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Ionization Engineering of Hydrogels Enables Highly Efficient Salt‑Impeded Solar Evaporation and Night‑Time Electricity Harvesting 被引量:2
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作者 Nan He Haonan Wang +3 位作者 Haotian Zhang Bo Jiang Dawei Tang Lin Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期131-146,共16页
Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic ... Interfacial solar evaporation holds immense potential for brine desalination with low carbon footprints and high energy utilization.Hydrogels,as a tunable material platform from the molecular level to the macroscopic scale,have been considered the most promising candidate for solar evaporation.However,the simultaneous achievement of high evaporation efficiency and satisfactory tolerance to salt ions in brine remains a challenging scientific bottleneck,restricting the widespread application.Herein,we report ionization engineering,which endows polymer chains of hydrogels with electronegativity for impeding salt ions and activating water molecules,fundamentally overcoming the hydrogel salt-impeded challenge and dramatically expediting water evaporating in brine.The sodium dodecyl benzene sulfonate-modified carbon black is chosen as the solar absorbers.The hydrogel reaches a ground-breaking evaporation rate of 2.9 kg m−2 h−1 in 20 wt%brine with 95.6%efficiency under one sun irradiation,surpassing most of the reported literature.More notably,such a hydrogel-based evaporator enables extracting clean water from oversaturated salt solutions and maintains durability under different high-strength deformation or a 15-day continuous operation.Meantime,on the basis of the cation selectivity induced by the electronegativity,we first propose an all-day system that evaporates during the day and generates salinity-gradient electricity using waste-evaporated brine at night,anticipating pioneer a new opportunity for all-day resource-generating systems in fields of freshwater and electricity. 展开更多
关键词 Solar evaporation Hydrogel evaporators Salt impeding Ionization engineering Cyclic vapor-electricity generation
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Tree‑Inspired Structurally Graded Aerogel with Synergistic Water,Salt,and Thermal Transport for High‑Salinity Solar‑Powered Evaporation
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作者 Xiaomeng Zhao Heng Zhang +3 位作者 Kit‑Ying Chan Xinyue Huang Yunfei Yang Xi Shen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期19-37,共19页
Solar-powered interfacial evaporation is an energy-efficient solution for water scarcity.It requires solar absorbers to facilitate upward water transport and limit the heat to the surface for efficient evaporation.Fur... Solar-powered interfacial evaporation is an energy-efficient solution for water scarcity.It requires solar absorbers to facilitate upward water transport and limit the heat to the surface for efficient evaporation.Furthermore,downward salt ion transport is also desired to prevent salt accumulation.However,achieving simultaneously fast water uptake,downward salt transport,and heat localization is challenging due to highly coupled water,mass,and thermal transport.Here,we develop a structurally graded aerogel inspired by tree transport systems to collectively optimize water,salt,and thermal transport.The arched aerogel features root-like,fan-shaped microchannels for rapid water uptake and downward salt diffusion,and horizontally aligned pores near the surface for heat localization through maximizing solar absorption and minimizing conductive heat loss.These structural characteristics gave rise to consistent evaporation rates of 2.09 kg m^(-2) h^(-1) under one-sun illumination in a 3.5 wt%NaCl solution for 7 days without degradation.Even in a high-salinity solution of 20 wt%NaCl,the evaporation rates maintained stable at 1.94 kg m^(-2) h^(-1) for 8 h without salt crystal formation.This work offers a novel microstructural design to address the complex interplay of water,salt,and thermal transport. 展开更多
关键词 Composite aerogel Graded structure Solar-powered evaporation Thermal insulation Salt rejection
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Nitrogen-doped microporous graphite-enhanced copper plasmonic effect for solar evaporation
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作者 Xintao Wu Chengcheng Li +7 位作者 Ziqi Zhang Yang Cao Jieqiong Wang Xinlong Tian Zhongxin Liu Yijun Shen Mingxin Zhang Wei Huang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第3期215-223,共9页
Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Imp... Water scarcity is a global challenge,and solar evaporation technology offers a promising and eco-friendly solution for freshwater production.Photothermal conversion materials(PCMs)are crucial for solar evaporation.Improving photothermal conversion efficiency and reducing water evaporation enthalpy are the two key strategies for the designing of PCMs.The desired PCMs that combine both of these properties remain a challenging task,even with the latest advancements in the field.Herein,we developed copper nanoparticles(NPs)with different conjugated nitrogen-doped microporous carbon coatings(Cu@C–N)as PCMs.The microporous carbon enveloping layer provides a highly efficient pathway for water transport and a nanoconfined environment that protects Cu NPs and facilitates the evaporation of water clusters,reducing the enthalpy of water evaporation.Meanwhile,the conjugated nitrogen nodes form strong metal-organic coordination bonds with the surface of copper NPs,acting as an energy bridge to achieve rapid energy transfer and provide high solar-to-vapor conversion efficiency.The Cu@C–N exhibited up to 89.4%solar-to-vapor conversion efficiency and an evaporation rate of 1.94 kgm^(−2) h^(−1) under one sun irradiation,outperforming conventional PCMs,including carbon-based materials and semiconductor materials.These findings offer an efficient design scheme for high-performance PCMs essential for solar evaporators to address global water scarcity. 展开更多
关键词 NANOCONFINEMENT photothermal conversion materials plasmonic resonance seawater desalination solar evaporation
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Rebuilding the theory of isotope fractionation for evaporation of silicate melts under vacuum condition
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作者 Jie Wang Yun Liu 《Acta Geochimica》 EI CAS CSCD 2024年第4期661-676,共16页
Isotope eff ects are pivotal in understanding silicate melt evaporation and planetary accretion processes.Based on the Hertz-Knudsen equation,the current theory often fails to predict observed isotope fractionations o... Isotope eff ects are pivotal in understanding silicate melt evaporation and planetary accretion processes.Based on the Hertz-Knudsen equation,the current theory often fails to predict observed isotope fractionations of laboratory experiments due to its oversimplified assumptions.Here,we point out that the Hertz-Knudsen-equation-based theory is incomplete for silicate melt evaporation cases and can only be used for situations where the vaporized species is identical to the one in the melt.We propose a new model designed for silicate melt evaporation under vacuum.Our model considers multiple steps including mass transfer,chemical reaction,and nucleation.Our derivations reveal a kinetic isotopic fractionation factor(KIFF orα)αour model=[m(^(1)species)/m(^(2)species)]^(0.5),where m(species)is the mass of the reactant of reaction/nucleation-limiting step or species of diffusion-limiting step and superscript 1 and 2 represent light and heavy isotopes,respectively.This model can eff ectively reproduce most reported KIFFs of laboratory experiments for various elements,i.e.,Mg,Si,K,Rb,Fe,Ca,and Ti.And,the KIFF-mixing model referring that an overall rate of evaporation can be determined by two steps jointly can account for the eff ects of low P_(H2)pressure,composition,and temperature.In addition,we find that chemical reactions,diffusion,and nucleation can control the overall rate of evaporation of silicate melts by using the fitting slope in ln(−ln f)versus ln(t).Notably,our model allows for the theoretical calculations of parameters like activation energy(E_(a)),providing a novel approach to studying compositional and environmental eff ects on evaporation processes,and shedding light on the formation and evolution of the proto-solar and Earth-Moon systems. 展开更多
关键词 evaporation Kinetic isotopic fractionation Chemical kinetics Hertz-Knudsen equation CAIS
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Harnessing overlapped temperature-salinity gradient in solar-driven interfacial seawater evaporation for efficient steam and electricity generation
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作者 Peida Li Dongtong He +2 位作者 Jingchang Sun Jieshan Qiu Zhiyu Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期694-700,I0015,共8页
Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity grad... Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold. 展开更多
关键词 Solar-driven interfacial water evaporation Steam generation Electricity generation Seawater
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Systematic study of the synthesis of heavy and superheavy nuclei in 48Ca-induced fusion-evaporation reactions
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作者 Shi-Hao Zhu Tian-Liang Zhao Xiao-Jun Bao 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第7期157-172,共16页
