Laser-induced periodic surface structured electrodes with 45% energy saving in electrochemical fuel generation through field localization

Electrochemical oxidation/reduction of radicals is a green and environmentally friendly approach to generating fuels.These reactions,however,suffer from sluggish kinetics due to a low local concentration of radicals around the electrocatalyst.A large applied electrode potential can enhance the fuel generation efficiency via enhancing the radical concentration around the electrocatalyst sites,but this comes at the cost of electricity.Here,we report about a~45%saving in energy to achieve an electrochemical hydrogen generation rate of 3×10^(16) molecules cm^(–2)s^(–1)(current density:10 mA/cm^(2))through localized electric field-induced enhancement in the reagent concentration(LEFIRC)at laser-induced periodic surface structured(LIPSS)electrodes.The finite element model is used to simulate the spatial distribution of the electric field to understand the effects of LIPSS geometric parameters in field localization.When the LIPSS patterned electrodes are used as substrates to support Pt/C and RuO_(2) electrocatalysts,the η_(10) overpotentials for HER and OER are decreased by 40.4 and 25%,respectively.Moreover,the capability of the LIPSS-patterned electrodes to operate at significantly reduced energy is also demonstrated in a range of electrolytes,including alkaline,acidic,neutral,and seawater.Importantly,when two LIPSS patterned electrodes were assembled as the anode and cathode into a cell,it requires 330 mVs of lower electric potential with enhanced stability over a similar cell made of pristine electrodes to drive a current density of 10 mA/cm^(2).This work demonstrates a physical and versatile approach of electrode surface patterning to boost electrocatalytic fuel generation performance and can be applied to any metal and semiconductor catalysts for a range of electrochemical reactions.

Strong field ionization of molecules on the surface of nanosystems

Besides the diverse investigations on the interactions between intense laser fields and molecular systems,extensive research has been recently dedicated to exploring the response of nanosystems excited by well-tailored femtosecond laser fields.Due to the fact that nanostructures hold peculiar effects when illuminated by laser pulses,the underlying mechanisms and the corresponding potential applications can make significant improvements in both fundamental research and development of novel techniques.In this review,we provide a summarization of the strong field ionization occurring on the surface of nanosystems.The molecules attached to the nanoparticle surface perform as the precursor in the ionization and excitation of the whole nanosystem,the fundamental processes of which are yet to be discovered.We discuss the influence on nanoparticle constituents,geometric shapes and sizes,as well as the specific waveforms of the excitation laser fields.The intriguing characteristics observed in surface ion emission reflect how enhanced near field affects the localized ionizations and nanoplasma expansions,thereby paving the way for further precision controls on the light-and-matter interactions in the extreme spatial temporal levels.

Tailoring of electromagnetic field localizations by twodimensional graphene nanostructures

Graphene has great potential for enhancing light−matter interactions in a two-dimensional regime due to surface plasmons with low loss and strong light confinement.Further utilization of graphene in nanophotonics relies on the precise control of light localization properties.Here,we demonstrate the tailoring of electromagnetic field localizations in the mid-infrared region by precisely shaping the graphene into nanostructures with different geometries.We generalize the phenomenological cavity model and employ nanoimaging techniques to quantitatively calculate and experimentally visualize the two-dimensional electromagnetic field distributions within the nanostructures,which indicate that the electromagnetic field can be shaped into specific patterns depending on the shapes and sizes of the nanostructures.Furthermore,we show that the light localization performance can be further improved by reducing the sizes of the nanostructures,where a lateral confinement of λ0/180 of the incidence light can be achieved.The electromagnetic field localizations within a nanostructure with a specific geometry can also be modulated by chemical doping.Our strategies can,in principle,be generalized to other two-dimensional materials,therefore providing new degrees of freedom for designing nanophotonic components capable of tailoring two-dimensional light confinement over a broad wavelength range.

Source-Space Compressive Matched Field Processing for Source Localization

Source localization by matched-field processing （MFP） can be accelerated by building a database of Green＇s functions which however requires a bulk-storage memory. According to the sparsity of the source locations in the search grids of MFP, compressed sensing inspires an approach to reduce the database by introducing a sensing matrix to compress the database. Compressed sensing is further used to estimate the source locations with higher resolution by solving the β -norm optimization problem of the compressed Green＇s function and the data received by a vertieal/horizontal line array. The method is validated by simulation and is verified with the experimental data.

