The tensile properties of 2297-T87 Al–Li alloy thick plates at different thickness position and in different direction were analyzed via tensile testing,optical microscopy(OM),X-ray diffraction(XRD),scanning electron...The tensile properties of 2297-T87 Al–Li alloy thick plates at different thickness position and in different direction were analyzed via tensile testing,optical microscopy(OM),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive spectrometry(EDS),and transmission electron microscopy(TEM).Results indicated that the ultimate tensile strength(UTS)and yield strength(YS)of the alloy decreased firstly and then increased from the 1/8T position to the 1/2T position,whereas elongation to failure(Ef)decreased gradually such that its value along the rolling direction(RD)was higher than those along the transverse direction(TD)at the same thickness position.From the 1/8T position to the 3/8T position of the alloy,the UTS and YS along the TD were higher than those along the RD.At the 1/2T position of the alloy,the UTS,YS,and Ef along the RD were the highest,whereas those along the normal direction(ND)were the lowest.Microstructural observations further revealed that the anisotropy of tensile properties was related to grain morphology,crystal texture,second-phase particles,and Li atom segregation.展开更多
The uncontrollable Li electrostripping and plating process that results in dendritic Li growth and huge volume change of Li anode limits the practicality of Li metal batteries(LMBs).To simultaneously address these iss...The uncontrollable Li electrostripping and plating process that results in dendritic Li growth and huge volume change of Li anode limits the practicality of Li metal batteries(LMBs).To simultaneously address these issues,designing three-dimensional(3D),lithiophilic and mechanically robust electrodes seems to be one of the cost-effective strategies.Herein,a new 3D Li-B-C-Al alloy anode is designed and fabricated.The prepared 3D alloy anode exhibits not only superior lithiophilicity that facilitates uniform Li nucleation and growth but also sufficient mechanical stability that maintains its structural integrity.Superior performance of the prepared 3D alloy is demonstrated through comprehensive electrochemical tests.In addition,non-destructive and 3D synchrotron X-ray computed tomography(SX-CT)technique is employed to investigate the underlying working mechanisms of the prepared alloy anode.A unique twofold Li electrostripping and plating mechanism under different electrochemical cycling conditions is revealed.Lastly,improved performance of the full cells built with the 3D alloy anode and LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode corroborate its potential application capability.Overall,the current work not only showcases the superiority of the 3D alloy as potential anode material for LMBs but also provides fundamental insights into its underlying working mechanisms that may further propel its research and development.展开更多
As a critical structure of aerospace equipment,aluminum alloy stiffened plate will influence the stability of spacecraft in orbit and the normal operation of the system.In this study,a GWO-ELM algorithm-based impact d...As a critical structure of aerospace equipment,aluminum alloy stiffened plate will influence the stability of spacecraft in orbit and the normal operation of the system.In this study,a GWO-ELM algorithm-based impact damage identification method is proposed for aluminum alloy stiffened panels to monitor and evaluate the damage condition of such stiffened panels of spacecraft.Firstly,together with numerical simulation,the experimental simulation to obtain the damage acoustic emission signals of aluminum alloy reinforced panels is performed,to establish the damage data.Subsequently,the amplitude-frequency characteristics of impact damage signals are extracted and put into an extreme learning machine(ELM)model to identify the impact location and damage degree,and the Gray Wolf Optimization(GWO)algorithm is employed to update the weight parameters of the model.Finally,experiments are conducted on the irregular aluminum alloy stiffened plate with the size of 2200 mm×500 mm×10 mm,the identification accuracy of impact position and damage degree is 98.90% and 99.55% in 68 test areas,respectively.Comparative experiments with ELM and backpropagation neural networks(BPNN)demonstrate that the impact damage identification of aluminum alloy stiffened plate based on GWO-ELM algorithm can serve as an effective way to monitor spacecraft structural damage.展开更多
Pretreated Mg-Li alloy sheets were pre-plated in a NiCO3?2Ni(OH)2?4H2O solution to form a thin Ni-P alloy film and then plating in a NiSO4?6H2O solution was carried out to obtain a protective coating.The surface ...Pretreated Mg-Li alloy sheets were pre-plated in a NiCO3?2Ni(OH)2?4H2O solution to form a thin Ni-P alloy film and then plating in a NiSO4?6H2O solution was carried out to obtain a protective coating.The surface morphology,structure and corrosion resistance of the coating were studied.The results showed that a flat,bright and compact plating layer,which was integrated into the matrix metal,was obtained.The P content of the Ni-P coating reached 13.56%(mass fraction).The hardness value of the Ni-P coating was about HV 549.The polarization curve showed that the corrosion potential of the Ni-P coating reached ?0.249 V(vs SCE).A long passivation region was found on the polarization curve,and this phenomenon indicated that the coating has an excellent anti-corrosion property.展开更多
Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achie...Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achieved by adjusting the diameters of the upper roll and the bottom roll and was used to prepare hot-rolled thick plate of 5182 aluminium alloy. The shear deformation and plate shape control were experimentally studied. The experimental results show that asymmetrical rolling has a significant effect on metal deformation stream and can somehow refine microstructure and improve the uniformity of microstructure and properties. The asymmetrical rolling process can also reduce the rolling force. However, bending of rolling plate often happens during asymmetrical rolling process. The factors affecting the bending were discussed.展开更多
