The silicification of rice straw is a factor that affects the grain production and straw nutritive quality. The procedure of chemical analysis for silicon in straw is, however, time and labor consuming, and slightly p...The silicification of rice straw is a factor that affects the grain production and straw nutritive quality. The procedure of chemical analysis for silicon in straw is, however, time and labor consuming, and slightly poor in accuracy. The study has attempted to apply near infrared reflectance spectroscopy (NIRS) technique as an advanced alternative to predict the fiber composition and silicification in rice straw. Ninety-two samples from different seasons and varieties were collected over the Fujian Province. Their chemical analyses were carried on the aspects of hemicellulose, cellulose, lignin, extractable and non-extractable silicon, and the results were used as a database for NIRS analyses. The prediction model was developed through modified partial least square regression (MPLS) for a calibration program. The factors that may affect the calibration, cross-validation and the prediction for the application of NIRS on rice straw were also discussed.展开更多
In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in har...In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in harsh seawater conditions is a concern. Researchers address this by exploring three approaches: coating fiber surfaces, hybridizing fibers and matrices with or without nanofillers, and interply rearrangement. This study focuses on evaluating the synergistic effects of interply rearrangement of glass/carbon fibers and hybrid nanofillers, specifically Multi-walled carbon nanotubes (MWCNT) and Halloysite nanotubes (HNT). The aim is to enhance impact properties by minimizing moisture absorption. Hybrid nanocomposites with equal-weight proportions of two nanofillers: 0 wt.%, 1 wt.%, and 2 wt.% were exposed to seawater for 90 days. Experimental data was subjected to modelling through the application of Predictive Fick’s Law. The study found that the hybrid composite containing 2 wt.% hybrid nanofillers exhibited a 22.10% increase in impact performance compared to non-modified counterparts. After 90 days of seawater aging, the material exhibited enhanced resistance to moisture absorption (15.74%) and minimal reduction in impact strength (8.52%) compared to its dry strength, with lower diffusion coefficients.展开更多
This work aims at investigating the microwave absorption and mechanical properties of short-cutted carbon fiber/glass fiber hybrid veil reinforced epoxy composites.The short-cutted carbon fibers(CFs)/glass fibers(GFs)...This work aims at investigating the microwave absorption and mechanical properties of short-cutted carbon fiber/glass fiber hybrid veil reinforced epoxy composites.The short-cutted carbon fibers(CFs)/glass fibers(GFs)hybrid veil were prepared by papermaking technology,and composites liquid molding was employed to manufacture CFs/GFs hybrid epoxy composites.The microstructure,microwave absorbing properties and mechanical properties of the hybrid epoxy composites were studied by using SEM,vector network analyzer and universal material testing,respectively.The reflection coefficient of the composites were calculated by the measured complex permittivity and permeability in the X-band(8.2-12.4 GHz)range.The optimum microwave absorption properties can be obtained when the content of CFs in the hybrid veil is 6 wt%and the thickness of the composites is 2 mm,the minimum reflection coefficient of-31.8 dB and the effective absorption bandwidth is 2.1 GHz,which is ascribed to benefitting impedance matching characteristic and dielectric loss of the carbon fiber.Simultaneously the tensile strength and modulus can achieve 104.0 and 2.98GPa,demonstrating that the CFs/GFs hybrid epoxy composites can be a promising candidate of microwave absorbing materials with high mechanical properties.展开更多
To study the static bending creep properties of glass fiber reinforced wood,glass fiber reinforced poplar(GFRP)specimens were obtained by pasting glass fiber on the upper and lower surfaces of Poplar(Populus euramevic...To study the static bending creep properties of glass fiber reinforced wood,glass fiber reinforced poplar(GFRP)specimens were obtained by pasting glass fiber on the upper and lower surfaces of Poplar(Populus euramevicana,P),the performance of Normal Creep(NC)and Mechanical Sorptive Creep(MSC)of GFRP and their influencing factors were tested and analyzed.The test results and analysis show that:(1)The MOE and MOR of Poplar were increased by 17.06%and 10.00%respectively by the glass fiber surface reinforced composite.(2)The surface reinforced P with glass fiber cloth only exhibits the NC pattern of wood and loses the MSC characteristics of wood,regardless of the constant or alternating changes in relative humidity.(3)The instantaneous elastic deformation,viscoelastic deformation,viscous deformation and total creep deflection of GFRP are positively correlated with the stress level of the external load applied to the specimen.Still,the specimen’s creep recovery rate is negatively correlated with the stress level of the external load applied to the specimen.The static creep deflection and viscous deformation of GFRP increase with the increase of the relative humidity of the environment.(4)The MSC maximum creep deflection of GFRP increased by only 7.41%over the NC maximum creep deflection,but the MSC maximum creep deflection of P increased by 199.25%over the NC maximum creep deflection.(5)The Burgers 4-factor model and the Weibull distribution equation can fit the NC and NC recovery processes of GFRP well.展开更多
