Key CO_(2)capture technology of pure oxygen exhaust gas combustion for syngas-fueled high-temperature fuel cells

Integrated gasification fuel cells(IGFCs)integrating high-temperature solid oxide fuel cell technology with CO_(2)capture processes represents highly-efficient power systems with negligible CO_(2)emissions.Flame burning with pure oxygen is an ideal method for fuel cell exhaust gas treatment,and this report describes experimental and numerical studies regarding an oxy-combustor for treating the exhaust gas of a 10 kW IGFC system anode.The applied simulation method was verified based on experiments,and the key performance indices of the combustor were studied under various conditions.It was determined that 315 K was the ideal condensation temperature to obtain flame stability.Under these pure oxygen flame burning conditions,CO was almost completely converted,and the dry mole fraction of CO_(2)after burning was C 0.958 when there was up to 5%excess O_(2).Overall,5%excess O_(2)was recommended to maximize CO_(2)capture and promote other environmental considerations.Additionally,the optimal tangential fuel jet angle to control the liner temperature was approximately 25°.The total fuel utilization had to be high enough to maintain the oxygen flame temperature of the anode exhaust gas below 1800 K to ensure that the system was environmentally friendly.The results presented herein have great value for designing IGFCs coupled with CO_(2)capture systems.

Quantitative analysis and time-resolved characterization of simulated tokamak exhaust gas by laser-induced breakdown spectroscopy

Tokamak exhaust is an important part of the deuterium-tritium fuel cycle system in fusion reactions.In this work,we present a laser-induced breakdown spectroscopy(LIBS)-based method to monitor the gas compositions from the exhaust system in the tokamak device.Helium(He),a main impurity in the exhaust gas,was mixed with hydrogen(H_(2))in different ratios through a self-designed gas distribution system,and sealed into a measurement chamber as a standard specimen.A 532 nm wavelength laser pulse with an output power of 100 mJ was used for plasma excitation.The time-resolved LIBS is used to study the time evolution characteristics of the signal strength,signal-to-background ratio(SBR),signal-to-noise ratio(SNR)and relative standard deviation(RSD)of the helium and hydrogen characteristic lines.The Boltzmann twoline method was employed to estimate the plasma temperature of laser-induced plasma(LIP).The Stark-broadened profile of He I 587.56 nm was exploited to measure the electron density.From these studies,an appropriate time was determined in which the low RSD%was consistent with the high signal-to-noise ratio.The He I 587.56 nm and Hαemission lines with good signalto-noise ratio were extracted from the spectrum and used in the external standard method and internal standard method for quantitative analysis.The test results for mixed gas showed that the average relative error of prediction was less than 11.15%,demonstrating the great potential of LIBS in detecting impurities in plasma exhaust gas.

EFFECTS OF COOLED EXTERNAL EXHAUST GAS RECIRCULATION ON DIESEL HOMOGENEOUS CHARGE COMPRESSION IGNITION ENGINE

The effects of cooled external exhaust gas recirculation （EGR） on the combustion and emission performance of diesel fuel homogeneous charge compression ignition （HCCI） are studied. Homogeneous mixture is formed by injecting fuel in-cylinder in the negative valve overlap （NVO） period. So, the HCCI combustion which has low NOx and smoke emission is achieved. Cooled external EGR can delay the start of combustion effectively, which is very useful for high cetane fuel （diesel） HCCI, because these fuels can easily self-ignition, which makes the start of combustion more early. External EGR can avoid the knock combustion of HCCI at high load which means that the EGR can expand the high load limit. HCCI maintains low smoke emission at various EGR rate and various load compared with conventional diesel engine because there is no fuel-rich area in cylinder.

Correlation of Performance, Exhaust Gas Temperature and Speed of a Spark Ignition Engine Using Kiva4

The objective of this study was to investigate performance characteristics of a spark ignition engine, particularly, the correlation between performance, exhaust gas temperature and speed, using Kiva4. Test data to validate kiva4 simulation results were conducted on a 3-cylinder, four-stroke Volkswagen (VW) Polo 6 TSI 1.2 gasoline engine. Three different tests were, therefore, carried out. In one set, variations in exhaust gas temperature were studied by varying the engine load, while keeping the engine speed constant. In another test, exhaust gas temperature variations were studied by keeping the engine at idling whilst varying the speeds. A third test involved studying variations in exhaust gas temperature under a constant load with variable engine speeds. To study variations in exhaust gas temperatures under test conditions, a basic grid/mesh generator, K3PREP, was employed to write an itape17 file comprising of a 45° asymmetrical mesh. This was based on the symmetry of the combustion chamber of the engine used in carrying out experimental tests. Simulations were therefore performed based on the input parameters established in the conducted tests. Simulations with the kiva4 code showed a significant predictability of the performance characteristics of the engine. This was evident in the appreciable agreement obtained in the simulation results when compared with the test data, under the considered test conditions. A percentage error, between experimental results and results from simulations with the kiva4 code of only between 2% to 3% was observed.

