Correlation of work function and stacking fault energy through Kelvin probe force microscopy and nanohardness in diluteα-magnesium

Electronic interactions of the Group 2A elements with magnesium have been studied through the dilute solid solutions in binary Mg-Ca,Mg-Sr and Mg-Ba systems.This investigation incorporated the difference in the‘Work Function'(ΔWF)measured via Kelvin Probe Force Microscopy(KPFM),as a property directly affected by interatomic bond types,i.e.the electronic structure,nanoindentation measurements,and Stacking Fault Energy values reported in the literature.It was shown that the nano-hardness of the solid-solutionα-Mg phase changed in the order of Mg-Ca>Mg-Sr>Mg-Ba.Thus,it was shown,by also considering the nano-hardness levels,that SFE of a solid-solution is closely correlated with its‘Work Function'level.Nano-hardness measurements on the eutectics andΔWF difference between eutectic phases enabled an assessment of the relative bond strength and the pertinent electronic structures of the eutectics in the three alloys.Correlation withΔWF and at least qualitative verification of those computed SFE values with some experimental measurement techniques were considered important as those computational methods are based on zero Kelvin degree,relatively simple atomic models and a number of assumptions.As asserted by this investigation,if the results of measurement techniques can be qualitatively correlated with those of the computational methods,it can be possible to evaluate the electronic structures in alloys,starting from binary systems,going to ternary and then multi-elemental systems.Our investigation has shown that such a qualitative correlation is possible.After all,the SFE values are not treated as absolute values but rather become essential in comparative investigations when assessing the influences of alloying elements at a fundamental level,that is,free electron density distributions.Our study indicated that the principles of‘electronic metallurgy'in developing multi-elemental alloy systems can be followed via practical experimental methods,i.e.ΔWF measurements using KPFM and nanoindentation.

Stacking fault energy,yield stress anomaly, and twinnability of Ni_3Al:A first principles study

Using first principles calculations combined with the quasiharmonic approach, we study the effects of temperature on the elastic constants, generalized stacking fault energies, and generalized planar fault energies of Ni3Al. The antiphase boundary energies, complex stacking fault energies, superlattice intrinsic stacking fault energies, and twinning energies decrease slightly with temperature. Temperature dependent anomalous yield stress of Ni3Al is predicted by the energybased criterion based on elastic anisotropy and antiphase boundary energies. It is found that p increases with temperature and this can give a more accurate description of the anomalous yield stress in Ni3Al. Furthermore, the predicted twinnablity of Ni3Al is also decreasing with temperature.

EFFECT OF Cr AND Al CONTENT ON THE STACKING FAULT ENERGY IN r-Fe-Mn ALLOYS

The effects of Cr and Al content were investigated on the stacking fault energy in austenitic Fe-31Mn-(0-7.26)Cr-0.96C and Fe-31Mn-(0-8.68)Al-0.85C alloys by the thermodynamic analysis. The results show that the additions of chromium or aluminum increase the non-magnetic component of the stacking fault energy in the γ-Fe-Mn alloys, and the effect of aluminum is larger than that of chromium. The change in the magnetic entropy caused in the antiferromagnetic transition increases the free energy difference between the γ and s phases in the γr-Fe-Mn alloys. The effects of chromium and aluminum on the magnetic component were discussed on the basis of the influence of both upon the antiferromagnetic transition in the γ-Fe-Mn alloys.

The generalized planar fault energy, ductility, and twinnability of Al and Al–RE( RE= Sc, Y, Dy, Tb, Nd) at different temperatures:A first-principles study

The genearlized planar fault energies of Al and Al-RE （RE = Sc, Y, Dy, Tb, Nd） alloys have been investigated using first-principles methods combined with a quasiharmonic approach. The stacking fault energies, unstable stacking fault energies, and unstable twinning energies decrease slightly with increasing temperature. The ductility parameter D, the relative barrier difference Sut, and the twinnability τa of Al and Al-RE alloys at different temperatures have been determined. It is found that the ductilities of Al and Al alloys are nearly the same and the ductilities increase slightly with increasing temperature. The RE alloying elements make twinning more likely and the twinnabilities of Al and Al alloys decrease with increasing temperature.

