The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus ar...The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.展开更多
The mantle xenoliths in the Quaternary ChangbaishanVolcano in southern Jilin Province contain spinel-facies lherzolites. The equilibration temperatures for these samples range from 902℃ to 1064℃ based on the two-pyr...The mantle xenoliths in the Quaternary ChangbaishanVolcano in southern Jilin Province contain spinel-facies lherzolites. The equilibration temperatures for these samples range from 902℃ to 1064℃ based on the two-pyroxene thermometer of Brey and Kohler (1990), and using the oxybarometry of Nell and Wood (1991), the oxidation state was estimated from FMQ-1.32 to -0.38 with an average value of FMQ-0.81 (n = 8), which is comparable to that of abyssal peridotites and the asthenospheric mantle. ThefO2 values of peridotites, together with their bulk rock compositions (e.g., Mg#, Al2O3, CaO, Ni, Co, Cr) and mineral compositions (e.g., Mg# of olivine and pyroxene, Cr# [=Cr/ [Cr+Al]] and Mg# [=Mg/[Mg+Fe2~] of spinel), suggest that the present-day subcontinental lithospheric mantle (SCLM) beneath the Changbaishan Volcano most likely formed from an upwelling asthenosphere at some time after the late Mesozoic and has undergone a low degree of partial melting. The studied lherzolite xenoliths show low concentrations of S, Cu, and platinum group elements (PGE), which plot a flat pattern on primitive-mantle normalized diagram. Very low concentrations in our samples suggest that PGEs occur as alloys or hosted by silicate and oxide minerals. The compositions of the studied samples are similar to those of peridotite xenoliths in the Longgang volcanic field (LVF) in their mineralogy and bulk rock compositions including the abundance of chalcophile and siderophile elements. However, they are distinctly different from those of peridotite xenoliths in other areas of the North China Craton (NCC) in terms of Cu, S and PGE. Our data suggest that the SCLM underlying the northeastern part of the NCC may represent a distinct unit of the newly formed lithospberic mantle.展开更多
Objective The North China Craton (NCC) is a large Archean craton with a long geological history, yet very few studies have been carried out on the evolution of the redox conditions of its underlying mantle. Oxidati...Objective The North China Craton (NCC) is a large Archean craton with a long geological history, yet very few studies have been carried out on the evolution of the redox conditions of its underlying mantle. Oxidation state of the mantle is critical in controlling the formation of metallic mineral deposits because metals can be readily released from the mantle to partial melt under oxidized conditions. In contrast, highly reduced and stable conditions are essential for the crystallization of diamond. The subcontinental lithospheric mantle (SCLM) beneath major cratons in the world has been stable since their formation and highly reduced in its oxidation state, but the SCLM below the NCC is different.展开更多
The compositions of the whole rocks and trace elements of minerals in peridotites can reflect the characteristics of the lithospheric mantle. The nature and evolution of the Cenozoic lithospheric mantle beneath Hannuo...The compositions of the whole rocks and trace elements of minerals in peridotites can reflect the characteristics of the lithospheric mantle. The nature and evolution of the Cenozoic lithospheric mantle beneath Hannuoba (汉诺坝), located on the north edge of the intra-North China orogenic belt, are discussed based on the in-situ LAM-ICPMS detected trace element compositions of clinopyroxenes in the Hannuoba peridotitic xenoliths combined with detailed petrography and geochemistry studies. The Hannuoba lithospheric mantle was formed by different partial meltings of the primitive mantle. Most of the samples reflect the partial melting degree of lower than 5% with a few samples of 15%-20%. Major element compositions of the whole rocks and geochemical compositions of clinopyroxenes reveal the coexistence of both fertile and depleted mantle underneath the Hannuoba region during the Cenozoic. This was probably caused by the asthenospheric mantle replacing the aged craton mantle through erosion, intermingling and modification. Our conclusion is further supported by the existence of both carbonatitic magmatic material and silicate melt/ fluid metasomatism as magnified by the trace elements of the clinopyroxencs from the Hannuoba lithospherJc mantle.展开更多
Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental ri...Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental rift basalts in Northeast and North China;2)the tension-fault basalts on the continental margins of Southeast China; and 3) the collision-zone high-K volcanics in the Qinghai-Xizang Plateau and its vicinities.The characteristics of 'depletion in the south and enrichment in the north'of the China continental mantle are strongly supported by isotopic evidence.The Cenozoic continental cal characters,into the following geochemical provinces:1)the depleted mantle in South China;2)the primary mantle in Northeast and NorthChina; 3)the hybrid and transi-tional mantle in the region of Shandong ,Anhui,Jiangsu and northern Zhejiang;4)the depleted mantle around the Bohai Bay and the Lower Liaohe River;5)the K-metasomatic enriched mantle in the northern part of Northeast China;and 6)the re-cycled enriched mantle in the ancient subduction zone in the Qinghai-Xizang Plateau and its surround-ings.These geochemical characteristics on a regional scale must be a reflection of the nature of lithosphere evolution.展开更多
Serpentinized peridotites in the Yangkou(YK),Suoluoshu(SLS) and Hujialin(HJL) areas in the Sulu ultrahighpressure terrane represent the relic of ancient subcontinental lithospheric mantle below the North China Craton....Serpentinized peridotites in the Yangkou(YK),Suoluoshu(SLS) and Hujialin(HJL) areas in the Sulu ultrahighpressure terrane represent the relic of ancient subcontinental lithospheric mantle below the North China Craton.Their protoliths,harzburgite and dunite,were variably hydrated by aqueous fluids released from subducting Yangtze continent.The rocks are enriched in fluid-mobile elements(FME) including Sb(42–333 times the depleted mantle value) and Pb(30–476 times).The degrees of the FME enrichment are comparable to that of the Himalayan forearc serpentinites,and greater than forearc mantle serpentinites from Marianas,suggesting that the degrees of FME enrichment in the forearc serpentinites are greater in continental subduction zones than those in the oceanic subduction zones.Lizardite after olivine in the SLS serpentinite shows higher degrees of enrichment in Sb and As than those for antigorite after both olivine and orthopyroxene in the YK area.The antigorite has highly enriched in Pb,U,Cs,and LREE,but not for the lizardite.The abundance of FME in two different species of serpentine reflects the different temperature of hydration.At temperature lower than 300 ℃,formed lizardite at shallow depths of the mantle wedge incorporates elements that are fluid mobile at low temperatures,such as Sb and As.When the temperature greater than 300 ℃,formed antigorite at a relatively deep mantle wedge incorporate more FME from the subducting continental slab(or fragments),including Pb,U,Cs,LREE as well as Sb and As.The eventual breakdown of antigorite(600–700 ℃) in prograde metamorphism would discharge water as well as FME into the subducting channel and/or the overlying mantle.展开更多
The nature and evolution of the lithospheric mantle underlying Northeast(NE)China were investigated by assessing the mineral chemistry,water contents,and noble gas(He-Ar)isotopes of peridotite xenoliths captured by Ce...The nature and evolution of the lithospheric mantle underlying Northeast(NE)China were investigated by assessing the mineral chemistry,water contents,and noble gas(He-Ar)isotopes of peridotite xenoliths captured by Cenozoic basalts from the Changbaishan and Longgang regions.The xenoliths,which have863–1141℃ equilibration temperatures,primarily comprise spinel lherzolites and rare spinel harzburgites.The Mg#(Fo)values of olivine in the peridotite xenoliths vary from 86.9 to 91.3.The clinopyroxenes have high Ti/Eu and low(La/Yb)N,and their chondrite-normalized rare earth elements(REEs)exhibit light REE-depletion to-enrichment patterns,indicating that the mantle underneath the investigated region was predominantly subjected to partial melting(1%–10%)and was metasomatized by silicate melts.The measured3He/4He ratios of the Changbaishan xenoliths have a narrow range from 5.8 Ra to 8.4 Ra with an average of 7.4 Ra.The3He/4He isotopic ratios of the Longgang xenoliths varied from 4.7 Ra to8.1 Ra with an average of 5.9 Ra;slightly lower than the Changbaishan xenoliths.The whole-rock H2Ocontents of the studied peridotite ranged from 9 to 132 ppm.The high H2O contents in excess of50 ppm(up to 132 ppm)might represent newly accreted and cooled asthenospheric materials,while those with H2O contents lower than 50 ppm(as little as 9 ppm)may represent thinned,relic,ancient lithospheric mantle.These geochemical evidences,in combination with published data,indicated that the lithospheric mantle beneath the Changbaishan and Longgang in NE China is dominated by the younger and more fertile lithospheric mantle with a minor ancient and refractory keel.In addition,the lithospheric mantle of this area was metasomatized by melts related to the recent subduction event(e.g.,Pacific oceanic plate).Therefore,the westward-dipping Pacific oceanic plate subduction had an important contribution to the transformation of the lithospheric mantle beneath NE China.展开更多