Analysis of Non-Selective Catalyst Reduction Performance with Dedicated Exhaust Gas Recirculation

Rich burn industrial natural gas engines offer best in class post catalyst emissions by using a non-selective catalyst reduction aftertreatment technology. However, they operate with reduced power density when compared to lean burn engines. Dedicated exhaust gas recirculation (EGR) offers a possible pathway for rich burn engines to use non-selective catalyst reduction aftertreatment technology without sacrificing power density. In order to achieve best in class post catalyst emissions, the precious metals and washcoat of a non-selective catalyst must be designed according to the expected exhaust composition of an engine. In this work, a rich burn industrial natural gas engine operating with dedicated EGR was paired with a commercially available non-selective catalyst. At rated brake mean effective pressure (BMEP) the air-fuel ratio was swept between rich and lean conditions to compare the catalyst reduction efficiency and post catalyst emissions of rich burn and dedicated EGR combustion. It was found that due to low oxides of nitrogen (NOx) emissions across the entire air-fuel ratio range, dedicated EGR offers a much larger range of air-fuel ratios where low regulated emissions can be met. Low engine out NOx also points towards a possibility of using an oxidation catalyst rather than a non-selective catalyst for dedicated EGR applications. The location of the NOx-CO tradeoff was shifted to more rich conditions using dedicated EGR.

Thermodynamic Performance Analysis of E/F/H-Class Gas Turbine Combined Cycle with Exhaust Gas Recirculation and Inlet/Variable Guide Vane Adjustment under Part-Load Conditions

Exhaust gas recirculation control(EGRC),an inlet air heating technology,can be utilized in combination with inlet/variable guide vane control(IGV/VGVC) and fuel flow control(FFC) to regulate the load,thereby effectively improving the part-load(i.e.,off-design) performance of the gas turbine combined cycle(GTCC).In this study,the E-,F-,and H-Class EGR-GTCC design and off-design system models were established and validated to perform a comparative analysis of the part-load performance under the EGR-IGV-FFC and conventional IGV-FFC strategies in the E/F/H-Class GTCC.Results show that EGR-IGV-FFC has considerable potential for the part-load performance enhancement and can show a higher combined cycle efficiency than IGV-FFC in the E-,F-,and H-Class GTCCs.However,the part-load performance improvement in the corresponding GTCC was weakened for the higher class of the gas turbine because of the narrower load range of EGR action and the deterioration of the gas turbine performance.Furthermore,EGR-IGV-FFC was inferior to IGV-FFC in improving the performance at loads below 50% for the H-Class GTCC.The results obtained in this paper could help guide the application of EGR-IGV-FFC to enhance the part-load performance of various classes of GTCC systems.

Experiment Study on the Exhaust-Gas Heat Exchanger for Small and Medium-Sized Marine Diesel Engine

This paper aims to design a special exchanger to recover the exhaust gas heat of marine diesel engines used in small and medium-sized fishing vessels,which can then be used to heat water up to 55°C–85°C for membrane desalination devices to produce fresh water.A new exhaust-gas heat exchanger of fins and tube,with a reinforced heat transfer tube section,unequal spacing fins,a mixing zone between the fin groups and four routes tube bundle,was designed.Numerical simulations were also used to provide reference information for structural design.Experiments were carried out for exhaust gas waste heat recovery from a marine diesel engine in an engine test bench utilizing the heat exchanger.The experimental results show that the difference between heat absorption by water and heat reduction of exhaust gas is less than 6.5%.After the water flow rate was adjusted,the exhaust gas waste heat recovery efficiency was higher than 70%,and the exhaust-gas heat exchanger’s outlet water temperature was 55°C–85°C at different engine loads.This means that the heat recovery from the exhaust gas of a marine diesel engine meets the requirement to drive a membrane desalination device to produce fresh water for fishers working in small and medium-sized fishing vessels.

