Mass transfer enhancement and hydrodynamic performance with wire mesh coupling solid particles in bubble column reactor

It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer.

Synergistic coupling among Mg_(2)B_(2)O_(5),polycarbonate and N,Ndimethylformamide enhances the electrochemical performance of PVDF-HFP-based solid electrolyte

Polymer solid electrolytes(SPEs)based on the[solvate-Li+]complex structure have promising prospects in lithium metal batteries(LMBs)due to their unique ion transport mechanism.However,the solvation structure may compromise the mechanical performance and safety,hindering practical application of SPEs.In this work,a composite solid electrolyte(CSE)is designed through the organic-inorganic syner-gistic interaction among N,N-dimethylformamide(DMF),polycarbonate(PC),and Mg_(2)B_(2)O_(5) in poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP).Flame-retardant Mg_(2)B_(2)O_(5) nanowires provide non-flammability to the prepared CSEs,and the addition of PC improves the dispersion of Mg_(2)B_(2)O_(5) nanowires.Simultaneously,the organic-inorganic synergistic action of PC plasticizer and Mg_(2)B_(2)O_(5) nanowires pro-motes the dissociation degree of LiTFSI and reduces the crystallinity of PVDF-HFP,enabling rapid Li ion transport.Additionally,Raman spectroscopy and DFT calculations confirm the coordination between Mg atoms in Mg_(2)B_(2)O_(5) and N atoms in DMF,which exhibits Lewis base-like behavior attacking adjacent C-F and C-H bonds in PVDF-HFP while inducing dehydrofluorination of PVDF-HFP.Based on the syner-gistic coupling of Mg_(2)B_(2)O_(5),PC,and DMF in the PVDF-HFP matrix,the prepared CSE exhibits superior ion conductivity(9.78×10^(-4) s cm^(-1)).The assembled Li symmetric cells cycle stably for 3900 h at a current density of 0.1 mA cm^(-2) without short circuit.The LFP||Li cells assembled with PDL-Mg_(2)B_(2)O_(5)/PC CSEs show excellent rate capability and cycling performance,with a capacity retention of 83.3%after 1000 cycles at 0.5 C.This work provides a novel approach for the practical application of organic-inorganic Synergistic CSEs in LMBs.

Gas-solid coupling laws for deep high-gas coal seams

A better understanding of gas-solid coupling laws for deep, gassy coal seams is vital for preventing the compound dynamic disasters such as rock burst and gas outburst. In this paper, a gas-solid coupling theoretical model under the influence of ground stress, gas pressure, and mining depth is established and simulated by using COMSOL Multiphysics software. Research results indicate that under the influence of factors such as high ground stress and gas pressure, the mutual coupling interaction between coal and gas is much more significant, which leads to the emergence of new characteristics of gas compound dynamic disasters. Reducing the ground stress concentration in front of the working face can not only minimize the possibility of rock burst accidents, which are mainly caused by ground stress, but also can weaken the role of ground stress as a barrier to gas, thereby decreasing the number of outburst accidents whose dominant factor is gas. The results have a great theoretical and practical significance in terms of accident prevention, enhanced mine safety, disaster prevention system design, and improved accident emergency plans.

FLUID-SOLID COUPLING MATHEMATICAL MODEL OF CONTAMINANT TRANSPORT IN UNSATURATED ZONE AND ITS ASYMPTOTICAL SOLUTION

The process of contaminant transport is a problem of multicomponent and multiphase flow in unsaturated zone. Under the presupposition that gas existence affects water transport, a coupled mathematical model of contaminant transport in unsaturated zone has been established based on fluid_solid interaction mechanics theory. The asymptotical solutions to the nonlinear coupling mathematical model were accomplished by the perturbation and integral transformation method. The distribution law of pore pressure, pore water velocity and contaminant concentration in unsaturated zone has been presented under the conditions of with coupling and without coupling gas phase. An example problem was used to provide a quantitative verification and validation of the model. The asymptotical solution was compared with Faust model solution. The comparison results show reasonable agreement between asymptotical solution and Faust solution, and the gas effect and media deformation has a large impact on the contaminant transport. The theoretical basis is provided for forecasting contaminant transport and the determination of the relationship among pressure_saturation_permeability in laboratory.

