An approach for full duty frequency-doubled triangle shape lightwave generation is proposed and demonstrated.It requires a dual-parallel Mach–Zehnder modulator(DP-MZM) driven by a sinusoidal signal. A stop band fil...An approach for full duty frequency-doubled triangle shape lightwave generation is proposed and demonstrated.It requires a dual-parallel Mach–Zehnder modulator(DP-MZM) driven by a sinusoidal signal. A stop band filter is coupled to filter out two undesired sidebands. By tuning the bias voltage applied to the DP-MZM, the output optical intensity with a full duty cycle triangle shape profile can be obtained. It is found that the required modulation index is no longer a fixed one. It can vary within a range, without degrading the target waveform. The principle is analyzed by theory and evaluated by simulation. A proof-of-concept experiment is also conducted.Good agreements between theoretical prediction and experimental results have been found. This approach might be attractive due to the feature of a variable modulation index, which insures simple operation in practice.展开更多
In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-h...In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ion-blocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity(RH)are superior to the devices encapsulated with polyisobutylene.The PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module(17.2%)encapsulated by PUA remains 92.6%within 1825 h.These results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead hazards.Moreover,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation.展开更多
A new generalized modular design (GMD) method is proposed based on designpractice of frame structure of hydraulic press machines. By building a series of flexible modules(FMs), design knowledge and structure features ...A new generalized modular design (GMD) method is proposed based on designpractice of frame structure of hydraulic press machines. By building a series of flexible modules(FMs), design knowledge and structure features are integrated into parametric models. Then,parametric design and variational analysis methods for GMD are presented according to user defineddesign objectives and customized product characteristics. A FM-centered GMD system is developed andsuccessfully used in the rapid design of relevant products.展开更多
We present a mechanically tunable broadband terahertz(THz) modulator based on the high-aligned Ni nanowire(NW)arrays. The modulator is a sandwich structure consisting of two polydimethylsiloxane layers and a central l...We present a mechanically tunable broadband terahertz(THz) modulator based on the high-aligned Ni nanowire(NW)arrays. The modulator is a sandwich structure consisting of two polydimethylsiloxane layers and a central layer of highaligned Ni NW arrays. Our experimental measurements reveal the transmittance of THz wave can be effectively modulated by mechanical stretching. The NW density in arrays increases with the strain increasing, which induced an enhancement in the absorption of THz wave. When the strain increases from 0 to 6.5%, a linear relationship is observed for the variation of modulation depth(MD) of THz wave regarding the strain, and the modulated range is from 0 to 85% in a frequency range from 0.3 THz to 1.8 THz. Moreover, the detectable MD is about 15% regarding the 1% strain change resolution. This flexible Ni NW-based modulator can be promised many applications, such as remote strain sensing, and wearable devices.展开更多
Efficient flexible perovskite solar cells and modules were developed using a combination of SnO2 and mesoporous-TiO2 as a fully solution-processed electron transport layer (ETL). Cells using such ETLs delivered a ma...Efficient flexible perovskite solar cells and modules were developed using a combination of SnO2 and mesoporous-TiO2 as a fully solution-processed electron transport layer (ETL). Cells using such ETLs delivered a maximum power conversion efficiency (PCE) of 14.8%, which was 30% higher than the PCE of cells with only SnO2 as the ETL. The presence of a mesoporous TiO2 scaffold layer over SnO2 led to higher rectification ratios, lower series resistances, and higher shunt resistances. The cells were also evaluated under 200 and 400 lx artificial indoor illumination and found to deliver maximum power densities of 9.77 μW/cm^2 (estimated PCE of 12.8%) and 19.2 μW/cm^2 (estimated PCE of 13.3%), respectively, representing the highest values among flexible photovoltaic technologies reported so far. Furthermore, for the first time, a fully laser-patterned flexible perovskite module was fabricated using a complete three-step laser scribing procedure (P1, P2, P3) with a PCE of 8.8% over an active area of 12 cm^2 under an illumination of 1 sun.展开更多
Organic semiconductors are inherently soft,making it possible to increase their mobilities by strains.Such a unique feature can be exploited directly in flexible electronics for improved device performance.The 2,7-dio...Organic semiconductors are inherently soft,making it possible to increase their mobilities by strains.Such a unique feature can be exploited directly in flexible electronics for improved device performance.The 2,7-dioctyl[1]benzothieno[3,2-b][1]-benzothiophene derivative,C8-BTBT is one of the best small-molecule hole transport materials.Here,we demonstrated its band structure modulation under strains by combining the non-equilibrium molecular dynamics simulations and first-principles calculations.We found that the C8-BTBT lattice undergoes a transition from monoclinic to triclinic crystal system at the temperature below 160 K.Both shear and uniaxial strains were applied to the low-temperature triclinic phase of C8-BTBT,and polymorphism was identified in the shear process.The band width enhancement is up to 8%under 2%of compressive strain along the x direction,and 14%under 4%of tensile strain along the y direction.The band structure modulation of C8-BTBT can be well related to its herringbone packing motifs,where the edge to face and edge to edge pairs constitute two-dimensional charge transport pathways and their electronic overlaps determine the band widths along the two directions respectively.These findings pave the way for utilizing strains towards improved performance of organic semiconductors on flexible substrates,for example,by bending the substrates.展开更多
基金supported in part by the National Natural Science Foundation of China under Grant No.61405007
文摘An approach for full duty frequency-doubled triangle shape lightwave generation is proposed and demonstrated.It requires a dual-parallel Mach–Zehnder modulator(DP-MZM) driven by a sinusoidal signal. A stop band filter is coupled to filter out two undesired sidebands. By tuning the bias voltage applied to the DP-MZM, the output optical intensity with a full duty cycle triangle shape profile can be obtained. It is found that the required modulation index is no longer a fixed one. It can vary within a range, without degrading the target waveform. The principle is analyzed by theory and evaluated by simulation. A proof-of-concept experiment is also conducted.Good agreements between theoretical prediction and experimental results have been found. This approach might be attractive due to the feature of a variable modulation index, which insures simple operation in practice.
