The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different s...The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different surface roughness.The effect of some factors on the surface roughness of flux film,such as reheating rate,cooling rate,flux film thickness and crystallization ratio,was discussed.展开更多
During continuous casting,properties of mold flux and mineralogical structures of flux film play important roles in controlling steel quality.The effect of soda ash on the physical properties and crystallization chara...During continuous casting,properties of mold flux and mineralogical structures of flux film play important roles in controlling steel quality.The effect of soda ash on the physical properties and crystallization characteristics of mold flux was investigated using process mineralogy,including polarizing microscopy,X-ray diffraction,and electron microprobe,etc.Mold flux was mainly prepared using cement clinker and industrial mineral materials under laboratory conditions,and the mineralogical structures of the flux film were systematically identified and quantitatively analyzed.The results showed that,by increasing the soda ash content from 10mass% to 18mass%,the crystallization temperature,critical cooling rate and crystallization ratio of the flux film decreased,but the crystallization ratio still reached 75% after adding soda ash,and the mineral compositions and microstructures of the flux film changed slightly.When the soda ash content exceeded 14mass%,the critical cooling rate and the crystallization ratio decreased slightly,whereas the mineral content of the flux film changed evidently,with a large amount of cuspidine precipitation and a significant decrease in the wollastonite content until it reached zero,which resulted in deterioration of the lubrication of the flux film.展开更多
The composition of the oxide film on the surface of Al-Li alloy was measured after accelerated oxidation at 500 and 540 ℃,and the reaction mechanism between CsF-AlF3 flux and the oxide film on the surface of Al-Li al...The composition of the oxide film on the surface of Al-Li alloy was measured after accelerated oxidation at 500 and 540 ℃,and the reaction mechanism between CsF-AlF3 flux and the oxide film on the surface of Al-Li alloy was also discussed.The results show that the oxide film on the surface of Al-Li alloy is mostly composed of Li2CO3 and amorphous Al2O3.The brazing technology for Al-Li alloy is accomplished using the improved CsF-AlF3 flux.The improved flux CsF-AlF3 can effectively remove the oxide film by the way of reacting and/or dissolving the oxide film,of which CsF compound plays an important role in the course of removing the oxide film.The key step is the generation of HF,which induces and accelerates the reaction of removing oxide film.The generation of H2O also accelerates the reaction.展开更多
The interaction of oxide film with molten flux during aluminum brazing has been studied by means of X-ray powder diffraction. The following conclusions have been deduced: The swell- ing of aluminum oxide film is cause...The interaction of oxide film with molten flux during aluminum brazing has been studied by means of X-ray powder diffraction. The following conclusions have been deduced: The swell- ing of aluminum oxide film is caused by Li^+ inserting into the vacancies of octahedral or tetrahedral structure of 0 atom skeleton in у-Al_2O_3 . The strength of oxide film decreases as the crytallinity increases by the treating of flux containing LiF.展开更多
YBa2Cu3O7-x（YBCO） films with co-doping BaTiO3（BTO） and Y2O3 nanostructures were prepared by metal organic deposition using trifluoroacetates（TFA-MOD）. The properties of the BTO/Y2O3co-doped YBCO films with diffe...YBa2Cu3O7-x（YBCO） films with co-doping BaTiO3（BTO） and Y2O3 nanostructures were prepared by metal organic deposition using trifluoroacetates（TFA-MOD）. The properties of the BTO/Y2O3co-doped YBCO films with different excess yttrium have been systematically studied by x-ray diffraction（XRD）, Raman spectra, and scanning electron microscope（SEM）. The optimized content of yttrium excess in the BTO/Y2O3co-doped YBCO films is 10 mol.%, and the critical current density is as high as - 17 mA/cm^2（self-field, 65 K） by the magnetic signal. In addition, the Y2Cu2O5 was formed when the content of yttrium excess increases to 24 mol.%, which may result in the deterioration of the superconducting properties and the microstructure. The unique combination of the different types of nanostructures of BTO and Y2O3 in the doped YBCO films, compared with the pure YBCO films and BTO doped YBCO films, enhances the critical current density（JC） not only at the self-magnetic field, but also in the applied magnetic field.展开更多
A square hole array is fabricated over a micro-bridge of NbN thin film by electron beam lithography and reactive ion milling. Magneto-resistance is measured across the micro-bridge filled with a hole array near the su...A square hole array is fabricated over a micro-bridge of NbN thin film by electron beam lithography and reactive ion milling. Magneto-resistance is measured across the micro-bridge filled with a hole array near the superconducting transition temperature. It is found that magneto-resistance minima occur when the number of vortices is an integer multiple or a fractional multiple of the number of holes. The temperature and the current dependences of the matching effect are studied.展开更多