Numerical Simulation and Experimental Study of Heat-fluid-solid Coupling of Double Flapper-nozzle Servo Valve

The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo valve would reach 120℃ and the valve core and valve sleeve deform in a short amount of time. So the control precision of servo valve significantly decreases and the clamping stagnation phenomenon of valve core appears. In order to solve the problem of degraded control accuracy and clamping stagnation of servo valve under large temperature difference circumstance, the numerical simulation of heat-fluid-solid coupling by using finite element method is done. The simulation result shows that zero position leakage of servo valve is basically impacted by oil temperature and change of fit clearance. The clamping stagnation is caused by warpage-deformation and fit clearance reduction of the valve core and valve sleeve. The distribution roles of the temperature and thermal-deformation of shell, valve core and valve sleeve and the pressure, velocity and temperature field of flow channel are also analyzed. Zero position leakage and electromagnet＇s current when valve core moves in full-stroke are tested using Electro-hydraulic Servo-valve Characteristic Test-bed of an aerospace sciences and technology corporation. The experimental results show that the change law of experimental current at different oil temperatures is roughly identical to simulation current. The current curve of the electromagnet is smooth when oil temperature is below 80℃, but the amplitude of current significantly increases and the hairy appears when oil temperature is above 80℃. The current becomes smooth again after the warped valve core and valve sleeve are reground. It indicates that clamping stagnation is caused by warpage-deformation and fit clearance reduction of valve core and valve sleeve. This paper simulates and tests the heat-fluid-solid coupling of double flapper-nozzle servo valve, and the obtained results provide the reference value for the design of double flapper-nozzle force feedback servo valve.

Fluid-solid coupling model for studying wellbore instability in drilling of gas hydrate bearing sediments

As the oil or gas exploration and development activities in deep and ultra- deep waters become more and more, encountering gas hydrate bearing sediments （HBS） is almost inevitable. The variation in temperature and pressure can destabilize gas hydrate in nearby formation around the borehole, which may reduce the strength of the formation and result in wellbore instability. A non-isothermal, transient, two-phase, and fluid-solid coupling mathematical model is proposed to simulate the complex stability performance of a wellbore drilled in HBS. In the model, the phase transition of hydrate dissociation, the heat exchange between drilling fluid and formation, the change of mechanical and petrophysical properties, the gas-water two-phase seepage, and its interaction with rock deformation are considered. A finite element simulator is developed, and the impact of drilling mud on wellbore instability in HBS is simulated. Results indicate that the re- duction in pressure and the increase in temperature of the drilling fluid can accelerate hydrate decomposition and lead to mechanical properties getting worse tremendously. The cohesion decreases by 25% when the hydrate totally dissociates in HBS. This easily causes the wellbore instability accordingly. In the first two hours after the formation is drilled, the regions of hydrate dissociation and wellbore instability extend quickly. Then, with the soaking time of drilling fluid increasing, the regions enlarge little. Choosing the low temperature drilling fluid and increasing the drilling mud pressure appropriately can benefit the wellbore stability of HBS. The established model turns out to be an efficient tool in numerical studies of the hydrate dissociation behavior and wellbore stability of HBS.

THE DOUBLE RESONANCES OF MAGNETISM AND SOLID COUPLING OF HYDROELECTRIC-GENERATOR STATOR SYSTEM

A double-shell model of hydroelectric-generator stator system was established. Applying the theory of mechano-electric analytical dynamics theory, the nonlinear vibration equation of magnetism and solid coupling of hydroelectric-generator stator system, under steadily balanced three-phases operating condition, was obtained. According to the method of multiple scales for nonlinear oscillations, the double resonances of magnetism and solid coupling of hydroelectric-generator stater system, were investigated. It is pointed out that the system has abundant dynamics phenomenon including the attendant jumps and coexistence of multiple stable motions.