This study focused on the development and characterization of TiO<sub>2</sub>-PES composite fibers with varying TiO<sub>2</sub> loading amounts using a phase inversion process. The resulting co...This study focused on the development and characterization of TiO<sub>2</sub>-PES composite fibers with varying TiO<sub>2</sub> loading amounts using a phase inversion process. The resulting composite fibers exhibited a sponge-like structure with embedded TiO<sub>2</sub> nanoparticles within a polymer matrix. Their photocatalytic performance for ammonia removal from aqueous solutions under UV-A light exposure was thoroughly investigated. The findings revealed that PeTi8 composite fibers displayed superior adsorption capacity compared to other samples. Moreover, the study explored the impact of pH, light intensity, and catalyst dosage on the photocatalytic degradation of ammonia. Adsorption equilibrium isotherms closely followed the Langmuir model, with the results indicating a correlation between qm values of 2.49 mg/g and the porous structure of the adsorbents. The research underscored the efficacy of TiO<sub>2</sub> composite fibers in the photocatalytic removal of aqueous under UV-A light. Notably, increasing the distance between the photocatalyst and the light source resulted in de-creased hydroxyl radical concentration, influencing photocatalytic efficiency. These findings contribute to our understanding of TiO<sub>2</sub> composite fibers as promising photocatalysts for ammonia removal in water treatment applications.展开更多
The application of natural fibers as reinforcement in composite material has increased due to environmental concerns,low cost,degradability and health concerns.The purpose of this study is to identify the best type of...The application of natural fibers as reinforcement in composite material has increased due to environmental concerns,low cost,degradability and health concerns.The purpose of this study is to identify the best type of bamboo fibers to be used as reinforcement for kenaf(K)/bamboo hybrid composite.There were three types of bamboo fibers evaluated in this study which include bamboo mat(B),bamboo fabric(BF)and bamboo powder(BP).Chemical composition of B,BF,BP and K fibers were analyzed in this study.The effect of different types of bamboo fibers on tensile,impact,and morphological properties were investigated.The B/epoxy composites displayed the highest tensile strength(53.03 MPa)while K/epoxy composite had the highest tensile modulus(4.71 GPa).Scanning electron micrographs of B/epoxy composites displayed better fiber/matrix interfacial bonding in comparison to other studied composites.Results showed that impact strength of BF-based composite was highest(45.70 J/m).In conclusion,the tensile strength of B/epoxy composite is superior to the other bamboo reinforced composites and will be further evaluated in the next study.展开更多
Dendrocalamus farinosus and Phyllostachys heterocycla bamboo logs were subjected to a novel treat- ment process for the preparation of bamboo fiber mats (BFMs), and the obtained BFM were used to fabricate bamboo fib...Dendrocalamus farinosus and Phyllostachys heterocycla bamboo logs were subjected to a novel treat- ment process for the preparation of bamboo fiber mats (BFMs), and the obtained BFM were used to fabricate bamboo fiber reinforced composite (BFRC). We studied the mechanical properties of the BFRCs manufactured from the mats with and without bamboo nodes. The pres- ence of nodes in BFM greatly reduced tensile strength, compressive strength, modulus of elasticity, and modulus of rupture of the BFRCs, while the BFRCs fabricated from BFMs with nodes possessed higher horizontal shear strength. Therefore, the nodes in bamboo culms were an important factor in the uniform distribution of mechanical properties, and BFMs should be homogeneously arranged to reduce the impact of nodes on the mechanical strengths of BFRCs.展开更多
Effect of rare earth treatment on surface physicochemical properties of carbon fibers and interfacial properties of carbon fiber/epoxy composites was investigated, and the interfacial adhesion mechanism of treated car...Effect of rare earth treatment on surface physicochemical properties of carbon fibers and interfacial properties of carbon fiber/epoxy composites was investigated, and the interfacial adhesion mechanism of treated carbon fiber/epoxy composite was analyzed. It was found that rare earth treatment led to an increase of fiber surface roughness, improvement of oxygeaa-containing groups, and introduction of rare earth element on the carbon fiber surface. As a result, coordination linkages between fibers and rare earth, and between rare earth and resin matrix were formed separately, thereby the interlaminar shear strength (ILSS) of composites increased, which indicated the improvement of the interfacial adhesion between fibers and matrix resin resulting from the increase of carboxyl and carbonyl.展开更多
Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission (AE) statistical analysis towards fi...Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission (AE) statistical analysis towards fiber composites under mode-Ⅱ delamination damage. The load curve, AE relative energy, amplitude distribution, and amplitude spectrum are obtained and the delamination damage mechanism of the composites is investigated by the microscopic observation of a fractured specimen. The results show that the micro-damage accumulation around the crack tip region has a great effect on the evolutionary process of delamination. AE characteristics and amplitude spectrum represent the damage and the physical mechanism originating from the hierarchical microstructure. Our finding provides a novel aud feasible strategy to simultaneously evaluate the dynamic response and micro-damage mechanism for fiber composites.展开更多
Composite polyurethane(PU)-SiO_2 hollow fiber membranes were successfully prepared via optimizing thetechnique of dry-jet wet spinning,and their pressure-responsibilities were confirmed by the relationships of pure wa...Composite polyurethane(PU)-SiO_2 hollow fiber membranes were successfully prepared via optimizing thetechnique of dry-jet wet spinning,and their pressure-responsibilities were confirmed by the relationships of pure water flux-transmembrane pressure(PWF-TP)for the first time.The origin for this phenomenon was analyzed on the basis of membranestructure and material characteristics.The effects of SiO_2 content on the structure and properties of membrane wereinvestigated.The experimental results indicated that SiO_2 in membrane created a great many interfacial micro-voids andplayed an important role in pressure-responsibility,PWF and rejection of membrane:with the increase of SiO_2 content,theability of membrane recovery weakened,PWF increased,and rejection decreased slightly.展开更多
