The F-rich granites in South China could be distinguished as the high-p subtype andthe low-p subtype according to their P2O5 contents. There are obvious differences in chemicalcomopition of these two subtypes. The hig...The F-rich granites in South China could be distinguished as the high-p subtype andthe low-p subtype according to their P2O5 contents. There are obvious differences in chemicalcomopition of these two subtypes. The high-p subtype is strongly peraluminous and characterized by low silica and very low REE contents, while the low-p subtype is weakly peraluminousand characterized by high silica and very high REE contents. There are also some differences inchemical compositions of feldspars and micas for these two subtypes. The phosphorus of thehigh-p subtype mainly appears to be in the feldspar structure as PAISi-2 substitution or subordinately in amblygonite as an accessory mineral, while the phosphorus of the low-p subtype ismainly in apatite and other phosphate minerals.展开更多
The younger granitoids of the Shalatin district in the Southeastern Desert of Egypt, are of biotite and two-mica granite compositions. The geochemistry of rare-earth elements (REE), yttrium, thorium and uranium forms ...The younger granitoids of the Shalatin district in the Southeastern Desert of Egypt, are of biotite and two-mica granite compositions. The geochemistry of rare-earth elements (REE), yttrium, thorium and uranium forms the basis for many important methods to reconstruct igneous petrogenesis. Since the recognition that REE, Y, Th, U-rich accessories may play an important role in controlling the geochemistry of crustal melts, a considerable amount of work has been done in an attempt to understand their effects. However, this effort has been almost exclusively focused on three minerals: zircon, monazite and apatite. Nevertheless, the variety of REE-Th-U-rich accessories in granite rocks are neither limited to these three minerals nor are they always the main REE, Y, Th carriers. The geochemistry of REE, Y, Th and U reflects the behavior of accessories and some key major minerals such as garnet and feldspars, and may therefore give valuable information about the conditions of partial melting, melt segregation and crystallization of granite magmas in different crustal regimes. The geochemistry of U and Th during magmatic differentiation has been studied in many granites from different areas and it has been known that the U and Th contents of granitic rocks generally increase during differentiation, although in some cases they decrease. The Th/U ratio can either increase or decrease, depending on redox conditions, the volatile content or alteration by endogene or supergene solutions. The accessory assemblage of muscovite-rich granites and high-grade rocks is composed of monazite, xenotime, apatite, Th-orthosilicate, secondary U-mineralization and betafite-pyrochlore. REE, Y, Th and U are not suitable for geochemical modeling of granitoids by means of equilibrium-based trace element fractionation equations, but are still useful petrogenetic tools.展开更多
Cassiterites from both the Beauvoir and Montebras geanited of France are typically rich in trace elements such as Nb and Ta, and contain quite a number of inclusions of columbite (dominantly manganocolumbite).Two thin...Cassiterites from both the Beauvoir and Montebras geanited of France are typically rich in trace elements such as Nb and Ta, and contain quite a number of inclusions of columbite (dominantly manganocolumbite).Two thin sections of cassiterite crystals have been prepared for Raman microprobe analysis).The spectra obtained from different parts of the cassiterites show that the vibra-tion frequency of the A1g peak decreases with increasing Nb ,Ta,Fe and Mn atomic contents.It is worthy to note that a new peak (named the “An peak”) has been reported for the first time in the part with oriented columbite inclusions.The vibration frequency varies from 827 to 830 cm^-1.The presence of th enew peak may be attributed to structural changes of cassiterite due to the excess of Nb and Ta in the lattice and the exsolution of columbite inclusions in cassiterite.展开更多
The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the par...The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the partition coefficients D_w,D_(Nb) and D_(Ta)(D_i^(v/m) = C_i^V/C_i^m,where C_i^V and C_i^m denote the concentrations of an element,i,in the aqueous fluid and the melt,respectively) were less than 0.1.All partition coefficients were affected by pressure,but there was no evidence for the complexation of P2O5 with these elements in the granitic melt or aqueous fluid,except for with W in the fluid.The results showed that W,Nb,and Ta tended to partition into the granitic melt and,in the late period of crystallization of P-rich magma,they formed independent minerals.展开更多
Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these e...Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these end-member rocks. Vertical zoning in Li-F granites, asreflected by increasing normative Q and C (corundum) and decreasing ALK (K2O + Na2O)with increasing content of fluorine, can be explained using the three-end-member scheme interms of petrochemistry and norms. Considering the difference in melt structure, viscosity anddensity between the end members, in couple with the reguarities that govern the Na-K and Si-ALK segregation known from field evidence and experiments, it is suggested that the three endmembers may have resulted from liquid segregation (immiscibility) rather than from crystalfractionation as commonly believed.展开更多