In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the ...In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the optimized mold flux were compared in a comprehensive way by using analytical measures, such as a slag film heat-flow simulator, a thermowire molten flux crystallization tester and an X-ray diffractometer in the laboratory. The results reveal that one of the major reasons for the cracks is the poor heat transfer ability of the original mold flux. However, the optimized mold flux with a high basicity features a high crystallizing rate,low crystallization temperature and low heat-flow density. Therefore, the optimized mold flux is more suitable for casting peritectic steel by the heavy slab continuous caster. The test results show that the slabs produced by using the optimized mold flux had no surface longitudinal crack in four test casts, while the surface longitudinal crack ratio of the slabs produced by using the original mold flux was 5%. The optimized mold flux can effectively prevent slab surface longitudinal cracks from occurring.展开更多
By the statistical entropy of the Dirac field of the static spherically symmetric black hole, the result is obtained that the radiation energy flux of the black hole is proportional to the quartic of the temperature o...By the statistical entropy of the Dirac field of the static spherically symmetric black hole, the result is obtained that the radiation energy flux of the black hole is proportional to the quartic of the temperature of its event horizon. That is, the thermal radiation of the black hole always satisfies the generalised Stenfan-Boltzmann law. The derived generalised Stenfan-Boltzmann coefficient is no longer a constant. When the cut-off distance and the thin film thickness are both fixed, it is a proportional coefficient related to the space-time metric near the event horizon and the average radial effusion velocity of the radiation particles from the thin film. Finally, the radiation energy fluxes and the radiation powers of the Schwarzschild black hole and the Reissner-NordstrSm black hole are derived, separately.展开更多
文摘The corundum plates with a groove were used to freeze molten flux into solid slice to simulate the flux film formed in continuous casting mold,and thereby to study the formation mechanism of flux film with different surface roughness.The effect of some factors on the surface roughness of flux film,such as reheating rate,cooling rate,flux film thickness and crystallization ratio,was discussed.
基金Item Sponsored by National Natural Science Foundation of China(51174073)National Natural Science Foundation-National Iron and Steel Joint Research of China(U1360106)
文摘During continuous casting,properties of mold flux and mineralogical structures of flux film play important roles in controlling steel quality.The effect of soda ash on the physical properties and crystallization characteristics of mold flux was investigated using process mineralogy,including polarizing microscopy,X-ray diffraction,and electron microprobe,etc.Mold flux was mainly prepared using cement clinker and industrial mineral materials under laboratory conditions,and the mineralogical structures of the flux film were systematically identified and quantitatively analyzed.The results showed that,by increasing the soda ash content from 10mass% to 18mass%,the crystallization temperature,critical cooling rate and crystallization ratio of the flux film decreased,but the crystallization ratio still reached 75% after adding soda ash,and the mineral compositions and microstructures of the flux film changed slightly.When the soda ash content exceeded 14mass%,the critical cooling rate and the crystallization ratio decreased slightly,whereas the mineral content of the flux film changed evidently,with a large amount of cuspidine precipitation and a significant decrease in the wollastonite content until it reached zero,which resulted in deterioration of the lubrication of the flux film.
基金Project supported by the Open Fund of State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials,Lanzhou University of Technology,China
文摘The composition of the oxide film on the surface of Al-Li alloy was measured after accelerated oxidation at 500 and 540 ℃,and the reaction mechanism between CsF-AlF3 flux and the oxide film on the surface of Al-Li alloy was also discussed.The results show that the oxide film on the surface of Al-Li alloy is mostly composed of Li2CO3 and amorphous Al2O3.The brazing technology for Al-Li alloy is accomplished using the improved CsF-AlF3 flux.The improved flux CsF-AlF3 can effectively remove the oxide film by the way of reacting and/or dissolving the oxide film,of which CsF compound plays an important role in the course of removing the oxide film.The key step is the generation of HF,which induces and accelerates the reaction of removing oxide film.The generation of H2O also accelerates the reaction.