The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites(CFGCC) with carbon fiber content(1% by the weight of cement),graphite powder contents (0%-50% by the weight of ce...The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites(CFGCC) with carbon fiber content(1% by the weight of cement),graphite powder contents (0%-50% by the weight of cement) and CCCW(cementitious capillary crystalline waterproofing materials,4% by the weight of cement) were studied.The experimental results showed that the relationship between the resistivity of CFGCC and the concentration of graphite powders had typical features of percolation phenomena.The percolation threshold was about 20%.A clear piezoresistive effect was observed in CFGCC with 1wt% of carbon fibers,20wt% or 30wt% of graphite powders under uniaxial compressive tests,indicating that this type of smart composites was a promising candidate for strain sensing.The measured gage factor (defined as the fractional change in resistance per unit strain) of CFGCC with graphite content of 20wt% and 30wt% were 37 and 22,respectively.With the addition of CCCW,the mechanical properties of CFGCC were improved,which benefited CFGCC piezoresistivity of stability.展开更多
2-D nanosheet Cu2O doped CuO coating poly m-phenylenediamine and melamine/graphene/carbon fibers composite(CuxO/MPM/GFs)was firstly fabricated by compound electrochemical method.CuxO/MPM/GFs was successfully used to t...2-D nanosheet Cu2O doped CuO coating poly m-phenylenediamine and melamine/graphene/carbon fibers composite(CuxO/MPM/GFs)was firstly fabricated by compound electrochemical method.CuxO/MPM/GFs was successfully used to the recovery of iodide(I-)from salt water by lower potential-aided sorption and desorption processes.The potential-aided recovery of I-at CuxO/MPM/GFs was characterized by FE-SEM,XRD,IR,Raman,XPS,UV-vis and electrochemical techniques in detail.The maximal adsorption capacity of 86.82 mg·g^-1 could be obtained with a pseudo-second-order model at 0.8 V for 210 min in pH 5.0,0.1 mol·L^-1 NaCl,and the process accompanied the generation of CuI,CuO and I5-.The I-could be quickly desorbed from the electrode with a transfer of CuI to Cu2O by cycle voltammetry from-1.0 to 0.5 V for 90 cycles in pH 9.0,0.1 mol·L^-1 KNO3.Thus,CuxO/MPM/GFs was renewable in the continuous electrochemical-adsorption-desorption processes.展开更多
Natural fiber reinforced polymer composites(NFRCs)have demonstrated great potential for many different applications in various industries due to their advantages compared to synthetic fiber-reinforced composites,such ...Natural fiber reinforced polymer composites(NFRCs)have demonstrated great potential for many different applications in various industries due to their advantages compared to synthetic fiber-reinforced composites,such as low environmental impact and low cost.However,one of the drawbacks is that the NFRCs present relatively low mechanical properties and the absorption of humidity due to the hydrophilic characteristic of the natural fibre.One method to increase their performance is hybridization.Therefore,understanding the properties and potential of using multiple reinforcement’s materials to develop hybrid composites is of great interest.This paper provides an overview of the recent advances in hybrid natural fiber reinforced polymer composites.First,the main factors that affect the performance of hybrid fiber-reinforced composites were briefly discussed.The effect of hybridization on the mechanical and thermal properties of hybrid composites reinforced with several types of natural fibers(i.e.,sisal,jute,curauá,ramie,banana,etc.)or natural fibers combined with synthetic fibers is pre-sented.Finally,the water absorption behaviour of hybrid fiber-reinforced composites is also discussed.It was con-cluded that the main challenges that need to be addressed in order to increase the use of natural-natural or natural-synthetic hybrid composites in industry are the poor adhesion between natural fibers and matrix,thermal stability and moisture absorption of natural fibers.Some of these challenges were addressed by recent develop-ment in fibers treatment and modification,and product innovation(hybridization).展开更多
The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and b...The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and ballistic test were performed to the prepared composites.After the tests,the specimens were recovered and analyzed for micromorphology.Three-point bending tests show that both the bending strength and stiffness of the WBFC surpass those of the UBFC.Low velocity impact test results show that the low velocity impact resistance to hemispherical impactor of the UBFC is higher than that of the WBFC,but the low velocity impact resistance to sharp impactor of the UBFC is lower than that of the WBFC.For the ballistic test,it can be found that the ballistic property of the UBFC is higher than that of the WBFC. After the tests,microscopic analysis of the specimens was applied,and their failure mechanism was discussed.The main failure modes of the UBFC are delamination and fibers breakage under the above loading conditions while the main failure mode of the WBFC is fibers breakage.Although delamination damage can be found in the WBFC under the above loading conditions,the degree of delamination is far less than that of the UBFC.展开更多
