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High-Order Spatial FDTD Solver of Maxwell’s Equations for Terahertz Radiation Production
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作者 Abdelrahman Mahdy 《Journal of Applied Mathematics and Physics》 2024年第4期1028-1042,共15页
We applied a spatial high-order finite-difference-time-domain (HO-FDTD) scheme to solve 2D Maxwell’s equations in order to develop a fluid model employed to study the production of terahertz radiation by the filament... We applied a spatial high-order finite-difference-time-domain (HO-FDTD) scheme to solve 2D Maxwell’s equations in order to develop a fluid model employed to study the production of terahertz radiation by the filamentation of two femtosecond lasers in air plasma. We examined the performance of the applied scheme, in this context, we implemented the developed model to study selected phenomena in terahertz radiation production, such as the excitation energy and conversion efficiency of the produced THz radiation, in addition to the influence of the pulse chirping on properties of the produced radiation. The obtained numerical results have clarified that the applied HO-FDTD scheme is precisely accurate to solve Maxwell’s equations and sufficiently valid to study the production of terahertz radiation by the filamentation of two femtosecond lasers in air plasma. 展开更多
关键词 The Finite-Difference-Time-Domain Terahertz Radiation production Filamentation of Femtosecond Laser Maxwell’s Equations solution
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The “productivity paradox” of Chinese export firms: Review and assessment 被引量:4
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作者 李春顶 尹翔硕 《China Economist》 2010年第2期74-82,共9页
This paper represents an attempt to test the relationship between the exports and productivity of Chinese firms using the data set of nearly 3 million industrial firms in 20 industrial sectors over the period 1998-200... This paper represents an attempt to test the relationship between the exports and productivity of Chinese firms using the data set of nearly 3 million industrial firms in 20 industrial sectors over the period 1998-2007. Our test finds that non-export firms were more productive than export firms, and exports were negatively related to productivity-namely that the lower the productivity of a firm, the higher its exports. This finding is in contradiction with the hypothesis of new-new trade theory. The contradiction is referred to as the "productivity paradox" in this paper. Further tests find that firm size is a key factor affecting firm exports, but the impact of exports on firm productivity is insignif icant. This paper reckons that the "productivity paradox" of Chinese export firms may be attributed to the disproportionate share of processing trade in export trade. 展开更多
关键词 New-new TRADE theory firm HETEROGENEITY productivity EXPORT TRADE
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A comparative analysis of Japanese firm productivity: Solow residual and Malmquist productivity index
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作者 Masaru Ichihashi Hidemichi Fujii 《Chinese Business Review》 2009年第6期26-36,共11页
关键词 全要素生产率 生产力指数 日本企业 剩余 微观经济学 MPI 相互独立 增长模式
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基于S-O-R模型的视觉营销对消费者购买意愿的影响研究——以红色文创网店为例
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作者 魏加兴 张婷婷 《市场周刊》 2024年第1期76-80,共5页
