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Ultrafine ordered L1_(2)-Pt-Co-Mn ternary intermetallic nanoparticles as high-performance oxygen-reduction electrocatalysts for practical fuel cells
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作者 Enping Wang Liuxuan Luo +12 位作者 Yong Feng Aiming Wu Huiyuan Li Xiashuang Luo Yangge Guo Zehao Tan Fengjuan Zhu Xiaohui Yan Qi Kang Zechao Zhuang Daihui Yang Shuiyun Shen Junliang Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期157-165,I0005,共10页
The long-range periodically ordered atomic structures in intermetallic nanoparticles(INPs)can significantly enhance both the electrocatalytic activity and electrochemical stability toward the oxygen reduction reaction... The long-range periodically ordered atomic structures in intermetallic nanoparticles(INPs)can significantly enhance both the electrocatalytic activity and electrochemical stability toward the oxygen reduction reaction(ORR)compared to the disordered atomic structures in ordinary solid-solution alloy NPs.Accordingly,through a facile and scalable synthetic method,a series of carbon-supported ultrafine Pt_3Co_(x)Mn_(1-x)ternary INPs are prepared in this work,which possess the"skin-like"ultrathin Pt shells,the ordered L1_(2) atomic structure,and the high-even dispersion on supports(L1_(2)-Pt_3Co_(x)Mn_(1-x)/~SPt INPs/C).Electrochemical results present that the composition-optimized L1_(2)-Pt_3Co_(0.7)Mn_(0.3)/~SPt INPs/C exhibits the highest electrocata lytic activity among the series,which are also much better than those of the pristine ultrafine Pt/C.Besides,it also has a greatly enhanced electrochemical stability.In addition,the effects of annealing temperature and time are further investigated.More importantly,such superior ORR electrocatalytic performance of L1_(2)-Pt_3Co_(0.7)Mn_(0.3)/~SPt INPs/C are also well demonstrated in practical fuel cells.Physicochemical characterization analyses further reveal the major origins of the greatly enhanced ORR electrocata lytic performance:the Pt-Co-Mn alloy-induced geometric and ligand effects as well as the extremely high L1_(2) atomic-ordering degree.This work not only successfully develops a highly active and stable ordered ternary intermetallic ORR electrocatalyst,but also elucidates the corresponding"structure-function"relationship,which can be further applied in designing other intermetallic(electro)catalysts. 展开更多
关键词 Platinum Cobalt Manganese Oxygen reduction reaction Ordered intermetallic L1_(2)atomic structure Proton-exchange membrane fuel cell
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EFFECT OF ALLOYING ELEMENTS ON SENSITIVITY TO ENVIRONMENTAL EMBRITTLEMENT OF L1_2 INTERMETALLICS 被引量:9
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作者 X.J.Wan, X.Y.Cheng and Y.X.Chen Materials Research Institute, Shanghai University, Shanghai 200072, China 《中国有色金属学会会刊:英文版》 CSCD 1999年第S1期117-124,共8页
The effect of Zr doping in Ni 3Al and B doping in Co 3Ti intermetallics on the sensitivity to moisture induced environmental embrittlement and on the hydrogen diffusivity was investigated. The results show that both B... The effect of Zr doping in Ni 3Al and B doping in Co 3Ti intermetallics on the sensitivity to moisture induced environmental embrittlement and on the hydrogen diffusivity was investigated. The results show that both B in Co 3Ti and Zr in Ni 3Al do not reduce the hydrogen diffusivity along the grain boundaries, therefore can not suppress the moisture induced environmental embrittlement. The above mentioned behavior of Zr in Ni 3Al and B in Co 3Ti is attributed to the fact that Zr and B are not segregated on the grain boundaries. 展开更多