To determinate the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints, energy dispersive X-ray spectroscopy analysis(EDX) is used to establish the content chan...To determinate the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints, energy dispersive X-ray spectroscopy analysis(EDX) is used to establish the content change of oxy- gen in the adhesive in adhesive/carbon fther reinforced epoxy resin composite joints. As water is made up of oxygen and hydrogen, the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints can be obtained from the change in the content of oxygen in the adhesive during humidity aging, via EDX analy-sis. The authors have calculated the water diffusion coefficients and dynamics in the adhesive/carbon fiber reinforced epoxy resin composite joints with the aid of beth energy dispersive X-ray spectroscopy and elemental analysis. The de- termined results with EDX analysis are almost the same as those determined with elemental analysis and the results al- so show that the durability of the adhesive/carbon fther reinforced epoxy resin composite joints subjected to silane cou- pling agent treatment is better than those subjected to sand paper burnishing treatment and chemical oxidation treat- ment.展开更多
Equilibrium paths of post-buckling are measured for large slenderness column specimensmade of the fiber reinforced composite material. The influence of the initial curvature is investigatedexperimentally and compared ...Equilibrium paths of post-buckling are measured for large slenderness column specimensmade of the fiber reinforced composite material. The influence of the initial curvature is investigatedexperimentally and compared with the result of the initial post-buckling theory. Both the theoreticaland experimental results reveal that the column with the initial curvature has stable post-buckling be-haviors and is not sensitive to the imperfection in the form of initial curvature. The experimental re-sults show that when the lateral buckling displacement is less than 20 percent of the column length, theexperimental results agree with the results from the theory of initial post-buckling quite well, whilethey agree with the results from the large deflection theory in a quite large range.展开更多
The 21 dog-bone specimens with different fiber contents and fiber distribution (random chopped fiber or directional continuous filament fiber bundles) were designed and tested under uniaxial tension using domestic PVA...The 21 dog-bone specimens with different fiber contents and fiber distribution (random chopped fiber or directional continuous filament fiber bundles) were designed and tested under uniaxial tension using domestic PVA (polyvinyl alcohol) fiber.High fiber content exerted positive influences on cracking stress,peak stress and deformation capacity of specimens with random chopped fiber,compared with the decrease shown in cracking stress of specimens containing directional fiber bundles.There were multiple cracks in specimens containing directional fiber bundles,while only 1-2 typical cracks could be shown in chopped fiber specimens after being broken.Random chopped fiber connected more closely with matrix compared with that only part of fiber bundles could contact with matrix.Double-fold line model and parabolic model could be used simultaneously to fit well with the uniaxial tension constitutive relations of engineered cementitious composite (ECC).Although the performance of PVA produced in China can not reach to the same level of those from Japan,there exists certain practical value in engineering according to its contribution to deformability of structure.展开更多
The in vitro degradation characteristic of the poly D, L-lactic acid ( PDLIA )/ hydroxyapatite ( HA ) compound were investigated. The compoundfibers were immersed in static phosphate buffer at 37℃ to degrade fo...The in vitro degradation characteristic of the poly D, L-lactic acid ( PDLIA )/ hydroxyapatite ( HA ) compound were investigated. The compoundfibers were immersed in static phosphate buffer at 37℃ to degrade for 22 weeks. The changes in pH value of the buffer solution, the mechanical strength and morphological of inside and outside of composite fibers with degrurlation characteristic were observed. Results show that pH value of the buffer solution stabilized to aboat 7.0 before 12 weeks, however after 20 weeks that pH value quick declined. After 7 weeks that composite fibers of mechanical strength cannot mensuration. SEM observation revealed ttua bimodal degradation occurred in composite fibers.展开更多
In the present scenario, there has been a rapid attention in research and development in the natural fiber composite field due to its better formability, abundant, renewable, cost-effective and eco-friendly features. ...In the present scenario, there has been a rapid attention in research and development in the natural fiber composite field due to its better formability, abundant, renewable, cost-effective and eco-friendly features. This paper exhibits an outline on natural fibers and its composites utilized as a part of different commercial and engineering applications. In this review, many articles were related to applications of natural fiber reinforced polymer composites. It helps to provide details about the potential use of natural fibers and its composite materials, mechanical and physical properties and some of their applications in engineering sectors.展开更多
文摘The silicification of rice straw is a factor that affects the grain production and straw nutritive quality. The procedure of chemical analysis for silicon in straw is, however, time and labor consuming, and slightly poor in accuracy. The study has attempted to apply near infrared reflectance spectroscopy (NIRS) technique as an advanced alternative to predict the fiber composition and silicification in rice straw. Ninety-two samples from different seasons and varieties were collected over the Fujian Province. Their chemical analyses were carried on the aspects of hemicellulose, cellulose, lignin, extractable and non-extractable silicon, and the results were used as a database for NIRS analyses. The prediction model was developed through modified partial least square regression (MPLS) for a calibration program. The factors that may affect the calibration, cross-validation and the prediction for the application of NIRS on rice straw were also discussed.