Localization of Vector Field on Pure Geometrical Thick Brane

We investigate the localization of a five-dimensional vector field on a pure geometrical thick brahe. By introducing two types of interactions between the vector field and the background scalar field, we obtain a typical volcano potential for the first type of coupling and a Posehl-Teller potential for the second one. These two types of couplings guarantee that the vector zero mode can be localized on the pure geometrical thick brahe under certain conditions.

Cortico-striatal gamma oscillations are modulated by dopamine D3 receptors in dyskinetic rats

Long-term levodopa administration can lead to the development of levodopa-induced dyskinesia.Gamma oscillations are a widely recognized hallmark of abnormal neural electrical activity in levodopa-induced dyskinesia.Currently,studies have reported increased oscillation power in cases of levodopa-induced dyskinesia.However,little is known about how the other electrophysiological parameters of gamma oscillations are altered in levodopa-induced dyskinesia.Furthermore,the role of the dopamine D3 receptor,which is implicated in levodopa-induced dyskinesia,in movement disorder-related changes in neural oscillations is unclear.We found that the cortico-striatal functional connectivity of beta oscillations was enhanced in a model of Parkinson’s disease.Furthermore,levodopa application enhanced cortical gamma oscillations in cortico-striatal projections and cortical gamma aperiodic components,as well as bidirectional primary motor cortex(M1)↔dorsolateral striatum gamma flow.Administration of PD128907(a selective dopamine D3 receptor agonist)induced dyskinesia and excessive gamma oscillations with a bidirectional M1↔dorsolateral striatum flow.However,administration of PG01037(a selective dopamine D3 receptor antagonist)attenuated dyskinesia,suppressed gamma oscillations and cortical gamma aperiodic components,and decreased gamma causality in the M1→dorsolateral striatum direction.These findings suggest that the dopamine D3 receptor plays a role in dyskinesia-related oscillatory activity,and that it has potential as a therapeutic target for levodopa-induced dyskinesia.

Ultrafast dynamics of femtosecond laser-induced high spatial frequency periodic structures on silicon surfaces

Femtosecond laser-induced periodic surface structures(LIPSS)have been extensively studied over the past few decades.In particular,the period and groove width of high-spatial-frequency LIPSS(HSFL)is much smaller than the diffraction limit,making it a useful method for efficient nanomanufacturing.However,compared with the low-spatial-frequency LIPSS(LSFL),the structure size of the HSFL is smaller,and it is more easily submerged.Therefore,the formation mechanism of HSFL is complex and has always been a research hotspot in this field.In this study,regular LSFL with a period of 760 nm was fabricated in advance on a silicon surface with two-beam interference using an 800 nm,50 fs femtosecond laser.The ultrafast dynamics of HSFL formation on the silicon surface of prefabricated LSFL under single femtosecond laser pulse irradiation were observed and analyzed for the first time using collinear pump-probe imaging method.In general,the evolution of the surface structure undergoes five sequential stages:the LSFL begins to split,becomes uniform HSFL,degenerates into an irregular LSFL,undergoes secondary splitting into a weakly uniform HSFL,and evolves into an irregular LSFL or is submerged.The results indicate that the local enhancement of the submerged nanocavity,or the nanoplasma,in the prefabricated LSFL ridge led to the splitting of the LSFL,and the thermodynamic effect drove the homogenization of the splitting LSFL,which evolved into HSFL.

Hippocampal ischemia causes deficits in local field potential and synaptic plasticity

The long-term enhancement in glutamate receptor mediated excitatory responses has been observed in stroke model. This pathological form of plasticity, termed post-ischemic long-term potentiation （i-LTP）, points to functional reorganization after stroke. Little is known, however, about whether and how this i-LTP would affect subsequent induction of synaptic plasticity. Here, we first directly confirmed that i-LTP was induced in the endothelin-l-induced ischemia model as in other in vitro models. We also demonstrated increased expression of NR2B, CaMKII and p-CaMKII, which are reminiscent of i-LTP. We further induced LTP of field excitatory post- synaptic potentials （fEPSPs） on CA1 hippocampal neurons in peri-infarct regions of the endothelin-l-induced mini-stroke model. We found that LTP of fEPSPs, induced by high-frequency stimulation, displayed a progressive impairment at 12 and 24 hours after ischemia. Moreover, using in vivo multi-channel recording, we found that the local field potential, which represents electrical property of cell ensembles in more restricted regions, was also dam- pened at these two time points. These results suggest that i-LTP elevates the induction threshold of subsequent synap- tic plasticity. Our data helps to deepen the knowledge of meta-synaptic regulation of plasticity after focal ischemia.

