A series of single bcc,bcc plus fcc duplex and single fcc microcrystalline coatings of 1Cr18Ni9Ti stainless steel were prepared by using sputtering technique.The resistance against pitting corrosion was studied by mea...A series of single bcc,bcc plus fcc duplex and single fcc microcrystalline coatings of 1Cr18Ni9Ti stainless steel were prepared by using sputtering technique.The resistance against pitting corrosion was studied by measurements of pitting corrosion potentials and electrochemical noise during initiation of corrosion pits.The results show that the sputtered coatings with single bcc phase or single fcc structure are more resistant to pitting corrosion than those with bcc plus fcc duplex phase structure.展开更多
The NiCoCrAlY coatings strengthened by three nano-particles with the same addition were prepared on a Ni-base super alloy using laser cladding technique. The dry frictional wear behaviors of the coatings at 500 ℃ in ...The NiCoCrAlY coatings strengthened by three nano-particles with the same addition were prepared on a Ni-base super alloy using laser cladding technique. The dry frictional wear behaviors of the coatings at 500 ℃ in static air were investigated. The comparison was made with the coating without nano-particles. The results show that the wear mechanism of the NiCoCrAlY coatings with nano-particles, like the coating without nano-particles, is the delamination wear due to the strong plastic deformation and oxidative wear. However, the frictional coefficient of the coatings increases and presents the decrease trend with the increase of sliding distance after adding nano-particles. Moreover, the wear rate of the coatings with nano-particles is only 34.0%-64.5% of the coating without nano-particles. Among the three nano-particles, the improvement of nano-SiC on the high temperature wear resistance of the coating is the most significant.展开更多
Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporate...Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporated with a HfC coating to construct a robust structure with Hf_(0.5)Ta_(0.5)C solid solution nanowires uniformly distributed and interconnected within the coating.The novel Hf_(0.5)Ta_(0.5)C solid solution nanowires could effectively hinder crack propagation through crack tip pinning and crack deflection.This mechanism substantially enhanced the elastic modulus and fracture toughness of the HfC coating by 53.29%and 59.67%,respectively.The toughened HfC coating displayed superior fracture toughness and good interfacial binding strength with the substrate to resist severe oxidation and scouring.Additionally,the high thermal conductivity of the toughened HfC coating promoted heat transmission.Thus,in comparison to the pure HfC coating,the toughened HfC coating displayed smaller mass and linear ablation rates of−0.35 mg·s^(−1)and−0.46μm·s^(−1),which decreased by 39.66%and 36.98%,respectively.Our work not only simultaneously enhances the mechanical properties and ablation resistance of HfC-coated carbon/carbon(C/C)composites but also provides novel prospects for advanced ultrahigh-temperature ceramic nanowires under extreme conditions.展开更多
Carbon/carbon （C/C） composites were deposited with graphite-like carbon （GLC） coating, and then, Arg-Gly- Asp acid （RGD） peptides were successfully immobilized onto the functionalized GLC coating. GLC coating wa...Carbon/carbon （C/C） composites were deposited with graphite-like carbon （GLC） coating, and then, Arg-Gly- Asp acid （RGD） peptides were successfully immobilized onto the functionalized GLC coating. GLC coating was utilized to prevent carbon particles releasing and create a uniform surface condition for C/C composites. RGD peptides were utilized to improve biocompatibility of GLC coating. Surface chemical characterizations of functionalized GLC coating were detected by contact angle measurement, X-ray photoelectron spectroscopy and Raman spectra. Optical morphology of GLC coatings was observed by confocal laser scanning microscopy. In vitro biological performance was determined using samples seeded with MC3T3-E1 osteoblast-like cells and cultured for 1 week. Surface characterizations and morphological analysis indicated that C/C composites were covered by a dense and uniform GLC coating. Contact angle of GLC coating was reduced to 27.2° when it was functionalized by H202 oxidation at 40 ℃ for 1 h. In vitro cytological test showed that the RGD peptides immobilized GLC coating had a significant improvement in biocompatibility. It was suggested that RGD peptides provided GLC coating with a bioactive surface to improve cell adhesion and proliferation on C/C composites.展开更多
To reveal the influence of substrate/coating interdiffusion on the cyclic oxidation property of a metallic coating, cyclic oxida- tion behavior of an EB-PVD CoCrAIY coating on directionally solidified Ni-based superal...To reveal the influence of substrate/coating interdiffusion on the cyclic oxidation property of a metallic coating, cyclic oxida- tion behavior of an EB-PVD CoCrAIY coating on directionally solidified Ni-based superalloy DZ125 at 1 050℃ is investigated. The 40 μm thick CoCrA1Y coating has a cyclic oxidation life of around 160 h, and the oxidation constant is 1.915× 10^-7 mg4.cm^-8.s-1. However, severe spallation of the oxides containing Co, Cr, Ni, Ta and Ti occurs with longer cyclic oxidation. The degradation in oxidation resistance for the coating is related to the depletion of A1 due to the oxide spallation and interdiffu- sion. Severe interdiffusion between the coating and underlying substrate occurs at 1 050 ℃. The composition of the substrate has an important effect on the thermal cycling lifetime of the coating. The influencing mechanism is discussed.展开更多
文摘A series of single bcc,bcc plus fcc duplex and single fcc microcrystalline coatings of 1Cr18Ni9Ti stainless steel were prepared by using sputtering technique.The resistance against pitting corrosion was studied by measurements of pitting corrosion potentials and electrochemical noise during initiation of corrosion pits.The results show that the sputtered coatings with single bcc phase or single fcc structure are more resistant to pitting corrosion than those with bcc plus fcc duplex phase structure.