The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The ^(187)Os/^(188)Os ratio o...The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The ^(187)Os/^(188)Os ratio of the sample set ranges from 0.119 to 0.129 (25 samples, USTC) and from 0.117 to 0.131 (17 samples, CRPG). The Os isotopic compositions of most samples are less than 0.129 and depleted relatively to the primitive mantle, showing a good correlation with the major element compositions. With the ^(187)Os/^(188)Os-AI2O3 alumichron, the samples yield a model age of 2.5±0.1 Ga (data of USTC) and 1.9±0.1 Ga (data of CRPG), late Archean to early Pro-terozoic. The two samples with the lowest ^(187)Os/^(188)Os ratio (0.119 and 0.117) have the T_(RD) (Re depleted age) of 1.1 Ga (USTC) and 1.4 Ga (CRPG), mid-Proterozoic. The Os isotope model age shows that the peridotite xenoliths from Cenozoic alkali basalt in Jiangsu-Anhui provinces have an old formation age (early- to mid- Proterozoic). They are not newly produced mantle after the Phanerozoic replacement of the lithosphere mantle, but residual fractions of Proterozoic mantle.展开更多
The components and evolution of subcontinental lithospheric mantle beneath the North China Craton and the Yangtze Craton is a current topic in the geological study of China and the carbon isotopic composition of diamo...The components and evolution of subcontinental lithospheric mantle beneath the North China Craton and the Yangtze Craton is a current topic in the geological study of China and the carbon isotopic composition of diamond is one of the most direct probes into cratonic lithospheric mantle processes.In this paper,in-situ SIMS(Secondary Ion Mass Spectrometry) techniques were used to analyze the carbon isotope compositions at different internal growth zones of diamonds from Shandong and Liaoning in the North China Craton and Hunan in the Yangtze Craton.It was found that the carbon isotopic range of diamonds from the North China Craton are rather distinct from those of the Yangtze Craton;the former has a range of 6.0‰ to 2.0‰(relative to VPDB) with an average value of 3.0‰ in their core areas,which is consistent with global peridotitic diamonds;the diamonds from the Yangtze Craton,however,have a carbon isotopic range from 8.6‰ to 3.0‰ with an average value of 7.4‰ in their core areas,being more consistent with global eclogitic diamonds.The variations of carbon isotope ratios between different internal growth zones in individual diamonds were different in the three diamond localities studied.There was a clear correlation between changes in carbon isotopic composition and phases of diamond dissolution and new growth,while no correlation was observed between δ13C and internal inclusions.The variations suggest that the carbon isotopic compositions of mantle fluids were changing during the process of diamond crystallization,and that the heterogeneity of the carbon isotopic composition in mantle carbon reservoirs was a more important factor than carbon isotope fractionation in controlling the carbon isotopic compositions and their variation in diamonds.In addition,the preliminary results of in-situ nitrogen analyses demonstrated that the variation of carbon isotopic compositions between the core and outer growth zones does not correlate with nitrogen abundances,implying either that diamonds crystallized in an open environment or that the carbon isotopic composition and nitrogen contents in mantle fluids were controlled by other,not yet understood factors.The experimental results provide hints that the isotopic composition of carbon and its original sources were different in metasomatic fluids controlling diamond formation in the mantle beneath the North China Craton and the Yangtze Craton.展开更多
