Corrosion fatigue behavior of epoxy-coated Mg-3Al-1Zn alloy in gear oil

The corrosion fatigue behavior of epoxy-coated Mg-3Al-1Zn alloy in gear oil was investigated. The corrosion and the fracture surfaces after fatigue test were analyzed by scanning electron microscopy(SEM) and the corrosion compositions were measured by energy-dispersive spectrometry(EDS). The fatigue properties and the crack initiation mechanisms of the specimens before and after epoxy coating treatment were discussed. The results indicate that the fatigue limit after epoxy coating treatment in gear oil is higher than that of the uncoated specimens. The epoxy coating is an excellent way to prevent direct contact between the Mg-3Al-1Zn alloy and surrounding environments. The mechanical properties of the epoxy coating layer are lower than that of magnesium alloy, which is the main reason for the fatigue crack initiation on the epoxy coating layer. In addition, the gear oil lubrication could lead to the flaking off of the epoxy-coated layer.

Review on Stress Corrosion and Corrosion Fatigue Failure of Centrifugal Compressor Impeller

Corrosion failure,especially stress corrosion cracking and corrosion fatigue,is the main cause of centrifugal compressor impeller failure.And it is concealed and destructive.This paper summarizes the main theories of stress corrosion cracking and corrosion fatigue and its latest developments,and it also points out that existing stress corrosion cracking theories can be reduced to the anodic dissolution（AD）,the hydrogen-induced cracking（HIC）,and the combined AD and HIC mechanisms.The corrosion behavior and the mechanism of corrosion fatigue in the crack propagation stage are similar to stress corrosion cracking.The effects of stress ratio,loading frequency,and corrosive medium on the corrosion fatigue crack propagation rate are analyzed and summarized.The corrosion behavior and the mechanism of stress corrosion cracking and corrosion fatigue in corrosive environments,which contain sulfide,chlorides,and carbonate,are analyzed.The working environments of the centrifugal compressor impeller show the behavior and the mechanism of stress corrosion cracking and corrosion fatigue in different corrosive environments.The current research methods for centrifugal compressor impeller corrosion failure are analyzed.Physical analysis,numerical simulation,and the fluid-structure interaction method play an increasingly important role in the research on impeller deformation and stress distribution caused by the joint action of aerodynamic load and centrifugal load.

Corrosion Fatigue Life Prediction of Aircraft Structure Based on Fuzzy Reliability Approach

Material performance of LY12CZ aluminum is greatly degraded because of corrosion and corrosion fatigue, which severely affect the integrity and safety of aircraft structure, especially those of lbe navy aircraft structure. The corrosion and corrosion fatigue failure process of aircraft structure are directly concerned with many factors, such as load, material characteristics, corrosive environment and so on. The damage mechanism is very complicated, and there are both randomness and fuzziness in the failure process. With consideration of the limitation of those conventional probabilistic approaches for prediction of corrosion fatigue life of aircraft structure at present, and based on the operational load spectrum obtained through investigating service status of the aircraft in naval aviation force, a fuzzy reliability approach is proposed, which is more reasonable and closer to the fact. The effects of the pit aspect ratio, the crack aspect ratio and all fuzzy factors on corrosion fatigue life of aircraft structure are discussed. The results demonstrate that the approach can be applied to predict the corrosion fatigue life of aircraft structure.

Corrosion fatigue crack growth mechanisms in welded joints of marine steel structures

This paper presents a model of fatigue crack growth in a welded joint and a two-dimensional model of anodic dissolution based on Donahue model and anodic dissolution mechanism,respectively.In addition,a model for predicting the corrosion fatigue crack growth rate in welded joints of steel marine structures is established and crack growth mechanisms are analyzed.The results show that during early stages of crack growth,corrosion fatigue crack growth rate in welded joints is mainly controlled by corrosion action,whereas cyclic loading becomes more influential during the later stage of crack propagation.Loading frequency and effective stress ratio can affect rupture period of protective film at the corrosion fatigue crack tip and the length of corrosion crack increment,respectively,which changes the influence of corrosion action on crack growth rate.However,the impact of stress amplitude on crack growth rate is only significant when crack propagation is caused by cyclic loading.Welding residual stress not only improves the effective stress ratio of cyclic loading,but also promotes crack closure and increases corrosion fatigue crack growth rate in welded joints.Compared to corrosion action,welding residual stress has a more significant influence on crack growth caused by cyclic loading.