RESEARCH ON SOLID-LIQUID COUPLING DYNAMICSOF PIPE CONVEYING FLUID

On the basis of Hamilton principle. the equation of sonlid-liquid coupling vibration of pipe conveying fluid is deduced. An asymmetrical sonlid-liquid coupling damp matrix and a symmetrical solid-liquid coupling Stiffness matrix are obtained. Using QR method , pipe’s nature frequencies are calculated. The curves of the first four orders of natural frequency-flow velocity of pipe waw given .The influence of flowing velocity ,pressure, solid-liquid coupling damp and solid-liquid coupling stiffness on natural frequency are discussed respectively.The dynamic respondence of the pipes for stepload with different flow velocity are calculated by Newmark method .It is found that,with the flow velocity increased, the nature frequency of the pipes reduced, increased,reduced again and so on.

Numerical Simulation of Bidirectional Flow and Solid Coupling of Single Pile and Single Row Pile Column and Wave

The three-dimensional model of the wave and pile structure was established by using Ansysworkbench software. The bidirectional fluid-structure interaction between the pile and wave was simulated by using Stokes wave theory and the Volume of Fluid Method. The pressure distribution diagram of the fluid-structure interface and the pile structure were observed and analyzed. The maximum equivalent stress on the pile was studied and its variation range was obtained. Compared with Von Mises yield criterion, it was concluded that the pile was stable under such wave conditions.

UNITIVE ANALYSIS SCHEMES ON PROBLEMS OF MULTIPLE MOVING BOUNDARIES WITH 3-D LIQUID-SOLID MULTIPLE NONLINEAR COUPLING FOR UPLIFT OF ANCHOREDLIQUID STORAGE TANKS

In the paper, 3-D analysis method with unitive schemes is set up, which is used to resolve the uplift with multiple moving boundaries and multiple nonlinear coupling for anchored liquid storage tanks. hi it, an algorithm of quasi-harmonious finite elements for arbitrary quadrilateral of thin plates and shells is built up to analyze the multiple coupling problems of general thin plates and shells structures with three dimensions, the complementary equations for analyzing uplifting moving boundary problems are deduced. The axial symmetry and presumption of beam type mode are not used. In it, an algorithm is put forward for analyzing the Navier-Stokes problems of unsteady, three-dimensional, and viscous liquid with sloshing of moving boundary surfaces in large amplitude under ALE frame by scheme of time-split-steps to which linear potential theory is not applied. The algorithms can be used to analyze the solid-liquid multiple nonlinear coupling problems with 3-D moving boundary with friction in multiple places.

Numerical solution to T-φ_S-C_L coupling in binary dendrite solidification with any solid-back diffusion effects

A previous numerical solution method to the strong nonlinear T φ S C L coupling for a Scheil type binary solidification process was extended and modified for single phase dendrite solidifications of any nominal alloy composition(in a composition range of single phase or eutectic solidification) and with any solid back diffusion extents. Numerical sample computations were performed on Al Cu system with different nominal compositions from almost pure Al to nearly eutectic and with different solid diffusion coefficients, which are factitiously enlarged or decreased in eight orders of magnitude. The calculation results exhibit the feasibility, capability and efficiency of the proposed numerical scheme in modeling an arbitrary binary dendrite solidification problem.

