La and CrCo-doped SrTiO_3 as an H_2 evolution photocatalyst for construction of a Z-scheme overall water splitting system

The photocatalytic activity of a semiconductor‐based photocatalyst largely depends on the semiconductor’s intrinsic crystal and electronic properties.We have prepared two types of La and Cr co‐doped SrTiO3photocatalysts(SrTiO3(La,Cr))using the polymerized complex method(PCM)and sol‐gel hydrothermal method(SHM).Under?>420‐nm visible light irradiation,only the Pt‐loaded SrTiO3(La,Cr)prepared by the SHM showed efficient photocatalytic activities for both H2evolution in the presence of an I?sacrificial reagent and for Z‐scheme overall water splitting when it was coupled with the Pt‐loaded WO3in the presence of I?and IO3?as the shuttle redox mediator.The superior photocatalytic activity of SrTiO3(La,Cr)prepared by the SHM has been ascribed to its more negative conduction‐band position,higher carrier concentration,and higher carrier mobility,demonstrating that the design and synthesis of an H2‐evolution photocatalyst with appropriate electronic properties is crucial for achieving Z‐scheme overall water splitting.

Zinc-doped g-C_3N_4/BiVO_4 as a Z-scheme photocatalyst system for water splitting under visible light

A two‐step photocatalytic water splitting system,termed a“Z‐scheme system”,was achieved using Zn‐doped g‐C3N4for H2evolution and BiVO4for O2evolution with Fe2+/Fe3+as a shuttle redox mediator.H2and O2were evaluated simultaneously when the doping amount of zinc was10%.Moreover,Zn‐doped(10%)g‐C3N4synthesized by an impregnation method showed superior active ability to form the Z‐scheme with BiVO4than by in‐situ synthesis.X‐ray diffraction,UV‐Vis spectroscopy,scanning electron microscopy,and X‐ray photoelectron spectroscopy were used to characterize the samples.It was determined that more Zn?N bonds could be formed on the surface of g‐C3N4by impregnation,which could facilitate charge transfer.

Splitting Based Scheme for Three-dimensional MHD with Dual Time Stepping

A new hybrid numerical scheme of combining an E-CUSP(Energy-Convective Upwind and Split Pressure) method for the fluid part and the Constrained Transport(CT) for the magnetic induction part is proposed.In order to avoid the occurrence of negative pressure in the reconstructed profiles and its updated value,a positivity preserving method is provided.Furthermore,the MHD equations are solved at each physical time step by advancing in pseudo time.The use of dual time stepping is beneficial in the computation since the use of dual time stepping allows the physical time step not to be limited by the corresponding values in the smallest cell and to be selected based on the numerical accuracy criterion.This newly established hybrid scheme combined with positivity preserving method and dual time technique has demonstrated the accurateness and robustness through numerical experiments of benchmark problems such as the 2D Orszag-Tang vortex problem and the3 D shock-cloud interaction problem.

THREE HIGH-ORDER SPLITTING SCHEMES FOR 3D TRANSPORT EQUATION

Two high-order splitting schemes based on the idea of the operators splitting method are given. The three-dimensional advection-diffusion equation was split into several one-dimensional equations that were solved by these two schemes, only three computational grid points were needed in each direction but the accuracy reaches the spatial fourth-order. The third scheme proposed is based on the classical ADI scheme and the accuracy of the advection term of it can reach the spatial fourth-order. Finally, two typical numerical experiments show that the solutions of these three schemes compare well with that given by the analytical solution when the Peclet number is not bigger than 5.