文摘The interaction of oxide film with molten flux during aluminum brazing has been studied by means of X-ray powder diffraction. The following conclusions have been deduced: The swell- ing of aluminum oxide film is caused by Li^+ inserting into the vacancies of octahedral or tetrahedral structure of 0 atom skeleton in у-Al_2O_3 . The strength of oxide film decreases as the crytallinity increases by the treating of flux containing LiF.
基金Project supported by the National Natural Science Foundation of China(Grant No.51272250)the National Basic Research Program of China(Grant No.2011CBA00105)+1 种基金the National High Technology Research and Development Program of China(Grant No.2014AA032702)the Natural Science Foundation of Beijing,China(Grant No.2152035)
文摘YBa2Cu3O7-x（YBCO） films with co-doping BaTiO3（BTO） and Y2O3 nanostructures were prepared by metal organic deposition using trifluoroacetates（TFA-MOD）. The properties of the BTO/Y2O3co-doped YBCO films with different excess yttrium have been systematically studied by x-ray diffraction（XRD）, Raman spectra, and scanning electron microscope（SEM）. The optimized content of yttrium excess in the BTO/Y2O3co-doped YBCO films is 10 mol.%, and the critical current density is as high as - 17 mA/cm^2（self-field, 65 K） by the magnetic signal. In addition, the Y2Cu2O5 was formed when the content of yttrium excess increases to 24 mol.%, which may result in the deterioration of the superconducting properties and the microstructure. The unique combination of the different types of nanostructures of BTO and Y2O3 in the doped YBCO films, compared with the pure YBCO films and BTO doped YBCO films, enhances the critical current density（JC） not only at the self-magnetic field, but also in the applied magnetic field.
基金Project supported by the Comsats Institute of Information Technology, Islamabad, Pakistan,the National Natural Science Foundation of China (Grant No 10674168)the State Key Program for Basic Research of China (Grant No 2006CB601006)
文摘A square hole array is fabricated over a micro-bridge of NbN thin film by electron beam lithography and reactive ion milling. Magneto-resistance is measured across the micro-bridge filled with a hole array near the superconducting transition temperature. It is found that magneto-resistance minima occur when the number of vortices is an integer multiple or a fractional multiple of the number of holes. The temperature and the current dependences of the matching effect are studied.
文摘In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the optimized mold flux were compared in a comprehensive way by using analytical measures, such as a slag film heat-flow simulator, a thermowire molten flux crystallization tester and an X-ray diffractometer in the laboratory. The results reveal that one of the major reasons for the cracks is the poor heat transfer ability of the original mold flux. However, the optimized mold flux with a high basicity features a high crystallizing rate,low crystallization temperature and low heat-flow density. Therefore, the optimized mold flux is more suitable for casting peritectic steel by the heavy slab continuous caster. The test results show that the slabs produced by using the optimized mold flux had no surface longitudinal crack in four test casts, while the surface longitudinal crack ratio of the slabs produced by using the original mold flux was 5%. The optimized mold flux can effectively prevent slab surface longitudinal cracks from occurring.
基金supported by the National Natural Science Foundation of China (Grant No.10773002)the Technology Planning Project of Education Bureau of Shandong Province,China (Grant No.J07WJ49)
文摘By the statistical entropy of the Dirac field of the static spherically symmetric black hole, the result is obtained that the radiation energy flux of the black hole is proportional to the quartic of the temperature of its event horizon. That is, the thermal radiation of the black hole always satisfies the generalised Stenfan-Boltzmann law. The derived generalised Stenfan-Boltzmann coefficient is no longer a constant. When the cut-off distance and the thin film thickness are both fixed, it is a proportional coefficient related to the space-time metric near the event horizon and the average radial effusion velocity of the radiation particles from the thin film. Finally, the radiation energy fluxes and the radiation powers of the Schwarzschild black hole and the Reissner-NordstrSm black hole are derived, separately.
