes
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Occurrence and volatility of several trace elements in pulverized coal boiler 被引量:1
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作者 HUANGYa-ji JINBao-sheng +3 位作者 ZHONGZhao-ping XIAORui TANGZhi-yong RENHui-feng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2004年第2期242-246,共5页
The contents of eight trace elements(Mn, Cr, Pb, As, Se, Zn, Cd, Hg) in raw coal, bottom ash and fly ash were measured in a 220 t/h pulverized coal boiler. Factors affecting distribution of trace elements were investi... The contents of eight trace elements(Mn, Cr, Pb, As, Se, Zn, Cd, Hg) in raw coal, bottom ash and fly ash were measured in a 220 t/h pulverized coal boiler. Factors affecting distribution of trace elements were investigated, including fly ash diameter, furnace temperature, oxygen content and trace elements' characters. One coefficient of Meij was also improved to more directly show element enrichment in combustion products. These elements may be classified into three groups according to their distribution: Group 1: Hg, which is very volatile. Group 2: Pb, Zn, Cd, which are partially volatile. Group 3: Mn, which is hardly volatile. Se may be located between groups 1 and 2 Cr has properties of both group 1 and 3 In addition, the smaller diameter of fly ash, the more relative enrichment of trace elements(except Mn). The fly ash showed different adsorption mechanisms of trace elements and the volatilization of trace elements rises with furnace temperature. Relative enrichments of trace elements(except Mn and Cr) in fly ash are larger than that in bottom ash. Low oxygen content can not always improve the volatilization of trace elements. Pb is easier to form chloride than Cd during coal combustion. Trace elements should be classified in accordance with factors. 展开更多
关键词 OCCURRENCE VOLATILITY relative enrichment trace element group of elements
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Occurrence characteristics and enrichment regularity of indium in pyrite: A case study of Dachang tin ore-field 被引量:2
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作者 Yong-sheng CHENG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第8期2197-2208,共12页
To reveal the occurrence state and enrichment regularity of the dispersed element indium in pyrite, the petrology,mineralogy, geochemistry, and mineral physics were researched detailedly. The results suggest that the ... To reveal the occurrence state and enrichment regularity of the dispersed element indium in pyrite, the petrology,mineralogy, geochemistry, and mineral physics were researched detailedly. The results suggest that the structure of pyrite is mainlycomposed of massive structure, disseminated structure, vein structure, reticular structure, comb structure and so on. Generally, thepyrite coexists with sphalerite, marmatite, pyrrhotite, chalcopyrite, galena, and arsenopyrite. And the texture of pyrite primarilyconsists of the metasomatic texture, solid solution texture, idiomorphic?hypidiomorphic granular texture, and disseminated texture.The content of indium in pyrite ranges from 0.491×10?6 to 65.1×10?6 with an average value of 14.38×10?6. Yet, the indium content inthe Gaofeng deposit is higher than that in the Dafulou and Tongkeng deposit, showing a particularly significant supernormalenrichment. Besides, the cadmium content in pyrite is also higher than other dispersed elements, and similarly the abnormalenrichment of cadmium in the Gaofeng deposit is also very significant. An obvious positive correlation exists between In and Cd, orTl, but a negative correlation between In and Re. It is difficult to find out a positive or negative correlation between In and Ga. Theelement zinc is of great importance to the enrichment of indium, which can possibly facilitate to the migration and crystallization of dispersed element indium. 展开更多
关键词 dispersed element indium PYRITE lattice structure enrichment regularity cassiterite-sulfide deposit Dachang ore-field
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