Texture evolution in nanocomposite Nd_2Fe_ 14B/α-Fe magnets prepared by direct melt spinning was investigated. The free surface and wheel-contacted surface exhibit different texture direction. Modification of composi...Texture evolution in nanocomposite Nd_2Fe_ 14B/α-Fe magnets prepared by direct melt spinning was investigated. The free surface and wheel-contacted surface exhibit different texture direction. Modification of composition not only enhances magnetic properties, but also changes texture direction of the ribbon. Low temperature heat treatment can increase the magnetic properties to some extent, and high temperature annealing decreases the magnetic properties. Both low and high temperature heat treatment have effects on grain orientation, but the difference still exists between the two surfaces of the ribbon. So it is infeasibility to prepare anisotropic Nd_2Fe_ 14B/α-Fe nanocomposite magnets by direct melt spinning.展开更多
The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The ...The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The results show that the common effects of both the heat flux and the substrate magnetization orientation constrain the columnar Nd_(2)Fe_(14)B solidified from the laser melting pool to form the c-axis texture orientated with the same direction as that of the substrate,when the geometric relationship between the heat flux in the laser scanning layer and c-axis texture orientation of the substrate is perpendicular to each other,and if the laser scanning velocity is no less than 25 mm·min^(-1).The c-axes of columnar Nd_(2)Fe_(14)B crystals are no longer randomly distributed in the plane normal to their preferential growing direction as they are randomly done in both ingots cooled by water-cooling copper mould and directionally solidified Nd-Fe-B rods.展开更多
Based on the observation of temperature variation of both domain structure and magnetic con- trast.the thermal demagnetization and randomness of domain nucleation was discussed.
This review summarizes the recent advances on the application of ^(57)Fe Mössbauer spectrometry to study the magnetic and phase characteristics of Nd–Fe–B-based permanent magnets. First of all, the hyperfine st...This review summarizes the recent advances on the application of ^(57)Fe Mössbauer spectrometry to study the magnetic and phase characteristics of Nd–Fe–B-based permanent magnets. First of all, the hyperfine structures of the Ce_(2)Fe_(14)B,(Ce,Nd)_(2)Fe_(14)B and MM_(2)Fe_(14)B phases are well-defined by using the model based on the Wigner-Seitz analysis of the crystal structure. The results show that the isomer shift δ and the quadrupole splitting öEQ of those 2:14:1 phases show minor changes with the Nd content, while the hyperfine field Bhfincreases monotonically with increasing Nd content and its value is influenced by the element segregation and phase separation in the 2:14:1 phase. Then, the hyperfine structures of the low fraction secondary phases are determined by the ^(57)Fe Mössbauer spectrometry due to its high sensitivity. On this basis,the content, magnetic behavior, and magnetization of the REFe_(2) phase, the amorphous grain boundary(GB) phase, and the amorphous worm-like phase, as well as their effects on the magnetic properties, are systematically studied.展开更多
A series of magnetic properties of Tm_2Fe_(14)B are explained quantitatively by the calculations based on the single ion model. The magnetic properties include the temperature dependence of the spontaneous magnetizati...A series of magnetic properties of Tm_2Fe_(14)B are explained quantitatively by the calculations based on the single ion model. The magnetic properties include the temperature dependence of the spontaneous magnetization, the spin reorientation temperature and the magnetization curves along the principal crystal axes at 4.2, 100, 150 and 200 K. The values of the exchange field and the crystalline electric field parameters used in the calculations are μ_BH_(ex)(T=0 K)=135, B_2~0=1.77, B_2~2=±2.97, B_4~0=-3.06×10^(-3), B_4^(-2)=0, B_4~4=-6.82×10^(-3), B_6~0=1.05× 10^(-5), B_6^(-2)=±7.40×10^(-5), B_6~4=1.96×10^(-4), and B_6^(-6)=0 all in K unit. The magnetization processes of the Fe-and Tm-sublattices at different temperatures are analysed. The processes are characterized by the non-collinearity between the magnetic moments of the Fe-and Tm-sublattices.展开更多
文摘Texture evolution in nanocomposite Nd_2Fe_ 14B/α-Fe magnets prepared by direct melt spinning was investigated. The free surface and wheel-contacted surface exhibit different texture direction. Modification of composition not only enhances magnetic properties, but also changes texture direction of the ribbon. Low temperature heat treatment can increase the magnetic properties to some extent, and high temperature annealing decreases the magnetic properties. Both low and high temperature heat treatment have effects on grain orientation, but the difference still exists between the two surfaces of the ribbon. So it is infeasibility to prepare anisotropic Nd_2Fe_ 14B/α-Fe nanocomposite magnets by direct melt spinning.