为提高红色文创网店的点击转化率,文章从消费者视角出发,研究影响消费者购买意愿的视觉因素。基于S-O-R模型理论,构建红色文创网店视觉营销对消费者购买意愿因素的理论模型。利用S-O-R模型分析了红色文创网店视觉营销中的商品形象、界... 为提高红色文创网店的点击转化率,文章从消费者视角出发,研究影响消费者购买意愿的视觉因素。基于S-O-R模型理论,构建红色文创网店视觉营销对消费者购买意愿因素的理论模型。利用S-O-R模型分析了红色文创网店视觉营销中的商品形象、界面形象以及品牌视觉形象对顾客感知价值及顾客购买意向的影响。通过设计量表和调查问卷进行实证研究,并结合结构方程模型加以论证,得出品牌视觉形象和界面形象是影响消费者购买意愿的关键因素,为设计师和红色文创品牌进行网店设计提供了一定的理论参考和建议。 展开更多
关键词 s-O-R模型 消费者购买意愿 红色文创产品 视觉营销
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Genetic and epigenetic targets of natural dietary compounds as anti-Alzheimer's agents 被引量:1
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作者 Willian Orlando Castillo-Ordoñez Nohelia Cajas-Salazar Mayra Alejandra Velasco-Reyes 《Neural Regeneration Research》 SCIE CAS CSCD 2024年第4期846-854,共9页
Alzheimer’s disease is a progressive neurodegenerative disorder and the most common cause of dementia that principally affects older adults.Pathogenic factors,such as oxidative stress,an increase in acetylcholinester... Alzheimer’s disease is a progressive neurodegenerative disorder and the most common cause of dementia that principally affects older adults.Pathogenic factors,such as oxidative stress,an increase in acetylcholinesterase activity,mitochondrial dysfunction,genotoxicity,and neuroinflammation are present in this syndrome,which leads to neurodegeneration.Neurodegenerative pathologies such as Alzheimer’s disease are considered late-onset diseases caused by the complex combination of genetic,epigenetic,and environmental factors.There are two main types of Alzheimer’s disease,known as familial Alzheimer’s disease(onset<65 years)and late-onset or sporadic Alzheimer’s disease(onset≥65 years).Patients with familial Alzheimer’s disease inherit the disease due to rare mutations on the amyloid precursor protein(APP),presenilin 1 and 2(PSEN1 and PSEN2)genes in an autosomaldominantly fashion with closely 100%penetrance.In contrast,a different picture seems to emerge for sporadic Alzheimer’s disease,which exhibits numerous non-Mendelian anomalies suggesting an epigenetic component in its etiology.Importantly,the fundamental pathophysiological mechanisms driving Alzheimer’s disease are interfaced with epigenetic dysregulation.However,the dynamic nature of epigenetics seems to open up new avenues and hope in regenerative neurogenesis to improve brain repair in Alzheimer’s disease or following injury or stroke in humans.In recent years,there has been an increase in interest in using natural products for the treatment of neurodegenerative illnesses such as Alzheimer’s disease.Through epigenetic mechanisms,such as DNA methylation,non-coding RNAs,histone modification,and chromatin conformation regulation,natural compounds appear to exert neuroprotective effects.While we do not purport to cover every in this work,we do attempt to illustrate how various phytochemical compounds regulate the epigenetic effects of a few Alzheimer’s disease-related genes. 展开更多
关键词 Alzheimer’s disease EPIGENETICs genes METHYLATION natural products
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水泵水轮机S特性区能量损失及流动特性研究
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作者 王李科 姚亮 +3 位作者 冯建军 朱国俊 卢金玲 阮辉 《水利学报》 EI CSCD 北大核心 2024年第3期344-354,366,共12页
为了调节电网的稳定性,抽水蓄能电站需要频繁启停和变换工况运行,导致水泵水轮机容易进入S特性区,机组振动增加,并网失败。本文以模型水泵水轮机为研究对象,采用熵产理论详细分析了S特性区不同工况下的能量损失规律,明确了熵产率分布与... 为了调节电网的稳定性,抽水蓄能电站需要频繁启停和变换工况运行,导致水泵水轮机容易进入S特性区,机组振动增加,并网失败。本文以模型水泵水轮机为研究对象,采用熵产理论详细分析了S特性区不同工况下的能量损失规律,明确了熵产率分布与内部流动结构的关系。结果表明:S特性区内近飞逸工况总熵产最大,约为设计工况的5.1倍,脉动熵产占据的比例接近80%,随着流量的减小,转轮熵产占比逐渐降低,活动导叶和尾水管的熵产占比增加。小流量工况转轮进口靠近下环位置首先出现了明显的漩涡,导致了活动导叶出口和转轮进口的高熵产区,随着流量进一步减小,漩涡逐渐向上冠转移,并且切向速度增大,在转轮进口形成挡水环,阻碍水流进入转轮,在无叶区内出现了环状分布的高熵产区。反水泵工况,水流在低压边与逆时针旋转的叶片撞击,导致水流很难进入叶片内部,形成了大尺度的回流涡结构;双列叶栅内充满大量涡结构,导致活动导叶吸力面的熵产率增大,并且向固定导叶传播。 展开更多