An electroless ternary Ni-Sn-P transition layer with high corrosion resistance was applied for acid electroless nickel plating on magnesium alloys. The surface morphologies and microstructure of the traditional alkali...An electroless ternary Ni-Sn-P transition layer with high corrosion resistance was applied for acid electroless nickel plating on magnesium alloys. The surface morphologies and microstructure of the traditional alkaline electroless Ni-P and novel Ni-Sn-P transition layers were compared by SEM and XRD, and the bonding strengths between the transition layers and AZ31 magnesium alloys were tested. The corrosion resistance of the samples was analyzed by porosity test, potentiodynamic polarization, electrochemical impedance spectroscopy(EIS) in acid electroless solution at p H 4.5 and immersion test in 10% HCl. The results indicate that the transition layer is essential for acid electroless plating Ni-P coatings on magnesium alloys. Under the same thin thickness(-6 μm), the electroless Ni-Sn-P transition layer possesses superior properties to the traditional Ni-P transition layer, including high amorphization, smooth and dense surface without pores, enhanced bonding strength and corrosion resistance. Most importantly, acid electroless Ni-P coatings can be successfully deposited on magnesium alloys by using Ni-Sn-P transition layer.展开更多
The corrosion anisotropy of 7050-T7451 A1 alloy thick plate in NaCI solution was investigated by immersion tests, slow strain rate testing (SSRT) technique, potentiodynamic and anode polarization measurements, optic...The corrosion anisotropy of 7050-T7451 A1 alloy thick plate in NaCI solution was investigated by immersion tests, slow strain rate testing (SSRT) technique, potentiodynamic and anode polarization measurements, optical microscropy (OM) and scanning electron microscopy (SEM) observations. The results show that the thick plate exhibits severe corrosion anisotropy due to the microstructure anisotropy. The observations of immersion surfaces together with the analysis of polarization curves reveal that the differences of the corrosion morphologies on various sections in this material are mainly related to the area fraction of the remnant second phase, and higher area fraction displays worst corrosion resistance. The stress corrosion cracking (SCC) susceptibility of different directions relative to the rolling direction is assessed by SSRT technique, ranked in the order: S direction 〉 L direction 〉 T direction. The result show that the smaller the grain aspect ratio, the better the corrosion resistance to SCC.展开更多
Drop-weight impact tests were conducted on 2024-T3 aluminum plates with five types of impactors, and then the effects of the dent on the residual ultimate strength of the 2024-T3 specimens were investigated through ax...Drop-weight impact tests were conducted on 2024-T3 aluminum plates with five types of impactors, and then the effects of the dent on the residual ultimate strength of the 2024-T3 specimens were investigated through axial compression tests. Results indicate that with increase in dent depth, the five types of dents affect the ultimate strength of the plate in different trends. Nevertheless, other than the plate global deflection caused by impacting, the dent itself has unremarkable effect on the ultimate strength. The mathematical expressions are derived regarding the relationship between impact energy factor and the dent depth factor as well as the compressive ultimate strength reduction rate and the dent depth factor.展开更多
In order to avoid the occurrence of fracture at room temperature in reverse deep drawing of aluminum alloy plate, the warm reverse deep drawing method was proposed. The experiments were conducted at room temperature,...In order to avoid the occurrence of fracture at room temperature in reverse deep drawing of aluminum alloy plate, the warm reverse deep drawing method was proposed. The experiments were conducted at room temperature, 280 and 360 ℃ with a 4.5 mm thick 5A06 aluminum alloy plate. The effect of temperature, blank-holding force and gap on the fracture and wrinkle of the reverse deep drawing process was investigated. A fully coupled thermal-mechanical simulation was carried out to obtain the stress distribution through the commercial software of Abaqus/Explicit. The results show that the fracture is avoided at 280 ℃ since the bending-induced stress gradient in the transient area between the inside corner and the straight wall decreases from 505 MPa at RT to 72 MPa at 280 ° C. Although the fracture is avoided as the temperature increases, the wrinkle occurs at the outside die corner at temperature over 280 ° C, where the circumferential compressive stress becomes larger than that at the inside. As the temperature increases to 360 ℃, the fracture occurs due to the excessive softening, the tensile stress in the straight wall reaches rapidly to the tensile strength at the beginning of reverse deep drawing. When 1.5t (t=4.5 mm) blank holding gap is applied at 280 ℃, both the fracture and wrinkle can be avoided, and 420 mm deep cups are drawn successfully.展开更多
Cu-4.7%Sn (mass fraction) alloy plate was prepared by the self-developed two-phase zone continuous casting (TZCC) process. The relationship between process parameters of TZCC and surface quality of the alloy plate...Cu-4.7%Sn (mass fraction) alloy plate was prepared by the self-developed two-phase zone continuous casting (TZCC) process. The relationship between process parameters of TZCC and surface quality of the alloy plate was investigated. The microstructure and mechanical properties of the TZCC alloy plate were analyzed. The results show that Cu-4.7%Sn alloy plate with smooth surface can be obtained by means of reasonable matching the entrance temperature of two-phase zone mold and the continuous casting speed. The microstructure of the TZCC alloy is composed of grains-covered grains, small grains with self-closed grain boundaries, columnar grains and equiaxed grains. Compared with cold mold continuous casting Cu-4.7%Sn alloy plate, the room temperature tensile strength and ductility of the TZCC alloy plate are greatly improved.展开更多