Geochemical comparison of two suites of Cenozoic potassic volcanic rocks in western Yunnan reveals the existence of two mantle domains beneath this region, which corre- spond to their respective tectonic affinity. The...Geochemical comparison of two suites of Cenozoic potassic volcanic rocks in western Yunnan reveals the existence of two mantle domains beneath this region, which corre- spond to their respective tectonic affinity. The Erhai ultrapotassic rocks (42—24Ma) in western Yangtze Craton are characterized by LILE enrichment, HFSE depletion, low TiO2 content (<1%), high initial Sr/86Sr (0.7064—0.7094) and negative εNd (?3.84—?4.64). Geochemically similar to 87 K-rich volcanism in subduction setting, they were probably originated from a refractory spinel harzburgitic source metasomatized by subduction-related fluids. In contrast, the Maguan potas- sic magmas (<16Ma) in the South China Block show an OIB-type trace elemental signature, high TiO2 content (>2%), low initial 87 Sr/86Sr (0.7041—0.7060) and positive εNd (5.46—7.03). These features resemble the typical intraplate potassic rocks around the world. These rocks are thus interpreted as melting products of a fertile garnet lherzolitic source which has been infiltrated by small-volume, asthenosphere-derived silicate melts. The temporal and spatial distribution of these two types of K-rich rocks cannot be explained by any unified tectonic model. It is proposed that the Oligocene magmatism in the Erhai area may have resulted from convective thinning of the thickened lithosphere, whereas the post-Miocene volcanism in the Maguan area was related to the opening of South China Sea.展开更多
Minerals of spinel- and garnet-facies mantle xenoliths entrained in Cenozoicbasalts from eastern China (North China, Northeastern China and Southeastern China coastal area)contains lots of melt inclusions. Studies on ...Minerals of spinel- and garnet-facies mantle xenoliths entrained in Cenozoicbasalts from eastern China (North China, Northeastern China and Southeastern China coastal area)contains lots of melt inclusions. Studies on these melt inclusions show that the glass inclusionsare rich in SiO_2 (60%—68%) and alkalis (K_2O+Na_2O = 5%—11%, especially for K_2O) as well asvolatiles such as H_2O and CO_2 (2%—7%), which belong to dacites and andesites of the high-K calcicalkali series rocks with few shoshonites. High Al and Ca diopside in melt inclusion is the productof melt crystallization at high temperature and pressure, rather than the product ofdevitrification. Results show that these K-rich (in general K_2O 】 3%) intermediate-acidic silicatemelt inclusions have characteristics of continent without a genetical link to host basalts and theirphenocrystic minerals. Thus, these trapped melt inclusions represent melts of Mesozoic lithosphericmantle-crust interaction and imply that the continental lithospheric mantle beneath eastern Chinahad undergone fragmentation and recreation processes during the Mesozoic and Cenozoic periods. Thisresult undoubtly provides important implication for the evolution of sub-continental lithospherebeneath eastern China. We propose that these Si- and alkalis-rich melts should be responsible forthe mantle chemical heterogeneity underneath eastern China.展开更多
Recent seismic studies reveal a sharp velocity drop mostly at^70–100 km depth within the thick mantle keel beneath cratons, termed the mid-lithosphere discontinuity(MLD). The common presence of the MLD in cratonic re...Recent seismic studies reveal a sharp velocity drop mostly at^70–100 km depth within the thick mantle keel beneath cratons, termed the mid-lithosphere discontinuity(MLD). The common presence of the MLD in cratonic regions indicates structural and property layering of the subcontinental lithospheric mantle(SCLM). The nature and origin of the MLD, and many issues associated with the layering of the SCLM are essential to understand the formation and evolution of continents, and have become frontier subjects in the Earth sciences.展开更多
The determination of the formation age of subcontinental Lithosphere Mantle (SCLM) is a widely concerned issue in mantle geochemistry. it is difficult to obtain the formation age of SCLM using lithophile isotopic syst...The determination of the formation age of subcontinental Lithosphere Mantle (SCLM) is a widely concerned issue in mantle geochemistry. it is difficult to obtain the formation age of SCLM using lithophile isotopic systems such as Rb-Sr, Sm-Nd, U-Th-Pb, ete., but as siderophile elements, the Re-Os isotopic system provides a powerful tool for that work. Here a comprehensive review on the recent development in Re-Os dating for SCLM has been given.展开更多
根据北部湾涠洲岛晚更新世火山岩中尖晶石二辉橄榄岩的矿物化学和形成条件推测,它们是来自地下约40km~50 km 的大陆岩石圈地幔样品。涠洲岛地幔橄榄岩中同时出现高硅(64%~68%)和低硅(49%~57%)两种熔体成分,它们普遍富碱、Al_2O_3和 H...根据北部湾涠洲岛晚更新世火山岩中尖晶石二辉橄榄岩的矿物化学和形成条件推测,它们是来自地下约40km~50 km 的大陆岩石圈地幔样品。涠洲岛地幔橄榄岩中同时出现高硅(64%~68%)和低硅(49%~57%)两种熔体成分,它们普遍富碱、Al_2O_3和 H_2O、CO_2等挥发组分(2%~5%)。研究认为,两种熔体存在不同的成因机制。高硅熔体可能与软流圈上升的玄武质岩浆和斜方辉石反应或下地壳物质循环进入地幔后的部分熔融有关。低硅熔体直接提供了富硅熔体与橄榄石发生交代作用的证据。这可以用富 SiO_2熔体+Ol→贫 SiO_2熔体+Opx 反应解释,其结果是消耗橄榄石生成斜方辉石。涠洲岛橄榄岩中两种熔体的发现,进一步提供了发生在大陆岩石圈地幔流(熔)体与橄榄岩交代作用的普遍性、复杂性,以及地幔熔体多样性的新证据。展开更多
基金supported by the National Natural Science Foundation of China(Nos.41472065 and 42073059).