关键词 水泵水轮机 s特性 熵产理论 回流涡
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CuMn_(2)O_(4)/石墨炔S型异质结上锚定氧化助催化剂促进曙红敏化光催化析氢
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作者 杨成 李鑫 +2 位作者 李梅 梁桂杰 靳治良 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第1期88-103,共16页
半导体光催化剂有效的电荷分离及利用是光催化制氢的关键.单一半导体催化剂由于光生电子-空穴对的快速复合导致低的光催化活性,构建异质结是提高光生电荷分离以及电子转移效率的有效方法.此外,助催化剂的引入同样能够促进光催化剂表面... 半导体光催化剂有效的电荷分离及利用是光催化制氢的关键.单一半导体催化剂由于光生电子-空穴对的快速复合导致低的光催化活性,构建异质结是提高光生电荷分离以及电子转移效率的有效方法.此外,助催化剂的引入同样能够促进光催化剂表面电子和空穴的分离,并且其协同效应可促使更多载流子流向相应的助催化剂位点而增强光催化性能.因此,同时构建异质结及合适的氧化位点成为解决光生电子-空穴对有效分离及利用的重要研究方向.本文报道了一种同时构建S型异质结和氧化位点促进CuMn_(2)O_(4)光生电子-空穴对有效分离及利用的可行性策略.虽然在制备CuMn_(2)O_(4)的过程中通过调控制备温度能够自身诱导生成具有氧化能力的Mn_(2)O_(3)来作为氧化位点,但是只存在氧化位点时不能很好地克服光生电子-空穴对的重组现象而导致光催化活性较低.基于此,本文巧妙地利用CuMn_(2)O_(4)自身诱导生成氧化位点的特性并引入石墨炔还原端而构建S型异质结,在氧化位点及S型异质结同时存在的情况下增强光生电子的有效转移.此外,在自身诱导生成氧化位点和S型异质结的协同作用下,促进了复合光催化剂中的光生电子和光生空穴精确定向迁移到相应的还原位点和氧化位点.傅里叶变换红外光谱和拉曼光谱证实成功制备了石墨炔.X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和高分辨透射电子显微镜(TEM)等结果表明,成功制备了600-CuMn_(2)O_(4)/GDY-40%(6-CG-40%)样品(600°C焙烧,石墨炔质量百分含量为40%).经过组分优化的复合光催化剂6-CG-40%的催化性能达到1586.54μmol g^(‒1)h^(‒1),是CuMn_(2)O_(4)(106.73μmol g^(‒1)h^(‒1))和石墨炔(70.57μmol g^(‒1)h^(‒1))产氢活性的13.86倍和21.48倍高.利用UV-vis光谱、电化学性能和接触角测试等分析6-CG-40%复合光催化剂产氢性能提升的原因,并通过密度泛函理论计算和相关实验表征验证Mn_(2)O_(3)作为氧化助催化剂的合理性.结果表明,原位诱导生成的Mn_(2)O_(3)氧化助催化剂和引入石墨炔构建的S型异质结有效抑制了光生电子-空穴对的复合,从而优化了光生载流子转移效率,最终增强了曙红敏化6-CG-40%光催化析氢性能.综上所述,在控制诱导因子原位生成Mn_(2)O_(4)氧化助催化剂的基础上引入石墨炔还原端构建了S型异质结,在助催化剂与异质结两者的协同作用下极大程度地改善了光生电子-空穴对的严重复合现象,这项工作为解决光催化制氢领域中制约光催化剂制氢能力的关键问题提供了可行性思路. 展开更多
关键词 石墨炔 氧化助催化剂 电荷分离 s型异质结 光催化制氢
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Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S S型异质结的构筑及其光解水产氢性能研究 被引量:2
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作者 于佳慧 姚欣彤 +4 位作者 苏萍 王仕凯 张大凤 葛博 蒲锡鹏 《聊城大学学报(自然科学版)》 2024年第1期52-61,共10页
采用超声辅助研磨煅烧法制备了Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S S型异质结光催化剂,通过X射线粉末衍射仪、扫描电子显微镜、X射线光电子能谱、固体紫外漫反射等测试技术表征了样品的物相、形貌、化学元素组成以及光吸收能力等物理... 采用超声辅助研磨煅烧法制备了Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S S型异质结光催化剂,通过X射线粉末衍射仪、扫描电子显微镜、X射线光电子能谱、固体紫外漫反射等测试技术表征了样品的物相、形貌、化学元素组成以及光吸收能力等物理化学性质。在可见光加近红外光照射下进行了光催化析氢性能测试,结果表明,Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S复合材料的光解水产氢性能均优于纯相的Mn_(0.3)Cd_(0.7)S和Cu_(3)Mo_(2)O_(9),其中Cu 3Mo 2O 9的质量分数为1%的Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S显示出最佳的产氢速率(1.554 mmol·h^(-1)·g^(-1)),是Mn 0.3 Cd_(0.7)S的5.5倍。且经过四次循环实验后仍保持较好的光催化活性。此外,根据电化学测试以及红外热成像结果提出了合理的机理,Cu 3Mo 2O 9的光热效应与S型异质结的协同作用是Cu_(3)Mo_(2)O_(9)/Mn_(0.3)Cd_(0.7)S光催化活性提高的关键。 展开更多
关键词 光解水产氢 s型异质结 Mn_(0.3)Cd_(0.7)s Cu_(3)Mo_(2)O_(9) 光热效应
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绿色信贷政策、ESG表现与高污染企业资本结构调整
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作者 董越 潘海英 《资源与产业》 2024年第1期75-85,共11页
绿色信贷政策作为结构性去杠杆的重要举措,对于高污染企业资本结构升级大有裨益。与此同时,ESG概念的提出明确了企业发展需着重考量环境(E)、社会(S)和公司治理(G)三方面的表现,即企业ESG表现也将作用于高污染企业资本结构调整。因此,... 绿色信贷政策作为结构性去杠杆的重要举措,对于高污染企业资本结构升级大有裨益。与此同时,ESG概念的提出明确了企业发展需着重考量环境(E)、社会(S)和公司治理(G)三方面的表现,即企业ESG表现也将作用于高污染企业资本结构调整。因此,论文以2011—2020年中国A股上市的高污染企业为研究样本,基于ESG表现视角,探究绿色信贷政策对高污染企业资本结构调整的作用效果。研究表明:1)绿色信贷政策显著促进高污染企业资本结构调整,区分企业负债水平后发现,相比于低负债企业,绿色信贷政策显著加快高负债污染企业的资本结构调整速度;2)绿色信贷政策会提升高污染企业的ESG表现,企业ESG表现会削弱绿色信贷政策对高污染企业资本结构调整的促进效果;3)在深入探讨企业融资约束和商业信用程度的异质性是否会影响绿色信贷政策的实施效果时,发现相较于面临弱融资约束和拥有高商业信用的企业,绿色信贷政策显著促进面临强融资约束和低商业信用的高污染企业调整资本结构。因此,探讨绿色信贷政策与高污染企业资本结构调整的关系对优化信贷资源配置、推动高污染企业绿色转型意义重大。 展开更多