Variation in Creep Rupture of γ′ Strengthened Superalloys with Stacking Fault Energy of Matrices

The correlation between the creep rupture behaviour and the stacking fault energy of matrices of γ′strengthened superalloys has been studied dur- ing constant load creep.At high temperature and intermediate stress,the creep rupture time and strain strongly depend on the stacking fault energy of matrices rather than the creep friction stress,but at higher stress,the role of grain boundary carbides becomes more obvious. However,in the considerably extensive stress range investigated here,the mean creep rate is a power function of the stacking fault energy of matrices and the power index decreases with in- creasing initial applied stress.Particularly,at inter- mediate stresses the product of this index and the initial applied stress compensated by the shear modulus is same for two series of superalloys. Hence,this product may be a criterion predicting that the matrix deformation controls high tempera- ture creep rupture.

Stacking fault probability and stacking fault energy in CoNi alloys

The stacking fault probability of CoNi alloys with different contents of Ni was measured by X ray diffraction methods. The results show that the stacking fault decreases with increasing Ni content and with increasing temperature. The thermodynamical calculation has found an equation that can express the stacking fault energy γ of CoNi at temperature T . The phase equilibrium temperature depends on the composition of the certain alloy. The relationship between stacking fault energy γ and stacking fault probability P sf is determined.

Nanoscale fluctuation of stacking fault energy strengthens multi-principal element alloys

Chemical randomness and the associated energy fluctuation are essential features of multi-principal ele-ment alloys(MPEAs).Due to these features,nanoscale stacking fault energy(SFE)fluctuation is a natural and independent contribution to strengthening MPEAs.However,existing models for conventional alloys(i.e.,alloys with one principal element)cannot be applied to MPEAs.The extreme values of SFEs required by such models are unknown for MPEAs,which need to calculate the nanoscale volume relevant to the SFE fluctuation.In the present work,we developed an analytic model to evaluate the strengthening ef-fect through the SFE fluctuation,profuse in MPEAs.The model has no adjustable parameters,and all parameters can be determined from experiments and ab initio calculations.This model explains available experimental observations and provides insightful guidance for designing new MPEAs based on the SFE fluctuation.It generally applies to MPEAs in random states and with chemical short-range order.

Predicting the variation of stacking fault energy for binary Cu alloys by first-principles calculations

The variation of stacking fault energy(SFE)in a number of binary Cu alloys is predicted through considering the Suzuki segregation by the full potential linearly augmented plane wave(FPLAPW)method.The calculated results show that some solute atoms(Mg,Al,Si,Zn,Ga,Ge,Cd,Sn,and Pb),which prefer to form the Suzuki segregation,may decrease the value of SFE;while the others(Ti,Mn,Fe,Ni,Zr,Ag,and Au),which do not cause the Suzuki segregation may not decrease the SFE.Furthermore,it is interesting to find that the former alloying elements are located on the right of Cu group while the latter on the left of Cu group in the periodic table of elements.The intrinsic reasons for the new findings can be traced down to the valences electronic structure of solute and Cu atoms,i.e.,the similarity of valence electronic structure between solute and Cu atoms increases the value of SFE,while the difference decreases the value of SFE.