A thickness strain model of aluminium alloy plate under plastic deformation,based on thin plate assumption was proposed.It is found that when ratio of stress fractions is constant during in-plane loading,ratios of str...A thickness strain model of aluminium alloy plate under plastic deformation,based on thin plate assumption was proposed.It is found that when ratio of stress fractions is constant during in-plane loading,ratios of strain components under various loading conditions are linearly related and these points of ratios form a η-η line.Under these simple loadings,strains in thickness direction can be easily calculated by the η-η line equation without integral and differential work.When the plate is under more complicated loading conditions,the thickness can be computed by the proposed optimization and piecewise calculation model.Validation computations indicate that the relative error of the results of the presented model is less than 0.75% compared with the proven theories and FE simulation.Therefore,the developed model can be applied to engineering calculation,e.g.pre-stretching analysis of aerospace aluminium thick plate,with acceptable accuracy.展开更多
After Sn/Pd activating, the SiCp/Al composite with 65% SiC (volume fraction) was coated by electroless Ni?P alloy plating. Surface morphology of the composite and its effect on the Ni?P alloy depositing process and bo...After Sn/Pd activating, the SiCp/Al composite with 65% SiC (volume fraction) was coated by electroless Ni?P alloy plating. Surface morphology of the composite and its effect on the Ni?P alloy depositing process and bonding action of Ni and P atoms in the Ni?P alloy were studied. The results show that inhomogeneous distribution of the Sn/Pd activating points results in preferential deposition of the Ni?P alloy particles on the Al alloy and rough SiC particle surfaces and in the etched caves. The Ni?P alloy film has an amorphous structure where chemical bonding between Ni and P atoms exists. After a continuous Ni?P alloy film formed, electroless Ni?P alloy plating is not affected by surface morphology and characteristics of the SiCp/Al composite any longer, but by the electroless plating process itself. The Ni?P alloy film follows linear growth kinetics with an activation energy of 68.44 kJ/mol.展开更多
Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical comp...Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical composition and microstructure of Ni-P coating were studied. It is indicated that β phases are selectively removed, producing a microstructural homogeneous surface and the subsequent uniform and compact Zn immersion layer. A defect-free and well adhesive Ni-P coating can be successfully obtained due to its uniform nucleation and growth based on such pretreatment. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests reveal that Ni-P coating could significantly improve the corrosion resistance of AZ91D substrate.展开更多
Ni-W-P coatings were deposited on the surface of glass fibers by the electroless plating process. The bath was very stable through the palladium salt test. There was no phenomenon of peeling and blistering on the surf...Ni-W-P coatings were deposited on the surface of glass fibers by the electroless plating process. The bath was very stable through the palladium salt test. There was no phenomenon of peeling and blistering on the surface of the Ni-W-P alloy glass fibers in the thermal shock test. It showed that the deposit had high impact strength and good adhesion. The morphology of the coatings was observed by scanning electron microscope (SEM). The elements and their contents were tested and analyzed by energy dispersion spectrometer (EDS). The tungsten content reached up to 12.1 wt.%. The effects of the concentrations of NiSO4, Na2WO4, and NaH2PO2.H20 on the conductivity of the coatings were studied. The resistivity of the Ni-W-P alloy glass fibers reached 7.39 × 10^-3 Ωcm. The alloy coatings on glass fibers were analyzed by XRD. The results indicated that the deposit had an amorphous structure and good heat stability. The suitable work temperature range was lower than 190℃. Finally, the electromagnetic parameters of the Ni-W-P alloy glass fibers were tested and analyzed primarily. The magnetic loss reached 0.04023 and the dielectric loss reached -5.80239. The plated alloy is a kind of soft magnetic material.展开更多
A new technique of electroplating amorphous Fe-Ni-W alloy deposits was proposed.The structure and morphology o Fe-Ni-W alloy deposit were detected by XRD and SEM.The friction and wear behavior of Fe-Ni-W alloy deposit...A new technique of electroplating amorphous Fe-Ni-W alloy deposits was proposed.The structure and morphology o Fe-Ni-W alloy deposit were detected by XRD and SEM.The friction and wear behavior of Fe-Ni-W alloy deposit were studied and compared with that of chromium deposit.The corrosion properties against 5% sodium chloride,5% sulfuric acid and 5% sodium hydroxide were also discussed.The experimental results indicate that Fe-Ni-W alloy deposits have superior properties against wea than hard chromium deposits under dry sliding condition.Under oil sliding condition,except their better wear resistance,the deposits can protect their counterparts against wear.The deposits plated on brass and AISI 1045 steel show good behavior against corrosion o 5% sodium chloride,5% sulfuric acid and 5% sodium hydroxide.The bath of electroplating amorphous Fe-Ni-W alloy deposits is environmentally friendly and would find widely use in industry.展开更多