关键词 绿色信贷政策 资本结构调整 企业EsG表现 高污染企业
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Changes in Rainfall and Temperature and Its Impact on Crop Production in Moyamba District, Southern Sierra Leone
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作者 Keiwoma Mark Yila Mathew Lamrana Siaffa Gboku +1 位作者 Mohamed Sahr Lebbie Lamin Ibrahim Kamara 《Atmospheric and Climate Sciences》 CAS 2023年第1期19-43,共25页
Rainfall and temperature are the important variables that are often used to trace climate variability and change. A Perception study and analysis of climatic data were conducted to assess the changes in rainfall and t... Rainfall and temperature are the important variables that are often used to trace climate variability and change. A Perception study and analysis of climatic data were conducted to assess the changes in rainfall and temperature and their impact on crop production in Moyamba district, Sierra Leone. For the perception study, 400 farmers were randomly selected from Farmer-Based Organizations (FBOs) in 4 chiefdoms and 30 Agricultural Extension Workers (AWEs) in the Moyamba district were purposely selected as respondents. Descriptive statistics and Kendall’s test of concordance was used to analyze the data collected from the farmers and AEWs. Data for the analysis of variability and trends of rainfall and temperature from 1991 to 2020 were obtained from the Sierra Leone Meteorological Agency and Njala University and grouped into monthly, seasonal and annual time series. Regression analyses were used to determine the statistical values and trend lines for the seasonal and annual time series data. The Mann-Kendall test and Sen’s Slope Estimator were used to analyze the significance and magnitude of the trends respectively. The results of both studies show evidence of climate change in the Moyamba district. A substantial number of farmers and AEWs perceived a decrease in the annual rainfall amount, length of the rainy season, a late start and end of the rainy season, an increase in the temperature during the day and night, and a shortened harmattan period over the last 30 years. Analysis of the meteorological data shows evidence of variability in the seasonal and annual distribution of rainfall and temperature, a decreasing and non-significant trend in the rainy season and annual rainfall and an increasing and significant trend in seasonal and annual temperature from 1991 to 2020. However, the observed changes in rainfall and temperature by the farmers and AEWs partially agree with the results of the analyzed meteorological data. The majority of the farmers perceived that;adverse weather conditions have negatively affected crop production in the district. Droughts, high temperatures, and irregular rainfall are the three major adverse weather events that farmers perceived to have contributed to a substantial loss in the yields of the major crops cultivated in the district. In response to the negative effects of adverse weather events, a substantial number of farmers take no action due to their lack of knowledge, technical or financial capacity to implement climate-sensitive agricultural (CSA) practices. Even though few farmers are practicing some CSA practices on their farms, there is an urgent need to build the capacity of farmers and AEWs to adapt to and mitigate the negative impacts of climate change. The most priority support needed by farmers is the provision of climate-resilient crop varieties whilst the AEWs need training on CSA practices. 展开更多