We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applic... We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applicability of the model.To produce new proton-rich Fl and Lv isotopes through hot fusion reactions in the superheavy element region with Z≥104,we utilized the reactions ^(48)Ca+^(236,238,239) Pu and ^(48)Ca+^(242,243,244,250) Cm.However,owing to the detection limit of available equipment(0.1 pb),only 283Fl and 287−289Lv,which have the maximum evaporation residue cross section values of 0.149,0.130,9.522,and 0.309 pb,respectively,can be produced.Furthermore,to produce neutron-deficient isotopes of actinides near the proton drip line with Z=93−100,we attempted to generate the new isotopes(224−227Pu,228−232,237Cm)using the reactions ^(48)Ca+180,182,183 W and ^(48)Ca+^(184,186,187,192) Os.The maximum evaporation residue cross section values are 0.07,0.06,0.26,and 0.30 nb for the former set of reactions,and 1.96 pb,5.73 pb,12.16 pb,19.39 pb,54.79 pb,and 6.45 nb for the latter,respectively.These results are expected to provide new information for the future synthesis of unknown neutron-deficient isotopes. 展开更多
关键词 Dinuclear system(DNS)model evaporation residue cross section Neutron-deficient isotopes
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Influence of liquid film shape on evaporation performance of agitated thin film evaporator
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作者 顾鑫强 黄瑶 +1 位作者 邹鲲 彭倚天 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第8期305-314,共10页
The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of ... The agitated thin film evaporator(ATFE),which is known for its high efficiency,force the material to form a film through the scraping process of a scraper,followed by evaporation and purification.The complex shape of the liquid film inside the evaporator can significantly affect its evaporation capability.This work explores how change in shape of the liquid films affect the evaporation of the materials with non-Newtonian characteristics,achieved by changing the structure of the scraper.Examining the distribution of circumferential temperature,viscosity,and mass transfer of the flat liquid film shows that the film evaporates rapidly in shear-thinning region.Various wavy liquid films are developed by using shear-thinning theory,emphasizing the flow condition in the thinning area and the factors contributing to the exceptional evaporation capability.Further exploration is conducted on the spread patterns of the wavy liquid film and flat liquid film on the evaporation wall throughout the process.It is noted that breaking the wavy liquid film on the evaporating wall during evaporation is challenging due to its film-forming condition.For which the fundamental causes are demonstrated by acquiring the data regarding the flow rate and temperature of the liquid film.The definitive findings of the analysis reveal a significant improvement in the evaporation capability of the wavy liquid film.This enhancement is attributed to increasing the shear-thinning areas and maintaining the overall shape of the film throughout the entire evaporation process. 展开更多
关键词 liquid film shape shear-thinning fluids flow characteristics evaporative heat transfer
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Variations in evaporation from water surfaces along the margins of the Badain Jaran Desert over nearly 60 years and influencing factors
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作者 Li-juan Wang Zhe Wang +3 位作者 Gao-lei Jiang Zhen-long Nie Jian-mei Shen Sheng-hua Song 《Journal of Groundwater Science and Engineering》 2024年第3期253-263,共11页
Based on meteorological data collected over nearly 60 years(1960-2017)from four national meteorological stations along the margins of the Badain Jaran Desert,this study analyzed the spatiotemporal variations in evapor... Based on meteorological data collected over nearly 60 years(1960-2017)from four national meteorological stations along the margins of the Badain Jaran Desert,this study analyzed the spatiotemporal variations in evaporation from water surfaces and identified the dominant controlling factors.Methods used included linear trend analysis,linear tendency estimation,the departure method,the rank correlation coefficient-based method,and Multiple Linear Regression(MLR).Results indicate notable spatiotemporal differences in evaporation distribution and evolution.Spatially,average annual evaporation exhibited a pronounced altitude effect,decreasing at a rate of about 8.23 mm/m from east to west with increasing altitude.Temporally,annual evaporation showed significant upward trends after 1996 at the northeastern(Guaizi Lake)and western(Dingxin)margins,with rates of 132 mm/10a and 105 mm/10a,respectively.Conversely,along the northwestern(Ejina Banner)and southern(Alxa Right Banner)margins of the desert,an evaporation paradox was observed,with annual evaporation trending downward at rates of 162 mm/10a and 187 mm/10a,respectively,especially after 1987.The dominant factors controlling evaporation varied spatially:Average annual temperature and relative humidity influended the western margin(Dingxin),average annual temperature was the key factor for the northeastern margin(Guaizi Lake),and average wind speed was crucial for the northern(Ejina Banner)and southern(Alxa Right Banner)margins. 展开更多