Combustion analysis of a hydrogen-diesel fuel operated DI diesel engine with exhaust gas recirculation

The rapid depletion of fossil fuel and growing demand necessitates researchers to find alternative fuels which are clean and sustainable. The need for finding renewable, low cost and environmentally friendly fuel resources can never be understated. An efficient method of generation and storage of hydrogen will enable automotive manufacturers to introduce hydrogen fuelled engine in the market. In this paper, a conventional DI diesel engine was modified to operate as gas engine. The intake manifold of the engine was supplied with hydrogen along with recirculated exhaust gas and air. The injection rates of hydrogen were maintained at three levels with 2 L/min, 4 L/min, 6 L/min and 8 L/min and 10 L/min with an injection pressure of 2 bar. Many of the combustion parameters like heat release rate （HRR）, ignition delay, combustion duration, rate of pressure rise （ROPR）, cumulative heat release rate （CHR）, and cyclic pressure fluctuations were measured. The HRR peak pressure decreased with the increase in EGR rate, while combustion duration increased with the EGR rate. The cyclic pressure variation also increased with the increase in EGR rate.

A step parameters prediction model based on transfer process neural network for exhaust gas temperature estimation after washing aero-engines

The prediction of Exhaust Gas Temperature Margin(EGTM)after washing aeroengines can provide a theoretical basis for airlines not only to evaluate the energy-saving effect and emission reduction,but also to formulate reasonable maintenance plans.However,the EGTM encounters step changes after washing aeroengines,while,in the traditional models,a persistence tendency exists between the prediction results and the previous data,resulting in low accuracy in prediction.In order to solve the problem,this paper develops a step parameters prediction model based on Transfer Process Neural Networks(TPNN).Especially,“step parameters”represent the parameters that can reflect EGTM step changes.They are analyzed in this study,and thus the model concentrates on the prediction of step changes rather than the extension of data trends.Transfer learning is used to handle the problem that few cleaning records result in few step changes for model learning.In comparison with Long Short-Term Memory(LSTM)and Kernel Extreme Learning Machine(KELM)models,the effectiveness of the proposed method is verified on CFM56-5B engine data.

Influence of Exhaust Gas Recirculation on Low-Load Diesel Engine Performance

In the condition of constant speed and light load, an experimental study of a turbocharged and intercooled diesel engine with exhaust gas recirculation （EGR） system focuses on the influence of different EGR rates on combustion process, dynamic performance, economic performance and emission performance of a diesel engine. With the increase of EGR rate, the oxygen concentration of the intake-side decreases, the fuel air equivalence ratio increases, and the maximum explosion pressure in the cylinder decreases. Meanwhile, the average temperature in the cylinder drops, the ignition delay is prolonged, the ignition timing delays, and the maximum heat release rate decreases. The increase of EGR rate makes NOx emissions decrease obviously and continue to decline. When EGR is low, the smoke rate enlarges slowly with the increase of EGR rate, and enlarges greatly at the rate higher than 43% and reaches the maximum at the rate of 57%. When EGR rate is higher than 61%, the smoke rate drops rapidly, and the content of CO and hydrocarbon （HC） increases rapidly with high EGR rate.

Utilisation of waste heat from exhaust gases of drying process

Nowadays a lot of low-grade heat is wasted from the industry through the off- and flue-gasses with different compositions. These gases provide the sensitive heat with utilisation potential and latent heat with the components for condensation. In this paper, process integration methodology has been applied to the partly condensed streams. A hot composite curve that represents the gas mixture cooling according to equation of state for real gases was drawn to account the gas-liquid equilibrium. According to the pinch analysis methodology, the pinch point was specified and optimal minimal temperature difference was determined. The location of the point where gas and liquid phases can be split for better recuperation of heat energy within heat exchangers is estimated using the developed methodology. The industrial case study of tobacco drying process off-gasses is analysed for heat recovery. The mathematical model was developed by using MathCad software to minimise the total annualised cost using compact plate heat exchangers for waste heat utilisation. The obtained payback period for the required investments is less than six months. The presented method was validated by comparison with industrial test data.

Thermal fatigue behavior of 441 ferritic stainless steel in air and synthetic automotive exhaust gas

The thermal fatigue behavior of 441 ferritic stainless steel was investigated in air and synthetic automotive exhaust gas by the cyclic tests under 100℃-800℃ and 900℃ conditions.After the fracture failure,the microstructure,oxide film,and precipitated phases were analyzed using optical microscopy,X-ray diffraction,scanning electron microscopy,and transmission electron microscopy.In both atmospheres,increasing the maximum temperature from 800℃ to 900℃ results in lower strength and fatigue life and higher elongation and grain size.At the same maximum temperature,the thermal fatigue life of the specimen is lower in the synthetic exhaust gas than in the air.Both the higher maximum temperature and the synthetic exhaust gas facilitate fatigue failure.The failure mechanism is discussed according to the grain size,thermal stress,high-temperature oxidation rate,and the precipitation of secondary phases.Some precipitated carbides play an important role in the rapid fatigue failure of specimens in the synthetic exhaust gas.