关键词 Climate Change RAINFALL Temperature Farmer’s Perception Crop productivity sierra Leone
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N,S-CQDs/Mn_(0.5)Cd_(0.5)S的制备及光催化产氢性能
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作者 杨沫寒 贾子璇 +1 位作者 袁晓 张旭红 《河北师范大学学报(自然科学版)》 CAS 2024年第2期141-149,共9页
采用水热法制备了氮、硫共掺杂碳量子点(N,S-CQDs),并用超声辅助法合成了N,S-CQDs修饰的Mn_(0.5)Cd_(0.5)S(MCS)复合光催化材料.研究表明,在模拟太阳光照射下,质量分数为1%的N,S-CQDs/MCS的光催化产氢速率显著提高,为34159.25μmol/(g&#... 采用水热法制备了氮、硫共掺杂碳量子点(N,S-CQDs),并用超声辅助法合成了N,S-CQDs修饰的Mn_(0.5)Cd_(0.5)S(MCS)复合光催化材料.研究表明,在模拟太阳光照射下,质量分数为1%的N,S-CQDs/MCS的光催化产氢速率显著提高,为34159.25μmol/(g·h),是MCS的1.63倍,是质量分数为1%的CQDs/MCS的1.14倍.此复合物光催化产氢性能的提高主要归因于N,S-CQDs优异的电子迁移能力以及MCS与N,S-CQDs之间的紧密接触. 展开更多
关键词 N s共掺杂碳量子点 Mn_(0.5)Cd_(0.5)s 光催化剂 产氢
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Products of Odd Numbers or Prime Number Can Generate the Three Members’ Families of Fermat Last Theorem and the Theorem Is Valid for Summation of Squares of More Than Two Natural Numbers
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作者 Susmita Pramanik Deepak Kumar Das Panchanan Pramanik 《Advances in Pure Mathematics》 2023年第10期635-641,共7页
Fermat’s last theorem, had the statement that there are no natural numbers A, B, and C such that A<sup>n</sup> + B<sup>n</sup> = C<sup>n</sup>, in which n is a natural number great... Fermat’s last theorem, had the statement that there are no natural numbers A, B, and C such that A<sup>n</sup> + B<sup>n</sup> = C<sup>n</sup>, in which n is a natural number greater than 2. We have shown that any product of two odd numbers can generate Fermat or Pythagoras triple (A, B, C) following n = 2 and also it is applicable A<sup>2</sup> + B<sup>2</sup> + C<sup>2</sup> + D<sup>2</sup> + so on =A<sub>n</sub><sup>2 </sup>where all are natural numbers. 展开更多
关键词 Fermat Last Theorem Generation of Fermat’s Numbers Extension of Fermat’s Expression Fermat’s Expression from products of Odd Numbers
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利用电荷分离调控S型异质结光催化氧化产物选择性
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作者 谷苗莉 杨祎 +3 位作者 程蓓 张留洋 肖鹏 陈涛 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第4期185-194,共10页
半导体光催化技术为太阳能的高效利用提供了巨大的潜力.尽管众多单一半导体材料,如TiO_(2),CdS,g-C_(3)N_(4)等,已被广泛制备并用于光催化反应,但在单一光催化剂中,光生电子和空穴常因强库仑引力作用而迅速复合,导致光催化效率较低,难... 半导体光催化技术为太阳能的高效利用提供了巨大的潜力.尽管众多单一半导体材料,如TiO_(2),CdS,g-C_(3)N_(4)等,已被广泛制备并用于光催化反应,但在单一光催化剂中,光生电子和空穴常因强库仑引力作用而迅速复合,导致光催化效率较低,难以实现大规模产业化应用.针对这一问题,开发S型异质结光催化剂成为提高催化效率的有效途径之一.该异质结不仅能实现氧化还原位点在空间上的有效分离,同时保持了较强的氧化还原能力.然而,目前关于空间分离对光催化氧化产物选择性的影响研究较少.因此,深入探究S型异质结光催化剂中空间分离对产物选择性的作用机制,对于优化光催化过程、提高产物选择性具有重要意义.本文构建了具有良好暴露活性位点的2D/2D层状BiOBr/ZnIn_(2)S_(4)S型异质结(BOB/ZIS).实验发现,在纯ZnIn_(2)S_(4)体系中,由于无法实现空间上的有效电荷分离,氧还原反应(ORR)生成的H_(2)O_(2)在光生空穴的作用下进一步转化为•OH(羟基自由基),其氧化能力超过了体系中的光生空穴,导致2,5-呋喃二甲醛被过度氧化为经济性不高的产物呋喃二甲酸.在BOB/ZIS异质结中,我们实现了光生电子-空穴的有效转移和丰富的活性中心利用.ZnIn_(2)S_(4)价带上的电子通过ORR持续生成H_(2)O_(2)(1.15 mmol∙L^(-1),5 h),而BiOBr导带上的空穴则将5-羟甲基糠醛(HMF)氧化为具有高经济价值的2,5-呋喃二甲醛(有机合成中有价值的中间体).这一结果证实了S型异质结中光生电子-空穴的有效空间分离能够同时促进H_(2)O_(2)的产生和HMF的选择性氧化为2,5-呋喃二甲醛.这一发现不仅揭示了S型异质结在光催化反应中的优势,还证实了其相对于传统牺牲剂的经济可行性.原位光照X射线光电子能谱、飞秒超快瞬态吸收光谱和密度泛函理论计算均证实,在BOB/ZIS界面之间构建了S型电荷转移机制,加速了光生电子-空穴对的转移动力学.此外,通过原位傅里叶变换红外光谱研究了催化剂表面HMF氧化过程中官能团的变化,不仅加深了对纯ZnIn_(2)S_(4)体系中HMF过度氧化现象的认识,还揭示了S型异质结在选择性氧化HMF和原位生成H_(2)O_(2)中的独特光催化机制.综上所述,本文构建了2D/2D层状BiOBr/ZnIn_(2)S_(4)S型异质结,不仅实现了光生电子-空穴的有效空间分离,还提高了产物选择性和光催化效率.本文通过深入研究S型异质结在光催化反应中的作用机制,为调控光催化产物提供了新的见解,并为有机合成相关反应中S型异质结的设计提供了借鉴. 展开更多