UPWIND SPLITTING SCHEME FOR CONVECTION-DIFFUSION EQUATIONS

WT5,5”BX] A new class of numerical schemes is proposed to solve convection diffusion equations by combining the upwind technique and the method of operator splitting. For every time step, the multi dimensional approximation is performed in several independent directions alternatively, while the upwind technique is applied to treat the convection term in every individual direction. This scheme possesses maximum principle. Stability and convergence are analysed by energy method.[WT5,5”HZ]

TRANSONIC FLOW CALCULATION OF EULER EQUATIONS BY IMPLICIT ITERATING SCHEME WITH FLUX SPLITTING

Three dimensional Euler equations are solved in the finite volume form with van Leer's flux vector splitting technique. Block matrix is inverted by Gauss-Seidel iteration in two dimensional plane while strongly implicit alternating sweeping is implemented in the direction of the third dimension. Very rapid convergence rate is obtained with CFL number reaching the order of 100. The memory resources can be greatly saved too. It is verified that the reflection boundary condition can not be used with flux vector splitting since it will produce too large numerical dissipation. The computed flow fields agree well with experimental results. Only one or two grid points are there within the shock transition zone.

A Novel Basis Splitting Eavesdropping Scheme in Quantum Cryptography Based on the BB84 Protocol

We propose a novel strategy numed basis-splitting scheme to split the intercepted quanta into several portions based on different bases, for eavesdropping in the process of quantum cryptography. Compared with intercept- resend strategy, our simulation results of the basis-splitting scheme under the non-ideal condition show a greater performance, especially with the increase of the length of shifted bits. Consequently our scheme can aid eaves- dropper to gather much more useful information.

An Improved Splitting Method

In this paper, an improved splitting method, based on the completely square-conservative explicit difference schemes, is established. Not only can the time-direction precision of this method be higher than that of the traditional splitting methods but also can the physical feature of mutual dependence of the fast and the slow stages that are calculated separately and splittingly be kept as well. Moreover, the method owns an universality, it can be generalized to other square-conservative difference schemes, such as the implicit and complete ones and the explicit and instantaneous ones. Good time benefits can be acquired when it is applied in the numerical simulations of the monthly mean currents of the South China Sea.

Multi-Symplectic Splitting Method for Two-Dimensional Nonlinear Schrodinger Equation

Using the idea of splitting numerical methods and the multi-symplectic methods, we propose a multisymplectic splitting （MSS） method to solve the two-dimensional nonlinear Schrodinger equation （2D-NLSE） in this paper. It is further shown that the method constructed in this way preserve the global symplectieity exactly. Numerical experiments for the plane wave solution and singular solution of the 2D-NLSE show the accuracy and effectiveness of the proposed method.

THE UPWIND OPERATOR SPLITTING FINITE DIFFERENCE METHOD FOR COMPRESSIBLE TWO-PHASE DISPLACEMENT PROBLEM AND ANALYSIS

For compressible two-phase displacement problem, a kind of upwind operator splitting finite difference schemes is put forward and make use of operator splitting, of calculus of variations, multiplicative commutation rule of difference operators, decomposition of high order difference operators and prior estimates are adopted. Optimal order estimates in L 2 norm are derived to determine the error, in the approximate solution.

Multidimensional Numerical Simulation of Glow Discharge by Using the N-BEE-Time Splitting Method

In this work, a new numerical technique is proposed for the resolution of a fluid model based on three Boltzmann moments. The main purpose of this technique is to calculate electric and physical properties in the non-equilibrium electric discharge at low pressure. The transport and Poisson＇s equations form a self-consistent model. This equation system is written in cylindrical coordinates following the geometric shape of a plasma reactor. Our transport equation system is discretized using the finite volume approach and resolved by the N-BEE explicit scheme coupled to the time splitting method. This programming structure reduces computation time considerably. The 2D code is carried out and tested by comparing our results with those found in literature.