The mountain rocks in the Dushan Complex are Sr-rich granite with a much higher Sr level than those in other crustal lithospheres in eastern China. That presents a high potential for developing Sr-rich mineral water. ...The mountain rocks in the Dushan Complex are Sr-rich granite with a much higher Sr level than those in other crustal lithospheres in eastern China. That presents a high potential for developing Sr-rich mineral water. In this study, 6 groups of rock samples, together with 30 groups of water samples, were collected. Combining with the existing data, the Sr contents in three different types of underground water were obtained, which are the Quaternary pore water, the meshed bedrock fissure water in weathered zones and the tectonic bedrock fissure water. On the basis of preliminary understanding for the distribution characteristics of Sr-rich mineral water in the Dushan Mountain region, the causes for the Sr-rich mineral water were investigated. Our results showed that the Sr content of the rocks in the studied area ranges from 988 to 1 950 μg/g. In the horizontal direction, those in both the pore water and the meshed bedrock fissure water in weathered zones show high values in the west but low ones in the east, and high ones in the south but low ones in the north. Furthermore, both types of water meet the standard for Sr-rich mineral water in the western areas. In the vertical direction, the Sr content shows the lowest value in pore water(the average value is 0.707 mg/L), middle value in the meshed bedrock fissure water in weathered zones(the average value is 1.415 mg/L) and the highest value in the tectonic bedrock fissure water(the average value is 8.331 mg/L). It was thought that the widely-developed Sr-rich granite in this region provides physical sources for the formation of Sr-rich mineral water. The continuous dissolution of Sr during underground water runoff is the internal mechanism. In addition, the hydraulic interrelations may exist between the three vertical aquifers, leading a continuous accumulation of the Sr level during infiltration.展开更多
Though magmatic origin of Li-F-rich granite has been supported effectively by the existence of volcanic and subvolcanic rocks and melt inclusions trapped in them with similar chemical compositions, evidence from high ...Though magmatic origin of Li-F-rich granite has been supported effectively by the existence of volcanic and subvolcanic rocks and melt inclusions trapped in them with similar chemical compositions, evidence from high T-P experiments is poor up to now. To simulate the evolution process of Li-F-rich granite and to interpret its forming mechanism, a series of melting-crystallization experiments were carried out. Under the conditions of 1×108 Pa and 570–700°C, a magmatic mineral association of quartz + alkali feldspar + lithium muscovite/ferromuscovite ± fluorite ± cassiterite is found in leucogranite-HF-H2O system. This indicates the following points: (i) Fluorite, light-colored muscovite and cassiterite can crystallize directly from the Li-F-rich granitic melt. (ii) The coexistence of dark-colored micas (e.g. biotite) and light-colored micas (e.g. lithium muscovite and ferromuscovite) suggests that the muscovite granite and two-mica granite can be formed under magmatic condition. The zonal texture of micas is not the sole feature for the micas of hydrothermal origin. (iii) As crystallization proceeds, the SiO2 concentration of the residual melt decreases, while the Al2O3 and F concentrations and A/CNK, NKA/Si ratios of the melt incerese, favoring the formation of Li-F-rich granites. Our experiment results are well consistent with the vertical zonation widely observed in rare metal bearing granites, and therefore provide strong experimental evidence for magmatic origin of Li-F-rich granite.展开更多
The newly discovered three alkali\|rich intrusive rock belts in the Mt. Kunlun Mt. Altun region of southern Xinjiang are the Lapeiquan\|Yitunbulak alkali\|rich intrusive rock belt, the Gez\|Taxkorgan alkali\|rich intr...The newly discovered three alkali\|rich intrusive rock belts in the Mt. Kunlun Mt. Altun region of southern Xinjiang are the Lapeiquan\|Yitunbulak alkali\|rich intrusive rock belt, the Gez\|Taxkorgan alkali\|rich intrusive rock belt and the Beilisai\|Abulash alkali\|rich intrusive rock belt. The former two belts were formed during the Yanshanian period, and the third one was formed during the Himalayan period, which is the youngest alkali\|rich intrusive rock belt in China. The discovery of the alkali\|rich intrusive rock belts is of great significance in shedding light on the history of tectono\|magmatic activities in this region.展开更多
文摘The F-rich granites in South China could be distinguished as the high-p subtype andthe low-p subtype according to their P2O5 contents. There are obvious differences in chemicalcomopition of these two subtypes. The high-p subtype is strongly peraluminous and characterized by low silica and very low REE contents, while the low-p subtype is weakly peraluminousand characterized by high silica and very high REE contents. There are also some differences inchemical compositions of feldspars and micas for these two subtypes. The phosphorus of thehigh-p subtype mainly appears to be in the feldspar structure as PAISi-2 substitution or subordinately in amblygonite as an accessory mineral, while the phosphorus of the low-p subtype ismainly in apatite and other phosphate minerals.