Texture and Microstructure Evolution During Tensile Testing of TWIP Steels with Diverse Stacking Fault Energy

Texture and microstructure evolution in two kinds of the twinning induced plasticity （TWIP） steels （Fe-Mn- Si-AI and Fe-Mn-C） with diverse stacking fault energies during tensile testing were investigated by interrupted testing. The strain-hardening rate curves of the two steels were quite similar, but the texture characterization curves （maximum of pole density measured by X-ray diffraction） were varied. According to the curvature of max pole density curves, the evolution of the texture and the microstructure can be divided into three stages： low strain stage, medium stage and high stage. In low strain stage the difference of the microstructure came from the intensity of dislocation, which was much smaller in Fe-Mn-Si-AI. The main difference of the microstructure in medium and high strain stages originated from the numbers of activated twin systems. There were more than one twin systems activated in Fe-Mn-C, while only a single twin system activated in Fe-Mn-Si-AI. Texture showed various differences in the whole tensile process because it was affected by their micromechanism, such as concentration of the dislocation and the activation of twin systems. Texture in low strain stage was connected with annealing twin; the evolution ofthe texture was mainly induced by deformation twin generation. More than one activated twin systems in medium and high stages may counteract each other in the view of concentration of the grain orientations.

Influence of Temperature on Stacking Fault Energy and Creep Mechanism of a Single Crystal Nickel-based Superalloy

The influence of temperatures on the stacking fault energies and deformation mechanism of a Re- containing single crystal nickel-based superalloy during creep at elevated temperatures was investigated by means of calculating the stacking fault energy of alloy, measuring creep properties and performing contrast analysis of dislocation configuration. The results show that the alloy at 760 ℃ possesses lower stacking fault energy, and the stacking fault of alloy increases with increasing temperature. The defor- mation mechanism of alloy during creep at 760 ℃ is 7＇ phase sheared by 〈110〉 super-dislocations, which may be decomposed to form the configuration of Shockley partials plus super-lattice intrinsic stacking fault, while the deformation mechanism of alloy during creep at 1070 ℃ is the screw or edge super- dislocations shearing into the rafted 7＇ phase. But during creep at 7（50 and 980 ℃, some super- dislocations shearing into 7＇ phase may cross-slip from the {111} to {100} planes to form the K-W locks with non-plane core structure, which may restrain the dislocations slipping to enhance the creep resis- tance of alloy at high temperature. The interaction between the Re and other elements may decrease the diffusion rate of atoms to improve the microstructure stability, which is thought to be the main reason why the K-W locks are to be kept in the Re-containing superalloy during creep at 980 ℃.

Effect of Carbon Content on Stacking Fault Energy of Fe-20Mn-3Cu TWIP Steel

The influence of carbon content on the stacking fault energy （SFE） of Fe-20Mn-3Cu twinning-induced plasticity （TWIP） steel was investigated by means of X-ray diffraction peak-shift method and thermodynamic modeling. The experimental result indicated that the stacking fault probability decreases with increasing carbon addition, the SFE increases linearly when the carbon content in mass percent is between 0.23 M and 1.41%. The thermody namic calculation results showed that the SFE varied from 22.40 to 29.64 mJ ~ m 2 when the carbon content in mass percent changes from 0.23 % to 1.41%. The XRD analysis revealed that all steels were fully austenitic before and after deformation, which suggested that TWIP effect is the predominant mechanism during the tensile deformation process of Fe-20Mn-3Cu-XC steels.

Effective Stacking Fault Energy in Face-Centered Cubic Metals

As a typical configuration in plastic deformations, dislocation arrays possess a large variation of the separation of the partial dislocation pairs in face-centered cubic（fcc） metals. This can be manifested conveniently by an effective stacking fault energy（SFE）. The effective SFE of dislocation arrays is described within the elastic theory of dislocations and verified by atomistic simulations. The atomistic modeling results reveal that the general formulae of the effective SFE can give a reasonably satisfactory prediction for all dislocation types, especially for edge dislocation arrays. Furthermore, the predicted variation of the effective SFE is consistent with several previous experiments, in which the measured SFE is not definite, changing with dislocation density. Our approach could provide better understandings of cross-slip and the competition between slip and twinning during plastic deformations in fcc metals.