The Approximated Semi-Lagrangian WENO Methods Based on Flux Vector Splitting for Hyperbolic Conservation Laws

The paper is devised to combine the approximated semi-Lagrange weighted essentially non-oscillatory scheme and flux vector splitting. The approximated finite volume semi-Lagrange that is weighted essentially non-oscillatory scheme with Roe flux had been proposed. The methods using Roe speed to construct the flux probably generates entropy-violating solutions. More seriously, the methods maybe perform numerical instability in two-dimensional cases. A robust and simply remedy is to use a global flux splitting to substitute Roe flux. The combination is tested by several numerical examples. In addition, the comparisons of computing time and resolution between the classical weighted essentially non-oscillatory scheme (WENOJS-LF) and the semi-Lagrange weighted essentially non-oscillatory scheme (WENOEL-LF) which is presented (both combining with the flux vector splitting).

High-Order Semi-Lagrangian WENO Schemes Based on Non-polynomial Space for the Vlasov Equation

In this paper,we present a semi-Lagrangian(SL)method based on a non-polynomial function space for solving the Vlasov equation.We fnd that a non-polynomial function based scheme is suitable to the specifcs of the target problems.To address issues that arise in phase space models of plasma problems,we develop a weighted essentially non-oscillatory(WENO)scheme using trigonometric polynomials.In particular,the non-polynomial WENO method is able to achieve improved accuracy near sharp gradients or discontinuities.Moreover,to obtain a high-order of accuracy in not only space but also time,it is proposed to apply a high-order splitting scheme in time.We aim to introduce the entire SL algorithm with high-order splitting in time and high-order WENO reconstruction in space to solve the Vlasov-Poisson system.Some numerical experiments are presented to demonstrate robustness of the proposed method in having a high-order of convergence and in capturing non-smooth solutions.A key observation is that the method can capture phase structure that require twice the resolution with a polynomial based method.In 6D,this would represent a signifcant savings.

Modeling and Solving Lot-Splitting Scheduling Problem Based on Process

In flexible job-shop batch scheduling problem, the optimal lot-size of different process is not always the same because of different processing time and set-up time. Even for the same process of the same workpiece, the choice of machine also affects the optimal lot-size. In addition, different choices of lot-size between the constrained processes will impact the manufacture efficiency. Considering that each process has its own appropriate lot-size, we put forward the concept of scheduling with lot-splitting based on process and set up the scheduling model of lot-splitting to critical path process as the core. The model could update the set of batch process and machine selection strategy dynamically to determine processing route and arrange proper lot-size for different processes, to achieve the purpose of optimizing the makespan and reducing the processing batches effectively. The experiment results show that, comparing with lot-splitting scheduling scheme based on workpiece, this model optimizes the makespan and improves the utilization efficiency of the machine. It also greatly decreases the machined batches （42%） and reduces the complexity of shop scheduling production management.

Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S S型异质结的构筑及其光解水产氢性能研究

采用超声辅助研磨煅烧法制备了Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S S型异质结光催化剂,通过X射线粉末衍射仪、扫描电子显微镜、X射线光电子能谱、固体紫外漫反射等测试技术表征了样品的物相、形貌、化学元素组成以及光吸收能力等物理化学性质。在可见光加近红外光照射下进行了光催化析氢性能测试,结果表明,Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S复合材料的光解水产氢性能均优于纯相的Mn_(0.3)Cd_(0.7)S和Cu_(3)Mo_(2)O_(9),其中Cu 3Mo 2O 9的质量分数为1%的Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S显示出最佳的产氢速率(1.554 mmol·h^(-1)·g^(-1)),是Mn 0.3 Cd_(0.7)S的5.5倍。且经过四次循环实验后仍保持较好的光催化活性。此外,根据电化学测试以及红外热成像结果提出了合理的机理,Cu 3Mo 2O 9的光热效应与S型异质结的协同作用是Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S光催化活性提高的关键。

UPWIND SCHEME FOR IDEAL 2-D MHD FLOWS BASED ON UNSTRUCTURED MESH

An upwind scheme based on the unstructured mesh is developed to solve ideal 2-D magnetohydrodynamics （MHD） equations. The inviscid fluxes are approximated by using the modified advection upstream splitting method （AUSM） scheme, and a 5-stage explicit Runge-Kutta scheme is adopted in the time integration. To avoid the influence of the magnetic field divergence created during the simulation, the hyperbolic divergence cleaning method is introduced. The shock-capturing properties of the method are verified by solving the MHD shock-tube problem. Then the 2-D nozzle flow with the magnetic field is numerically simulated on the unstructured mesh. Computational results demonstrate the effects of the magnetic field and agree well with those from references.