文摘In the maritime industry, cost-effective and lightweight Fiber Reinforced Polymer (FRP) composites offer excellent mechanical properties, design flexibility, and corrosion resistance. However, their reliability in harsh seawater conditions is a concern. Researchers address this by exploring three approaches: coating fiber surfaces, hybridizing fibers and matrices with or without nanofillers, and interply rearrangement. This study focuses on evaluating the synergistic effects of interply rearrangement of glass/carbon fibers and hybrid nanofillers, specifically Multi-walled carbon nanotubes (MWCNT) and Halloysite nanotubes (HNT). The aim is to enhance impact properties by minimizing moisture absorption. Hybrid nanocomposites with equal-weight proportions of two nanofillers: 0 wt.%, 1 wt.%, and 2 wt.% were exposed to seawater for 90 days. Experimental data was subjected to modelling through the application of Predictive Fick’s Law. The study found that the hybrid composite containing 2 wt.% hybrid nanofillers exhibited a 22.10% increase in impact performance compared to non-modified counterparts. After 90 days of seawater aging, the material exhibited enhanced resistance to moisture absorption (15.74%) and minimal reduction in impact strength (8.52%) compared to its dry strength, with lower diffusion coefficients.
基金Funded by Key Research and Development Plan in Hubei Province of China(Nos.2022BCA082,2022BCA077,2021BCA153)Initial Scientific Research Fund for High-level Talents of Hubei University of Technology(No.GCRC2020017)。
文摘This work aims at investigating the microwave absorption and mechanical properties of short-cutted carbon fiber/glass fiber hybrid veil reinforced epoxy composites.The short-cutted carbon fibers(CFs)/glass fibers(GFs)hybrid veil were prepared by papermaking technology,and composites liquid molding was employed to manufacture CFs/GFs hybrid epoxy composites.The microstructure,microwave absorbing properties and mechanical properties of the hybrid epoxy composites were studied by using SEM,vector network analyzer and universal material testing,respectively.The reflection coefficient of the composites were calculated by the measured complex permittivity and permeability in the X-band(8.2-12.4 GHz)range.The optimum microwave absorption properties can be obtained when the content of CFs in the hybrid veil is 6 wt%and the thickness of the composites is 2 mm,the minimum reflection coefficient of-31.8 dB and the effective absorption bandwidth is 2.1 GHz,which is ascribed to benefitting impedance matching characteristic and dielectric loss of the carbon fiber.Simultaneously the tensile strength and modulus can achieve 104.0 and 2.98GPa,demonstrating that the CFs/GFs hybrid epoxy composites can be a promising candidate of microwave absorbing materials with high mechanical properties.
基金The present work was financially sponsored by the National Natural Science Foundation of China(Grant No.31960291).
文摘To study the static bending creep properties of glass fiber reinforced wood,glass fiber reinforced poplar(GFRP)specimens were obtained by pasting glass fiber on the upper and lower surfaces of Poplar(Populus euramevicana,P),the performance of Normal Creep(NC)and Mechanical Sorptive Creep(MSC)of GFRP and their influencing factors were tested and analyzed.The test results and analysis show that:(1)The MOE and MOR of Poplar were increased by 17.06%and 10.00%respectively by the glass fiber surface reinforced composite.(2)The surface reinforced P with glass fiber cloth only exhibits the NC pattern of wood and loses the MSC characteristics of wood,regardless of the constant or alternating changes in relative humidity.(3)The instantaneous elastic deformation,viscoelastic deformation,viscous deformation and total creep deflection of GFRP are positively correlated with the stress level of the external load applied to the specimen.Still,the specimen’s creep recovery rate is negatively correlated with the stress level of the external load applied to the specimen.The static creep deflection and viscous deformation of GFRP increase with the increase of the relative humidity of the environment.(4)The MSC maximum creep deflection of GFRP increased by only 7.41%over the NC maximum creep deflection,but the MSC maximum creep deflection of P increased by 199.25%over the NC maximum creep deflection.(5)The Burgers 4-factor model and the Weibull distribution equation can fit the NC and NC recovery processes of GFRP well.