Counter-balancing effects of Si on C partitioning and stacking fault energy of austenite in 10Mn quenching and partitioning steel

Silicon is an essential alloying element in quenching and partitioning(Q&P)steels,because it is known to suppress carbide precipitation during partitioning step and promote carbon partitioning to stabilize austenite.When 2 wt%Si was added to 10Mn-2Al-0.2C steel,the size and fraction of the carbides formed during partitioning became smaller than in the Si-free counterpart.Moreover,the suppression of carbide formation promoted C partitioning into austenite as expected.However,austenite stability was always lower with Si under the equivalent partitioning condition because Si effectively decreased the stacking fault energy of austenite.As partitioning progressed,the both yield and tensile strengths of the Si-added steel exceeded that of the Si-free steel with the similar ductility level.This was because Si was an effective solid solution strengthener,and the austenite in the Si-added steel exhibited the appropriate stability to gradually transform into martensite throughout the deformation.The resulting strengthening effect compensated for the softening caused by martensite recovery.Consequently,strain hardening rate decreased continuously throughout deformation,which resulted in high tensile strength and ductility.

Uniaxial Ratcheting Behaviors of Metals with Different Crystal Structures or Values of Fault Energy: Macroscopic Experiments

The uniaxial ratcheting behaviors of several metals with different crystal structures or values of fault energy were observed by the stress-controlled cyclic tests at room temperature. The prescribed metals included 316L stainless steel, pure copper, pure aluminum, and ordinary 20# carbon steel. The effects of applied mean stress, stress amplitude and stress ratio on the uniaxial ratcheting were also investigated. The observations show that different crystal structures or values of fault energy result in more or less different ratcheting behaviors for the prescribed metals. The different ratcheting behaviors are partially caused by the variation of dislocation mobility.

On the stacking fault forming probability and stacking fault energy in carbon-doped 17 at%Mn steels via transmission electron microscopy and atom probe tomography

Assessing the stacking fault forming probability(P_(sf)) and stacking fault energy(SFE)in medium-or highMn base structural materials can anticipate and elucidate the microstructural evolution before and after deformation.Typically,these two parameters have been determined from theoretical calculations and empirical results.However,the estimation of SFE values in Fe–Mn–C ternary systems is a longstanding debate due to the complicated nature of carbon:that is,whether the carbon doping indeed plays an important role in the formation of stacking faults;and how the amount of carbon atoms exist at grain boundaries or at internal grains with respect to the nominal carbon doping contents.Herein,the use of atom probe tomography and transmission electron microscopy(TEM)unveils the influence of carbondoping contents on the structural properties of dual-phase Fe–17 Mn–x C(x=0–1.56 at%)steels,such as carbon segregation free energy at grain boundaries,carbon concentration in grain interior,interplanar D-spacings,and mean width of intrinsic stacking faults,which are essential for SFE estimation.We next determined the Psfvalues by two different methods,viz.,reciprocal-space electron diffraction measurements and stacking fault width measurements in real-space TEM images.Then,SFEs in the Fe–17 Mn–x C systems were calculated on the basis of the generally-known SFE equations.We found that the high amount of carbon doping gives rise to the increased SFE from 8.6 to 13.5 m J/m^(2)with non-linear variation.This SFE trend varies inversely with the mean width of localized stacking faults,which pass through both other stacking faults and pre-existingε-martensite plates without much difficulty at their intersecting zones.The high amount of carbon doping acts twofold,through increasing the segregation free energy(due to more carbon at grain boundaries)and large lattice expansion(due to increased soluble carbon at internal grains).The experimental data obtained here strengthens the composition-dependent SFE maps for predicting the deformation structure and mechanical response of other carbon-doped high-Mn alloy compositions.

HYBRID WAVELET PACKET-TEAGER ENERGY OPERATOR ANALYSIS AND ITS APPLICATION FOR GEARBOX FAULT DIAGNOSIS

Based on wavelet packet decomposition （WPD） algorithm and Teager energy operator （TEO）, a novel gearbox fault detection and diagnosis method is proposed. Its process is expatiated after the principles of WPD and TEO modulation are introduced respectively. The preprocessed sigaaal is interpolated with the cubic spline function, then expanded over the selected basis wavelets. Grouping its wavelet packet components of the signal based on the minimum entropy criterion, the interpolated signal can be decomposed into its dominant components with nearly distinct fault frequency contents. To extract the demodulation information of each dominant component, TEO is used. The performance of the proposed method is assessed by means of several tests on vibration signals collected from the gearbox mounted on a heavy truck. It is proved that hybrid WPD-TEO method is effective and robust for detecting and diagnosing localized gearbox faults.