关键词 L1 2 intermetallics environmental EMBRITTLEMENT hydrogen DIFFUSIVITY grain boundary SEGREGATION
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Influence of mechanical alloying time on the properties of Fe_3Al intermetallics prepared by spark plasma sintering 被引量:6
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作者 Chengchang Jia Qing He Jie Meng Lina Guo 《Journal of University of Science and Technology Beijing》 CSCD 2007年第4期331-334,共4页
The Fe3Al-based intermetallics were prepared by mechanical alloying and spark plasma sintering (SPS), and the influence of milling time on the properties of materials was investigated. The phase identification was i... The Fe3Al-based intermetallics were prepared by mechanical alloying and spark plasma sintering (SPS), and the influence of milling time on the properties of materials was investigated. The phase identification was investigated by X-ray, and the surface morphology and fractography were observed by scanning electron microscope (SEM). The mechanical properties such as bending strength, strain, and microhardness were tested. The results show that Fe reacts with Al completely to form Fe3Al during short SPS processing time. The relative densities of the sintered samples were nearly 100%. The mechanical properties of the sintered samples can be improved along with the milling time. The representative values are the bend strength of 1327 MPa and the microhardness of 434. 展开更多
关键词 Fe3A1 intermetallics mechanical properties mechanical alloying and milling powder metallurgy
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Volta Potential Analysis of Intermetallics in 7A52 Aluminum Alloy
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作者 张平 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第2期227-230,共4页
In order to study the effect of intermaetallics on the corrosion behaviour of 7A52 aluminum alloy, the alloy was characterized by means of SEM-EDS and scanning Kelvin probe force microscopy(SKPFM). The experimental ... In order to study the effect of intermaetallics on the corrosion behaviour of 7A52 aluminum alloy, the alloy was characterized by means of SEM-EDS and scanning Kelvin probe force microscopy(SKPFM). The experimental results indicate that there are two different intermetallics:A1-Mn-Fe and Mg2Si. Both intermetallics exhibite the negative volta potential relative to the matrix indicating an anodic behaviour. Hereby, they are easy to be dissolved and corroded under the erosive environment, and there become the corrosion initiation sites. The A1-Mn-Fe intermetallics show stronger anodic behaviour than those of Mg2Si intermetalics. It means that A1-Mn-Fe intermetalics are easier to be corroded. 展开更多
关键词 intermetallics volta potential A1-Mn-Fe MG2SI 7A52 aluminum alloy
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Structures and Magnetic Properties of Europium-Transition Metal-Gallium Ternary Intermetallic Compounds with 1:3 Type
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作者 何强 郭永权 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第1期158-161,共4页
The crystal structures and magnetic properties of novel Eu TrGa3-r (T=Pd, It, Rh) in termetallic compounds are investigated by using powder x-ray diffraction and magnetic measurements. EuTrGa3-r crystallizes in orth... The crystal structures and magnetic properties of novel Eu TrGa3-r (T=Pd, It, Rh) in termetallic compounds are investigated by using powder x-ray diffraction and magnetic measurements. EuTrGa3-r crystallizes in orthorhombic structure with space group of Cmcm and Z = 4. There are four kinds of nonequivalent 4c crystal positions in EuTrGaa-r unit cell, which are occupied by 4Eu, 4GaⅠ, 4(GaⅡ, T) and 4GaⅢ, respectively. EuTrGa3-r ex- hibits the complex magnetic states in low-temperature regime, with the three-, two- and one-antiferromagnetic transitions occurring for T=Ir, T=Rh and T=Pd, respectively. It might be due to the Kondo effect: a localized antiferromagnetic interaction of the isolated impurity spins with the surrounding conduction electrons at low-temperature regime. 展开更多