CALCULUS ON FRACTALS BASED UPON LOCAL FIELDS─In memory of Founding Editor Professor M.T.Cheng with great respect and deep sorrow

The main contents in this note are: 1. introduction; 2. locally compact groups and local fields; 3. calculus on fractals based upon local fields; 4. fractional calculus and fractals; 5. fractal function spaces and PDE on fractals.

Novel Biological Based Method for Robot Navigation and Localization

The capability and reliability are crucial characteristics of mobile robots while navigating in complex environments. These robots are expected to perform many useful tasks which can improve the quality of life greatly. Robot localization and decisionmaking are the most important cognitive processes during navigation. However, most of these algorithms are not efficient and are challenging tasks while robots navigate through complex environments. In this paper,we propose a biologically inspired method for robot decision-making, based on rat’s brain signals. Rodents accurately and rapidly navigate in complex spaces by localizing themselves in reference to the surrounding environmental landmarks. Firstly, we analyzed the rats’ strategies while navigating in the complex Y-maze, and recorded local field potentials(LFPs), simultaneously.The recorded LFPs were processed and different features were extracted which were used as the input in the artificial neural network(ANN) to predict the rat’s decision-making in each junction. The ANN performance was tested in a real robot and good performance is achieved. The implementation of our method on a real robot, demonstrates its abilities to imitate the rat’s decision-making and integrate the internal states with external sensors, in order to perform reliable navigation in complex maze.

Some New Inequalities for Wavelet Frames on Local Fields

Wavelet frames have gained considerable popularity during the past decade, primarily due to their substantiated applications in diverse and widespread fields of science and engineering. Finding general and verifiable conditions which imply that the wavelet systems are wavelet frames is among the core problems in time-frequency analysis. In this article, we establish some new inequalities for wavelet frames on local fields of positive characteristic by means of the Fourier transform. As an application, an improved version of the Li-Jiang inequality for wavelet frames on local fields is obtained.

Simultaneous low extinction and high local field enhancement in Ag nanocubes

We theoretically investigate surface plasmon resonance properties in Au and Ag cubic nanoparticles and find a novel plasmonic mode that exhibits simultaneous low extinction and high local field enhancement properties. We analyse this mode from different aspects by looking at the distribution patterns of local field intensity, energy flux, absorption and charge density. We find that in the mode the polarized charge is highly densified in a very limited volume around the corner of the nanocube and results in very strong local field enhancement. Perturbations of the incident energy flux and light absorption are also strongly localized in this small volume of the corner region, leading to both low absorption and low scattering cross section. As a result, the extinction is low for the mode. Metal nanoparticles involving such peculiar modes may be useful for constructing nonlinear compound materials with low linear absorption and high nonlinearity.

Effect of Lorentz local field correction on propagation of ultrashort laser pulse in one-dimensional para-nitroaniline (PNA) molecules

This paper investigates the effect of Lorentz local field correction （LFC） on the propagation of ultrashort laser pulses in a para-nitroaniline molecular medium under resonant and nonresonant conditions by solving numerically the full-wave Maxwell-Bloch equations beyond slowly-varying envelope approximation and rotating-wave approximation. The effect of the LFC is considerably obvious when pulses with large areas propagate in the dense molecular medium. In the case of resonance, the group velocity of the sub-pulses split from the incident pulse along propagation is severely decreased by the LFC, especially for the latest sub-pulse. However, in the case of nonresonance, the influence of the LFC on the temporal evolution of the pulse is less obvious and lacks homogeneity with an increase in incident pulse area, propagation distance and molecular density.