关键词 BiOBr/ZnIn_(2)s_(4) s型异质结 过氧化氢制备 5-羟甲基糠醛选择性转化 转化机理
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Ni-MOF/Zn_(0.5)Cd_(0.5)S合成及其光催化废水制氢研究
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作者 蒋灶 徐龙君 刘成伦 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第1期97-104,共8页
为了提升Zn_(0.5)Cd_(0.5)S的光催化产氢性能,采用水热法制备了Ni-MOF改性Zn_(0.5)Cd_(0.5)S复合光催化剂,通过XRD、SEM、TEM、XPS等分析方法对制备样品的结构及光电化学性能进行了表征,并研究了其光催化垃圾渗滤液混合页岩气返排废水... 为了提升Zn_(0.5)Cd_(0.5)S的光催化产氢性能,采用水热法制备了Ni-MOF改性Zn_(0.5)Cd_(0.5)S复合光催化剂,通过XRD、SEM、TEM、XPS等分析方法对制备样品的结构及光电化学性能进行了表征,并研究了其光催化垃圾渗滤液混合页岩气返排废水制氢的可行性及动力学特征。结果表明,Zn_(0.5)Cd_(0.5)S主要呈现为纳米颗粒状结构,Ni-MOF主要由长约为10 μm、宽约为9 μm的超薄方形片构成,当Ni-MOF与Zn_(0.5)Cd_(0.5)S复合时,Zn_(0.5)Cd_(0.5)S纳米颗粒沉积在Ni-MOF方形片的表面,粒径显著降低,减少了Zn_(0.5)Cd_(0.5)S纳米颗粒的团聚,光吸收范围出现了蓝移,但仍然具有优异的可见光响应能力。质量分数为15%的Ni-MOF/Zn_(0.5)Cd_(0.5)S在垃圾渗滤液混合页岩气返排废水中展现出最优的光催化产氢性能,模拟太阳光照射3 h产氢量达1887 μmol,产氢过程遵从零级反应动力学模型,产氢速率为685.9 μmol/h,约为Zn_(0.5)Cd_(0.5)S的5.7倍。 展开更多
关键词 Zn_(0.5)Cd_(0.5)s Ni-MOF 垃圾渗滤液 页岩气返排废水 光催化产氢
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A Study on the Activities During the Fuzzy Front End in New Product Development Projects of Korean ICT Firms
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作者 Heeja Yoon Jeonglim Yun +1 位作者 Akio Nagahira Shuichi Ishida 《Management Studies》 2019年第4期257-275,共19页
Although previous studies on Korean manufacturing firms have empirically analyzed the causal relationship between activities during the FFE(Fuzzy Front End)and success of NPD(New Product Development)of Korean manufact... Although previous studies on Korean manufacturing firms have empirically analyzed the causal relationship between activities during the FFE(Fuzzy Front End)and success of NPD(New Product Development)of Korean manufacturing firms,no study has concretely focused on Korean ICT(Information and Communications Technology)firms and their FFE activities.The main aim of this study is to identify the activities of these firms during their FFE and provide managerial insights into the other ICT firms.The authors conducted a survey(106 valid responses)that their FFE activities on new product development project managers in Korean ICT firms.The results showed that even though new product development managers of Korean ICT firms did not search for ideas systemically,they communicated with those departments/divisions that had frequent interaction with customers for idea assessment,with the active involvement of middle-or higher-level managers.They thoroughly established initial plans in the pre-development stages and seriously analyzed competitors’products and direct and indirect customer interactions in their market survey activities. 展开更多
关键词 KOREAN ICT firms new product development project MANAGER fuzzy front end activities
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Impact of Different Rates of Nitrogen Supplementation on Soil PhysicochemicalProperties and Microbial Diversity in Goji Berry
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作者 Xiaojie Liang Wei An +4 位作者 Yuekun Li Yajun Wang Xiaoya Qin Yanhong Cui Shuchai Su 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第3期467-486,共20页