关键词 evaporation from water surface evaporation paradox Dominant controlling factor Variation trend
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Evaluation of Water Losses by Evaporation in the Nakanbe Basin
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作者 Bayala Alfred Kabre Sayouba +5 位作者 Yonli Hamma Fabien Chesneau Xavier Thierry Sikoudouin Maurice Ky Zeghmati Belkacem Kieno P. Florent Kam Sié 《Atmospheric and Climate Sciences》 2024年第1期29-41,共13页
A numerical approach to heat and mass transfer in a large water reservoir is presented. This water reservoir is likened to a parallelepiped reservoir whose vertical and lower walls are adiabatic and impermeable. The e... A numerical approach to heat and mass transfer in a large water reservoir is presented. This water reservoir is likened to a parallelepiped reservoir whose vertical and lower walls are adiabatic and impermeable. The equations that govern natural convection in water are solved by the finite volume method and Thomas’salgorithm. The adequacy between the velocity and pressure fields is ensured by the SIMPLE algorithm. We are going to evaluate the water losses by evaporation from three dams in the Nakanbé basin in Burkina Faso for a period of thirty years, that is to say from January 1, 1991, to March 15, 2020. The three dams have a rate of evaporation greater than 40% of the volume of water stored. Indeed the rate of evaporation in each dam increases with the water filling rate in the reservoir: we have observed the following results for each dam in the Nakanbé basin;for the date of 02/27/1988 to 03/13/2020., the Loumbila dam received a total volume of stored water of 22.02 Mm<sup>3</sup> and 10.57 Mm<sup>3</sup> as the total volume of water evaporated at the same date. At the Ouaga dam (2 + 3), it stored a water volume of 4.06 Mm<sup>3</sup> and evaporated 2.03 Mm<sup>3</sup> of its storage volume from 01/01/1988 to 05/07/2016. Finally, with regard to the Bagré dam, it stored 745.16 Mm<sup>3</sup> of water and 365.13 Mm<sup>3</sup> as the volume of water evaporated from 01/01/1993 to 03/31/2020. 展开更多
关键词 Numerical Study evaporation Meteorological Data Natural Convection BASINS DAMS
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Water Photomolecular Evaporation Due to Light-Mediated Ortho-Para Spin Transitions
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作者 Sergey Pershin Irina Bjørnø Michael Grishin 《Open Journal of Applied Sciences》 2024年第8期2201-2206,共6页
Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis tha... Recent discoveries have revealed a groundbreaking phenomenon where light alone, without any thermal input, can induce water evaporation, termed the “photomolecular effect”. This study explores a novel hypothesis that this effect can be explained by ortho-para magnetic spin interactions in water molecules within the water-air interface layer. Water molecules, consisting of hydrogen and oxygen, exhibit different nuclear spin states: ortho-(triplet) and para-(singlet). The interaction of polarized light with these spin states may induce transitions between the rotational levels of ortho- and para-forms due to catalysts like triplet oxygen (O2) in its inhomogeneous magnetic field. Resonance pumping at 532 nm (~18,797 cm−1) due to the transition v1-v2-v3 ~ 0-8-2 (~18,796 cm−1) results in an increase in molecular energy sufficient to overcome intermolecular forces at the water surface, thereby causing evaporation. The proposed ortho-para conversion mechanism involves spin-orbit coupling and specific resonance conditions. This theory provides a quantum mechanical perspective on the photomolecular effect, potentially offering insights into natural processes such as cloud formation and climate modeling, as well as practical applications in solar desalination and industrial drying. Further experimental validation is required to confirm the role of spin interactions in light-induced water evaporation. 展开更多
关键词 Ortho-Para Spin Transition Water Structure evaporation Theory Photo Molecular Effect
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Recentadvancesincarbon‐basedmaterials for solar‐driven interfacial photothermal conversion water evaporation:Assemblies,structures,applications,and prospective 被引量:6
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作者 Yanmin Li Yanying Shi +4 位作者 Haiwen Wang Tiefeng Liu Xiuwen Zheng Shanmin Gao Jun Lu 《Carbon Energy》 SCIE EI CAS CSCD 2023年第11期101-142,共42页