Construction Theory of Function on Local Fields

We establish the construction theory of function based upon a local field Kp as underlying space. By virture of the concept of pseudo-differential operator, we introduce ＂fractal calculus＂ （or, p-type calculus, or, Gibbs-Butzer calculus）. Then, show the Jackson direct approximation theorems, Bermstein inverse approximation theorems and the equivalent approximation theorems for compact group D（C Kp） and locally compact group Kp^＋-（= Kp）, so that the foundation of construction theory of function on local fields is established. Moreover, the Jackson type, Bernstein type, and equivalent approximation theorems on the HOlder-type space C^σ（Kp）, σ 〉0, are proved; then the equivalent approximation theorem on Sobolev-type space Wr（Kp）, σ≥0, 1≤r 〈∞, is shown.

Enhanced Photovoltaic Properties for Rear Passivated Crystalline Silicon Solar Cells by Fabricating Boron Doped Local Back Surface Field

In order to enhance the p-type doping concentration in the LBSF, boron was added into the aluminum paste and boron doped local back surface field（B-LBSF） was successfully fabricated in this work. Through boron doping in the LBSF, much higher doping concentration was observed for the B-LBSF over the Al-LBSF. Higher doping concentration in the LBSF is expected to lead to better rear passivation and lower rear contact resistance. Based on one thousand pieces of solar cells for each type, it was found that the rear passivated crystalline silicon solar cells with B-LBSF showed statistical improvement in their photovoltaic properties over those with Al-LBSF.

Fingerprint Matching Based on Local Relative Orientation Field

A fingerprint matching method based on local relative orientation field is proposed. It extracts local relative orientation field around each minutia for minutiae matching. Local orientation features are also used to sorting minutiae in order to speed up searching a minutia when pairing minutiae. The experimental result reveals that this method achieves improved recognition accuracy. Key words fingerprint matching - ridge-based minutiae matching - local relative orientation field - sorting minutiae CLC number TP 391 Foundation item: Supported by the National Natural Science Foundation of China (60373023)Biography: ZHU En (1976-), male, Ph. D candidate, research direction: pattern recognition, image processing and information security.

Electric field distribution and effective nonlinear AC and DC responses of graded cylindrical composites

The perturbation method is used to study the localization of electric field distribution and the effective nonlinear response of graded composites under an external alternating-current（AC） and direct-current（DC） electric field E app = E 0（1 ＋ sin ωt）.The dielectric profile of the cylindrical inclusions is modeled by function ε i（r） = C k r k（r ≤ a）,where r is the radius of the cylindrical inclusion,and C k,k,a are parameters.In the dilute limit,the local potentials and the effective nonlinear responses at all harmonics are derived.Meanwhile,the general effective nonlinear responses are also derived and compared with the effective nonlinear responses at harmonics under the AC and DC external field.It is found that the effective nonlinear AC and DC responses at harmonics can be calculated by those of the general effective nonlinear of the graded composites under the external DC electric field.Moreover,the obtained local electrical fields show that the electrical field distribution in the cylindrical inclusions is controllable,and the maximum of the electric field inside the cylinder is at its center.

ON RIESZ TYPE KERNELS OVER LOCAL FIELDS

Based on a representation lemma. Riesz type kernels on the local field K and on the integer ring O in K are coitstructed. Furthermore, we discuss approximation theorems for the Lipschitz class Lip(L ;α) ana the Lp boundedness of such operators motivated by the open problem: Does σηfa,s→f for f ∈L1(O) (see M. H. Taible-son [6] and [5])?

Effect of focused ultrasound stimulation at different ultrasonic power levels on the local field potential power spectrum

Local field potential(LFP) signals of the rat hippocampus were recorded under noninvasive focused ultrasound stimulation(FUS) with different ultrasonic powers. The LFP mean absolute power was calculated with the Welch algorithm at the delta, theta, alpha, beta, and gamma frequency bands. The experimental results demonstrate that the LFP mean absolute power at different frequency bands increases as the ultrasound power increases.

LOCAL HARDY SPACES ON HEISENBERG GROUP OVER LOCAL FIELDS

Let G be a Heisenberg group over local field K. In the paper we give some local maximal functions which define the Hardy spaces h(P)(G) equivalently, obtain the atomic decomposition of local Hardy spaces. We also give some bounded convolution operators h(P)(G), from which we can characterize h(P)(G) by sqare functions.