EFFECT OF POTENTIAL ON INTERACTION BETWEEN STRESS CORROSION CRACKING AND CORROSION FATIGUE OF AUSTENITIC STAINLESS STEEL IN BOILING 42% MgCl_2 SOLUTION

The environment-sensitive fracture behaviour of 0Cr18Ni9Ti austenitic stainless steel in boiling 42% MgCl_2 under the specific load of low frequency and high mean stress was inves- tigated from the relations and differences of crack growth rates and fractographs between stress corrosion fatigue and stress corrosion cracking.The interaction between stress corro- sion cracking and corrosion fatigue was also studied from fracture characteristics with empha- sis on the effects of applied potential on the interaction.

EFFECTS OF STRESS RATIO AND FREQUENCY ON CORROSION FATIGUE CRACK GROWTH MECHANISM IN LOW ALLOY STEELS

Based on theoretical analysis about local strain,strain rate and dissolving rate at crack tip, the corrosion fatigue crack growth rate of steels ZG20SiMn and SM50B-Zc in fresh water and 3.5% NaCl solution were measured experimentally,and the PH and electrode potential within crack were also measured continuously along with crack propagating.It showed that the increase of crack growth rate,caused by both decreasing frequency and raising stress ratio,was mainly accelerated by hydrogen embrittlement.

Corrosion and Fatigue Testing of Microsized 304 Stainless Steel Beams Fabricated by Femtosecond Laser

The 304 stainless steel （SS） microcantilever specimens with dimensions of 30 #m ×30 #m ×50 #m （thicknessx width × length） were fabricated by femtosecond （fs） laser. The microsized cantilevers of good quality with structure and dimensions according commendably with that of the designed cantilever were obtained. The result shows that fs laser micromachining is a promising method for directly fabricating metallic microcomponents. Corrosion and fatigue properties of microsized specimens were carried out on the microsized 304 SS cantilever beams by a newly developed fatigue testing machine. The results show that the microsized 304 SS specimens appear to have an improved resistance towards localized corrosion compared to ordinary-sized 304 SS specimens after the static corrosion testing. The testing result shows that the presence of corrosive solution reduces the fatigue lifetime of the 304 SS specimen by a factor of 10-100. The maximum bending loads measured by fatigue testing machine decrease rapidly at the terminal stage of environment assisted fatigue testing. Corrosion fracture first occurred at the range of notch with a higher tensile bending stress, and exhibited clear evidence of trans-columnar fracture detected by SEM （scanning electron microscopy）.

Corrosion fatigue of the extruded Mg-Zn-Y-Nd alloy in simulated body fluid

Magnesium alloys were considered to be used as biodegradable implants due to their biocompatibility,biodegradability and nontoxicity.However,under the simultaneous action of corrosive environment and mechanical loading in human body,magnesium alloys are easy to be affected by corrosion fatigue and stress corrosion cracking.In this work,the fatigue behavior of the extruded Mg-Zn-Y-Nd alloy used for vascular stents was studied both in air and in simulated body fluid(SBF).It was revealed that the fatigue limit of as-extruded Mg-Zn-Y-Nd alloy in air is about 65 MPa at 10^7 cycles,while there is no limit in SBF and shows a linear relationship between the fatigue life and stress amplitudes.The fatigue crack source in air was formed by the inclusions and defects.However,the stress corrosion and hydrogen embrittlement are the main reasons for the formation of the fatigue initial crack source in SBF.