The shortage of fresh water in the world has brought upon a serious crisis to human health and economic development.Solar‐driven interfacial photothermal conversion water evaporation including evaporating seawater,la... The shortage of fresh water in the world has brought upon a serious crisis to human health and economic development.Solar‐driven interfacial photothermal conversion water evaporation including evaporating seawater,lake water,or river water has been recognized as an environmentally friendly process for obtaining clean water in a low‐cost way.However,water transport is restricted by itself by solar energy absorption capacity's limits,especially for finite evaporation rates and insufficient working life.Therefore,it is important to seek photothermal conversion materials that can efficiently absorb solar energy and reasonably design solar‐driven interfacial photothermal conversion water evaporation devices.This paper reviews the research progress of carbon‐based photothermal conversion materials and the mechanism for solar‐driven interfacial photothermal conversion water evaporation,as well as the summary of the design and development of the devices.Based on the research progress and achievements of photothermal conversion materials and devices in the fields of seawater desalination and photothermal electric energy generation in recent years,the challenges and opportunities faced by carbon‐based photothermal conversion materials and devices are discussed.The prospect of the practical application of solar‐driven interfacial photothermal conversion evaporation technology is foreseen,and theoretical guidance is provided for the further development of this technology. 展开更多
关键词 APPLICATIONS carbon‐based materials EVAPORATOR photothermal conversion water evaporation
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Micro–Nano Water Film Enabled High‑Performance Interfacial Solar Evaporation 被引量:1
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作者 Zhen Yu Yuqing Su +3 位作者 Ruonan Gu Wei Wu Yangxi Li Shaoan Cheng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第11期503-517,共15页
Interfacial solar evaporation holds great promise to address the freshwater shortage.However,most interfacial solar evaporators are always filled with water throughout the evaporation process,thus bringing unavoidable... Interfacial solar evaporation holds great promise to address the freshwater shortage.However,most interfacial solar evaporators are always filled with water throughout the evaporation process,thus bringing unavoidable heat loss.Herein,we propose a novel interfacial evaporation structure based on the micro–nano water film,which demonstrates significantly improved evaporation performance,as experimentally verified by polypyrrole-and polydopamine-coated polydimethylsiloxane sponge.The 2D evaporator based on the as-prepared sponge realizes an enhanced evaporation rate of 2.18 kg m^(−2)h^(−1)under 1 sun by fine-tuning the interfacial micro–nano water film.Then,a homemade device with an enhanced condensation function is engineered for outdoor clean water production.Throughout a continuous test for 40 days,this device demonstrates a high water production rate(WPR)of 15.9–19.4 kg kW^(−1)h^(−1)m^(−2).Based on the outdoor outcomes,we further establish a multi-objective model to assess the global WPR.It is predicted that a 1 m^(2)device can produce at most 7.8 kg of clean water per day,which could meet the daily drinking water needs of 3 people.Finally,this technology could greatly alleviate the current water and energy crisis through further large-scale applications. 展开更多
关键词 Micro–nano water film Interfacial solar evaporation Solar desalination Artificial neural networks PPy sponge
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Facile synthesis of chromium chloride/poly(methyl methacrylate) core/shell nanocapsules by inverse miniemulsion evaporation method and application as delayed crosslinker in secondary oil recovery
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作者 Jing-Yang Pu Keith P.Johnston +4 位作者 Ping-Keng Wu Muaaz Ahmad Ming-Liang Luo Na Zhang Ju-Tao He 《Petroleum Science》 SCIE EI CAS CSCD 2023年第1期396-406,共11页