文摘The younger granitoids of the Shalatin district in the Southeastern Desert of Egypt, are of biotite and two-mica granite compositions. The geochemistry of rare-earth elements (REE), yttrium, thorium and uranium forms the basis for many important methods to reconstruct igneous petrogenesis. Since the recognition that REE, Y, Th, U-rich accessories may play an important role in controlling the geochemistry of crustal melts, a considerable amount of work has been done in an attempt to understand their effects. However, this effort has been almost exclusively focused on three minerals: zircon, monazite and apatite. Nevertheless, the variety of REE-Th-U-rich accessories in granite rocks are neither limited to these three minerals nor are they always the main REE, Y, Th carriers. The geochemistry of REE, Y, Th and U reflects the behavior of accessories and some key major minerals such as garnet and feldspars, and may therefore give valuable information about the conditions of partial melting, melt segregation and crystallization of granite magmas in different crustal regimes. The geochemistry of U and Th during magmatic differentiation has been studied in many granites from different areas and it has been known that the U and Th contents of granitic rocks generally increase during differentiation, although in some cases they decrease. The Th/U ratio can either increase or decrease, depending on redox conditions, the volatile content or alteration by endogene or supergene solutions. The accessory assemblage of muscovite-rich granites and high-grade rocks is composed of monazite, xenotime, apatite, Th-orthosilicate, secondary U-mineralization and betafite-pyrochlore. REE, Y, Th and U are not suitable for geochemical modeling of granitoids by means of equilibrium-based trace element fractionation equations, but are still useful petrogenetic tools.
文摘Cassiterites from both the Beauvoir and Montebras geanited of France are typically rich in trace elements such as Nb and Ta, and contain quite a number of inclusions of columbite (dominantly manganocolumbite).Two thin sections of cassiterite crystals have been prepared for Raman microprobe analysis).The spectra obtained from different parts of the cassiterites show that the vibra-tion frequency of the A1g peak decreases with increasing Nb ,Ta,Fe and Mn atomic contents.It is worthy to note that a new peak (named the “An peak”) has been reported for the first time in the part with oriented columbite inclusions.The vibration frequency varies from 827 to 830 cm^-1.The presence of th enew peak may be attributed to structural changes of cassiterite due to the excess of Nb and Ta in the lattice and the exsolution of columbite inclusions in cassiterite.
基金supported by the Chinese National Natural Science Foundation(Project No.40273030)the Chinese Academy of Sciences through an innovation project (Project No.KZCX3-SW-124)
文摘The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the partition coefficients D_w,D_(Nb) and D_(Ta)(D_i^(v/m) = C_i^V/C_i^m,where C_i^V and C_i^m denote the concentrations of an element,i,in the aqueous fluid and the melt,respectively) were less than 0.1.All partition coefficients were affected by pressure,but there was no evidence for the complexation of P2O5 with these elements in the granitic melt or aqueous fluid,except for with W in the fluid.The results showed that W,Nb,and Ta tended to partition into the granitic melt and,in the late period of crystallization of P-rich magma,they formed independent minerals.