Mechanism of corrosion fatigue fracture of friction stir welding joints of 7075 aluminium alloy in 3.5% NaCl solution

The corrosion fatigue fracture mechanism of friction stir welding(FSW) joints of 7075 aluminium alloy in3.5% NaCl solution is investigated. The corrosion fatigue crack source originates from the junction of nugget zone(NZ)and thermo-mechanical affected zone(TMAZ). Multiple crack sources are developed at the same time, and they merge into large cracks along the boundary line of NZ and TMAZ during the propagation stage. Furthermore, a mutual reinforcement coupling always exists between corrosion and cyclic loading during the initiation and propagation of corrosion fatigue crack. It is necessary to consider the effect of welding residual stress for understanding the mechanism of corrosion fatigue fracture of FSW joints.

EFFECT OF MICROSTRUCTURE ON CORROSION FATIGUE BEHAVIOUR OF A LOW CARBON BAINITE STEEL

The behaviour towards corrosion fatigue of low carbon bainite steel with various microstructures after tempered at different temperatures has been examined. The susceptibility of the steel to corrosion fatigue may be improved by tempering at 300℃.

EFFECIS OF TEMPERATURE AND OVERLOAD RETARDATION ON CORROSION FATIGUE CRACK GROWTH OF HIGH STRENGTH STEEL

The fatigue crack growth rate (CGR) of ultra high strength steel 30CrMnSiNi2A in distilled water at 18,35 and 55℃ were measured.It was confirmed that the temperature is strongly af- fected on the corrosion fatigue CGR of ultra high strength steel.An expression concerning the effects of Δ K and temperature on the CGR was proposed.The fact that the apparent activation energy (36.6 kJ/mol) resulted from regressive analysis of CGR data was similar to the activation energy of hydrogen diffusion in γ-Fe,strongly supporting the theory of hydrogen-assisted crack growth.The overload retardation effect was greatly reduced in cor- rosion fatigue crack growth,especially at lower frequency,e.g.,0.1 Hz.This phenomenon might be due to the increase of the SCC component of CGR after an overload.

The Corrosion Fatigue Properties of High Performance Concrete

With the loading test equipment of corrosion fatigue specially designed, the corrosion fatigue characteristics of high performance concrete (HPC) withstanding the interaction of third point fatigue loading and Na_2SO_4 solution were investigated and analyzed. The experimental results indicate that water-binder ratio evidently influences the corrosion fatigue characteristics of HPC, and a moderate quantitative fine mineral admixture enhances the corrosion fatigue resistance of HPC. The effect is more significant when fly ash and silica fume are added.

Corrosion fatigue behavior of fastening hole structure and virtual crack propagation tests

The fatigue crack propagation behavior of the LY12CZ aluminum alloy fastener involving a central hole in air or in 3.5wt% NaCl solution was investigated. The experimental results indicated that the corrosion fatigue crack growth rate decreased with the increasing loading frequency,and in a corrosive environment,the crack growth rate was slightly larger than that in air. Based on the experimental results,the virtual corrosion fatigue crack propagation tests were investigated and the stochastic process method and the AFGROW simulation method were presented. The normal process and lognormal process were considered for the stochastic process method based on the numerically fitted Paris equation. The distribution of crack size and the corresponding probabilistic model of crack length distribution for a given number of cycles can be found by integrating the stochastic process over time. Using the AFGROW software,the virtual simulation was carried out to analyze the corrosion fatigue crack growth behavior and the predicted crack growth curve was in good agreement with the experimental results.

Corrosion Fatigue Behavior of Duplex Stainless Steel in 3.5% Sodium Chloride Solution

The corrosion fatigue behavior of duplex stainless steel (DSS) was studied at different cyclic stress levels in 3.5%NaCl (mass fraction, so as the follows) solution (pH=7) at 50 degreesC. The results showed that DSS was susceptible to pitting corrosion and corrosion fatigue. Both intergranluar corrosion cracking and transgranlular corrosion cracking initiated at the bottom of pitting holes. Furthermore, the corrosion fatigue properties of DSS in 3.5%NaCl solution may be relatived to complex electrochemical and mechanical coupling effects between the three phases (austenite, ferrite and martensite), where martensite and ferrite were anodic in the corrosion cell and could be prone to cracking under certain condition.