Cr(III)ehydrolyzed polyacrylamide(HPAM)gels have been extensively studied as a promising strategy controlling waste water production for mature oilfields.However,the gelation time of the current technologies is not lo... Cr(III)ehydrolyzed polyacrylamide(HPAM)gels have been extensively studied as a promising strategy controlling waste water production for mature oilfields.However,the gelation time of the current technologies is not long enough for in-depth placement.In this study,we report a novel synthesis method to obtain chromium chloride/poly(methyl methacrylate)(PMMA)nanocapsules which can significantly delay the gelation of HPAM through encapsulating the chromium chloride crosslinker.The chromium chloride-loaded nanocapsules(CreNC)are prepared via a facile inverse miniemulsion evaporation method during which the hydrophobic PMMA polymers,pre-dispersed in an organic solvent,were carefully controlled to precipitate onto stable aqueous miniemulsion droplets.The stable aqueous nanodroplets(W)containing Cr(III)are dispersed in a mixture of organic solvent(O1)with PMMA and nonsolvent medium(O2)to prepare an inverse miniemulsion.With the evaporation of the O1,PMMA forms CreNCs around the aqueous droplets.The CreNCs are readily transferred into water from the organic nonsolvent phase.The CreNCs exhibit the tunable size(358-983 nm),Cr loading(7.1%-19.1%),and Cr entrapment efficiency(11.7%-80.2%),with tunable zeta potentials in different PVA solutions.The CreNCs can delay release of Cr(III)and prolong the gelation time of HPAM up to 27 days. 展开更多
关键词 NANOCAPSULES Inverse miniemulsion evaporation Chromium chloride crosslinker HPAM gelation Secondary oil recovery
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Janus membrane with enhanced interfacial activation for solar evaporation
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作者 Hao Chen Guangze Pan +3 位作者 Mei Yan Fang Wang Yadong Wu Chongshen Guo 《Journal of Energy Chemistry》 SCIE EI CSCD 2023年第12期1-11,I0002,共12页
Low solar spectrum coverage,high evaporation enthalpy,and undesired salt deposition severely limited the solar-driven interfacial evaporation technology for further sewage purification and seawater desalination.To ove... Low solar spectrum coverage,high evaporation enthalpy,and undesired salt deposition severely limited the solar-driven interfacial evaporation technology for further sewage purification and seawater desalination.To overcome these problems,we designed an amphiphilic Janus-structured polyaniline(PANI)/ZrC/cellulose acetate(CA)(J-PZCA) membrane.Firstly,the interfacial interaction between PANI and ZrC enhances the photoabsorption and photothermal conversion efficiency.Secondly,low thermal conductivity reduces the heat lost at the interface.Most importantly,ZrC could facilitate interfacial activation,which weakens the intermolecular forces of water by affecting the hydrogen bond.Under 1 solar irradiation(1 sun),the composite membrane exhibits a high evaporation rate of 1.31 kg m^(-2)h^(-1) and an excellent efficiency of 79.4%.In addition,the sewage purification and seawater desalination experiments reveal a remarkable purification capability of J-PZCA membrane.Especially for the treatment of high-concentration salt solution,it realizes a long-term stable evaporation performance due to the excellent salt deposition resistance.Therefore,the J-PZCA membrane constructed in this study provides a new perspective for the design of efficient interfacial evaporation devices. 展开更多
关键词 Interfacial water evaporation Photothermal synergy Interfacial activation ZRC PANI
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Controllable growth of wafer-scale PdS and PdS_(2) nanofilms via chemical vapor deposition combined with an electron beam evaporation technique
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作者 Hui Gao Hongyi Zhou +6 位作者 Yulong Hao Guoliang Zhou Huan Zhou Fenglin Gao Jinbiao Xiao Pinghua Tang Guolin Hao 《Journal of Semiconductors》 EI CAS CSCD 2023年第12期64-71,共8页
Palladium(Pd)-based sulfides have triggered extensive interest due to their unique properties and potential applications in the fields of electronics and optoelectronics.However,the synthesis of large-scale uniform Pd... Palladium(Pd)-based sulfides have triggered extensive interest due to their unique properties and potential applications in the fields of electronics and optoelectronics.However,the synthesis of large-scale uniform PdS and PdS_(2)nanofilms(NFs)remains an enormous challenge.In this work,2-inch wafer-scale PdS and PdS_(2) NFs with excellent stability can be controllably prepared via chemical vapor deposition combined with electron beam evaporation technique.The thickness of the pre-deposited Pd film and the sulfurization temperature are critical for the precise synthesis of PdS and PdS_(2) NFs.A corresponding growth mechanism has been proposed based on our experimental results and Gibbs free energy calculations.The electrical transport properties of PdS and PdS_(2) NFs were explored by conductive atomic force microscopy.Our findings have achieved the controllable growth of PdS and PdS_(2) NFs,which may provide a pathway to facilitate PdS and PdS_(2) based applications for next-generation high performance optoelectronic devices. 展开更多
关键词 PDS PdS_(2) NANOFILMS controllable growth chemical vapor deposition electron beam evaporation