文摘The experimental results of the reactions between an alkaline basaltic melt and mantle orthopyroxenes under high-temperature and high-pressure conditions of 1300–1400℃ and 2.0–3.0 GPa using a six-anvil apparatus are reported in this paper.The reactions are proposed to simulate the interactions between melts from the asthenospheric mantle and the lithospheric mantle.The starting melt in the experiments was made from the alkaline basalt occurring in Fuxin,Liaoning Province,and the orthopyroxenes were separated from the mantle xenoliths in Damaping,Hebei Province.The results show that clinopyroxenes were formed in all the reactions between the alkaline basaltic melt and orthopyroxenes under the studied P–T conditions.The formation of clinopyroxene in the reaction zone is mainly controlled by dissolution–crystallization,and the chemical compositions of the reacted melt are primarily infl uenced by the diff usion eff ect.Temperature is the most important parameter controlling the reactions between the melt and orthopyroxenes,which has a direct impact on the melting of orthopyroxenes and the diff usion of chemical components in the melt.Temperature also directly controls the chemical compositions of the newly formed clinopyroxenes in the reaction zone and the reacted melt.The formation of clinopyroxenes from the reactions between the alkaline basaltic melt and orthopyroxenes can result in an increase of CaO and Al_(2)O_(3) contents in the rocks containing this mineral.Therefore,the reactions between the alkaline basaltic melt from the asthenospheric mantle and orthopyroxenes from the lithospheric mantle can lead to the evolution of lithospheric mantle in the North China Craton from refractory to fertile with relatively high CaO and Al 2 O 3 contents.In addition,the reacted melts in some runs were transformed from the starting alkaline basaltic into tholeiitic after reactions,indicating that tholeiitic magma could be generated from alkaline basaltic one via reactions between the latter and orthopyroxene.
基金supported by grants from National Natural Science Foundation of China (Nos.40873016,41173034,90814003)supportedby a grant from China Geological Survey (No.1212011121088)
文摘The mantle xenoliths in the Quaternary ChangbaishanVolcano in southern Jilin Province contain spinel-facies lherzolites. The equilibration temperatures for these samples range from 902℃ to 1064℃ based on the two-pyroxene thermometer of Brey and Kohler (1990), and using the oxybarometry of Nell and Wood (1991), the oxidation state was estimated from FMQ-1.32 to -0.38 with an average value of FMQ-0.81 (n = 8), which is comparable to that of abyssal peridotites and the asthenospheric mantle. ThefO2 values of peridotites, together with their bulk rock compositions (e.g., Mg#, Al2O3, CaO, Ni, Co, Cr) and mineral compositions (e.g., Mg# of olivine and pyroxene, Cr# [=Cr/ [Cr+Al]] and Mg# [=Mg/[Mg+Fe2~] of spinel), suggest that the present-day subcontinental lithospheric mantle (SCLM) beneath the Changbaishan Volcano most likely formed from an upwelling asthenosphere at some time after the late Mesozoic and has undergone a low degree of partial melting. The studied lherzolite xenoliths show low concentrations of S, Cu, and platinum group elements (PGE), which plot a flat pattern on primitive-mantle normalized diagram. Very low concentrations in our samples suggest that PGEs occur as alloys or hosted by silicate and oxide minerals. The compositions of the studied samples are similar to those of peridotite xenoliths in the Longgang volcanic field (LVF) in their mineralogy and bulk rock compositions including the abundance of chalcophile and siderophile elements. However, they are distinctly different from those of peridotite xenoliths in other areas of the North China Craton (NCC) in terms of Cu, S and PGE. Our data suggest that the SCLM underlying the northeastern part of the NCC may represent a distinct unit of the newly formed lithospberic mantle.
基金granted by the National Natural Science Foundation of China(grants no.41173034 and 41472051)
文摘Objective The North China Craton (NCC) is a large Archean craton with a long geological history, yet very few studies have been carried out on the evolution of the redox conditions of its underlying mantle. Oxidation state of the mantle is critical in controlling the formation of metallic mineral deposits because metals can be readily released from the mantle to partial melt under oxidized conditions. In contrast, highly reduced and stable conditions are essential for the crystallization of diamond. The subcontinental lithospheric mantle (SCLM) beneath major cratons in the world has been stable since their formation and highly reduced in its oxidation state, but the SCLM below the NCC is different.