基金Project(20060287019)supported by the Research Fund for Doctoral Program of Higher Education of ChinaProject(kjsmcx07001)supported by the Opening Research Fund of Jiangsu Key Laboratory of Tribology,ChinaProject(BK2010267)supported by the Jiangsu Provincial Natural Science Foundation of Jiangsu Province,China
文摘The NiCoCrAlY coatings strengthened by three nano-particles with the same addition were prepared on a Ni-base super alloy using laser cladding technique. The dry frictional wear behaviors of the coatings at 500 ℃ in static air were investigated. The comparison was made with the coating without nano-particles. The results show that the wear mechanism of the NiCoCrAlY coatings with nano-particles, like the coating without nano-particles, is the delamination wear due to the strong plastic deformation and oxidative wear. However, the frictional coefficient of the coatings increases and presents the decrease trend with the increase of sliding distance after adding nano-particles. Moreover, the wear rate of the coatings with nano-particles is only 34.0%-64.5% of the coating without nano-particles. Among the three nano-particles, the improvement of nano-SiC on the high temperature wear resistance of the coating is the most significant.
基金the National Key R&D Program of China(No.2021YFA0715803)the National Natural Science Foundation of China(Nos.52293373 and 52130205)+1 种基金the Joint Fund of Henan Province Science and Technology R&D Program(No.225200810002)the Fundamental Research Funds of Henan Academy of Sciences(No.240621040).
文摘Ultra-high-temperature ceramic nanowires have shown increasing potential for use as thermal structural components.Herein,novel single-crystal Hf_(0.5)Ta_(0.5)C solid solution nanowires were synthesized and incorporated with a HfC coating to construct a robust structure with Hf_(0.5)Ta_(0.5)C solid solution nanowires uniformly distributed and interconnected within the coating.The novel Hf_(0.5)Ta_(0.5)C solid solution nanowires could effectively hinder crack propagation through crack tip pinning and crack deflection.This mechanism substantially enhanced the elastic modulus and fracture toughness of the HfC coating by 53.29%and 59.67%,respectively.The toughened HfC coating displayed superior fracture toughness and good interfacial binding strength with the substrate to resist severe oxidation and scouring.Additionally,the high thermal conductivity of the toughened HfC coating promoted heat transmission.Thus,in comparison to the pure HfC coating,the toughened HfC coating displayed smaller mass and linear ablation rates of−0.35 mg·s^(−1)and−0.46μm·s^(−1),which decreased by 39.66%and 36.98%,respectively.Our work not only simultaneously enhances the mechanical properties and ablation resistance of HfC-coated carbon/carbon(C/C)composites but also provides novel prospects for advanced ultrahigh-temperature ceramic nanowires under extreme conditions.
基金supported by the National Natural Science Foundation of China under Grant Nos.51202194 and 51221001the Programme of Introducing Talents of Discipline to Universities(‘‘111’’project of China)under Grant No.B08040
文摘Carbon/carbon （C/C） composites were deposited with graphite-like carbon （GLC） coating, and then, Arg-Gly- Asp acid （RGD） peptides were successfully immobilized onto the functionalized GLC coating. GLC coating was utilized to prevent carbon particles releasing and create a uniform surface condition for C/C composites. RGD peptides were utilized to improve biocompatibility of GLC coating. Surface chemical characterizations of functionalized GLC coating were detected by contact angle measurement, X-ray photoelectron spectroscopy and Raman spectra. Optical morphology of GLC coatings was observed by confocal laser scanning microscopy. In vitro biological performance was determined using samples seeded with MC3T3-E1 osteoblast-like cells and cultured for 1 week. Surface characterizations and morphological analysis indicated that C/C composites were covered by a dense and uniform GLC coating. Contact angle of GLC coating was reduced to 27.2° when it was functionalized by H202 oxidation at 40 ℃ for 1 h. In vitro cytological test showed that the RGD peptides immobilized GLC coating had a significant improvement in biocompatibility. It was suggested that RGD peptides provided GLC coating with a bioactive surface to improve cell adhesion and proliferation on C/C composites.
基金National Natural Science Foundation of China (50731001, 51071013, 51001032)National Basic Research Program of China (2010CB631200)
文摘To reveal the influence of substrate/coating interdiffusion on the cyclic oxidation property of a metallic coating, cyclic oxida- tion behavior of an EB-PVD CoCrAIY coating on directionally solidified Ni-based superalloy DZ125 at 1 050℃ is investigated. The 40 μm thick CoCrA1Y coating has a cyclic oxidation life of around 160 h, and the oxidation constant is 1.915× 10^-7 mg4.cm^-8.s-1. However, severe spallation of the oxides containing Co, Cr, Ni, Ta and Ti occurs with longer cyclic oxidation. The degradation in oxidation resistance for the coating is related to the depletion of A1 due to the oxide spallation and interdiffu- sion. Severe interdiffusion between the coating and underlying substrate occurs at 1 050 ℃. The composition of the substrate has an important effect on the thermal cycling lifetime of the coating. The influencing mechanism is discussed.