NEW DEMODULATION TECHNOLOGY OF OPTIMIZING ENERGY OPERATOR AND APPLICATION TO GEAR FAULT DIAGNOSIS

Although many methods have been applied to diagnose the gear thult currently, the sensitivity of them is not very good. In order to make the diagnosis methods have more excellent integrated ability in such aspects as precision, sensitivity, reliability and compact algorithm, and so on, and enlightened by the energy operator separation algorithm （EOSA）, a new demodulation method which is optimizing energy operator separation algorithm （OEOSA） is presented. In the algorithm, the non-linear differential operator is utilized to its differential equation： Choosing the unit impulse response length of filter and fixing the weighting coefficient for inportant points. The method has been applied in diagnosing tooth broden and fatiguing crack of gear faults successfully. It provides demodulation analysis of machine signal with a new approach.

Determination of stacking fault energies in a high-Nb TiAl alloy at 298 K and 1273 K

The stacking fault energies of Ti-46Al-8.5Nb-0.2W alloy at 298 K and 1273 K were determined. The principle for the determination of the stacking fault energies is based on the fact that the stacking fault energy and the elastic interaction energy acting on the dissociated partial dislocations are equal. After the compress deformations with the strain of 0.2% at 298 K and 1273 K, and water quench to maintain the dislocation structures deformed at 1273 K, the dissociation distances between two partial dislocations were determined by weak beam transmission electron microscopy (WBTEM) technique. Based on these dissociation distances and the corresponding calculation method, the stacking fault energies were determined to be 77-81 mJ/m2 at 298 K and to be 57-60mJ/m2 at 1273 K respectively.

First-principles study of the effects of selected interstitial atoms on the generalized stacking fault energies, strength, and ductility of Ni

We analyze the influences of interstitial atoms on the generalized stacking fault energy （GSFE）, strength, and ductility of Ni by first-principles calculations. Surface energies and GSFE curves are calculated for the （112） （111） and / 101） （ 1 1 1） systems. Because of the anisotropy of the single crystal, the addition of interstitials tends to promote the strength of Ni by slipping along the （10T） direction while facilitating plastic deformation by slipping along the （115） direction. There is a different impact on the mechanical behavior of Ni when the interstitials are located in the slip plane. The evaluation of the Rice criterion reveals that the addition of the interstitials H and O increases the brittleness in Ni and promotes the probability of cleavage fracture, while the addition of S and N tends to increase the ductility. Besides, P, H, and S have a negligible effect on the deformation tendency in Ni, while the tendency of partial dislocation is more prominent with the addition of N and O. The addition of interstitial atoms tends to increase the high-energy barrier γmax, thereby the second partial resulting from the dislocation tends to reside and move on to the next layer.

Determination of stacking fault energies in a high-Nb TiAl alloy at 298 K and 1273 K

The stacking fault energies of Ti-46Al-8.5Nb-0.2W alloy at 298 K and 1273 Kwere determined. The principle for the determination of the stacking fault energies is based on thefact that the stacking fault energy and the elastic interaction energy acting on the dissociatedpartial dislocations are equal. After the compress deformations with the strain of 0.2% at 298 K and1273 K, and water quench to maintain the dislocation structures deformed at 1273 K, thedissociation distances between two partial dislocations were determined by weak beam transmissionelectron microscopy (WBTEM) technique. Based on these dissociation distances and the correspondingcalculation method, the stacking fault energies were determined to be 77-81 mJ/m^2 at 298 K and tobe 57-60mJ/m^2 at 1273 K respectively.