The ageing behavior of a pre-stretched thick plate of Al-Zn-Mg-Cu alloy was systemically studied including one-step ageing, two-step ageing, and retrogression and reageing treatment (RRA). One-step ageing of the all...The ageing behavior of a pre-stretched thick plate of Al-Zn-Mg-Cu alloy was systemically studied including one-step ageing, two-step ageing, and retrogression and reageing treatment (RRA). One-step ageing of the alloy resulted in peak ultimate tensile strengths of 595 and 575 MPa after 22 and 6 h at 120 and 135°C, respectively. The strengthening phase in peak aged (T6 temper) alloy contained GP zones and the η′ phase predominantly. After two-step ageing, the electrical conductivity was increased markedly, but the pre-stretched thick plate sacrificed a great loss of strength. RRA treatment provided a method for maintaining the strength close to that obtained by T6 temper and for obtaining the high electrical conductivity close to that obtained by T7 temper; the ultimate tensile strength and electrical conductivity were 583 MPa and 21.0 MS/m, respectively. TEM analysis of T7 and RRA specimens revealed two types of precipitates that contributed to age strengthening i.e. the η′ and η phases.展开更多
High-temperature tribological properties of Ni-P alloy coatings processed by electro-brush plating on 20CrMo steel have been investigated. A baU-on-disc configuration was employed and 4 mm diameter Si3N4 balls were us...High-temperature tribological properties of Ni-P alloy coatings processed by electro-brush plating on 20CrMo steel have been investigated. A baU-on-disc configuration was employed and 4 mm diameter Si3N4 balls were used as static counterpart. All the wear tests were carried out at 450℃ for 180 rain without lubricants. The electro-brush plating Ni-P coating is amorphous in as-deposited condition, and it becomes polycrystalline with the formation of Ni and Ni3P after heat treatment at 450℃for 1 h. The friction coefficient of the Ni-P coating is just 50% of that of the 20CrMo steel at the friction temperature of 450℃. A mild adhesive wear mechanism was found for the electro-brush plating Ni-P coating tested at 450℃, whereas for the 20CrMo steel at the same temperature a mixed adhesive and abrasive wear mechanism was observed.展开更多
The influence of bath constituents and pulse parameters on cobalt content, surface morphologies and grain size of Zn-Co alloy deposits was studied using a pulse plating technique with a square- wave current containing...The influence of bath constituents and pulse parameters on cobalt content, surface morphologies and grain size of Zn-Co alloy deposits was studied using a pulse plating technique with a square- wave current containing reverse pulse, It is found that Zn-Co alloy coatings obtained from the bath with the cobalt ion concentration over 60 wt% have a higher cobalt content in deposits. The results of pulse plating show that the average current density and reverse anodic current density amongst the variables investigated have very strong effects on the cobalt content in the Zn-Co alloy deposits. It is possible to electrodeposit Zn-Co alloy coatings with 10-90 wt% cobalt by modulating pulse parameters. The grain size, surface appearance and internal stress in the deposit were improved significantly by introducing the reverse current.展开更多
The electroless deposition of Ni68-Fe10.5-P21.5 alloy has been investigated. The crystallization behavior of the deposit was comparatively studied by using differential scanning calorimetry and X-ray diffractometry. T...The electroless deposition of Ni68-Fe10.5-P21.5 alloy has been investigated. The crystallization behavior of the deposit was comparatively studied by using differential scanning calorimetry and X-ray diffractometry. The deposit transforms into a square Ni3P phase at 380. 0 ℃, then changes into a cubic FeNi3 phase at 490. 0 ℃. The microhardness, the size of the formed grains and the magnetic performance of the deposit increase with the increase of the heat treatment temperature below 500 ℃, then they decrease after this temperature. The effect of heat treatment time at 500 ℃ on the surface micromorphology, the structure and the magnetic performance of the deposit were also studied. The resuits show that with the increase of heat treatment time, the extent of crystallization of the deposit increases and the size of the formed grains becomes uniform. The results also show that the magnetic performance of the deposit under heat treatment for 40 min is maximal and then decreases with the increase of heat treatment time. The property change of the deposit is related to the crystal structure and the size of the formed grains of the deposit.展开更多
The current research processes of electroplating and electroless Ni-P alloy plating on magnesium alloys were reviewed. Theoretically,the reason for difficulties in electroplating and electroless plating on magnesium a...The current research processes of electroplating and electroless Ni-P alloy plating on magnesium alloys were reviewed. Theoretically,the reason for difficulties in electroplating and electroless plating on magnesium alloys was given.The zinc immersion, copper immersion,direct electroless Ni-P alloy plating and electroplating and electroless plating on magnesium alloys prepared by chemical conversion coating were presented in detail.Especially,the research development of magnesium alloy AZ91 and AZ31 was discussed briefly.Based on the analysis,the existing problems and future research directions were then given.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.52171029,51671038)the Major Natural Science Research Project of Higher Education Institutions in Jiangsu Province(No.18KJA430002)。
文摘The tensile properties of 2297-T87 Al–Li alloy thick plates at different thickness position and in different direction were analyzed via tensile testing,optical microscopy(OM),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive spectrometry(EDS),and transmission electron microscopy(TEM).Results indicated that the ultimate tensile strength(UTS)and yield strength(YS)of the alloy decreased firstly and then increased from the 1/8T position to the 1/2T position,whereas elongation to failure(Ef)decreased gradually such that its value along the rolling direction(RD)was higher than those along the transverse direction(TD)at the same thickness position.From the 1/8T position to the 3/8T position of the alloy,the UTS and YS along the TD were higher than those along the RD.At the 1/2T position of the alloy,the UTS,YS,and Ef along the RD were the highest,whereas those along the normal direction(ND)were the lowest.Microstructural observations further revealed that the anisotropy of tensile properties was related to grain morphology,crystal texture,second-phase particles,and Li atom segregation.