Saturation Dislocation Microstructures of Double-slip-oriented Copper Single Crystal during the Corrosion Fatigue in a 0.5 mol/L NaCl Aqueous Solution

Copper single crystal specimens with the longitudinal axis parallel to the [013] double-slip-orientation were grown through Bridgman technique. The fatigue tests were performed using a symmetric tension-compression load mode at room temperature in an open-air and a 0.5 mol/L NaCl solution, respectively. The dislocation microstructures were observed with scanning electron microscopy (SEM) by the electron channeling contrast (ECC) and transmission electron microscopy (TEM). The results show that the saturation dislocation microstructures during the corrosion fatigue in the aqueous solution of 0.5 mol/L NaCI, mainly consisted of labyrinth, wall and vein dislocation structures, which differs from the dislocation structures of the walls and veins in an open-air environment.

CORROSION FATIGUE CRACK GROWTH OF MEDIUM STRENGTH STEEL HT60 IN SYNTHETIC SEA WATER

The corrosion fatigue crack growth and near-threshold characteristics of a medium strength steel HT60 were investigated using compact tension specimens exposed to synthetic sea water. The da/dN-△AK_(eff) relation in air can give a conservative estimation of da/dN-△K relations in sea water. In the case of high R, however, crack growth acceleration at high △K regions appears to be cantrolled by the stress-assisted dissolution. The crack opening stress inlensity factor K_(op) detected by the back-face-strain method is the result of crack surface in contact with the corrosion products and therefore an overestimated value of K_(op) at the crack tip is given.

EFFECTS OF HEAT TREATMENT AND ENVIRONMENT ON CRACK PROPAGATION RATE IN STEEL GC-4 UNDER CORROSION FATIGUE AND STRESS CORROSION

Comparative investigations were carried out of the effect of heat treatment regimes Jor steel GC-4(40CrMnSiMoVA)on its crack propagating rates,from corrosion fatigue, (da/dN)_(CF),or stress corrosion cracking,(da/dt)_(SCC),in media with various constituents and pH values.Both(da/dN)_(CF) and(da/dt)_(SCC) accelerate with the increase of yield stress of the steel,yet the former is far less than the later.In comparison with media,the (da/dt)_(SCC) in distilled water is slightly greater than that in 3.5% NaCl solution,and the (da/dN)_(CF) in distilled water is far less than that in 3.5% NaCl solution.With the pH value increasing in 3.5% NaCl solution,the(da/dN)_(CF) lowers down and the(da/dt)_(SCC) speeds up.An explanation was also proposed with concept of the cyclic hardening and softening at crack tip,as well as the crack closure and occluded cell effect.

CORROSION FATIGUE BEHAVIOR OF STAINLESS STEEL 3RE60 IN 3.5% SODIUM CHLORIDE SOLUTION

The corrosion fatigue behavior of stainless steel 3RE60 in 3.5%NaCl solution was studied at different cyclic stress levels. The results showed that both intergranular corrosion cracking and transgranular corrosion cracking initiated at the bottom of pits. The corrosion fatigue behavior of 3RE60 may be related to complex electrochemical and mechanical coupling effects between the three phases (austenite, ferrite and martensite), where martensite and ferrite were anodic in the corrosion cell and could be prone to crack under certain conditions.

Role of Pits in Corrosion Fatigue of Offshore Structural Steel

From the corrosion fatigue test under intermit- tent wetting condition for offshore structural steel of A537 cl.l and data analysis,some results associ- ated with the role of pits in fatigue process have been discussed.

Seawater Corrosion Fatigue of Welded Joints Under Random Variable Amplitude Loading

Offshore platforms are always subjected to wave action which is random variable amplitude cyclic loading. In order to simulate the stressing condition at the 'hot spot' of the tubular joints and the marine environment, random variable amplitude fatigue tests have been carried out on welded plate joints in sea water. The tests have been conducted under the conditions of loading frequency of 0.2 Hz/, stress ratio of -1, seawater temperature of about 20°C and cathodic protection with the potential about -850 mV, SCE. The test results have been compared with the seawater corrosion fatigue life under constant amplitude loading. Miner's linear cumulative damage summation rule has been used to predict the corrosion fatigue life under variable amplitude loading. The predicted life is in good agreement with the test data.