文摘This study focused on the development and characterization of TiO<sub>2</sub>-PES composite fibers with varying TiO<sub>2</sub> loading amounts using a phase inversion process. The resulting composite fibers exhibited a sponge-like structure with embedded TiO<sub>2</sub> nanoparticles within a polymer matrix. Their photocatalytic performance for ammonia removal from aqueous solutions under UV-A light exposure was thoroughly investigated. The findings revealed that PeTi8 composite fibers displayed superior adsorption capacity compared to other samples. Moreover, the study explored the impact of pH, light intensity, and catalyst dosage on the photocatalytic degradation of ammonia. Adsorption equilibrium isotherms closely followed the Langmuir model, with the results indicating a correlation between qm values of 2.49 mg/g and the porous structure of the adsorbents. The research underscored the efficacy of TiO<sub>2</sub> composite fibers in the photocatalytic removal of aqueous under UV-A light. Notably, increasing the distance between the photocatalyst and the light source resulted in de-creased hydroxyl radical concentration, influencing photocatalytic efficiency. These findings contribute to our understanding of TiO<sub>2</sub> composite fibers as promising photocatalysts for ammonia removal in water treatment applications.
文摘The application of natural fibers as reinforcement in composite material has increased due to environmental concerns,low cost,degradability and health concerns.The purpose of this study is to identify the best type of bamboo fibers to be used as reinforcement for kenaf(K)/bamboo hybrid composite.There were three types of bamboo fibers evaluated in this study which include bamboo mat(B),bamboo fabric(BF)and bamboo powder(BP).Chemical composition of B,BF,BP and K fibers were analyzed in this study.The effect of different types of bamboo fibers on tensile,impact,and morphological properties were investigated.The B/epoxy composites displayed the highest tensile strength(53.03 MPa)while K/epoxy composite had the highest tensile modulus(4.71 GPa).Scanning electron micrographs of B/epoxy composites displayed better fiber/matrix interfacial bonding in comparison to other studied composites.Results showed that impact strength of BF-based composite was highest(45.70 J/m).In conclusion,the tensile strength of B/epoxy composite is superior to the other bamboo reinforced composites and will be further evaluated in the next study.
基金financially supported by the Key Laboratory of Wood Industry and Furniture Engineering of Sichuan Provincial Colleges and Universitiesthe National Forestry Public Welfare Scientific Research Program(201304503)the Science and Technology Innovation Foundation for College Students
文摘Dendrocalamus farinosus and Phyllostachys heterocycla bamboo logs were subjected to a novel treat- ment process for the preparation of bamboo fiber mats (BFMs), and the obtained BFM were used to fabricate bamboo fiber reinforced composite (BFRC). We studied the mechanical properties of the BFRCs manufactured from the mats with and without bamboo nodes. The pres- ence of nodes in BFM greatly reduced tensile strength, compressive strength, modulus of elasticity, and modulus of rupture of the BFRCs, while the BFRCs fabricated from BFMs with nodes possessed higher horizontal shear strength. Therefore, the nodes in bamboo culms were an important factor in the uniform distribution of mechanical properties, and BFMs should be homogeneously arranged to reduce the impact of nodes on the mechanical strengths of BFRCs.
基金Project supported by the National Natural Science Foundation of China (50333030)
文摘Effect of rare earth treatment on surface physicochemical properties of carbon fibers and interfacial properties of carbon fiber/epoxy composites was investigated, and the interfacial adhesion mechanism of treated carbon fiber/epoxy composite was analyzed. It was found that rare earth treatment led to an increase of fiber surface roughness, improvement of oxygeaa-containing groups, and introduction of rare earth element on the carbon fiber surface. As a result, coordination linkages between fibers and rare earth, and between rare earth and resin matrix were formed separately, thereby the interlaminar shear strength (ILSS) of composites increased, which indicated the improvement of the interfacial adhesion between fibers and matrix resin resulting from the increase of carboxyl and carbonyl.
基金Supported by the Natural Science Foundation of Hebei Province under Grant No E2012201084the National University Students’ Innovative Training Program under Grant No 201410075004
文摘Realizing the accurate characterization for the dynamic damage process is a great challenge. Here we carry out testing simultaneously for dynamic monitoring and acoustic emission (AE) statistical analysis towards fiber composites under mode-Ⅱ delamination damage. The load curve, AE relative energy, amplitude distribution, and amplitude spectrum are obtained and the delamination damage mechanism of the composites is investigated by the microscopic observation of a fractured specimen. The results show that the micro-damage accumulation around the crack tip region has a great effect on the evolutionary process of delamination. AE characteristics and amplitude spectrum represent the damage and the physical mechanism originating from the hierarchical microstructure. Our finding provides a novel aud feasible strategy to simultaneously evaluate the dynamic response and micro-damage mechanism for fiber composites.