Effect of exhaust gas recirculation and ethyl hexyl nitrate additive on biodiesel fuelled diesel engine for the reduction of NOx emissions

Cetane improvers reduce the ignition delay, which in turn reduces the combustion temperatures thereby reduce NOx emissions. Exhaust gas recirculation （EGR） proved to be an effective way to reduce the NOx emissions. In this present experimental work, a combination of exhaust gas recirculation and cetane improver ethyl hexyl nitrate （EHN） is used to investigate the performance and exhaust emissions of a single cylinder four stroke naturally aspirated direct injection and air cooled diesel engine. Test results show that the brake thermal efficiency increases with the increase in the percentage of EGR which is accompanied by a reduction in brake specific fuel consumption and exhaust gas temperatures, and that bio- diesel with cetane improver under 20% EGR reduces NOx emissions by 33% when compared to baseline fuel without EGR. However carbon monoxide （CO）, hydro carbon （HC） and smoke emissions increase with an increase in percentage of EGR.

Estimation of Residual Exhaust Gas of Homogeneous Charge Compression Ignition Gasoline Engine Operating Under Negative Valve Overlap Strategy

To meet the requirements of the homogeneous charge compression ignition gasoline engine’s rapid cylinder exhaust gas rate and accurate control of combustion phasing,a residual exhaust gas rate model was proposed.A heat dissipation model for gas flow in the exhaust passage and exhaust pipe was established,and the exhaust gas was established.Flow through the exhaust valve was considered as an adiabatic expansion process,the exhaust temperature was used to estimate the temperature in the cylinder at the time that the valve was closed,and the cylinder exhaust gas rate was calculated.To meet the requirements of transient operating conditions,a first-order inertial link was used to correct the thermocouple temperature measurement.Addressing this delay problem and modification of the exhaust wall temperature according to different conditions effectively improved the accuracy of the model.The relative error between the calculated results of this model and the simulation results determined using GT-POWER software was within 3.5%.

CeO_2-ZrO_2-La_2O_3-Al_2O_3 composite oxide and its supported palladium catalyst for the treatment of exhaust of natural gas engined vehicles

Composite supports CeO2-ZrO2-Al2O3（CZA） and CeO2-ZrO2-Al2O3-La2O3（CZALa） were prepared by co-precipitation method. Palladium catalysts were prepared by impregnation and their purification ability for CH4, CO and NOx in the mixture gas simulated the exhaust from natural gas vehicles （NGVs） operated under stoichiometric condition was investigated. The effect of La2O3 on the physicochemical properties of supports and catalysts was characterized by various techniques. The characterizations with X-ray diffraction （XRD） and Raman spectroscopy revealed that the doping of La2O3 restrained effectively the sintering of crystallite particles, maintained the crystallite particles in nanoscale and stabilized the crystal phase after calcination at 1000 ℃. The results of N2-adsorption, H2-temperatnre-programmed reduction （H2-TPR） and oxygen storage capacity （OSC） measurements indicated that La2O3 improved the textural properties, reducibility and OSC of composite supports. Activity testing results showed that the catalysts exhibit excellent activities for the simultaneous removal of methane, CO and NOx in the simulated exhaust gas. The catalysts supported on CZALa showed remarkable thermal stability and catalytic activity for the three pollutants, especially for NOx. The prepared palladium catalysts have high ability to remove NOx, CH4 and CO, and they can be used as excellent catalysts for the purification of exhaust from NGVs operated under stoichiometric condition. The catalysts reported in this work also have significant potential in industrial application because of their high performance and low cost.

Analysis of impulse electric field effect on organic exhaust gas decomposition

１ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｏｒｇａｎｉｃｅｘｈａｕｓｔｇａｓｅｓｍａｉｎｌｙｃｏｎｔａｉｎａｄｉｐｏｓｅ，ａｒｏｍａｔｉｃｈｙｄｒｏｃａｒｂｏｎ，ａｌｃｏｈｏｌ，ｅｔｈｅｒａｎｄａｍｉｎｅａｎｄｓｏｏｎ．Ｔｈｅｙｈａｖｅｇｒｅａｔｌｙｐｏｌｕｔ...