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Effects of Groundwater with Various Salinities on Evaporation and Redistribution of Water and Salt in Saline-sodic Soils in Songnen Plain,Northeast China
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作者 ZHU Wendong ZHAO Dandan +6 位作者 YANG Fan WANG Zhichun DONG Shide AN Fenghua MA Hongyuan ZHANG Lu TIBOR Tóth 《Chinese Geographical Science》 SCIE CSCD 2023年第6期1141-1152,共12页
Groundwater mineralization is one of the main factors affecting the transport of soil water and salt in saline-sodic areas.To investigate the effects of groundwater with different levels of salinity on evaporation and... Groundwater mineralization is one of the main factors affecting the transport of soil water and salt in saline-sodic areas.To investigate the effects of groundwater with different levels of salinity on evaporation and distributions of soil water and salt in Songnen Plain,Northeast China,five levels of groundwater sodium adsorption ration of water(SARw)and total salt content(TSC mmol/L)were conducted in an oil column lysimeters.The five treated groundwater labeled as ST0:0,ST0:10,ST5:40,ST10:70 and ST20:100,were prepared with NaCl and CaCl2 in proportion,respectively.The results showed the groundwater evaporation(GWE)and soil evaporation(SE)increased firstly and then decreased with the increase of groundwater salinity.The values of GWE and SE in ST10:70 treatment were the highest,which were 2.09 and 1.84 times the values in the ST0:0 treatment with the lowest GWE and SE.There was a positive linear correlation between GWE and the Ca^(2+)content in groundwater,with R^(2)=0.998.The soil water content(SWC)of ST0:0 treatment was significantly(P<0.05)less than those of other treatments during the test.The SWC of the ST0:0 and ST0:10 treatments increased with the increase of soil depth,while the other treatments showed the opposite trend.Statistical analysis indicated the SWC in the 0–60 cm soil layer was positively correlated with the groundwater TSC and its ion contents during the test.Salt accumulation occurred in the topsoil and the salt accumulation in the 0–20 cm soil layer was significantly(P<0.05)greater than that in the subsoil.This study revealed the effects of the salinity level of groundwater,especially the Ca^(2+)content and TSC of groundwater,on the GWE and distributions of soil water and salt,which provided important support for the prevention and reclamation of soil salinization and sodificaton in shallow groundwater regions. 展开更多
关键词 groundwater evaporation sodium adsorption ratio total salt content ion composition soil salinization water and salt dynamics Songnen Plain China
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Boosting extraction of Pb in contaminated soil via interfacial solar evaporation of multifunctional sponge
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作者 Pan Wu Xuan Wu +3 位作者 Yida Wang Jingyuan Zhao Haolan Xu Gary Owens 《Green Energy & Environment》 SCIE EI CAS CSCD 2023年第5期1459-1468,共10页
Interfacial solar water evaporation is a reliable way to accelerate water evaporation and contaminant remediation.Embracing the recent advance in photothermal technology,a functional sponge was prepared by coating a s... Interfacial solar water evaporation is a reliable way to accelerate water evaporation and contaminant remediation.Embracing the recent advance in photothermal technology,a functional sponge was prepared by coating a sodium alginate(SA)impregnated sponge with a surface layer of reduced graphene oxide(rGO)to act as a photothermal conversion medium and then subsequently evaluated for its ability to enhance Pb extraction from contaminated soil driven by interfacial solar evaporation.The SA loaded sponge had a Pb adsorption capacity of 107.4 mg g^(-1).Coating the top surface of the SA sponge with rGO increased water evaporation performance to 1.81 kg m^(-2)h^(-1)in soil media under one sun illumination and with a wind velocity of 2 m s^(-1).Over 12 continuous days of indoor evaporation testing,the Pb extraction efficiency was increased by 22.0%under 1 sun illumination relative to that observed without illumination.Subsequently,Pb extraction was further improved by 48.9%under outdoor evaporation conditions compared to indoor conditions.Overall,this initial work shows the significant potential of interfacial solar evaporation technologies for Pb contaminated soil remediation,which should also be applicable to a variety of other environmental contaminants. 展开更多
关键词 Photothermal materials Interfacial solar evaporation Reduced graphene oxide Pb extraction Soil remediation
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Experimental study on the desulfurization and evaporation characteristics of Ca(OH)_(2) droplets