文摘Composite polyurethane(PU)-SiO_2 hollow fiber membranes were successfully prepared via optimizing thetechnique of dry-jet wet spinning,and their pressure-responsibilities were confirmed by the relationships of pure water flux-transmembrane pressure(PWF-TP)for the first time.The origin for this phenomenon was analyzed on the basis of membranestructure and material characteristics.The effects of SiO_2 content on the structure and properties of membrane wereinvestigated.The experimental results indicated that SiO_2 in membrane created a great many interfacial micro-voids andplayed an important role in pressure-responsibility,PWF and rejection of membrane:with the increase of SiO_2 content,theability of membrane recovery weakened,PWF increased,and rejection decreased slightly.
基金Funded by the National Natural Science Foundation of China(No.50878170 and No. 10672128)
文摘The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites(CFGCC) with carbon fiber content(1% by the weight of cement),graphite powder contents (0%-50% by the weight of cement) and CCCW(cementitious capillary crystalline waterproofing materials,4% by the weight of cement) were studied.The experimental results showed that the relationship between the resistivity of CFGCC and the concentration of graphite powders had typical features of percolation phenomena.The percolation threshold was about 20%.A clear piezoresistive effect was observed in CFGCC with 1wt% of carbon fibers,20wt% or 30wt% of graphite powders under uniaxial compressive tests,indicating that this type of smart composites was a promising candidate for strain sensing.The measured gage factor (defined as the fractional change in resistance per unit strain) of CFGCC with graphite content of 20wt% and 30wt% were 37 and 22,respectively.With the addition of CCCW,the mechanical properties of CFGCC were improved,which benefited CFGCC piezoresistivity of stability.
基金supported by the National Natural Science Foundation of China(U1407110)Anhui Province Key Research and Development Plan(JZ2018AKKG0332)。
文摘2-D nanosheet Cu2O doped CuO coating poly m-phenylenediamine and melamine/graphene/carbon fibers composite(CuxO/MPM/GFs)was firstly fabricated by compound electrochemical method.CuxO/MPM/GFs was successfully used to the recovery of iodide(I-)from salt water by lower potential-aided sorption and desorption processes.The potential-aided recovery of I-at CuxO/MPM/GFs was characterized by FE-SEM,XRD,IR,Raman,XPS,UV-vis and electrochemical techniques in detail.The maximal adsorption capacity of 86.82 mg·g^-1 could be obtained with a pseudo-second-order model at 0.8 V for 210 min in pH 5.0,0.1 mol·L^-1 NaCl,and the process accompanied the generation of CuI,CuO and I5-.The I-could be quickly desorbed from the electrode with a transfer of CuI to Cu2O by cycle voltammetry from-1.0 to 0.5 V for 90 cycles in pH 9.0,0.1 mol·L^-1 KNO3.Thus,CuxO/MPM/GFs was renewable in the continuous electrochemical-adsorption-desorption processes.
基金The authors acknowledge the National Council for Scientific and Technological Development(CNPq),Coordenacao de Aperfeiçoamento de Pessoal de Nivel Superior-Brasil(CAPES)-Finance Code 001Fundacao de AmparoàPesquisa do Estado do Rio de Janeiro(FAPERJ),Brazil.
文摘Natural fiber reinforced polymer composites(NFRCs)have demonstrated great potential for many different applications in various industries due to their advantages compared to synthetic fiber-reinforced composites,such as low environmental impact and low cost.However,one of the drawbacks is that the NFRCs present relatively low mechanical properties and the absorption of humidity due to the hydrophilic characteristic of the natural fibre.One method to increase their performance is hybridization.Therefore,understanding the properties and potential of using multiple reinforcement’s materials to develop hybrid composites is of great interest.This paper provides an overview of the recent advances in hybrid natural fiber reinforced polymer composites.First,the main factors that affect the performance of hybrid fiber-reinforced composites were briefly discussed.The effect of hybridization on the mechanical and thermal properties of hybrid composites reinforced with several types of natural fibers(i.e.,sisal,jute,curauá,ramie,banana,etc.)or natural fibers combined with synthetic fibers is pre-sented.Finally,the water absorption behaviour of hybrid fiber-reinforced composites is also discussed.It was con-cluded that the main challenges that need to be addressed in order to increase the use of natural-natural or natural-synthetic hybrid composites in industry are the poor adhesion between natural fibers and matrix,thermal stability and moisture absorption of natural fibers.Some of these challenges were addressed by recent develop-ment in fibers treatment and modification,and product innovation(hybridization).