基金This work was financially supported by the Zhejiang Provincial Natural Science Fund of China(No.M503096)by Ministry of Science and Technology(No.2004CCA04000).
文摘The arrangements of the easy magnetization axis[001]of columnar Nd_(2)Fe_(14)B crystals in the laser scanned layer on anisotropic sintered Nd_(15)Fe_(77)B_(8)magnets were investigated by XRD and the Bitter method.The results show that the common effects of both the heat flux and the substrate magnetization orientation constrain the columnar Nd_(2)Fe_(14)B solidified from the laser melting pool to form the c-axis texture orientated with the same direction as that of the substrate,when the geometric relationship between the heat flux in the laser scanning layer and c-axis texture orientation of the substrate is perpendicular to each other,and if the laser scanning velocity is no less than 25 mm·min^(-1).The c-axes of columnar Nd_(2)Fe_(14)B crystals are no longer randomly distributed in the plane normal to their preferential growing direction as they are randomly done in both ingots cooled by water-cooling copper mould and directionally solidified Nd-Fe-B rods.
文摘Based on the observation of temperature variation of both domain structure and magnetic con- trast.the thermal demagnetization and randomness of domain nucleation was discussed.
基金Project supported by the Zhejiang Provincial Natural Science Foundation of China(Grant Nos.LY20E010002,LR18E010001,and LD19E010001)the National Natural Science Foundation of China(Grant Nos.U1704253 and 51801047)+2 种基金Liaoning Revitalization Talents Program(Grant No.XLYC1807177)the Key Research and Development plan of Zhejiang Province,China(Grant No.2020C05014)Ten Thousand Talents Plan of Zhejiang Province,China(Grant No.2018R52003)。
文摘This review summarizes the recent advances on the application of ^(57)Fe Mössbauer spectrometry to study the magnetic and phase characteristics of Nd–Fe–B-based permanent magnets. First of all, the hyperfine structures of the Ce_(2)Fe_(14)B,(Ce,Nd)_(2)Fe_(14)B and MM_(2)Fe_(14)B phases are well-defined by using the model based on the Wigner-Seitz analysis of the crystal structure. The results show that the isomer shift δ and the quadrupole splitting öEQ of those 2:14:1 phases show minor changes with the Nd content, while the hyperfine field Bhfincreases monotonically with increasing Nd content and its value is influenced by the element segregation and phase separation in the 2:14:1 phase. Then, the hyperfine structures of the low fraction secondary phases are determined by the ^(57)Fe Mössbauer spectrometry due to its high sensitivity. On this basis,the content, magnetic behavior, and magnetization of the REFe_(2) phase, the amorphous grain boundary(GB) phase, and the amorphous worm-like phase, as well as their effects on the magnetic properties, are systematically studied.
文摘A series of magnetic properties of Tm_2Fe_(14)B are explained quantitatively by the calculations based on the single ion model. The magnetic properties include the temperature dependence of the spontaneous magnetization, the spin reorientation temperature and the magnetization curves along the principal crystal axes at 4.2, 100, 150 and 200 K. The values of the exchange field and the crystalline electric field parameters used in the calculations are μ_BH_(ex)(T=0 K)=135, B_2~0=1.77, B_2~2=±2.97, B_4~0=-3.06×10^(-3), B_4^(-2)=0, B_4~4=-6.82×10^(-3), B_6~0=1.05× 10^(-5), B_6^(-2)=±7.40×10^(-5), B_6~4=1.96×10^(-4), and B_6^(-6)=0 all in K unit. The magnetization processes of the Fe-and Tm-sublattices at different temperatures are analysed. The processes are characterized by the non-collinearity between the magnetic moments of the Fe-and Tm-sublattices.