基金supported by the National Natural Science Foundation of China(U1904216).
文摘The uncontrollable Li electrostripping and plating process that results in dendritic Li growth and huge volume change of Li anode limits the practicality of Li metal batteries(LMBs).To simultaneously address these issues,designing three-dimensional(3D),lithiophilic and mechanically robust electrodes seems to be one of the cost-effective strategies.Herein,a new 3D Li-B-C-Al alloy anode is designed and fabricated.The prepared 3D alloy anode exhibits not only superior lithiophilicity that facilitates uniform Li nucleation and growth but also sufficient mechanical stability that maintains its structural integrity.Superior performance of the prepared 3D alloy is demonstrated through comprehensive electrochemical tests.In addition,non-destructive and 3D synchrotron X-ray computed tomography(SX-CT)technique is employed to investigate the underlying working mechanisms of the prepared alloy anode.A unique twofold Li electrostripping and plating mechanism under different electrochemical cycling conditions is revealed.Lastly,improved performance of the full cells built with the 3D alloy anode and LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)cathode corroborate its potential application capability.Overall,the current work not only showcases the superiority of the 3D alloy as potential anode material for LMBs but also provides fundamental insights into its underlying working mechanisms that may further propel its research and development.
基金supported by National Key Research and Development Project(2020YFE0204900)National Natural Science Foundation of China(Grant Nos.61903224,62073193,61873333)Key Research and Development Plan of Shandong Province(Grant Nos.2019TSLH0301,2021CXGC010204).
文摘As a critical structure of aerospace equipment,aluminum alloy stiffened plate will influence the stability of spacecraft in orbit and the normal operation of the system.In this study,a GWO-ELM algorithm-based impact damage identification method is proposed for aluminum alloy stiffened panels to monitor and evaluate the damage condition of such stiffened panels of spacecraft.Firstly,together with numerical simulation,the experimental simulation to obtain the damage acoustic emission signals of aluminum alloy reinforced panels is performed,to establish the damage data.Subsequently,the amplitude-frequency characteristics of impact damage signals are extracted and put into an extreme learning machine(ELM)model to identify the impact location and damage degree,and the Gray Wolf Optimization(GWO)algorithm is employed to update the weight parameters of the model.Finally,experiments are conducted on the irregular aluminum alloy stiffened plate with the size of 2200 mm×500 mm×10 mm,the identification accuracy of impact position and damage degree is 98.90% and 99.55% in 68 test areas,respectively.Comparative experiments with ELM and backpropagation neural networks(BPNN)demonstrate that the impact damage identification of aluminum alloy stiffened plate based on GWO-ELM algorithm can serve as an effective way to monitor spacecraft structural damage.
基金Projects(50974114,51174060) supported by National Natural Science Foundation of ChinaProject(2008AA03Z512) supported by High-tech Research and Development Program of ChinaProject(20070145049) supported by PhD Programs Foundation of Ministry of Education of China
文摘Pretreated Mg-Li alloy sheets were pre-plated in a NiCO3?2Ni(OH)2?4H2O solution to form a thin Ni-P alloy film and then plating in a NiSO4?6H2O solution was carried out to obtain a protective coating.The surface morphology,structure and corrosion resistance of the coating were studied.The results showed that a flat,bright and compact plating layer,which was integrated into the matrix metal,was obtained.The P content of the Ni-P coating reached 13.56%(mass fraction).The hardness value of the Ni-P coating was about HV 549.The polarization curve showed that the corrosion potential of the Ni-P coating reached ?0.249 V(vs SCE).A long passivation region was found on the polarization curve,and this phenomenon indicated that the coating has an excellent anti-corrosion property.