关键词 Pd Ga Structures and Magnetic Properties of Europium-Transition Metal-Gallium Ternary intermetallic Compounds with 1 Type Eu
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高速电弧喷涂Fe-Al/Cr_3C_2粉芯丝材的研制与性能研究 被引量:5
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作者 徐维普 徐滨士 +2 位作者 张伟 孟凡军 李新 《兵器材料科学与工程》 CAS CSCD 2004年第2期43-45,共3页
介绍了Fe -Al/Cr3 C2 粉芯丝材的研制过程 ,采用高速电弧喷涂技术 (HVAS) ,用Fe -Al/Cr3 C2 粉芯丝材原位合成了铁铝金属间化合物涂层 ;阐明了粉芯丝材在高速电弧喷涂技术应用中的优点 ;探讨了添加增强相Cr3 C2 对涂层氧化层的影响 ;研... 介绍了Fe -Al/Cr3 C2 粉芯丝材的研制过程 ,采用高速电弧喷涂技术 (HVAS) ,用Fe -Al/Cr3 C2 粉芯丝材原位合成了铁铝金属间化合物涂层 ;阐明了粉芯丝材在高速电弧喷涂技术应用中的优点 ;探讨了添加增强相Cr3 C2 对涂层氧化层的影响 ;研究了高速电弧喷涂铁铝金属间化合物涂层的性能。结果表明 ,用Fe -Al/Cr3 C2 粉芯丝材得到的高速电弧喷涂涂层具有较高的结合强度和显微硬度 ,良好的耐高温冲蚀、耐磨损性能。 展开更多
关键词 高速电弧喷涂 fe-a1 CR3C2 粉芯丝材 涂层氧化层 性能
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金属间化物(Sm_(1-x)Y_x)_2Fe_(17)N_y结构的X射线衍射研
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作者 罗广圣 贺伦燕 +1 位作者 曾贻伟 杨伏明 《南昌大学学报(工科版)》 CAS 1995年第3期78-84,共7页
通过X射线衍射等手段对赝三元金屑间化物(Sm_(1-x)Y_x)_2Fe_(17)N_y(x=0,0.2.0.4.0.6,0.8和1.0;2<y<3)的晶体结构及自旋磁结构进行了研究。由试验结果得出以下结论:1)当Y... 通过X射线衍射等手段对赝三元金屑间化物(Sm_(1-x)Y_x)_2Fe_(17)N_y(x=0,0.2.0.4.0.6,0.8和1.0;2<y<3)的晶体结构及自旋磁结构进行了研究。由试验结果得出以下结论:1)当Y的含量x为0.4时,已出现两相共存现象,但两相中以Th_2Zn_(17)型结构相为主,Th_2Ni_(17)型结构相为次;当Y的含量了达到0.6时,其晶体结构由Th_2Zh_(17)型结构变为Th_2Ni_(17)型结构;2)当Y的含量x在0.8~1.0的范围内,存在自旋磁结构的变化,即由易C轴各向异性变为易C平面各向异性;3)杂质相(α-Fe相)的含量随着Y含量x的增加而减小。 展开更多
关键词 X射线衍射 自旋磁结构 晶体结构 金属间化合物
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金属间化物(Sm_(1-x)Pr_x)_2Fe_(17)N_y 的各向异性机制探讨
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作者 罗广圣 贺伦燕 《南昌大学学报(工科版)》 CAS 1998年第2期63-66,共4页
制备了金属间化物(Sm1-xPrx)2Fe17Ny(x=0,0.2,0.4,0.6,0.8,1.0;2<y<3)的粉末样品,并通过穆斯堡尔谱等手段研究了金属间化物(Sm1-xPrx)2Fe17Ny中Pr原子的替代效应... 制备了金属间化物(Sm1-xPrx)2Fe17Ny(x=0,0.2,0.4,0.6,0.8,1.0;2<y<3)的粉末样品,并通过穆斯堡尔谱等手段研究了金属间化物(Sm1-xPrx)2Fe17Ny中Pr原子的替代效应,进而对其中的各向异性产生机制等方面进行了分析由实验得出以下结论:1)(Sm1-xPrx)2Fe17Ny当x=0.6时发生了自旋磁结构相变,即由易C轴各向异性变为易锥面各向异性;2)金属间化物(Sm1-xPrx)2Fe17Ny中Pr次格子的面各向异性较弱。 展开更多
关键词 穆斯堡尔谱 各向异性 金属间化合物 永磁材料
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Mg-Fe-Al复合氧化物的制备及其对刚果红吸附性能的研究 被引量:2
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作者 王雲生 陈元涛 +2 位作者 张炜 王建 胡春联 《环境污染与防治》 CAS CSCD 北大核心 2016年第6期58-62,48,共6页
通过共沉淀法制备了Mg-Fe-Al复合氧化物,并将其应用于水中刚果红的吸附研究。考察了Mg∶Fe∶Al(摩尔比)、pH、煅烧温度等因素对刚果红吸附性能的影响,并进行了吸附热力学和动力学研究。采用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(F... 通过共沉淀法制备了Mg-Fe-Al复合氧化物,并将其应用于水中刚果红的吸附研究。考察了Mg∶Fe∶Al(摩尔比)、pH、煅烧温度等因素对刚果红吸附性能的影响,并进行了吸附热力学和动力学研究。采用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FTIR)和X射线衍射仪对Mg-Fe-Al复合氧化物进行表征。结果表明,Mg-Fe-Al复合氧化物的最佳制备条件为Mg∶Fe∶Al=2∶1∶1、pH=10、煅烧温度为500℃,并经结构表征确认,对刚果红的最大吸附量达到768.9mg/g。吸附过程符合Langmuir等温吸附方程和准二级速率方程。 展开更多
关键词 Mg—fe-a1复合氧化物 吸附 刚果红热力学 动力学
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Co-Ni-Al-Ti系L2_1/L1_2型双相金属间化合物合金热处理显微组织研究 被引量:2
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作者 王立军 李建国 +1 位作者 张永刚 陈昌麒 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2001年第2期114-117,共4页
对由 L21型(Co,Ni)2AlTi和L12型(Co,Ni)3(Al,Ti)两种有序相组成的Co-Ni-Al-Ti系新型金属间化合物高温结构实验用合金进行了不同制度的热处理,并对相应的显微组织特征进行了分析研究,找... 对由 L21型(Co,Ni)2AlTi和L12型(Co,Ni)3(Al,Ti)两种有序相组成的Co-Ni-Al-Ti系新型金属间化合物高温结构实验用合金进行了不同制度的热处理,并对相应的显微组织特征进行了分析研究,找到了控制显微组织以优化性能的热处理参数。 展开更多
关键词 Co-Ni-Al-Ti 热处理 金属间化合物 显微组织
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Effect of Trace La Addition on the Microstructure and Mechanical Property of As-cast ADC12 Al-Alloy 被引量:25