基金supported by the National Science Foundation of China(No.51571033)supported in part by the National Natural Science Foundation of China under Grant No.11521062。
文摘The woven basalt fiber composites(WBFC) and the unidirectional [0°/90°/45°/-45°]s basalt fiber composites(UBFC) were prepared by hot-pressing.Three-point bending test,low velocity impact test,and ballistic test were performed to the prepared composites.After the tests,the specimens were recovered and analyzed for micromorphology.Three-point bending tests show that both the bending strength and stiffness of the WBFC surpass those of the UBFC.Low velocity impact test results show that the low velocity impact resistance to hemispherical impactor of the UBFC is higher than that of the WBFC,but the low velocity impact resistance to sharp impactor of the UBFC is lower than that of the WBFC.For the ballistic test,it can be found that the ballistic property of the UBFC is higher than that of the WBFC. After the tests,microscopic analysis of the specimens was applied,and their failure mechanism was discussed.The main failure modes of the UBFC are delamination and fibers breakage under the above loading conditions while the main failure mode of the WBFC is fibers breakage.Although delamination damage can be found in the WBFC under the above loading conditions,the degree of delamination is far less than that of the UBFC.
基金Supported by Commission of Science Technology and Industry for National Defense of China(No.JPPT-115-477).
文摘To determinate the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints, energy dispersive X-ray spectroscopy analysis(EDX) is used to establish the content change of oxy- gen in the adhesive in adhesive/carbon fther reinforced epoxy resin composite joints. As water is made up of oxygen and hydrogen, the water diffusion coefficients and dynamics in adhesive/carben fiber reinforced epoxy resin composite joints can be obtained from the change in the content of oxygen in the adhesive during humidity aging, via EDX analy-sis. The authors have calculated the water diffusion coefficients and dynamics in the adhesive/carbon fiber reinforced epoxy resin composite joints with the aid of beth energy dispersive X-ray spectroscopy and elemental analysis. The de- termined results with EDX analysis are almost the same as those determined with elemental analysis and the results al- so show that the durability of the adhesive/carbon fther reinforced epoxy resin composite joints subjected to silane cou- pling agent treatment is better than those subjected to sand paper burnishing treatment and chemical oxidation treat- ment.
文摘Equilibrium paths of post-buckling are measured for large slenderness column specimensmade of the fiber reinforced composite material. The influence of the initial curvature is investigatedexperimentally and compared with the result of the initial post-buckling theory. Both the theoreticaland experimental results reveal that the column with the initial curvature has stable post-buckling be-haviors and is not sensitive to the imperfection in the form of initial curvature. The experimental re-sults show that when the lateral buckling displacement is less than 20 percent of the column length, theexperimental results agree with the results from the theory of initial post-buckling quite well, whilethey agree with the results from the large deflection theory in a quite large range.
基金Funded by the National Key Research and Development Program of China (No. 2019YFE0112600)the Science and Technology Innovation Action Plan of Shanghai of China (No. 19DZ1204900)the Fundamental Research Funds for the Central Universities (Nos. 22120180087 and 2020QNA4018)。
文摘The 21 dog-bone specimens with different fiber contents and fiber distribution (random chopped fiber or directional continuous filament fiber bundles) were designed and tested under uniaxial tension using domestic PVA (polyvinyl alcohol) fiber.High fiber content exerted positive influences on cracking stress,peak stress and deformation capacity of specimens with random chopped fiber,compared with the decrease shown in cracking stress of specimens containing directional fiber bundles.There were multiple cracks in specimens containing directional fiber bundles,while only 1-2 typical cracks could be shown in chopped fiber specimens after being broken.Random chopped fiber connected more closely with matrix compared with that only part of fiber bundles could contact with matrix.Double-fold line model and parabolic model could be used simultaneously to fit well with the uniaxial tension constitutive relations of engineered cementitious composite (ECC).Although the performance of PVA produced in China can not reach to the same level of those from Japan,there exists certain practical value in engineering according to its contribution to deformability of structure.
文摘The in vitro degradation characteristic of the poly D, L-lactic acid ( PDLIA )/ hydroxyapatite ( HA ) compound were investigated. The compoundfibers were immersed in static phosphate buffer at 37℃ to degrade for 22 weeks. The changes in pH value of the buffer solution, the mechanical strength and morphological of inside and outside of composite fibers with degrurlation characteristic were observed. Results show that pH value of the buffer solution stabilized to aboat 7.0 before 12 weeks, however after 20 weeks that pH value quick declined. After 7 weeks that composite fibers of mechanical strength cannot mensuration. SEM observation revealed ttua bimodal degradation occurred in composite fibers.
文摘In the present scenario, there has been a rapid attention in research and development in the natural fiber composite field due to its better formability, abundant, renewable, cost-effective and eco-friendly features. This paper exhibits an outline on natural fibers and its composites utilized as a part of different commercial and engineering applications. In this review, many articles were related to applications of natural fiber reinforced polymer composites. It helps to provide details about the potential use of natural fibers and its composite materials, mechanical and physical properties and some of their applications in engineering sectors.