Goji berry(Lycium barbarum L.)is substantially dependent on nitrogen fertilizer application,which can signifi-cantly enhance fruit yield and Goji berry industrial development in Ningxia,China.This study aimed to analyz... Goji berry(Lycium barbarum L.)is substantially dependent on nitrogen fertilizer application,which can signifi-cantly enhance fruit yield and Goji berry industrial development in Ningxia,China.This study aimed to analyze the functions of differential nitrogen application rates including low(N1),medium(N2),and high(N3)levels in soil microbial community structure(bacterial and fungal)at 2 diverse soil depths(0-20,20-40 cm)through high-throughput sequencing technology by targeting 16S RNA gene and ITS1&ITS2 regions.All the observed physicochemical parameters exhibited significant improvement(p<0.05)with increased levels of nitrogen and the highest values for most parameters were observed at N2.However,pH decreased(p<0.05)gradually.The alpha and beta diversity analyses for bacterial and fungal communities’metagenome displayed more similarities than differences among all groups.The top bacterial and fungal phyla and genera suggested no obvious(p>0.05)differences among three group treatments(N1,N2,and N3).Furthermore,the functional enrichment analysis demonstrated significant(p<0.05)enrichment of quorum sensing,cysteine and methionine metabolism,and transcriptional machinery for bacterial communities,while various saprotrophic functional roles for fungal communities.Conclusively,moderately reducing the use of N-supplemented fertilizers is conducive to increasing soil nitrogen utilization rate,which can contribute to sustainable agriculture practices through improved soil quality,and microbial community structure and functions. 展开更多
关键词 Goji berry production Ningxia China differential nitrogen supplementation rates 16s RNA gene and IT1&IT2 region sequencing soil physicochemical properties
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Productivity Growth in the Transportation Industries in the United States: An Application of the DEA Malmquist Productivity Index
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作者 Jaesung Choi David C. Roberts EunSu Lee 《American Journal of Operations Research》 2015年第1期1-20,共20页
This study reviews productivity growth in the five major transportation industries in the United States (airline, truck, rail, pipeline, and water) and the pooled transportation industry from 2004 to 2011. We measure ... This study reviews productivity growth in the five major transportation industries in the United States (airline, truck, rail, pipeline, and water) and the pooled transportation industry from 2004 to 2011. We measure the average productivity for these eight years by state in each transportation industry and the annual average productivity by transportation industry. The major findings are that the U.S. transportation industry shows strong and positive productivity growth except that in the years of the global financial crisis in 2007, 2008, and 2010, and among the five transportation industries, the rail and water sectors show the highest productivity growth in 2011. 展开更多
关键词 DEA MALMQUIsT productivity Index productivity Growth U.s. TRANsPORTATION Industry
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S-型MnCo_(2)S_(4)/g-C_(3)N_(4)异质结光催化产氢性能研究 被引量:2
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作者 孙涛 李晨曦 +2 位作者 鲍钰鹏 樊君 刘恩周 《物理化学学报》 SCIE CAS CSCD 北大核心 2023年第6期112-121,共10页