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作者 黄昕 闫洪 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第1期202-205,共4页
The effects of addition of La on the microstructure of as-cast ADC12 A1-Alloy were investigated by using optical microscope (OM), X-ray diffraction (XRD), scanning electron microscope (SEM), and energy disperse ... The effects of addition of La on the microstructure of as-cast ADC12 A1-Alloy were investigated by using optical microscope (OM), X-ray diffraction (XRD), scanning electron microscope (SEM), and energy disperse spectroscopy (EDS). The experimental results showed that the a-A1 and eutectic Si crystals were modified with the addition of 0.3 wt% La. The eutectic Si crystals showed a granular distribution. At the same time, the alloy possessed the best mechanical property. When more than 0.3 wt% La was added to ADC12 aluminum alloy, the microstructure of as-cast alloy was coarsening gradually with the increase of the content of La and the mechanical property decreased. The effect of rare earth La which was added in ADC 12 A1-Alloy for up to 0.9 wt% had been investigated in this study. The dendrites ofADC12 Al-alloy was refined obviously and the morphology of Si crystals showed a particle structure when the addition of La reached 0,3 wt%. Besides, the acicular La-rich intermetallics in the alloy deteriorated the mechanical property of alloy: To avoid this unwanted phase, the amount of added rare earth La must be less than 0.6 wt%. 展开更多
关键词 as-cast ADC12 A1-Alloy rare earth microstructure intermetallic compound mechanical property
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First Principles Study of AI-Li Intermetallic Compounds 被引量:1
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作者 Hai-li Yu Xiao-hui Duan +1 位作者 Yong-jun Ma Min Zeng 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2012年第6期659-665,I0003,共8页
The structural properties, heats of formation, elastic properties, and electronic structures of four compositions of binary A1-Li intermetallics, A13Li, A1Li, A12Li3, and A14Li9, are ana- lyzed in detail by using dens... The structural properties, heats of formation, elastic properties, and electronic structures of four compositions of binary A1-Li intermetallics, A13Li, A1Li, A12Li3, and A14Li9, are ana- lyzed in detail by using density functional theory. The calculated formation heats indicate a strong chemical interaction between A1 and Li for all the A1-Li intermetallics. In partic- ular, in the Li-rich A1-Li compounds, the thermodynamic stability of intermetallics linearly decreases with increasing concentration of.Li. According to the computational single crystal elastic constants, all the four A1-Li intermetallic compounds considered here are mechani- cally stable. The polycrystalline elastic modulus and Poisson's ratio have been deduced by using Voigt, Reuss, and Hill approximations, and the calculated ratios of bulk modulus to shear modulus indicate that the four compositions of binary A1-Li intermetallics are brittle materials. With the increase of Li concentration, the bulk modulus of A1-Li intermetallics decreases in a linear manner. 展开更多
关键词 First principles A1-Li intermetallic compound Mechanical property Forma-tion heat Elastic properties
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Co-Ni-Al-Ti系L2_1/L1_2型双相金属间化合物合金的显微组织和力学行为研究
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作者 王立军 李建国 +1 位作者 张永刚 陈昌麒 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2001年第4期249-252,共4页
对于由 L2 1 型 ( Co,Ni) 2 Al Ti和 L12 型 ( Co,Ni) 3( Al,Ti)两种有序相组成的 Co- Ni- Al- Ti系新型金属间化合物高温结构用合金 ,经热处理后获得不同显微组织的高温压缩和室温断裂等力学行为进行了分析研究 ,确立了合金成分、显微... 对于由 L2 1 型 ( Co,Ni) 2 Al Ti和 L12 型 ( Co,Ni) 3( Al,Ti)两种有序相组成的 Co- Ni- Al- Ti系新型金属间化合物高温结构用合金 ,经热处理后获得不同显微组织的高温压缩和室温断裂等力学行为进行了分析研究 ,确立了合金成分、显微组织和机械性能之间的关系 ,找到了进一步提高高温强度和室温塑性的途径。 展开更多