Z型InN/SnS_(2)范德华异质结增强光催化水分解

寻找高效的光催化剂分解水制氢是解决能源危机和环境问题的有效途径之一.基于第一性原理,对InN/SnS_(2)异质结的几何结构、电子结构和光催化水分解性能进行研究.结果表明InN/SnS_(2)异质结是具有的Ⅱ型能带排列半导体材料可以有效地分离电子空穴对.在光激发下,较小的带隙以及合适的内建电场使得光生载流子迁移路径成“Z”字型,这保留了InN/SnS_(2)异质结强氧化还原能力.光生电子在InN的导带底累积并发生析氢反应,而积累在SnS_(2)上的光生空穴使析氧反应自发发生.它们的带边位置都跨越了水的氧化还原电位,证明能够实现水的完全分解.因此,InN/SnS_(2)异质结有希望成为高效光解水催化剂.

High-Order Decoupled and Bound Preserving Local Discontinuous Galerkin Methods for a Class of Chemotaxis Models

In this paper,we explore bound preserving and high-order accurate local discontinuous Galerkin(LDG)schemes to solve a class of chemotaxis models,including the classical Keller-Segel(KS)model and two other density-dependent problems.We use the convex splitting method,the variant energy quadratization method,and the scalar auxiliary variable method coupled with the LDG method to construct first-order temporal accurate schemes based on the gradient flow structure of the models.These semi-implicit schemes are decoupled,energy stable,and can be extended to high accuracy schemes using the semi-implicit spectral deferred correction method.Many bound preserving DG discretizations are only worked on explicit time integration methods and are difficult to get high-order accuracy.To overcome these difficulties,we use the Lagrange multipliers to enforce the implicit or semi-implicit LDG schemes to satisfy the bound constraints at each time step.This bound preserving limiter results in the Karush-Kuhn-Tucker condition,which can be solved by an efficient active set semi-smooth Newton method.Various numerical experiments illustrate the high-order accuracy and the effect of bound preserving.

0D/1D Cd_(0.5)Zn_(0.5)S/VO_(2)S型异质结的构建及其可见光催化析氢性能研究

采用共沉淀法制备了零维/一维(0D/1D)Cd_(0.5)Zn_(0.5)S/VO_(2)(CZS/VO)S型异质结光催化剂。采用X射线粉末衍射仪、X射线光电子能谱仪、扫描和透射电子显微镜等,表征了样品的物相结构、元素组成及微观形貌等,测试了材料的可见光催化析氢性能。研究结果表明CZS/VO复合材料具有优异的可见光催化析氢活性。其中,当VO的质量分数为10%时,CZS/VO催化剂的析氢速率最高可达7.2 mmol·h^(-1)·g^(-1),是单相CZS的4.2倍,并且在四次循环试验中表现出良好的循环稳定性。这主要归因于其独特的0D/1D形貌和S型异质结的协同作用显著加速了光生载流子的界面迁移和分离,同时使载流子具有更高的氧化还原能力。

京西山岭隧道爆破开挖方案比选

国道109高速十工区清水1号山岭隧道进口开挖爆破掘进1700 m,由于工期紧、任务重、要求高,项目部根据相关规程,对多方案进行比较选用最适应的方案,计划采用劈裂棒非爆开挖方案、二氧化碳爆破方案、山岭隧道光面爆破方案等比选,推动施工进展,确保如期履约。经现场实际试验爆破,劈裂棒非爆开挖和二氧化碳爆破,从安全、进度、环保、经济成本方面均不能满足山岭隧道掘进开挖需求。