Analytical modelling of end thermal coupling in a solid-state laser longitudinally bonded by a vertical-cavity top-emitting laser diode

The intrinsic features involving a circularly symmetric beam profile with low divergence, planar geometry as well as the increasingly enhanced power of vertical-cavity surface-emitting lasers （VCSELs） have made the VCSEL a promising pump source in direct end bonding to a solid-state laser medium to form the minimized, on-wafer integrated laser system. This scheme will generate a surface contact pump configuration and thus additional end thermal coupling to the laser medium through the joint interface of both materials, apart from pump beam heating. This paper analytically models temperature distributions in both VCSEL and the laser medium from the end thermal coupling regarding surface contact pump configuration using a top-emitting VCSEL as the pump source for the first time. The analytical solutions are derived by introducing relative temperature and mean temperature expressions. The results show that the end contact heating by the VCSEL could lead to considerable temperature variations associated with thermal phase shift and thermal lensing in the laser medium. However, if the central temperature of the interface is increased by less than 20 K, the end contact heating does not have a significant thermal influence on the laser medium. In this case, the thermal effect should be dominated by pump beam heating. This work provides useful analytical results for further analysis of hybrid thermal effects on those lasers pumped by a direct VCSEL bond.

Emitting stability of poly(9,9-dialkylfluorene-co-N-butylcarbazole) by solid-state oxidative coupling polymerization

Dihexylfluorene and N-butylcarbazole were copolymerized by solid-state oxidative coupling polymerization in the presence of anhydrous FeCl3 at room temperature. The solid-state films of the copolymers emitted blue light after beating at 150 ℃ in air for 24 h, no red-shifted emission was observed by fluorescence spectroscopy.

A new numerical approach of coupled modeling for solid deformation and gas leak flow in multi-coal-seams

From the viewpoint of interaction mechanics for solid and gas, a coupled mathematical model was presented for solid coal/rock deformation and gas leak flow in parallel deformable coal seams. Numerical solutions using the SIP (Strong Implicit Proce- dure) method to the coupled mathematical model for double parallel coal seams were also developed in detail. Numerical simulations for the prediction of the safety range using protection layer mining were performed with experimental data from a mine with potential danger of coal/gas outbursts. Analyses show that the numerical simulation results are consistent with the measured data in situ.

Controlling Roll Temperature by Fluid-Solid Coupled Heat Transfer

Currently, when magnesium alloy sheet is rolled, the method of controlling roll temperature is simple and inaccurate. Furthermore, roll temperature has a large influence on the quality of magnesium alloy sheet; therefore, a new model using circular fluid flow control roll temperature has been designed. A fluid heat transfer structure was designed, the heat transfer process model of the fluid heating roll was simplified, and the finite di erence method was used to cal?culate the heat transfer process. Fluent software was used to simulate the fluid?solid coupling heat transfer, and both the trend and regularity of the temperature field in the heat transfer process were identified. The results show that the heating e ciency was much higher than traditional heating methods(when the fluid heat of the roll and tempera?ture distribution of the roll surface was more uniform). Moreover, there was a bigger temperature di erence between the input and the output, and after using reverse flow the temperature di erence decreased. The axial and circum?ferential temperature distributions along the sheet were uniform. Both theoretical calculation results and numerical simulation results of the heat transfer between fluid and roll were compared. The error was 1.8%–12.3%, showing that the theoretical model can both forecast and regulate the temperature of the roll(for magnesium alloy sheets) in the rolling process.

Solid state interfacial reactions in electrodeposited Cu/Sn couples

Cu/Sn couples, prepared by sequentially electroplating Cu and Sn layers on metallized Si wafers, were employed to study the microstructures, phases and the growth kinetics of Cu-Sn intermediate phases, when electroplated Cu/Sn couples were aged at room temperature or annealed at temperatures from 373 K to 498 K for various time. Only Cu6Sn5 formed in aged couples or couples annealed at temperature below 398 K. The Cu6Sn5 layer was continuous, but not uniform, with protrusions extending into the Sn matrix. When Cu/Sn couples were annealed at temperatures from 423 K to 498 K, two continuous and uniform Cn6Sn5/Cu3Sn layers formed within the reaction region between Sn and Cu. There were many voids near the Cu3Sn/Cu interface and within the Cu3Sn layer. Cu6Sn5 and Cu3Sn formations both follow parabolic growth kinetics with activation energies of 41.4 kJ/mol for Cu6Sn5 and 90.4 kJ/mol for Cu3Sn, respectively.