基金Projects(51104043,51374067)supported by the National Natural Science Foundation of ChinaProject(2012CB619506)supported by the National Basic Research Program of ChinaProject(N120409002)supported by the Fundamental Research Funds for the Central Universities,China
文摘Asymmetric rolling (ASR), as one of severe plastic deformation (SPD) methods to make ultra-fine materials with enhanced performance is mainly used to prepare foil and thin strip. The asymmetrical rolling was achieved by adjusting the diameters of the upper roll and the bottom roll and was used to prepare hot-rolled thick plate of 5182 aluminium alloy. The shear deformation and plate shape control were experimentally studied. The experimental results show that asymmetrical rolling has a significant effect on metal deformation stream and can somehow refine microstructure and improve the uniformity of microstructure and properties. The asymmetrical rolling process can also reduce the rolling force. However, bending of rolling plate often happens during asymmetrical rolling process. The factors affecting the bending were discussed.
基金Project(20120407)supported by the Science and Technology Key Development Plan of Jilin Province,China
文摘An electroless ternary Ni-Sn-P transition layer with high corrosion resistance was applied for acid electroless nickel plating on magnesium alloys. The surface morphologies and microstructure of the traditional alkaline electroless Ni-P and novel Ni-Sn-P transition layers were compared by SEM and XRD, and the bonding strengths between the transition layers and AZ31 magnesium alloys were tested. The corrosion resistance of the samples was analyzed by porosity test, potentiodynamic polarization, electrochemical impedance spectroscopy(EIS) in acid electroless solution at p H 4.5 and immersion test in 10% HCl. The results indicate that the transition layer is essential for acid electroless plating Ni-P coatings on magnesium alloys. Under the same thin thickness(-6 μm), the electroless Ni-Sn-P transition layer possesses superior properties to the traditional Ni-P transition layer, including high amorphization, smooth and dense surface without pores, enhanced bonding strength and corrosion resistance. Most importantly, acid electroless Ni-P coatings can be successfully deposited on magnesium alloys by using Ni-Sn-P transition layer.
基金Project(2012CB619502)supported by the National Basic Research Program of China
文摘The corrosion anisotropy of 7050-T7451 A1 alloy thick plate in NaCI solution was investigated by immersion tests, slow strain rate testing (SSRT) technique, potentiodynamic and anode polarization measurements, optical microscropy (OM) and scanning electron microscopy (SEM) observations. The results show that the thick plate exhibits severe corrosion anisotropy due to the microstructure anisotropy. The observations of immersion surfaces together with the analysis of polarization curves reveal that the differences of the corrosion morphologies on various sections in this material are mainly related to the area fraction of the remnant second phase, and higher area fraction displays worst corrosion resistance. The stress corrosion cracking (SCC) susceptibility of different directions relative to the rolling direction is assessed by SSRT technique, ranked in the order: S direction 〉 L direction 〉 T direction. The result show that the smaller the grain aspect ratio, the better the corrosion resistance to SCC.
基金Projects(13R21421700,13R21421800)sponsored by Shanghai Postdoctoral Scientific Program,China
文摘Drop-weight impact tests were conducted on 2024-T3 aluminum plates with five types of impactors, and then the effects of the dent on the residual ultimate strength of the 2024-T3 specimens were investigated through axial compression tests. Results indicate that with increase in dent depth, the five types of dents affect the ultimate strength of the plate in different trends. Nevertheless, other than the plate global deflection caused by impacting, the dent itself has unremarkable effect on the ultimate strength. The mathematical expressions are derived regarding the relationship between impact energy factor and the dent depth factor as well as the compressive ultimate strength reduction rate and the dent depth factor.
基金Project(IRT1229)supported by the Program for Chang-jiang Scholars and Innovative Research Team in University,ChinaProject(51375114)supported by the National Natural Science Foundation of China
文摘In order to avoid the occurrence of fracture at room temperature in reverse deep drawing of aluminum alloy plate, the warm reverse deep drawing method was proposed. The experiments were conducted at room temperature, 280 and 360 ℃ with a 4.5 mm thick 5A06 aluminum alloy plate. The effect of temperature, blank-holding force and gap on the fracture and wrinkle of the reverse deep drawing process was investigated. A fully coupled thermal-mechanical simulation was carried out to obtain the stress distribution through the commercial software of Abaqus/Explicit. The results show that the fracture is avoided at 280 ℃ since the bending-induced stress gradient in the transient area between the inside corner and the straight wall decreases from 505 MPa at RT to 72 MPa at 280 ° C. Although the fracture is avoided as the temperature increases, the wrinkle occurs at the outside die corner at temperature over 280 ° C, where the circumferential compressive stress becomes larger than that at the inside. As the temperature increases to 360 ℃, the fracture occurs due to the excessive softening, the tensile stress in the straight wall reaches rapidly to the tensile strength at the beginning of reverse deep drawing. When 1.5t (t=4.5 mm) blank holding gap is applied at 280 ℃, both the fracture and wrinkle can be avoided, and 420 mm deep cups are drawn successfully.