面向未来低碳道路养护的超薄罩面功能性研究综述

Highway maintenance mileage reached 5.25 million kilometers in China by 2021.Ultra-thin overlay is one of the most commonly used maintenance technologies,which can significantly enhance the economic and environmental benefits of pavements.To promote the low-carbon development of ultrathin overlays,this paper mainly studied the mechanism and influencing factors of several ultra-thin overlay functions.Firstly,the skid resistance,noise reduction,rutting resistance,and crack resistance of ultrathin overlays were evaluated.The results indicated that the high-quality aggregates improved the skid and rutting resistance of ultra-thin overlay by 5%-20%.The optimized gradations and modified binders reduced noise of ultra-thin overlay by 0.4-6.0 dB.The high viscosity modified binders improved the rutting resistance of ultra-thin overlay by about 10%-130%.Basalt fiber improved the cracking resistance of ultra-thin overlay by more than 20%.Due to the thinner thickness and better road performance,the performance-based engineering cost of ultra-thin overlay was reduced by about 30%-40%compared with conventional overlays.Secondly,several environmentally friendly functions of ultra-thin overlay were investigated,including snow melting and deicing,exhaust gas purification and pavement cooling.The lower thickness of ultra-thin overlay was conducive to the diffusion of chloride-based materials to the pavement surface.Therefore,the snow melting effect of self-ice-melting was better.In addition,the ultra-thin overlay mixture containing photocatalytic materials could decompose 20%-50%of the exhaust gas.The colored ultra-thin overlay was able to reduce the temperature of the pavement by up to 8.1℃.The temperature difference between the upper and lower surfaces of the ultra-thin overlay containing thermal resistance materials could reach up to 12.8℃.In addition,numerous typical global engineering applications of functional ultra-thin overlay were summarized.This review can help better understand the functionality of ultra-thin overlays and promote the realization of future multi-functional and low-carbon road maintenance.

Optimization and Evaluation of a Vehicular Exhaust Heat Recovery System

Exhaust waste heat recovery system based on organic Rankine cycle(ORC)has been considered as an effective method to achieve energy conservation and emissions reduction of engine.The performance of adiesel engine with an on-board ORC exhaust heat recovery system was evaluated through simulations in this study.The combined system was optimized through controlling the exhaust gas mass flow rate entering the ORC system.The models of the engine with ORC system were developed in GT-suite and Simulink environment.The validation results showed high accuracy of the models.The performance of the system recovering heat from different exhaust gas mass flow rates was evaluated.The comparative analysis of the performance between the optimized and un-optimized system was also presented.The results indicated that the exhaust gas mass flow rate had significant effects on the system performance.Integration with the onboard ORC system could effectively improve the engine power performance.The power output of the engineORC combined system with optimization had further improvement,and the maximum improvement could reach up to 1.16 kW.

Study on the Application of Drying Furnace Waste Gas Treatment Technology in Painting Workshop

With the continuous development of our country's economy,the demand for automobile is higher and higher after people's living standard is improving day by day.In just 40 years of reform and opening up,China's automobile production and per capita possession have made a qualitative leap and a breakthrough in quantity.Greatly promoted the automobile industry's great development.

Atomic-scale engineering of advanced catalytic and energy materials via atomic layer deposition for eco-friendly vehicles

Zero-emission eco-friendly vehicles with partly or fully electric powertrains have exhibited rapidly increased demand for reducing the emissions of air pollutants and improving the energy efficiency. Advanced catalytic and energy materials are essential as the significant portions in the key technologies of eco-friendly vehicles, such as the exhaust emission control system,power lithium ion battery and hydrogen fuel cell. Precise synthesis and surface modification of the functional materials and electrodes are required to satisfy the efficient surface and interface catalysis, as well as rapid electron/ion transport. Atomic layer deposition(ALD), an atomic and close-to-atomic scale manufacturing method, shows unique characteristics of precise thickness control, uniformity and conformality for film deposition, which has emerged as an important technique to design and engineer advanced catalytic and energy materials. This review has summarized recent process of ALD on the controllable preparation and modification of metal and oxide catalysts, as well as lithium ion battery and fuel cell electrodes. The enhanced catalytic and electrochemical performances are discussed with the unique nanostructures prepared by ALD. Recent works on ALD reactors for mass production are highlighted. The challenges involved in the research and development of ALD on the future practical applications are presented, including precursor and deposition process investigation, practical device performance evaluation, large-scale and efficient production, etc.