本文通过简单的水热法和热解法分别得到MnCo_(2)S_(4)和g-C_(3)N_(4)催化剂,之后采用溶剂蒸发法将MnCo_(2)S_(4)和g-C_(3)N_(4)纳米片结合构建获得无贵金属的S-型MnCo_(2)S_(4)/g-C_(3)N_(4)异质结。研究结果表明,优化后的复合材料具有... 本文通过简单的水热法和热解法分别得到MnCo_(2)S_(4)和g-C_(3)N_(4)催化剂,之后采用溶剂蒸发法将MnCo_(2)S_(4)和g-C_(3)N_(4)纳米片结合构建获得无贵金属的S-型MnCo_(2)S_(4)/g-C_(3)N_(4)异质结。研究结果表明,优化后的复合材料具有良好的光催化产氢活性,其产氢速率最高可到2979μmol·g^(-1)·h^(-1),分别为g-C_(3)N_(4)(113μmol·g^(-1)·h^(-1))和MnCo_(2)S_(4)(341μmol·g^(-1)·h^(-1))的26.4和8.7倍。这主要归因于形成的S-型异质结具有比单体更低的反应阻抗,更高的光电流和高效的电子-空穴分离能力,以及低的析氢过电势。本研究为开发稳定、高效的非贵金属产氢异质结催化剂提供了实验基础。 展开更多
关键词 MnCo_(2)s_(4) g-C_(3)N_(4) s-型异质结 光催化分解水
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NiMoO_(4)/ZnIn_(2)S_(4)S-scheme异质结的制备及光催化产氢性能增强机制 被引量:6
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作者 李艳 李卓 刘恩周 《聊城大学学报(自然科学版)》 2023年第2期1-10,共10页
首先通过水热法制备得到NiMoO_(4)·x H_(2)O前驱体,再经高温煅烧得到NiMoO_(4)纳米棒,最后通过超声混合及溶剂蒸干处理将NiMoO_(4)与ZnIn_(2)S_(4)复合构建了NiMoO_(4)/ZnIn_(2)S_(4)S-scheme异质结光催化剂。研究结果表明,NiMoO_... 首先通过水热法制备得到NiMoO_(4)·x H_(2)O前驱体,再经高温煅烧得到NiMoO_(4)纳米棒,最后通过超声混合及溶剂蒸干处理将NiMoO_(4)与ZnIn_(2)S_(4)复合构建了NiMoO_(4)/ZnIn_(2)S_(4)S-scheme异质结光催化剂。研究结果表明,NiMoO_(4)质量分数为10.7%时,复合材料(10.7-NiMoO_(4)/ZnIn_(2)S_(4))具有较好的载流子分离效率,较低的界面电荷转移阻力和较大的电化学活性面积。在300 W氙灯照射下,其产氢速率可达29.04 mmol·g^(-1)·h^(-1),约为单体ZnIn_(2)S_(4)(5.58 mmol·g^(-1)·h^(-1))的5.20倍。自由基捕获实验及能带结构分析表明,NiMoO_(4)和ZnIn_(2)S_(4)之间形成了S-scheme电荷转移机制,不仅促进了载流子的分离与迁移,而且保留了较强的氧化还原能力。此外,NiMoO_(4)的引入提高了异质结的电化学活性面积,以上因素协同提高了体系的光催化析氢性能。 展开更多
关键词 NiMoO_(4) ZnIn_(2)s_(4) s-scheme异质结 光催化产氢
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Identification of Behavior of Voluntary Traceability and Analysis of Its Determinants: A Case Study of Hog Slaughtering and Processing Firms in Zhejiang Province,China 被引量:2
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作者 ZHOU Jie-hong YAN Zhen LIU Qing-yu 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2013年第6期1112-1121,共10页
In recent years, the Chinese government has highlighted the importance of adopting hog safety/quality traceability, and a growing amount of research continues to entice firms to adopt traceability systems. In this stu... In recent years, the Chinese government has highlighted the importance of adopting hog safety/quality traceability, and a growing amount of research continues to entice firms to adopt traceability systems. In this study, a survey was conducted on a sample of pig slaughtering and processing firms in Zhejiang, China through personal interviews and emails. The aim of this study was to examine the determinants of firm behavior on the implementation of voluntary traceability systems with more stringent standards and controls than those of the mandatory system in China. The results revealed that motivation based on product quality improvement, capital ability and role perception (business type) had significantly positive relationships with a firm's voluntary traceability. Other incentives, such as operation improvement, recall risk reduction, reduced occurrence of safety issues, and technical strength were not found to be supportive in our study. This study provides an opportunity to better understand the determinants of firm behavior on voluntary traceability, particularly in light of the fact that some Chinese firms are facing the threat of criminal action for the use of illegal additives and the abuse of Clenbuterol. Policy recommendations on encouraging the implementation of pork safety voluntary traceability by hog slaughtering and processing firms are also discussed. 展开更多
关键词 voluntary traceable behavior product quality improvement capital ability role perception hog slaughtering and processing firm
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