基金Project(51374025) supported by the National Natural Science Foundation of ChinaProject(2014Z-05) supported by the State Key Laboratory for Advanced Metals and Materials,University of Science and Technology Beijing,ChinaProject(2152020) supported by the Beijing Natural Science Foundation,China
文摘Cu-4.7%Sn (mass fraction) alloy plate was prepared by the self-developed two-phase zone continuous casting (TZCC) process. The relationship between process parameters of TZCC and surface quality of the alloy plate was investigated. The microstructure and mechanical properties of the TZCC alloy plate were analyzed. The results show that Cu-4.7%Sn alloy plate with smooth surface can be obtained by means of reasonable matching the entrance temperature of two-phase zone mold and the continuous casting speed. The microstructure of the TZCC alloy is composed of grains-covered grains, small grains with self-closed grain boundaries, columnar grains and equiaxed grains. Compared with cold mold continuous casting Cu-4.7%Sn alloy plate, the room temperature tensile strength and ductility of the TZCC alloy plate are greatly improved.
基金Project(51475483)supported by the National Natural Science Foundation of ChinaProject(2014FJ3002)supported by Science and Technology Project of Hunan Province,ChinaProject supported by Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province,China
文摘A thickness strain model of aluminium alloy plate under plastic deformation,based on thin plate assumption was proposed.It is found that when ratio of stress fractions is constant during in-plane loading,ratios of strain components under various loading conditions are linearly related and these points of ratios form a η-η line.Under these simple loadings,strains in thickness direction can be easily calculated by the η-η line equation without integral and differential work.When the plate is under more complicated loading conditions,the thickness can be computed by the proposed optimization and piecewise calculation model.Validation computations indicate that the relative error of the results of the presented model is less than 0.75% compared with the proven theories and FE simulation.Therefore,the developed model can be applied to engineering calculation,e.g.pre-stretching analysis of aerospace aluminium thick plate,with acceptable accuracy.
基金Project(2014DFA50860)supported by International Science&Technology Cooperation Program of China
文摘After Sn/Pd activating, the SiCp/Al composite with 65% SiC (volume fraction) was coated by electroless Ni?P alloy plating. Surface morphology of the composite and its effect on the Ni?P alloy depositing process and bonding action of Ni and P atoms in the Ni?P alloy were studied. The results show that inhomogeneous distribution of the Sn/Pd activating points results in preferential deposition of the Ni?P alloy particles on the Al alloy and rough SiC particle surfaces and in the etched caves. The Ni?P alloy film has an amorphous structure where chemical bonding between Ni and P atoms exists. After a continuous Ni?P alloy film formed, electroless Ni?P alloy plating is not affected by surface morphology and characteristics of the SiCp/Al composite any longer, but by the electroless plating process itself. The Ni?P alloy film follows linear growth kinetics with an activation energy of 68.44 kJ/mol.
基金Project(51371116)supported by the National Natural Science Foundation of ChinaProject(2009AA033501)supported by the Ministry of Science and Technology,China
文摘Electroless nickel plating on AZ91D substrate with a new and eco-friendly pretreatment process based on tuning an electrochemical homogeneous surface was investigated. The morphology, deposition process, chemical composition and microstructure of Ni-P coating were studied. It is indicated that β phases are selectively removed, producing a microstructural homogeneous surface and the subsequent uniform and compact Zn immersion layer. A defect-free and well adhesive Ni-P coating can be successfully obtained due to its uniform nucleation and growth based on such pretreatment. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests reveal that Ni-P coating could significantly improve the corrosion resistance of AZ91D substrate.
基金The project was financially supported by The Space Foundation of Supporting-Technology of China (No. 2002EK1803)the Graduate Starting Seed Fund of Northwestern Polytechnical University (No. W016663)
文摘Ni-W-P coatings were deposited on the surface of glass fibers by the electroless plating process. The bath was very stable through the palladium salt test. There was no phenomenon of peeling and blistering on the surface of the Ni-W-P alloy glass fibers in the thermal shock test. It showed that the deposit had high impact strength and good adhesion. The morphology of the coatings was observed by scanning electron microscope (SEM). The elements and their contents were tested and analyzed by energy dispersion spectrometer (EDS). The tungsten content reached up to 12.1 wt.%. The effects of the concentrations of NiSO4, Na2WO4, and NaH2PO2.H20 on the conductivity of the coatings were studied. The resistivity of the Ni-W-P alloy glass fibers reached 7.39 × 10^-3 Ωcm. The alloy coatings on glass fibers were analyzed by XRD. The results indicated that the deposit had an amorphous structure and good heat stability. The suitable work temperature range was lower than 190℃. Finally, the electromagnetic parameters of the Ni-W-P alloy glass fibers were tested and analyzed primarily. The magnetic loss reached 0.04023 and the dielectric loss reached -5.80239. The plated alloy is a kind of soft magnetic material.