文摘Li-F granites all over the world can be represented by three end members, i. e., theNa-rich ongonite (O), the K-rich xianghualingite (X) and the Si-rich topazite (T). Charac-ters and criteria are presented for these end-member rocks. Vertical zoning in Li-F granites, asreflected by increasing normative Q and C (corundum) and decreasing ALK (K2O + Na2O)with increasing content of fluorine, can be explained using the three-end-member scheme interms of petrochemistry and norms. Considering the difference in melt structure, viscosity anddensity between the end members, in couple with the reguarities that govern the Na-K and Si-ALK segregation known from field evidence and experiments, it is suggested that the three endmembers may have resulted from liquid segregation (immiscibility) rather than from crystalfractionation as commonly believed.
基金financially supported by scientific research project of Hebei Geological and Mineral Resource Bureau(454-0601-YBN-VKK1)
文摘The mountain rocks in the Dushan Complex are Sr-rich granite with a much higher Sr level than those in other crustal lithospheres in eastern China. That presents a high potential for developing Sr-rich mineral water. In this study, 6 groups of rock samples, together with 30 groups of water samples, were collected. Combining with the existing data, the Sr contents in three different types of underground water were obtained, which are the Quaternary pore water, the meshed bedrock fissure water in weathered zones and the tectonic bedrock fissure water. On the basis of preliminary understanding for the distribution characteristics of Sr-rich mineral water in the Dushan Mountain region, the causes for the Sr-rich mineral water were investigated. Our results showed that the Sr content of the rocks in the studied area ranges from 988 to 1 950 μg/g. In the horizontal direction, those in both the pore water and the meshed bedrock fissure water in weathered zones show high values in the west but low ones in the east, and high ones in the south but low ones in the north. Furthermore, both types of water meet the standard for Sr-rich mineral water in the western areas. In the vertical direction, the Sr content shows the lowest value in pore water(the average value is 0.707 mg/L), middle value in the meshed bedrock fissure water in weathered zones(the average value is 1.415 mg/L) and the highest value in the tectonic bedrock fissure water(the average value is 8.331 mg/L). It was thought that the widely-developed Sr-rich granite in this region provides physical sources for the formation of Sr-rich mineral water. The continuous dissolution of Sr during underground water runoff is the internal mechanism. In addition, the hydraulic interrelations may exist between the three vertical aquifers, leading a continuous accumulation of the Sr level during infiltration.
基金This work was supported by the National Natural Science Foundation of China (Grant Nos. 40073008 and 40132010) the China Universities PhD Subject Foundation Project (Grant No.1999028420).
文摘Though magmatic origin of Li-F-rich granite has been supported effectively by the existence of volcanic and subvolcanic rocks and melt inclusions trapped in them with similar chemical compositions, evidence from high T-P experiments is poor up to now. To simulate the evolution process of Li-F-rich granite and to interpret its forming mechanism, a series of melting-crystallization experiments were carried out. Under the conditions of 1×108 Pa and 570–700°C, a magmatic mineral association of quartz + alkali feldspar + lithium muscovite/ferromuscovite ± fluorite ± cassiterite is found in leucogranite-HF-H2O system. This indicates the following points: (i) Fluorite, light-colored muscovite and cassiterite can crystallize directly from the Li-F-rich granitic melt. (ii) The coexistence of dark-colored micas (e.g. biotite) and light-colored micas (e.g. lithium muscovite and ferromuscovite) suggests that the muscovite granite and two-mica granite can be formed under magmatic condition. The zonal texture of micas is not the sole feature for the micas of hydrothermal origin. (iii) As crystallization proceeds, the SiO2 concentration of the residual melt decreases, while the Al2O3 and F concentrations and A/CNK, NKA/Si ratios of the melt incerese, favoring the formation of Li-F-rich granites. Our experiment results are well consistent with the vertical zonation widely observed in rare metal bearing granites, and therefore provide strong experimental evidence for magmatic origin of Li-F-rich granite.
文摘The newly discovered three alkali\|rich intrusive rock belts in the Mt. Kunlun Mt. Altun region of southern Xinjiang are the Lapeiquan\|Yitunbulak alkali\|rich intrusive rock belt, the Gez\|Taxkorgan alkali\|rich intrusive rock belt and the Beilisai\|Abulash alkali\|rich intrusive rock belt. The former two belts were formed during the Yanshanian period, and the third one was formed during the Himalayan period, which is the youngest alkali\|rich intrusive rock belt in China. The discovery of the alkali\|rich intrusive rock belts is of great significance in shedding light on the history of tectono\|magmatic activities in this region.