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作者 Yilin Song Yize Zhang Hao Zhou 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期127-135,共9页
The experiments were conducted to focus on the desulfurization and evaporation characteristics of lime slurry droplets at 298-383 K. We designed an evaporation-reaction chamber with quartz glass windows.The monodisper... The experiments were conducted to focus on the desulfurization and evaporation characteristics of lime slurry droplets at 298-383 K. We designed an evaporation-reaction chamber with quartz glass windows.The monodisperse slurry droplet stream was injected into the evaporation reaction chamber, and the inlet gas components(air, air + SO_(2)) were introduced into the chamber. We applied the magnified digital in-line holography to measure the droplet parameters and calculated the evaporation rate. The effects of temperature, droplet concentration, and SO_(2) concentration on the evaporation rate of Ca(OH)_(2) droplets were discussed. Moreover, the Ca(OH)_(2) droplets under different experimental conditions were sampled,and the droplets were observed and analyzed using an off-line microscope. The evaporation rate of the Ca(OH)_(2) droplet increased at first, and then decreased during the falling process, and remained constant at last. The average evaporation rate of the Ca(OH)_(2) droplets increased significantly with the temperature increasing. 展开更多
关键词 Magnified digital in-line holography evaporation Gas–liquid absorption reaction Ca(OH)_(2) Micro-droplet
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A Model for Droplet Evaporation
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作者 Pirooz Mohazzabi Gabrielle A. Richardson Gwendolyn A. Richardson 《Journal of Applied Mathematics and Physics》 2023年第7期1837-1845,共9页
Based on the kinetic theory of gases, a simple model for droplet vaporization, in particular mercury, is developed to study the variation of droplet radius as a function of time. This model is in agreement with more s... Based on the kinetic theory of gases, a simple model for droplet vaporization, in particular mercury, is developed to study the variation of droplet radius as a function of time. This model is in agreement with more sophisticated models for water, such as the kinetic model and the Kulmala model. Findings indicate that complete evaporation of a 1-mm-radius mercury droplet, in a ventilated room at normal temperatures, should take about 1.8 × 10<sup>4</sup> seconds or 5 hours. The findings of this study can be utilized to direct further research in the field of toxin remediation. 展开更多
关键词 evaporation RATE MERCURY DROPLET RADIUS
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Effects of Different Thicknesses of Gravel Covering on Daily Soil Evaporation 被引量:1
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作者 周约 谢铁娜 《Agricultural Science & Technology》 CAS 2015年第10期2347-2349,2353,共4页
[Objective] The research aimed to explore the most suitable gravel cover- ing thickness for selenium sand melon in arid region of central Ningxia. [Method] The natural gravel, which was from Nanshantai Region in Zhong... [Objective] The research aimed to explore the most suitable gravel cover- ing thickness for selenium sand melon in arid region of central Ningxia. [Method] The natural gravel, which was from Nanshantai Region in Zhongwei City, Ningxia, was acted as test materials to study the effects of different thicknesses of gravel covering on daily evaporation using evaporator overall weighing method. [Result] The daily evaporation capacity order of the gravel covering thickness was as follows: CK〉HI(5 cm)〉 H2(8 cm)〉 H3(10 cm)〉 H4(15 cm). Meanwhile, with the increase of test days, the difference of cumulative evaporation capacity between H3 (10 cm) and H4 (15 cm) decreased gradually. Soil evaporation capacity reduced at the pow- er function with the increase of gravel covering thickness, and the decision coeffi- cient of the fitted curve reached to 0.925 5. [Conclusion] With the increase of gravel covering thickness, evaporation capacity of soil reduced gradually, and the soil water content increased gradually. Gravel covering could effectively reduce the evapora- tion. The thicker of covering, the more obvious inhibition effect on evaporation. The thickness of covering should increase moderately to prevent moisture loss from e- vaporation. Gravel inhibition effect on the evaporation wasn't obvious when the gravel covering thickness reached more than 10 cm. 10 cm gravel covering was the most appropriate thickness for local natural condition. The soil evaporation capacity along with the change of gravel covering could be simulated with power function e- quation Y=at^b. 展开更多
关键词 Thickness Gravel covering Soil evaporation
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