基金Project(04GK1007) supported by the Science and Technology Office of Hunan Province,China
文摘A new technique of electroplating amorphous Fe-Ni-W alloy deposits was proposed.The structure and morphology o Fe-Ni-W alloy deposit were detected by XRD and SEM.The friction and wear behavior of Fe-Ni-W alloy deposit were studied and compared with that of chromium deposit.The corrosion properties against 5% sodium chloride,5% sulfuric acid and 5% sodium hydroxide were also discussed.The experimental results indicate that Fe-Ni-W alloy deposits have superior properties against wea than hard chromium deposits under dry sliding condition.Under oil sliding condition,except their better wear resistance,the deposits can protect their counterparts against wear.The deposits plated on brass and AISI 1045 steel show good behavior against corrosion o 5% sodium chloride,5% sulfuric acid and 5% sodium hydroxide.The bath of electroplating amorphous Fe-Ni-W alloy deposits is environmentally friendly and would find widely use in industry.
基金the National High-Tech Research Development Program of China (No.G2003AA331100).
文摘The ageing behavior of a pre-stretched thick plate of Al-Zn-Mg-Cu alloy was systemically studied including one-step ageing, two-step ageing, and retrogression and reageing treatment (RRA). One-step ageing of the alloy resulted in peak ultimate tensile strengths of 595 and 575 MPa after 22 and 6 h at 120 and 135°C, respectively. The strengthening phase in peak aged (T6 temper) alloy contained GP zones and the η′ phase predominantly. After two-step ageing, the electrical conductivity was increased markedly, but the pre-stretched thick plate sacrificed a great loss of strength. RRA treatment provided a method for maintaining the strength close to that obtained by T6 temper and for obtaining the high electrical conductivity close to that obtained by T7 temper; the ultimate tensile strength and electrical conductivity were 583 MPa and 21.0 MS/m, respectively. TEM analysis of T7 and RRA specimens revealed two types of precipitates that contributed to age strengthening i.e. the η′ and η phases.
基金financially supported by the Special Foundation of the Shanghai Education Commission for Nano-Materials Research (0852nm01400)Shanghai Leading Academic Discipline Project (J51402)
文摘High-temperature tribological properties of Ni-P alloy coatings processed by electro-brush plating on 20CrMo steel have been investigated. A baU-on-disc configuration was employed and 4 mm diameter Si3N4 balls were used as static counterpart. All the wear tests were carried out at 450℃ for 180 rain without lubricants. The electro-brush plating Ni-P coating is amorphous in as-deposited condition, and it becomes polycrystalline with the formation of Ni and Ni3P after heat treatment at 450℃for 1 h. The friction coefficient of the Ni-P coating is just 50% of that of the 20CrMo steel at the friction temperature of 450℃. A mild adhesive wear mechanism was found for the electro-brush plating Ni-P coating tested at 450℃, whereas for the 20CrMo steel at the same temperature a mixed adhesive and abrasive wear mechanism was observed.
文摘The influence of bath constituents and pulse parameters on cobalt content, surface morphologies and grain size of Zn-Co alloy deposits was studied using a pulse plating technique with a square- wave current containing reverse pulse, It is found that Zn-Co alloy coatings obtained from the bath with the cobalt ion concentration over 60 wt% have a higher cobalt content in deposits. The results of pulse plating show that the average current density and reverse anodic current density amongst the variables investigated have very strong effects on the cobalt content in the Zn-Co alloy deposits. It is possible to electrodeposit Zn-Co alloy coatings with 10-90 wt% cobalt by modulating pulse parameters. The grain size, surface appearance and internal stress in the deposit were improved significantly by introducing the reverse current.
文摘The electroless deposition of Ni68-Fe10.5-P21.5 alloy has been investigated. The crystallization behavior of the deposit was comparatively studied by using differential scanning calorimetry and X-ray diffractometry. The deposit transforms into a square Ni3P phase at 380. 0 ℃, then changes into a cubic FeNi3 phase at 490. 0 ℃. The microhardness, the size of the formed grains and the magnetic performance of the deposit increase with the increase of the heat treatment temperature below 500 ℃, then they decrease after this temperature. The effect of heat treatment time at 500 ℃ on the surface micromorphology, the structure and the magnetic performance of the deposit were also studied. The resuits show that with the increase of heat treatment time, the extent of crystallization of the deposit increases and the size of the formed grains becomes uniform. The results also show that the magnetic performance of the deposit under heat treatment for 40 min is maximal and then decreases with the increase of heat treatment time. The property change of the deposit is related to the crystal structure and the size of the formed grains of the deposit.
文摘The current research processes of electroplating and electroless Ni-P alloy plating on magnesium alloys were reviewed. Theoretically,the reason for difficulties in electroplating and electroless plating on magnesium alloys was given.The zinc immersion, copper immersion,direct electroless Ni-P alloy plating and electroplating and electroless plating on magnesium alloys prepared by chemical conversion coating were presented in detail.Especially,the research development of magnesium alloy AZ91 and AZ31 was discussed briefly.Based on the analysis,the existing problems and future research directions were then given.