基金This paper is supported by the Research Foundation for OutstandingYoung Teachers , China University of Geosciences ( Wuhan )(CUGQNL0510)the National Natural Science Foundation of China(No .40425002) .
文摘The compositions of the whole rocks and trace elements of minerals in peridotites can reflect the characteristics of the lithospheric mantle. The nature and evolution of the Cenozoic lithospheric mantle beneath Hannuoba (汉诺坝), located on the north edge of the intra-North China orogenic belt, are discussed based on the in-situ LAM-ICPMS detected trace element compositions of clinopyroxenes in the Hannuoba peridotitic xenoliths combined with detailed petrography and geochemistry studies. The Hannuoba lithospheric mantle was formed by different partial meltings of the primitive mantle. Most of the samples reflect the partial melting degree of lower than 5% with a few samples of 15%-20%. Major element compositions of the whole rocks and geochemical compositions of clinopyroxenes reveal the coexistence of both fertile and depleted mantle underneath the Hannuoba region during the Cenozoic. This was probably caused by the asthenospheric mantle replacing the aged craton mantle through erosion, intermingling and modification. Our conclusion is further supported by the existence of both carbonatitic magmatic material and silicate melt/ fluid metasomatism as magnified by the trace elements of the clinopyroxencs from the Hannuoba lithospherJc mantle.
文摘Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental rift basalts in Northeast and North China;2)the tension-fault basalts on the continental margins of Southeast China; and 3) the collision-zone high-K volcanics in the Qinghai-Xizang Plateau and its vicinities.The characteristics of 'depletion in the south and enrichment in the north'of the China continental mantle are strongly supported by isotopic evidence.The Cenozoic continental cal characters,into the following geochemical provinces:1)the depleted mantle in South China;2)the primary mantle in Northeast and NorthChina; 3)the hybrid and transi-tional mantle in the region of Shandong ,Anhui,Jiangsu and northern Zhejiang;4)the depleted mantle around the Bohai Bay and the Lower Liaohe River;5)the K-metasomatic enriched mantle in the northern part of Northeast China;and 6)the re-cycled enriched mantle in the ancient subduction zone in the Qinghai-Xizang Plateau and its surround-ings.These geochemical characteristics on a regional scale must be a reflection of the nature of lithosphere evolution.
基金by the National Natural Science Foundation of China(Grant Nos.41603032,41472051,41802215 and 4176201)Applied Basic Research Foundation of Yunnan Province(Grant No.2017FB075)to ZPX,JW and YPD.
文摘Serpentinized peridotites in the Yangkou(YK),Suoluoshu(SLS) and Hujialin(HJL) areas in the Sulu ultrahighpressure terrane represent the relic of ancient subcontinental lithospheric mantle below the North China Craton.Their protoliths,harzburgite and dunite,were variably hydrated by aqueous fluids released from subducting Yangtze continent.The rocks are enriched in fluid-mobile elements(FME) including Sb(42–333 times the depleted mantle value) and Pb(30–476 times).The degrees of the FME enrichment are comparable to that of the Himalayan forearc serpentinites,and greater than forearc mantle serpentinites from Marianas,suggesting that the degrees of FME enrichment in the forearc serpentinites are greater in continental subduction zones than those in the oceanic subduction zones.Lizardite after olivine in the SLS serpentinite shows higher degrees of enrichment in Sb and As than those for antigorite after both olivine and orthopyroxene in the YK area.The antigorite has highly enriched in Pb,U,Cs,and LREE,but not for the lizardite.The abundance of FME in two different species of serpentine reflects the different temperature of hydration.At temperature lower than 300 ℃,formed lizardite at shallow depths of the mantle wedge incorporates elements that are fluid mobile at low temperatures,such as Sb and As.When the temperature greater than 300 ℃,formed antigorite at a relatively deep mantle wedge incorporate more FME from the subducting continental slab(or fragments),including Pb,U,Cs,LREE as well as Sb and As.The eventual breakdown of antigorite(600–700 ℃) in prograde metamorphism would discharge water as well as FME into the subducting channel and/or the overlying mantle.