关键词 Co-Ni-Al-Ti四元系 金属间化合物 显微组织 力学行为
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Phase equilibria of Mg-rich corner in Mg Zn Al ternary system at 300 °C 被引量:5
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作者 任玉平 秦高梧 +3 位作者 裴文利 李松 郭运 赵宏达 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第2期241-245,共5页
The phase equilibria and compositions in Mg-rich comer at 300℃ were determined in the Mg-Zn-A1 ternary system through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy ... The phase equilibria and compositions in Mg-rich comer at 300℃ were determined in the Mg-Zn-A1 ternary system through the equilibrated alloy method by using X-ray diffraction (XRD) and scanning electron microscopy (SEM) assisted with energy dispersive spectroscopy of X-ray (EDS). The results show that there exist three three-phase regions consisted of a-Mg+Mg17A112(7)+A15Mg11Zn4(φ), a-Mg+Mga2(Al, Zn)49(r)+A15MgllZn4(φ) and a-Mg+MgZn+Mg32(A1, Zn)49(r), respectively. The intermetallic compounds in equilibrium with a-Mg phase all have large composition ranges, not appear to be linear. At the same time, both zinc and aluminum are soluble in the a-Mg solid solution, with which the compounds are in equilibrium. 展开更多
关键词 Mg-Zn-A1 system isothermal section SOLUBILITY intermetallic compound
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Highly dispersed L1_(0)-PtZn intermetallic catalyst for efficient oxygen reduction 被引量:6
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作者 Tuo Zhao Ergui Luo +4 位作者 Yang Li Xian Wang Changpeng Liu Wei Xing Junjie Ge 《Science China Materials》 SCIE EI CAS CSCD 2021年第7期1671-1678,共8页
Highly active and durable electrocatalysts with minimal Pt usage are desired for commercial fuel cell applications.Herein,we present a highly dispersed L1_(0)-PtZn intermetallic catalyst for the oxygen reduction react... Highly active and durable electrocatalysts with minimal Pt usage are desired for commercial fuel cell applications.Herein,we present a highly dispersed L1_(0)-PtZn intermetallic catalyst for the oxygen reduction reaction(ORR),in which a Zn-rich metal–organic framework(MOF)is used as an in situ generated support to confine the growth of PtZn particles.Despite requiring high-temperature treatment,the intermetallic L1_(0)-PtZn particles exhibit a small mean size of3.95 nm,which confers the catalysts with high electrochemical active surface area(81.9 m^(2)g_(Pt)^(-1))and atomic utilization.The Pt electron structure and binding strength between Pt and oxygen intermediates are optimized through ligand effect and compressive strain.These advantages result in ORR mass activity and specific activity of 0.926 A mg_(Pt)^(-1) and 1.13 mA cm^(-2),respectively,which are 5.4 and 4.0 times those of commercial Pt/C.The stable L10structure provides the catalysts with superb durability;only a halfwave potential loss of 11 mV is observed after 30,000 cycles of accelerated stress tests,through which the structure evolves into a more stable PtZn-Pt core-shell structure.Therefore,the development of a Zn-based MOF as a catalyst support is demonstrated,providing a synergy strategy to prepare highly dispersed intermetallic alloys with high activity and durability. 展开更多
关键词 L1_(0)-PtZn intermetallic catalyst Zn vapor protect confinement effect morphological evolution ORR
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Synthesis and characterization of FeAl nanoparticles by flow-levitation method 被引量:1
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作者 陈善俊 陈艳 +4 位作者 唐永建 罗炳池 易早 韦建军 孙卫国 《Journal of Central South University》 SCIE EI CAS 2013年第4期845-850,共6页