基金financially supported by the China National Key Research and Development Plan Project(2019YFE0107200)the National Natural Science Foundation of China(52072284)+1 种基金Joint Funds of Natural Science Foundation of Hubei Province(2023cFD087)Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory(XHD2020-001)
文摘In this work,a modified polyurethane adhesive(PUA)was prepared to realize a convenient encapsulation strategy for lead sedimentation and attachable perovskite solar cells(A-PSCs).The modified PUA can completely self-heal within 45 min at room temperature with an efficient lead ion-blocking rate of 99.3%.The PUA film can be coated on a metal electrode with slight efficiency improvement from 23.96%to 24.15%.The thermal stability at 65℃and the humidity stability at 55%relative humidity(RH)are superior to the devices encapsulated with polyisobutylene.The PUA film has strong adhesion to the flexible substrate and the initial efficiency of the flexible perovskite module(17.2%)encapsulated by PUA remains 92.6%within 1825 h.These results suggest that PUA encapsulation is universal for rigid and flexible PSCs with enhanced stability and low lead hazards.Moreover,it was found that flexible PSCs can be well attached to various substrates with PUA,providing a facile route for the A-PSCs in various scenarios without additional encapsulation and installation.
文摘A new generalized modular design (GMD) method is proposed based on designpractice of frame structure of hydraulic press machines. By building a series of flexible modules(FMs), design knowledge and structure features are integrated into parametric models. Then,parametric design and variational analysis methods for GMD are presented according to user defineddesign objectives and customized product characteristics. A FM-centered GMD system is developed andsuccessfully used in the rapid design of relevant products.
基金Project supported by the National Natural Science Foundation of China (Grant No. 62075245)Xinjiang Uygur Autonomous Region University Scientific Research Foundation (Grant No. XJEDU2018I021)。
文摘We present a mechanically tunable broadband terahertz(THz) modulator based on the high-aligned Ni nanowire(NW)arrays. The modulator is a sandwich structure consisting of two polydimethylsiloxane layers and a central layer of highaligned Ni NW arrays. Our experimental measurements reveal the transmittance of THz wave can be effectively modulated by mechanical stretching. The NW density in arrays increases with the strain increasing, which induced an enhancement in the absorption of THz wave. When the strain increases from 0 to 6.5%, a linear relationship is observed for the variation of modulation depth(MD) of THz wave regarding the strain, and the modulated range is from 0 to 85% in a frequency range from 0.3 THz to 1.8 THz. Moreover, the detectable MD is about 15% regarding the 1% strain change resolution. This flexible Ni NW-based modulator can be promised many applications, such as remote strain sensing, and wearable devices.
文摘Efficient flexible perovskite solar cells and modules were developed using a combination of SnO2 and mesoporous-TiO2 as a fully solution-processed electron transport layer (ETL). Cells using such ETLs delivered a maximum power conversion efficiency (PCE) of 14.8%, which was 30% higher than the PCE of cells with only SnO2 as the ETL. The presence of a mesoporous TiO2 scaffold layer over SnO2 led to higher rectification ratios, lower series resistances, and higher shunt resistances. The cells were also evaluated under 200 and 400 lx artificial indoor illumination and found to deliver maximum power densities of 9.77 μW/cm^2 (estimated PCE of 12.8%) and 19.2 μW/cm^2 (estimated PCE of 13.3%), respectively, representing the highest values among flexible photovoltaic technologies reported so far. Furthermore, for the first time, a fully laser-patterned flexible perovskite module was fabricated using a complete three-step laser scribing procedure (P1, P2, P3) with a PCE of 8.8% over an active area of 12 cm^2 under an illumination of 1 sun.
基金supported by the National Natural Science Foundation of China(21273124,21290190,21290191 and 91333202)the Innovative Research Groups of the National Science Foundation of China(21421064)the National Basic Research Program of China(2013CB933503 and 2015CB655002)
文摘Organic semiconductors are inherently soft,making it possible to increase their mobilities by strains.Such a unique feature can be exploited directly in flexible electronics for improved device performance.The 2,7-dioctyl[1]benzothieno[3,2-b][1]-benzothiophene derivative,C8-BTBT is one of the best small-molecule hole transport materials.Here,we demonstrated its band structure modulation under strains by combining the non-equilibrium molecular dynamics simulations and first-principles calculations.We found that the C8-BTBT lattice undergoes a transition from monoclinic to triclinic crystal system at the temperature below 160 K.Both shear and uniaxial strains were applied to the low-temperature triclinic phase of C8-BTBT,and polymorphism was identified in the shear process.The band width enhancement is up to 8%under 2%of compressive strain along the x direction,and 14%under 4%of tensile strain along the y direction.The band structure modulation of C8-BTBT can be well related to its herringbone packing motifs,where the edge to face and edge to edge pairs constitute two-dimensional charge transport pathways and their electronic overlaps determine the band widths along the two directions respectively.These findings pave the way for utilizing strains towards improved performance of organic semiconductors on flexible substrates,for example,by bending the substrates.