基金supported by the Key Research Project of Frontier Sciences of Chinese Academy of Sciences (QYZDY-SSW-DQC030)the National Natural Science Foundation of China (41476034)
文摘The nature and evolution of the lithospheric mantle underlying Northeast(NE)China were investigated by assessing the mineral chemistry,water contents,and noble gas(He-Ar)isotopes of peridotite xenoliths captured by Cenozoic basalts from the Changbaishan and Longgang regions.The xenoliths,which have863–1141℃ equilibration temperatures,primarily comprise spinel lherzolites and rare spinel harzburgites.The Mg#(Fo)values of olivine in the peridotite xenoliths vary from 86.9 to 91.3.The clinopyroxenes have high Ti/Eu and low(La/Yb)N,and their chondrite-normalized rare earth elements(REEs)exhibit light REE-depletion to-enrichment patterns,indicating that the mantle underneath the investigated region was predominantly subjected to partial melting(1%–10%)and was metasomatized by silicate melts.The measured3He/4He ratios of the Changbaishan xenoliths have a narrow range from 5.8 Ra to 8.4 Ra with an average of 7.4 Ra.The3He/4He isotopic ratios of the Longgang xenoliths varied from 4.7 Ra to8.1 Ra with an average of 5.9 Ra;slightly lower than the Changbaishan xenoliths.The whole-rock H2Ocontents of the studied peridotite ranged from 9 to 132 ppm.The high H2O contents in excess of50 ppm(up to 132 ppm)might represent newly accreted and cooled asthenospheric materials,while those with H2O contents lower than 50 ppm(as little as 9 ppm)may represent thinned,relic,ancient lithospheric mantle.These geochemical evidences,in combination with published data,indicated that the lithospheric mantle beneath the Changbaishan and Longgang in NE China is dominated by the younger and more fertile lithospheric mantle with a minor ancient and refractory keel.In addition,the lithospheric mantle of this area was metasomatized by melts related to the recent subduction event(e.g.,Pacific oceanic plate).Therefore,the westward-dipping Pacific oceanic plate subduction had an important contribution to the transformation of the lithospheric mantle beneath NE China.
基金the National Natural Science Foundation of China (Grant Nos. 49837005 and 49733110).
文摘The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The ^(187)Os/^(188)Os ratio of the sample set ranges from 0.119 to 0.129 (25 samples, USTC) and from 0.117 to 0.131 (17 samples, CRPG). The Os isotopic compositions of most samples are less than 0.129 and depleted relatively to the primitive mantle, showing a good correlation with the major element compositions. With the ^(187)Os/^(188)Os-AI2O3 alumichron, the samples yield a model age of 2.5±0.1 Ga (data of USTC) and 1.9±0.1 Ga (data of CRPG), late Archean to early Pro-terozoic. The two samples with the lowest ^(187)Os/^(188)Os ratio (0.119 and 0.117) have the T_(RD) (Re depleted age) of 1.1 Ga (USTC) and 1.4 Ga (CRPG), mid-Proterozoic. The Os isotope model age shows that the peridotite xenoliths from Cenozoic alkali basalt in Jiangsu-Anhui provinces have an old formation age (early- to mid- Proterozoic). They are not newly produced mantle after the Phanerozoic replacement of the lithosphere mantle, but residual fractions of Proterozoic mantle.
基金supported by the Public Research Project of the Ministry of Land and Resources of the People’s Republic of China(200811012)the National Natural Science Foundation of China(41272086)
文摘The components and evolution of subcontinental lithospheric mantle beneath the North China Craton and the Yangtze Craton is a current topic in the geological study of China and the carbon isotopic composition of diamond is one of the most direct probes into cratonic lithospheric mantle processes.In this paper,in-situ SIMS(Secondary Ion Mass Spectrometry) techniques were used to analyze the carbon isotope compositions at different internal growth zones of diamonds from Shandong and Liaoning in the North China Craton and Hunan in the Yangtze Craton.It was found that the carbon isotopic range of diamonds from the North China Craton are rather distinct from those of the Yangtze Craton;the former has a range of 6.0‰ to 2.0‰(relative to VPDB) with an average value of 3.0‰ in their core areas,which is consistent with global peridotitic diamonds;the diamonds from the Yangtze Craton,however,have a carbon isotopic range from 8.6‰ to 3.0‰ with an average value of 7.4‰ in their core areas,being more consistent with global eclogitic diamonds.The variations of carbon isotope ratios between different internal growth zones in individual diamonds were different in the three diamond localities studied.There was a clear correlation between changes in carbon isotopic composition and phases of diamond dissolution and new growth,while no correlation was observed between δ13C and internal inclusions.The variations suggest that the carbon isotopic compositions of mantle fluids were changing during the process of diamond crystallization,and that the heterogeneity of the carbon isotopic composition in mantle carbon reservoirs was a more important factor than carbon isotope fractionation in controlling the carbon isotopic compositions and their variation in diamonds.In addition,the preliminary results of in-situ nitrogen analyses demonstrated that the variation of carbon isotopic compositions between the core and outer growth zones does not correlate with nitrogen abundances,implying either that diamonds crystallized in an open environment or that the carbon isotopic composition and nitrogen contents in mantle fluids were controlled by other,not yet understood factors.The experimental results provide hints that the isotopic composition of carbon and its original sources were different in metasomatic fluids controlling diamond formation in the mantle beneath the North China Craton and the Yangtze Craton.