The synthesis of high purity intermetallic FeAI nanoparticles using the flow-levitation (FL) method was reported. Iron and aluminium droplets were levitated stably at about 2 230℃. The morphology, clystal structure... The synthesis of high purity intermetallic FeAI nanoparticles using the flow-levitation (FL) method was reported. Iron and aluminium droplets were levitated stably at about 2 230℃. The morphology, clystal structure and chemical composition of FeAI nanoparticles were investigated by transmission electron microscopy (TEM), high-resolution TEM, X-ray diffraction and energy dispersive spectrometry. The results show that the average particle size of these nanoparticles is about 34.5 nm. Measurements of the d-spacing from X-ray diffraction and electron diffraction studies confirm that the intermetallic nanoparticles have the same crystal structure (B2) as the bulk FeA1. A thin oxidation coating is formed around the particles when being exposed to air. Based on the XPS measurements, the surface coating of the FeAI nanoparticles is composed of Fe2O3 and FeAl2O4. Besides, hysteresis curve reveals that saturation magnetization (Ms) of FeA1 is 1.66 A/m2, and the coercivity is about 1.214×10^3 A/re. 展开更多
关键词 intermetallic compound FeA1 nanoparticles flow-levitation method
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Inverse identification of constitutive parameters of Ti_2AlNb intermetallic alloys based on cooperative particle swarm optimization 被引量:5
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作者 Linjiang HE Honghua SU +1 位作者 Jiuhua XU Liang ZHANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2018年第8期1774-1785,共12页
Ti_2AlNb intermetallic alloy is a relatively newly developed high-temperature-resistant structural material, which is expected to replace nickel-based super alloys for thermally and mechanically stressed components in... Ti_2AlNb intermetallic alloy is a relatively newly developed high-temperature-resistant structural material, which is expected to replace nickel-based super alloys for thermally and mechanically stressed components in aeronautic and automotive engines due to its excellent mechanical properties and high strength retention at elevated temperature. The aim of this work is to present a fast and reliable methodology of inverse identification of constitutive model parameters directly from cutting experiments. FE-machining simulations implemented with a modified Johnson-Cook(TANH) constitutive model are performed to establish the robust link between observables and constitutive parameters. A series of orthogonal cutting experiments with varied cutting parameters is carried out to allow an exact comparison to the 2 D FE-simulations. A cooperative particle swarm optimization algorithm is developed and implemented into the Matlab programs to identify the enormous constitutive parameters. Results show that the simulation observables(i.e., cutting forces, chip morphologies, cutting temperature) implemented with the identified optimal material constants have high consistency with those obtained from experiments,which illustrates that the FE-machining models using the identified parameters obtained from the proposed methodology could be predicted in a close agreement to the experiments. Considering the wide range of the applied unknown parameters number, the proposed inverse methodology of identifying constitutive equations shows excellent prospect, and it can be used for other newly developed metal materials. 展开更多
关键词 Constitutive parameters Cooperative particle swarmoptimization Finite element modelling Inverse identification Ti2A1Nb intermetallic alloys
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