Flow Field and Temperature Field of Water-Cooling-Type Magnetic Coupling

At present, the water-cooling simulation of the water-cooled magnetic coupler is based on the water-cooled motor and the hydraulic coupler, which cannot accurately characterize the temperature distribution of the rotating watercooled coupling of the coupler. Focusing on rotating water cooling radiating, the present paper proposes simulating the water cooling temperature field as well as the flow field through the method of combining fluid-solid coupled heat transfer and MRF(Multiphase Reference Frame). In addition, taking an 800 kW magnetic coupling as an example, the paper optimizes the shape, number, cooling water inlet speed? and so on? of the cooling channel. Considering factors such as the complete machine’s temperature, and drag torque, it is proved that the cooling e ect is best when there are 36 involute curved channels and when the inlet speed is 3 m/s. Further, through experiments, the actual temperature values at six di erent positions when 50 kW and 70 kW thermal losses di er are measured. The measured values agree with the simulation results, proving the correctness of the proposed method. Further, data have been collected during the entire experimental procedure? and the variation in the coupling’s temperature is analyzed in depth, with the objective of laying a foundation for the estimation of the inner temperature rise as well as for the optimization of the structural design.

Stability analysis of unsaturated soil slope during rainfall infiltration using coupled liquid-gas-solid three-phase model

Generally, most soil slope failures are induced by rainfall infiltration, a process that involves interactions between the liquid phase, gas phase,and solid skeleton in an unsaturated soil slope. In this study, a loosely coupled liquid-gas-solid three-phase model, linking two numerical codes,TOUGH2/EOS3, which is used for water-air two-phase flow analysis, and FLAC^(3D), which is used for mechanical analysis, was established. The model was validated through a documented water drainage experiment over a sandy column and a comparison of the results with measured data and simulated results from other researchers. The proposed model was used to investigate the features of water-air two-phase flow and stress fields in an unsaturated soil slope during rainfall infiltration. The slope stability analysis was then performed based on the simulated water-air two-phase seepage and stress fields on a given slip surface. The results show that the safety factor for the given slip surface decreases first, then increases, and later decreases until the rainfall stops. Subsequently, a sudden rise occurs. After that, the safety factor decreases continually and reaches its lowest value, and then increases slowly to a steady value. The lowest value does not occur when the rainfall stops, indicating a delayed effect of the safety factor. The variations of the safety factor for the given slip surface are therefore caused by a combination of pore-air pressure, matric suction, normal stress, and net normal stress.

Development and validation of THM coupling model of methane-containing coal

Based on nine necessary basic assumptions for THM coupling model,this research comprehensively applied the theories of elastic mechanics,seepage mechanics and heat transfer,and established a real three-field and two-way coupled mathematical model to reveal the connections among seepage field,deformation field and temperature field within the system of methane-containing coal.In comparison between numerical and analytical solutions,the coupling modeling for THM of methane-containing coal was proved to be correct by model application in the physical simulation experiment of coal and gas outburst.The model established in this paper was the improvement of traditional seepage theory of methane-containing coal and fluid-solid coupled model theory,which can be widely used in prevention of coal and gas outburst as well as exploitation of coal bed methane.

COUPLED FIELDS OF TWO-DIMENSIONAL ANISOTROPIC MAGNETO-ELECTRO-ELASTIC SOLIDS WITH AN ELLIPTICAL INCLUSION

The two-dimensional elliptical inclusion problems in infinite anisotropic magnetoelectro-elastic solids are considered. Based on the extended Stroh formalism, the technique of conformal mapping and the concept of perturbation, the magneta-electro-elastic fields in both the matrix: and the inclusion are obtained explicitly. The results are of very importance for studying the effective properties of piezoelectric-piezomagnetic composite materials.