基金supported by the National Natural Science Foundation of China(Grant No.49925308)the Chinese Academy of Sciences(Gramt Nos.KZCX2-SW-117,KZCX2-101 and KZCX2-209).
文摘Geochemical comparison of two suites of Cenozoic potassic volcanic rocks in western Yunnan reveals the existence of two mantle domains beneath this region, which corre- spond to their respective tectonic affinity. The Erhai ultrapotassic rocks (42—24Ma) in western Yangtze Craton are characterized by LILE enrichment, HFSE depletion, low TiO2 content (<1%), high initial Sr/86Sr (0.7064—0.7094) and negative εNd (?3.84—?4.64). Geochemically similar to 87 K-rich volcanism in subduction setting, they were probably originated from a refractory spinel harzburgitic source metasomatized by subduction-related fluids. In contrast, the Maguan potas- sic magmas (<16Ma) in the South China Block show an OIB-type trace elemental signature, high TiO2 content (>2%), low initial 87 Sr/86Sr (0.7041—0.7060) and positive εNd (5.46—7.03). These features resemble the typical intraplate potassic rocks around the world. These rocks are thus interpreted as melting products of a fertile garnet lherzolitic source which has been infiltrated by small-volume, asthenosphere-derived silicate melts. The temporal and spatial distribution of these two types of K-rich rocks cannot be explained by any unified tectonic model. It is proposed that the Oligocene magmatism in the Erhai area may have resulted from convective thinning of the thickened lithosphere, whereas the post-Miocene volcanism in the Maguan area was related to the opening of South China Sea.
基金supported by the National Natural Science Foundation of China(Grant No.40372044).
文摘Minerals of spinel- and garnet-facies mantle xenoliths entrained in Cenozoicbasalts from eastern China (North China, Northeastern China and Southeastern China coastal area)contains lots of melt inclusions. Studies on these melt inclusions show that the glass inclusionsare rich in SiO_2 (60%—68%) and alkalis (K_2O+Na_2O = 5%—11%, especially for K_2O) as well asvolatiles such as H_2O and CO_2 (2%—7%), which belong to dacites and andesites of the high-K calcicalkali series rocks with few shoshonites. High Al and Ca diopside in melt inclusion is the productof melt crystallization at high temperature and pressure, rather than the product ofdevitrification. Results show that these K-rich (in general K_2O 】 3%) intermediate-acidic silicatemelt inclusions have characteristics of continent without a genetical link to host basalts and theirphenocrystic minerals. Thus, these trapped melt inclusions represent melts of Mesozoic lithosphericmantle-crust interaction and imply that the continental lithospheric mantle beneath eastern Chinahad undergone fragmentation and recreation processes during the Mesozoic and Cenozoic periods. Thisresult undoubtly provides important implication for the evolution of sub-continental lithospherebeneath eastern China. We propose that these Si- and alkalis-rich melts should be responsible forthe mantle chemical heterogeneity underneath eastern China.
基金supported by the National Natural Science Foundation of China (41225016, 41688103, 91414301)Chinese Academy of Sciences
文摘Recent seismic studies reveal a sharp velocity drop mostly at^70–100 km depth within the thick mantle keel beneath cratons, termed the mid-lithosphere discontinuity(MLD). The common presence of the MLD in cratonic regions indicates structural and property layering of the subcontinental lithospheric mantle(SCLM). The nature and origin of the MLD, and many issues associated with the layering of the SCLM are essential to understand the formation and evolution of continents, and have become frontier subjects in the Earth sciences.
文摘The determination of the formation age of subcontinental Lithosphere Mantle (SCLM) is a widely concerned issue in mantle geochemistry. it is difficult to obtain the formation age of SCLM using lithophile isotopic systems such as Rb-Sr, Sm-Nd, U-Th-Pb, ete., but as siderophile elements, the Re-Os isotopic system provides a powerful tool for that work. Here a comprehensive review on the recent development in Re-Os dating for SCLM has been given.